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Wyniki wyszukiwania dla: PUR-PIR foam
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Enhancement of PUR/PIR foam thermal stability after addition of Zostera marina biomass component investigated via thermal analysis and isoconversional kinetics
PublikacjaIn the present work, a thorough thermogravimetric (TG) analysis of bio-based polyurethane–polyisocyanurate (PUR–PIR) foams in both nitrogen and oxygen atmosphere is performed. A sustainable element of the foam is a biopolyol obtained via acid-catalyzed liquefaction of Zostera marina and Enteromorpha Algae biomass. Based on isoconversional analysis and apparent activation energies, several conclusions are obtained. In contradiction...
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Effect of bio-polyol molecular weight on the structure and properties of polyurethane-polyisocyanurate (PUR-PIR) foams
PublikacjaThe increasing interest in polyurethane materials has raised the question of the environmental impact of these materials. For this reason, the scientists aim to find an extremely difficult balance between new material technologies and sustainable development. This work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties...
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Effect of bio-polyol molecular weight on the structure and properties of polyurethane-polyisocyanurate (PUR-PIR) foams
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The Influence of Substitution of a Phosphorus-Containing Polyol with the Bio-polyol on the Properties of Bio-based PUR/PIR Foams
PublikacjaIn this work, effects of incorporating of a phosphorus-containing polyol into rigid polyurethane/polyisocyanurate foams’ formulations developed with use of two different bio-based polyols, derived from crude glycerol or liquefied cellulose were examined. The bio-polyol derived from crude glycerol was synthesized via two-step process from crude glycerol and castor oil, whereas the bio-polyol derived from liquefied cellulose was...
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Physico‐Mechanical Properties and Flammability of PUR/PIR Foams Containing Expandable Graphite Core‐Shell Composite Particles
PublikacjaIn this work, polyurethane/polyisocyanurate (PUR/PIR) foams were modified by two types of expandable graphite (EG) core-shell composite particles. The pulverized EG core-shell composite particles were prepared during emulsion polymerization using methyl methacrylate or glycidyl methacrylate for the synthesis of the polymeric shells (poly(methyl methacrylate) (PMMA) and poly (glycidyl methacrylate) (PGMA)), and then the obtained EG_PMMA...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
PublikacjaThe paper describes the preparation and characterization of rigid polyurethane-polyisocyanurate (PUR-PIR) foams obtained with biopolyol synthesized in the process of liquefaction of biomass from the Baltic Sea. The obtained foams differed in the content of biopolyol in polyol mixture (0–30 wt%) and the isocyanate index (IISO = 200, 250, and 300). The prepared foams were characterized in terms of processing parameters (processing...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
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Influence of bio-polyols with different molecular weight on properites of PUR-PIR foams
Dane BadawczeThis work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties of rigid polyurethane-polyisocyanurate (PUR-PIR). The influence of bio-polyols addition on foam properties was investigated by mechanical testing, Fourier transform infrared spectroscopy...
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Bio based PUR-PIR foams thermal degradation (TG) and isoconversional kinetics
Dane BadawczeIn the present work, we perform a thorough thermogravimetric (TG) analysis of the bio-based polyurethane – polyisocyanurate (PUR-PIR) foams in both nitrogen and oxygen atmosphere. A sustainable element of the foam was a biopolyol obtained via acid-catalyzed liquefaction of Zostera Marina and Enteromorpha Algae biomass. Based on isoconversional analysis...
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Synthesis and Physicochemical Characteristics of Chitosan-Based Polyurethane Flexible Foams
PublikacjaThe use of shrimp waste to obtain chitosan (Ch) is an essential issue, considering a circular economy, waste management, and its application to environmentally friendly materials. In this study, northern prawn shells were utilized to obtain Ch, which could then be used for synthesizing chitosan-based polyurethane (PUR+Ch) foams with different Ch concentration. The chemical structure, morphology, hardness, thermal properties, viscoelastic...
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Rheological properties, oxidative and thermal stability, and potential application of biopolyols prepared via two-step process from crude glycerol
PublikacjaIn this work, previously synthesized biopolyols were analyzed in terms of their rheological and thermal properties, very important from the technological point of view. For better evaluation of performed synthesis, the influence of its time and temperature on the properties of biopolyols was determined. In the end, obtained materials were used to prepare rigid polyurethane-polyisocyanurate (PUR-PIR) foams, to evaluate their potential...
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Biobased Ultralow-Density Polyurethane Foams with Enhanced Recyclability
PublikacjaPolyurethane (PUR) foams are widely used in many engineering applications, but their efficient recycling has remained a major challenge for many years. This study presents a novel strategy of incorporating hydrolyzable ester units into the PUR structure to enhance PUR foam recyclability. The present ecodesign concept of PUR materials enables fully the replacement of petrochemical polyols with biobased alternatives and production...
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Structural, thermal and physico-mechanical properties of polyurethane/brewers’ spent grain composite foams modified with ground tire rubber
PublikacjaIn this work, brewers’ spent grain (BSG) and ground tire rubber (GTR) waste fillers were applied as low-cost reinforcement phase in rigid polyurethane foam (PUR). PUR/BSG/GTR composites were prepared by a single step method, using polyglycerol as partial substitute of commercially available petrochemical polyols. Foaming parameters, chemical structure, dynamic mechanical properties, thermal stability, physico-mechanical properties...
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Preparation and characterization of rigid polyurethane-polyglycerolnanocomposite foams
PublikacjaThis work reports on the preparation of polyurethane-polyisocyanurate (PUR-PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Preparation and characterization of rigid polyurethane -polyglycerol nanocomposite foams
PublikacjaThis work reports on the preparation of polyurethane–polyisocyanurate (PUR–PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Performance properties of rigid polyurethane-polyisocyanurate/brewers’ spent grain foamed composites as function of isocyanate index
PublikacjaIn the presented work, rigid polyurethane-polyisocyanurate (PUR-PIR) foams filled with brewers’ spent grain (BSG) were prepared. The influence of the isocyanate index (II) on its performance was investigated. Foams obtained with higher isocyanate index required a higher amount of hydrofluorocarbon physical blowing agent to provide the same apparent density of material. An increase of isocyanate index resulted in a slight decrease...
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Michał Strankowski dr hab. inż.
OsobyJest zatrudniony w Katedrze Technologii Polimerów na Wydziale Chemicznym od 2006 roku. W tym samym roku uzyskał stopień doktora nauk technicznych w zakresie technologii chemicznej. Stopień doktora habilitowanego w dziedzinie nauk ścisłych i przyrodniczych uzyskał w 2019 roku. W okresie 2013-2015 pełnił funkcję kierownika projektu „PUR-GRAF” pt. „Nanokompozyty poliuretanowe zawierające zredukowany tlenek grafenu”. Za opracowane...
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Ultradźwiękowy moduł antymaskingu dla czujek ruchu PIR
PublikacjaPrzedstawiono podstawowe założenia, jakie powinien spełniać moduł funkcji antymaskingu, stosowany wraz z czujnikami ruchu opartymi o technologię PIR, umożliwiający spełnienie podstawowych wymagań zawartych w normach serii EN50131. W oparciu o wymagania, stworzono układ spełniający wszystkie wymagania zawarte w normach i dostosowano go do zainstalowania w istniejących obudowach czujek. W pracy przybliżone zostaną podstawy teoretyczne...
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Application of foam made of post-consumer pet materials for the construction of footbridges
PublikacjaThe article presents the possibility of application in civil engineering of highly ecological PET foam, manufactured from 100% recycled plastic packaging. It may find uses in construction of numerous engineering structures, such as pedestrian and cycle footbridges. Properly processed waste from post-consumer PET packaging may constitute a quality structural core for use in multilayered composite materials, commonly referred to...
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Increasing the Seismic Resistance of Wood-frame Buildings by Applying PU Foam as Thermal Insulation
PublikacjaWood-frame buildings are very common in regions that are exposed to earthquakes. Most of residential buildings are constructed using this technology; therefore, the seismic resistance of them is really essential in order to prevent human losses and structural damage. The aim of the present article is to show the results of the detailed numerical FEM analysis focused on the seismic behaviour of the wood-frame house with different...
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Microstructure, mechanical properties, and flame retardancy of nanoclay-incorporated polyurethane flexible foam composites
PublikacjaThe present work seeks to investigate microstructure, mechanical properties, and flame retardancy of polyurethane/nanoclay flexible foam composites. In this regard, we prepared various nanocomposites with and without nanoclay and observed the resulting morphologies to correlate them with the other corresponding characteristics. The results provided support for the fact that tensile strength and compression set will increase with...
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Timber-frame house resistant to dynamic loads - analysis of wall panel filled with polyurethane foam
PublikacjaThe present study shows the experimentally and numerically determined response of a single timber-frame house wall panel filled with polyurethane (PU) foam under dynamic loads. The harmonic tests were conducted for the following frequencies: 0.5 Hz, 1.0 Hz, 2.0 Hz and 5.0 Hz for various values of the specified displacement. Based on the results of the comparison between the experimental tests and the numerical analyses, the numerical...
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XRD-Ni foam as received and oxidised at 500_C
Dane BadawczeThese data contain XRD patterns of porous nickel foam commercial and oxidised in air at 500 C degrees for 8 hours.
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Ground Tire Rubber Filled Flexible Polyurethane Foam—Effect of Waste Rubber Treatment on Composite Performance
PublikacjaThe application range of flexible polyurethane (PU) foams is comprehensive because of their versatility and flexibility in adjusting structure and performance. In addition to the investigations associated with further broadening of their potential properties, researchers are looking for new raw materials, beneficially originated from renewable resources or recycling. A great example of such a material is ground tire rubber (GTR)—the...
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Local and global response of sandwich beams made of GFRP facings and PET foam core in three point bending test
PublikacjaIn the paper behaviour of laminated sandwich beams (FRP face sheet – PET foam core – FRP face sheet) subjected to three point bending is studied. The paper aim is to find practical descriptions enabling effective and accurate estimation of the elastic response, damage and failure of the beams, basing on experiments and static calculations. Therefore a number of tests are described, that were done on laminated coupons and foam specimens...
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Analysis of Validation and Simplification of Timber-Frame Structure Design Stage with PU-Foam Insulation
PublikacjaThe transition from experimental studies to the realm of numerical simulations is often necessary for further studies, but very difficult at the same time. This is especially the case for extended seismic analysis and earthquake-resistant design. This paper describes an approach to moving from the experimental testing of an elementary part of a wood-frame building structure to a numerical model, with the use of a commercial engineering...
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Współczynnik przewodzenia ciepła λ izolacji PIR w świetle polityki zgodności
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Hierarchical MnO2 nanoflowers blooming on 3D nickel foam: A novel micro-macro catalyst for peroxymonosulfate activation
PublikacjaIn this work, birnessite-type δ-MnO2 nanoflowers were uniformly deposited on 3D nickel foam (NF) by one-step hydrothermal route for high-efficient activation of peroxymonosulfate (PMS) towards degradation of acid orange 7 (AO7). High specific surface area, large pore volume and 3D hierarchical structure promotes the mass and electron transfer for great catalytic activity. Low reaction energy barrier (Ea=27.5 kJ/mol) and outstanding...
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XPS-Ni foam as received, after photocatalysis and after oxidation at 500_C.
Dane BadawczeThis dataset contains XPS spectra recorded for nickel foam as received from supplier, after photocatalytic process and after oxidation at 500C. Each set contains: survery spectrum, O1, C1s, Ni2p. The detailed equipment and measurement data was described in "readme XPS.txt" file
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Application of Peracetic Acid for Biological Foam Elimination in the SBR Bioreactor
PublikacjaPrzedstawiono wyniki wstępnych badań nad zastosowaniem kwasu nadoctowego (PAA) do likwidacji piany biologicznej, spowodowanej przez bakterię nitkowatą Microthrix parvicella. Wykazano, że okresowe zraszanie powierzchni piany małymi dawkami kwasu nadoctowego (rzędu kilkudziesięciu ml 1% roztworu PAA/na 1 m2 piany o grubości 1 cm) powoduje niemal natychmiastwy zanik piany, wytworzonej na powierzchni osadu czynnego w bioreaktorze...
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Prediction of the fatigue lifetime of PUR structural elements using a combined experimental-numerical approach
PublikacjaThis paper presents a method for estimating the fatigue life of polyurethane elastomeric components. A rubber replacement - polyurethane of hardness 80ShA commonly used in vibration damping systems, for example, in motor vehicle suspensions, was used for the study. A metal-rubber bushing component was selected for analysis, and numerical analysis was carried out along with a fatigue model proposal based on a modification of the...
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One More Step Towards a Circular Economy for Thermal Insulation Materials—Development of Composites Highly Filled with Waste Polyurethane (PU) Foam for Potential Use in the Building Industry
PublikacjaThe rapid development of the building sector has created increased demand for novel materials and technologies, while on the other hand resulting in the generation of a severe amount of waste materials. Among these are polyurethane (PU) foams, which are commonly applied as thermal insulation materials. Their management is a serious industrial problem, due to, for example, their complex chemical composition. Although some chemical...
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Photocatalytic decomposition of acetaldehyde over TiO2 (titanium dioxide) supported on nickel foam and Ni-doped (nickel-doped) TiO2
Dane BadawczeThis dataset contains chromatograms recorded during the decomposition of acetaldehyde in a high-temperature reaction chamber under UV irradiation using as photocatalytic systems TiO2 (titanium dioxide) supported on nickel foam, TiO2 supported on oxidized nickel foam and TiO2 doped by metallic nickel (Ni) powder. The detailed equipment and measurement...
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Lightweight Cement Mortars with Granulated Foam Glass and Waste Perlite Addition
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Thermal properties of polyurethanes synthesized using waste polyurethane foam glycolysates
PublikacjaW pracy przedstawiono wyniki analizy termicznej (DMTA i TG-FTIR) glikolizatów i otrzymanych z nich poliuretanów. Glikolizaty uzyskiwano w reakcji odpadowej pianki poliuretanowej z 1,6 heksametylenodiolem (HDO) przy różnym stosunku masowym pianki do HDO (1:1 - 10:1). Poliuretany syntezowano metodą dwuetapową z prepolimeru (diizocyjanian MDI + glikolizat), który przedłużano handlowym małocząsteczkowym glikolem.
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Al(III) and Cu(II) simultaneous foam separation: Physicochemical problems
PublikacjaSimultaneous removal of Al(III) and Cu(II) from dilute aqueous solutions by ion and precipitate flotation methods is investigated. Influence of the pH of the initial solution, the surface active collector concentration and the gas flow rate on the final removal ratio and the course of ion and precipitate flotations is presented. Results show that simultaneous flotations of Al(OH)3 and Cu(OH)2 insoluble species occur allowing to...
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Morphological and electrochemical characterization of ceramic carbon foam electrodes water treatment applications
Dane BadawczeThis dataset contains morphological and electrochemical characterization of ceramic carbon foam employed as an electrode (CFFE) for the oxidation of a target pollutant. The dataset includes:
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Enhanced Degradation of Ethylene in Thermo-Photocatalytic Process Using TiO2/Nickel Foam
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Operational Properties Investigation of The Flat-Plate Solar Collector with Poliuretane Foam Insulation
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Static and dynamic properties of light PU foam for building the shallow river barges
PublikacjaPrzedstawiono wyniki badań wytrzymałości statycznej na rozciąganie, ściskanie i ścinanie oraz zmęczeniowej przy obciążeniach ściskających jednostronnie tętniących pian poliuretanowych o gęstości 53 i 62 kg/m3, mierzonych w kierunku podłużnym i prostopadłym do kierunku wzrostu piany w procesie jej otrzymywania. Stwierdzono wyraźną anizotropię własności mechanicznych piany. Obserwowano znacznie silniejsze zniszczenie zmęczeniowe...
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Effect of the absence of clear contractual conditions for the pur-chase of combined heat and power systems through public tenders
PublikacjaW artykule przedstawiono dyskusję konsekwencji stosowania różnych podejść do obliczeń kontraktowych parametrów technicznych zespołów kogeneracyjnych. Obliczenia te wykonywane są na potrzeby oferty przygotowywanej w związku z ogłoszeniem przetargu publicznego na zakup siłowni kogeneracyjnej. Brak precyzyjnych zasad określających warunk, i jakie należy przyjąć do wyznaczania parametrów kontraktowych zespołów kogeneracyjnych umożliwia...
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Enhanced Degradation of Ethylene in ThermoPhotocatalytic Process Using TiO2/Nickel Foam: Reaction Mechanism
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Application of TiO2 Supported on Nickel Foam for Limitation of NOx in the Air via Photocatalytic Processes
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Synthesis and characterization of novel aliphatic polyurethanes for tissue engineering applications
PublikacjaSummarizing, in this thesis was described the synthesis of novel PUR system, which was obtained by using aliphatic diisocyanate (HDI), amorphous macrodiol (PEBA) and chain extender (BDO). This PUR system was established as suitable for TE purpose and successfully modified with AA, which as expected improved its biocompatibility. According to this, AA-modified HDI-based PURs is the PUR system ready for further studies including...
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublikacjaA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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3D mesoporous α-Co(OH)2 nanosheets electrodeposited on nickel foam: A new generation of macroscopic cobalt-based hybrid for peroxymonosulfate activation
PublikacjaCobalt-based catalysts with high stability and facile recovery for heterogeneous peroxymonosulfate (PMS) activation are still rather sparse and therefore highly desirable. Herein, 3D mesoporous α-Co(OH)2 nanosheets was created on robust nickel foam (NF) via facile electrodeposition approach at 6 mA/cm2 for only 400 s. Almost complete removal of phenol can be achieved within 7 min with a degradation rate of 0.39 min−1, 2 times higher...
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The Superiority of TiO2 Supported on Nickel Foam over Ni-Doped TiO2 in the Photothermal Decomposition of Acetaldehyde
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Nowe konstrukcje przekładkowe metal-pianka poliuretanowa = New sandwich plate systems metal - PU foam
PublikacjaWyznaczono statyczne własności mechaniczne przy ściskaniu, rozciąganiu oraz ścinaniu w óżnych kierunkach względem wzrostu piany oraz przy cyklicznych naprężeniach ściskających i ścinających. Stwierdzono różnice własności mechanicznych w zależności od kierunku i formy naprężeń.
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Composite Polyurethane-Polylactide (PUR/PLA) Flexible Filaments for 3D Fused Filament Fabrication (FFF) of Antibacterial Wound Dressings for Skin Regeneration
Publikacjahis paper addresses the potential application of flexible thermoplastic polyurethane (TPU) and poly(lactic acid) (PLA) compositions as a material for the production of antibacterial wound dressings using the Fused Filament Fabrication (FFF) 3D printing method. On the market, there are medical-grade polyurethane filaments available, but few of them have properties required for the fabrication of wound dressings, such as flexibility...
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Effects of manufacturing and face /core bonding on impact damage in glass/polyester - PVC foam core sandwich panels
PublikacjaZbadano podatność na inicjację uszkodzeń pod wpływem spadającego obciążenia w konstrukcjach przekładkowych poliestrowo szklanych z rdzeniem z pianki PVC przy dwóch sposobach łączenia okładek z rdzeniem: przy pomocy 2 klejów proponowanych do tego celu przez ich producentów oraz czystej żywicy. Zastosowano oprzyrządowany młot spadowy , określając rozmiar zniszczeń na powierzchni próbki metodą wizualna i ultradźwiękową. Inicjacja...