Wyszukiwarka
Filtry
wszystkich: 1741
wybranych: 1459
-
Katalog
Filtry wybranego katalogu
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: direct internal reforming
-
Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
-
Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems
PublikacjaA series of Cu-support systems were tested as potential candidates for DIR-SOFC (Direct Internal Reforming SOFC) catalysts towards a dry reforming of methane (DRM). The various supports (-Al2O3, CeO2, ZrO2, SrTiO3) with comparable specific surface area (SSA), and additionally -Al2O3 with SSA an order of magnitude larger than that of the other supports has been applied. The obtained Cu-support systems were characterized in terms...
-
Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublikacjaThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
-
In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublikacjaThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
-
Investigation of praseodymium and samarium co-doped ceria as an anode catalyst for DIR-SOFC fueled by biogas
PublikacjaThe Pr and Sm co-doped ceria (with up to 20 mol.% of dopants) compounds were examined as catalytic layers on the surface of SOFC anode directly fed by biogas to increase a lifetime and the efficiency of commercially available DIR-SOFC without the usage of an external reformer. The XRD, SEM and EDX methods were used to investigate the structural properties and the composition of fabricated materials. Furthermore, the electrical...
-
Novel sugar-based nickel-tungsten carbide catalysts for dry reforming of hydrocarbons
PublikacjaThe search for new materials for dry reforming of hydrocarbons with high activity, stability, and ease of synthesis is still one of the main directions of research in the field of heterogeneous catalysis. Traditional methods of carbide synthesis require the use of combustible gases of petrochemical origin. The search for new catalysts based on renewable and safe carbon sources is highly demanded. Therefore, we report WC and Ni-WC...
-
CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublikacjaSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
-
Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas
PublikacjaThe nanocrystalline compounds of Co and Cu co-doped ceria (with up to 20 mol.% of dopants) were fabricated by the reverse microemulsion synthesis method. They were deposited in a form of layers on the surface of SOFC anode in an aim to act as electrochemically active materials for biogas reforming process. Fourier Transformed Infrared Spectroscopy was used to analyze a composition of outlet gases simultaneously with the tests of...
-
Verification of punching shear outside the shear cap by the direct method
PublikacjaThe proposition of a method to verify the punching resistance for very large supports based on the EN 1992-1-1 standard is described in this paper. The present standard guidelines for the calculation of the punching resistance for large supports are also summarised. The proposed direct method is compared with other standard methods using an example taken from design practice. This method consists of a direct check of the shear...
-
A method of measuring RLC components for microcontroller systems
PublikacjaA new method of measuring RLC components for microcontroller systems dedicated to compact smart impedance sensors based on a direct sensor-microcontroller interface is presented. In the method this direct interface composed of a reference resistor connected in series with the tested sensor impedance is stimulated by a square wave generated by the microcontroller, and then its voltage response is sampled by an internal ADC of the...
-
A measurement method for lossy capacitive relative humidity sensors based on a direct sensor-to-microcontroller interface circuit
PublikacjaA new time-domain measurement method for determining the capacitance and resistance values of lossy relative humidity capacitive sensors is presented. The method is based on a direct sensor-to-microcontroller interface for microcontrollers with internal analog comparators and timers. The interface circuit consists only of four reference resistors (two reference resistors if a microcontroller includes a voltage reference source),...
-
Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublikacjaIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
-
Friction Resistances in Internal Gear Pump with Modified Sickle Made of Plastic
PublikacjaThis paper presents modifications of the sickle insert (constructional and material) made in a gear pump with internal meshing. The introduced design change consists in making an incision in the sickle insert. Due to this treatment, the races of the insert are pressed against the apex wheels of the gears. The introduced compensation causes a smaller drop in pump efficiency with increasing discharge pressure. The article describes...
-
Time-domain measurement methods for R, L and C sensors based on aversatile direct sensor-to-microcontroller interface circuit
PublikacjatIn the paper new time-domain measurement methods for determining values of resistive (R), inductive(L) and capacitive (C) sensors based on a versatile direct sensor-to-microcontroller interface for microcon-trollers with internal analog-to-digital converters (ADCs) and analog comparators (ACs) are presented.The interface circuit consists of a reference resistor Rrworking as a voltage divider, a given R, L or C sensorand a microcontroller...
-
A compact smart sensor based on a neural classifier for objects modeled by Beaunier's model
PublikacjaA new solution of a smart microcontroller sensor based on a simple direct sensor-microcontroller interface for technical objects modeled by two-terminal networks and by the Beaunier’s model of anticorrosion coating is proposed. The tested object is stimulated by a square pulse and its time voltage response is sampled four times by the internal ADC of microcontroller. A neural classifier based on measurement data classifies the...
-
Exact resultant equilibrium conditions in the non-linear theory of branching and self-intersecting shells
PublikacjaWe formulate the exact, resultant equilibrium conditions for the non-linear theory of branching and self-intersecting shells. The conditions are derived by performing direct through-the-thickness integration in the global equilibrium conditions of continuum mechanics. At each regular internal and boundary point of the base surface our exact, local equilibrium equations and dynamic boundary conditions are equivalent, as expected,...
-
A measurement method for capacitive sensors based on a versatile direct sensor-to-microcontroller interface circuit
PublikacjaIn the paper, there is presented a new time-domain measurement method for determining the capacitance values of capacitive sensors, dedicated, among others, to capacitive relative humidity sensors. The method is based on a versatile direct sensor-to-microcontroller interface for microcontrollers with internal analog comparators (ACs) and with precision voltage reference sources, e.g. digital-to-analog converters (DACs). The reference...
-
The Influence of External Load on the Performance of Microbial Fuel Cells
PublikacjaIn this work, the effect of the external load on the current and power generation, as well as on the pollutant removal by microbial fuel cells (MFCs), has been studied by step-wise modifying the external load. The load changes included a direct scan, in which the external resistance was increased from 120 Ω to 3300 Ω, and a subsequent reverse scan, in which the external resistance was decreased back to 120 Ω. The reduction in the...
-
Effect of Simultaneous Valve Closures in Hydraulic Piping Systems
PublikacjaThe paper investigates wave interference (between pressure waves) occurring in simple hydraulic systems. Water hammer was induced by simultaneous closure of three valves located at the reservoirs of a “Y” type hydraulic system. Numerical simulations were carried out with the help of the freeware computer package Allievi enabling the reader to replicate results in a direct manner. The influence of the following quantities has been...
-
Direct solid phase microextraction combined with gas chromatography – Mass spectrometry for the determination of biogenic amines in wine
PublikacjaA direct method based on immersion solid phase microextraction (DI-SPME) gas chromatography mass-spectrometry (GC-MS) was optimized and validated for the determination of 16 biogenic amines in Polish wines. In the analysis two internal standards were used: 1,7-diaminoheptane and bis-3-aminopropylamine. The method allows for simultaneous extraction and derivatization, providing a simple and fast mode of extraction and enrichment....
-
On the exact equilibrium conditions of irregular shells reinforced by beams along the junctions
PublikacjaThe exact, resultant equilibrium conditions for irregular shells reinforced by beams along the junctions are formulated. The equilibrium conditions are derived by performing direct integration of the global equilibrium conditions of continuum mechanics. New, exact resultant static continuity conditions along the singular curve modelling reinforced junction are presented. The results do not depend on shell thickness, internal through-the-thickness...
-
Rapid ion-exchange matrix removal for a decrease of detection limits in the analysis of salt-rich reservoir waters for fluorobenzoic acids by liquid chromatography coupled with tandem mass spectrometry
PublikacjaA matrix removal procedure with ion-exchange resin prior to analysis for 18 fluorinated benzoic acids (FBAs) tracers in saline (>25% salt) reservoir water was optimized. The elimination of >98% of salt and the simultaneous matrix sample cleanup allowed the direct analysis using the supernatant by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). This resulted in a gain in detection limits for most of the tracers...
-
Cuticular lipids of insects as potential biofungicides
PublikacjaThe term ''lipids'' refers to fatty acids, their derivatives and substances related with them biochemically or by the functions in the body. Lipids include compounds with different chemical structure. There are lipids with structures based on long-chain carboxylic acids and their direct derivatives, namely: fatty acids, alkanes, some alkenes, aldehydes and long chain alcohols and their derivatives (esters). The variety of lipid...
-
The role of biodegradable particulate and colloidal organic compounds in biological nutrient removal activated sludge systems
PublikacjaThe efficiency of denitrification and enhanced biological phosphorus removal in biological nutrient removal activated sludge systems is strongly dependent on the availability of appropriate carbon sources. Due to high costs of commercial compounds (such as methanol, ethanol, acetic acid, etc.) and acclimation periods (usually) required, the effective use of internal substrates is preferred. The aim of this study was to determine...
-
Fatigue and Professional Burnout in Police Officers and Firefighters
PublikacjaExcessive demands, work overload and the working time arrangements are an important cause of burnout and fatigue in employees. Specific working time arrangements are characteristic of the internal security services, such as police officers and firefighters. This applies to both the ordering of day and night shifts and the length of shifts. Depletion of personal resources is a common component for acute fatigue and burnout. However,...
-
Supervisory Control System for Adaptive Phase and Work Cycle Management of Sequencing Wastewater Treatment Plant
PublikacjaThe paper presents the design of the integrated control system applied to Sequencing Batch Reactor (SBR) in a biological Wastewater Treatment Plant (WWTP) in Swarzewo, which operates under activated sludge technology. Based on the real data records, ASM2d biological processes model and aeration system model, hierarchical control system for dissolved oxygen tracking and cycle management is designed. Internal Model Controller (IMC)...
-
Facilitating free travel in the Schengen area—A position paper by the European Association for Biometrics
PublikacjaDue to migration, terror-threats and the viral pandemic, various EU member states have re-established internal border control or even closed their borders. European Association for Biometrics (EAB), a non-profit organisation, solicited the views of its members on ways which biometric technologies and services may be used to help with re-establishing open borders within the Schengen area while at the same time mitigating any adverse...
-
Determination of chlorinated solvents in industrial water and wastewater by DAI- GC-ECD
PublikacjaA very simple and quick analytical method, basedon direct aqueous injection, for determination of halogenatedsolvents in refinery water and wastewater, is described.There is a need to determine halogenated solvents in refinerywater streams, because they may originate from severalprocesses. There is also a need to develop methods enablingVOX to be determined in samples containing oil fractions.The method described enables simultaneous...
-
Reforming the University
Publikacja -
An optimized dissolved oxygen concentration control in SBR with the use of adaptive and predictive control schemes
PublikacjaThis paper addresses the problem of optimizing control of the aeration process in a water resource recovery facility (WRRF) using sequencing batch reactor (SBR), one that affects the efficiency of wastewater treatment by stimulating metabolic reactions of microorganisms through dissolved oxygen (DO) level control, and accounts for the predominant part of operating costs. Two independent approaches to DO control algorithm design...
-
Operational Performance and Weld Bead Characteristics of Experimental Tubular-Wires for Underwater Welding
PublikacjaAiming to evaluate new formulations and their operational behavior underwater, two experimental tubular wires with different chemical compositions in their internal flux were initially manufactured, employing a pilot machine and a unique manufacturing process. Weld beads were deposited on a plate placed in a flat position inside a tank using a mechanized system and the IMC 300 welding power source. The work was done at a depth...
-
Vibrational Quenching of Optically Pumped Carbon Dimer Anions
PublikacjaCareful control of quantum states is a gateway to research in many areas of science such as quantum information, quantum-controlled chemistry, and astrophysical processes. Precise optical control of molecular ions remains a challenge due to the scarcity of suitable level schemes, and direct laser cooling has not yet been achieved for either positive or negative molecular ions. Using a cryogenic wire trap, we show how the internal...
-
Development of Gas Sensor Array for Methane Reforming Process Monitoring
PublikacjaThe article presents a new method of monitoring and assessing the course of the dry methane reforming process with the use of a gas sensor array. Nine commercially available TGS chemical gas sensors were used to construct the array (seven metal oxide sensors and two electrochemical ones). Principal Component Regression (PCR) was used as a calibration method. The developed PCR models were used to determine the quantitative parameters...
-
Mixed integer nonlinear optimization of biological processes in wastewater sequencing batch reactor
PublikacjaWastewater treatment plays a key role for humanity. The waste entering lakes, rivers, and seas deteriorates daily quality of life. Therefore, it is very important to improve the efficiency of wastewater treatment. From a control point of view, a biological wastewater treatment plant is a complex, non-linear, multidimensional, hybrid control system. The paper presents the design of the optimizing hierarchical control system applied...
-
Selective H2 production from plastic waste through pyrolysis and in-line oxidative steam reforming
PublikacjaThis study deals with the proposal of pyrolysis and in-line oxidative steam reforming (P-OSR) for plastic waste valorization and assesses the potential of this strategy for the selective production of H2. Overall, the study aims at progressing towards the fine-tuning of the pyrolysis-reforming technology by co-feeding O2. Thus, a multi-point O2 injection system has been developed to ensure a suitable O2 distribution in the reforming...
-
The effect of fishing basin construction on the behaviour of a footbrdge over the port channel
PublikacjaThe paper analyses possible causes of failure of the rotating footbridge over the Ustka port channel. In July, 2015, strange behaviour of this object was observed in the form of excessive vibrations of bridge platform suspension rods, with the accompanying acoustic effects. A preliminary geotechnical analysis has revealed that this destructive effect was caused by the nearby construction works, namely construction of a fishing...
-
Investigating the Effects of Geometrical Parameters of Re-Entrant Cells of Aluminum 7075-T651 Auxetic Structures on Fatigue Life
PublikacjaIn this study, the effects of two geometrical parameters of the re-entrant auxetic cells, namely, internal cell angle (θ) and H/L ratio in which H is the cell height, and L is the cell length, have been studied on the variations of Poisson’s ratio and fatigue life of Aluminum 7075-T6 auxetic structures. Five different values of both the H/L ratio and angle θ were selected. Numerical simulations and fatigue life predictions have...
-
Characterization of Arctic Driftwood as Naturally Modified Material. Part 1: Machinability
PublikacjaArctic driftwood has reached the coast of Iceland for centuries. This material was used by the inhabitants of the island as a building material for houses, boats, churches and pasture fences. Nowadays, the driftwood is used in the furniture industry, for the finishing of internal and external walls of buildings and also by artists. The properties of driftwood differ to that of original resource due the long-term effects of exposure...
-
Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process
PublikacjaDry reforming of methane (DRM) is an eco-friendly method of syngas production due to the utilization of two main greenhouse gases—methane and carbon dioxide. An industrial application of methane dry reforming requires the use of a catalyst with high activity, stability over a long time, and the ability to catalyze a reaction, leading to the needed a hydrogen/carbon monoxide ratio. Thus, the aim of the study was to investigate the...
-
Assessment of fitness for service of Cr-Mo steel tubes in catalytic reforming charge heaters
PublikacjaIn this paper characteristic features of metal dusting corrosion in high temperature gas mixtures of high carbon activity in catalytic reforming units, including Continuous Catalyst Regeneration (CCR) platformer are presented. Examples of 2.25Cr-1Mo and 9Cr-1Mo steel tubes at advanced stages of metal dusting process after long-term service in charge heaters are used to prove that destructive examinations are necessary to provide...
-
INTERNAL DETERMINANTS OF FIRMS’ INNOVATIVENESS
PublikacjaThis article presents an analysis of the determinants of a firm’s innovativeness deriving from its internal potential and characteristics. The analysis is based on research carried out on 1355 firms that applied for public subsidies from the Innovative Economy Operational Program in 2014. The methods applied are logit regression, comparative analysis and literature review. The analysis is structured ac- cording to Bielski’s model...
-
Reactions of solute species at an electrode modified with titanocene functionalized polypyrrole film: ferrocene and titanocene dichloride
PublikacjaPo raz pierwszy zbadano możliwość intermediacji ładunku poprzez centra tytanocenowe polimeru modyfikowanego chemicznie związanymi grupami dichloro tytanocenowymido polipirolu. Badano reakcje elektrodowe ferrocenu i dichlorotytanocenu. Wykazano aktywność elektrodową w zakresie potencjałów redoks pary Ti(IV/TiIII)w stosunku do reakcji redoks ferrocenu i reakcji dichlorotytanocenu. Wykazano, że centra TcCl2 polimeru są zadowalająco...
-
Influence of Actual Curing Conditions on Mechanical Properties of Concrete in Bridge Superstructures
PublikacjaThis article presents the research on the mechanical characteristics of concrete in the construction of three concrete bridges. A system of recording the internal temperature of concrete and automatic control of laboratory ovens was used for specimen curing. This allowed the specimens to be cured under conditions similar to those occurring in the structure. Before the construction, reference blocks were used to define similar curing...
-
Direct detection of quantum entanglement
PublikacjaBasing on positive maps separability criterion we propose the experimentally viable, direct detection of quantum entanglement. It is efficient and does not require any a priori knowledge about the state. For two qubits it provides a sharp (i.e., “if and only if”) separability test and estimation of amount of entanglement. We view this method as a new form of quantum computation, namely, as a decision problem with quantum data structure.
-
Effect of small quantities of potassium promoter and steam on the catalytic properties of nickel catalysts in dry/combined methane reforming
PublikacjaCarbon dioxide and methane are two of the principal greenhouse gases. Reduction of their content in the atmosphere is currently the subject of much worldwide research. Dry and combined reforming of methane are effective methods of CO2 and CH4 utilization and production of synthesis gas (syngas) in chemical technology. Testing of catalysts that provide the desired H2/CO ratio and long operation time is one of the critical aspects...
-
Amplification of a single-locus variable-number direct-repeats with restriction fragment length polymorphism (DR-PCR/RFLP) for genetic typing of Acinetobacter baumannii strains
PublikacjaW celu poszukiwania nowych metod typowania genetycznego szczepów Acinetobacter baumannii przydatnych w szpitalnych badaniach epidemiologicznych przeprowadzono analizę dostępnych w banku genów sekwencji szczepów referencyjnych na obecność nowych motywów repetytywnych. Do badania polimorfizmu sekwencji repetytywnych w szczepach Acinetobacter sp. wykorzystano proste powtórzenia typu "direct repeat" (DR) zlokalizowane w jednym miejscu...
-
Modeling of the internal combustion engine cooling system
PublikacjaThe article concerns computer modelling of processes in cooling systems of internal combustion engines. Modelling objectives and existing commercial programs are presented. It also describes Author’s own method of binding graphs used to describe phenomena in the cooling system of a spark ignition engine. The own model has been verified by tests on the engine dynamometer. An example of using a commercial program for experimental...
-
Mass Spectrometry-Based Direct Analytical Techniques
PublikacjaDirect analysis of samples is considered as one of the most environmentally sustainable solutions in analytical chemistry. In the ideal case, such solutions do not require sample preparation and analytes separation steps, therefore do not consumpt harmful substances (or consumpt only minimum amounts of them) and do not generate hazardous waste. Technical solutions for direct analysis also offer miniaturized and field-portable analyzers...
-
Quantum mechanical which-way experiment with an internal degree of freedom
PublikacjaFor a particle travelling through an interferometer, the trade-off between the available which-way information and the interference visibility provides a lucid manifestation of the quantum mechanical wave-particle duality. Here we analyse this relation for a particle possessing an internal degree of freedom such as spin. We quantify the trade-off with a general inequality that paints an unexpectedly intricate picture of wave-particle...
-
Pyrolysis Combined with the Dry Reforming of Waste Plastics as a Potential Method for Resource Recovery—A Review of Process Parameters and Catalysts
Publikacja: Emissions of greenhouse gases and growing amounts of waste plastic are serious environmental threats that need urgent attention. The current methods dedicated to waste plastic recycling are still insufficient and it is necessary to search for new technologies for waste plastic management. The pyrolysis-catalytic dry reforming (PCDR) of waste plastic is a promising pro-environmental way employed for the reduction of both CO2 and...