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Wyniki wyszukiwania dla: Proton transfer mechanisams
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Directed percolation effects emerging from superadditivity of quantum networks
PublikacjaEntanglement-induced nonadditivity of classical communication capacity in networks consisting of quantum channels is considered. Communication lattices consisting of butterfly-type entanglement-breaking channels augmented, with some probability, by identity channels are analyzed. The capacity superadditivity in the network is manifested in directed correlated bond percolation which we consider in two flavors: simply directed and...
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Selectivity of lithium electrodes: correlation with ion-ionophore complexstability constants and with interfacial exchange current densities
PublikacjaMembranowe elektrody selektywne na jony litu oparte na dwóch różnych dicyk-lohesyloamidowych jonoforach poddane zostały systematycznym badaniom. Potencjometrycznie wyznaczono wartości współczynników selektywności. Wartości stałych trwałości kompleksów z jonami litu, sodu i potasu wyznaczono metodą membran "sandwichowych". Transfer ładunków przez membranę oraz przez granicę faz membrana/roztwór badano metodą spektroskopii impedancyjnej....
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On the differential effect of temperature on the Nusselt-Rayleigh relationship in free convection
PublikacjaThe aim of and inspiration behind this paper was to explain the reasons, also observed by other researchers, of the discrepancy in the results of experimental free convection, which for small Rayleigh and Nusselt numbers in the initial phase of research can sometimes reach several hundred percent. These discrepancies decrease with increasing heating power and plate surface temperature, in proportion to the increase in Ra and Nu,...
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Experimental Investigations on the Influence of Coil Arrangement on Melting/Solidification Processes
PublikacjaThe latent heat thermal energy storage units are very popular because of their high energy density and almost close to constant temperature during the charging/discharging. In the present study has been proposed new shell-and-coil geometry with a shifted coil position to enhance the performance of phase change thermal magazine. The experimental investigations have been performed both for the melting and solidification process of...
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Spin-Resolved Band Structure of Hoffman Clathrate [Fe(pz)2Pt(CN)4] as an Essential Tool to Predict Optical Spectra of Metal–Organic Frameworks
PublikacjaParamount spin-crossover properties of the 3D-Hoffman metalorganic framework (MOF) [Fe(pz)2Pt(CN)4] are generally described on the basis of the ligand field theory, which provides adequate insight into theoretical and simulation analysis of spintronic complexes. However, the ligand field approximation does not take into account the 3D periodicity of the actual complex lattice and surface effects and therefore cannot predict a full-scale...
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A Parallel Corpus-Based Approach to the Crime Event Extraction for Low-Resource Languages
PublikacjaThese days, a lot of crime-related events take place all over the world. Most of them are reported in news portals and social media. Crime-related event extraction from the published texts can allow monitoring, analysis, and comparison of police or criminal activities in different countries or regions. Existing approaches to event extraction mainly suggest processing texts in English, French, Chinese, and some other resource-rich...
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Photophysics and Halide Quenching of Soret-excited ZnTPPS4- in Aqueous Media
PublikacjaSteady state S2-S0 and S1-S0 absorption and emission spectra and picosecond S2 decay and S1 fluorescence rise times have been measured for the model porphyrin ZnTPPS4− in water and in aqueous iodide solutions of constant ionic strength. The dynamics of S1 quenching by iodide are well-modeled by a Stern-Volmer mechanism yielding kQ = 1.75 × 109 M−1 s−1. The S2 state is quenched on a ps time scale by a static electron-transfer mechanism...
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Elastic electron scattering and vibrational excitation of isoxazole molecules in the energy range from 2 to 20 eV
PublikacjaDifferential cross sections for elastic electron scattering and the excitation of the C-H vibrational modes of isoxazole molecules were measured in the energy range from 2 to 20 eV and over the scattering angle range from 10◦ to 180◦. The cross sections at the scattering angles of and above 90◦ were accessible with the use of a magnetic angle changer. The differential cross sections were integrated to yield integral and momentum...
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Te use of acoustic emission for assessment of the oil lubricity in a four-ball tester
Publikacjain view of the increased dynamic and temperature load in the compression-ignition engine tribological systems, particular attention is drawn to the problem of such lubrication of the friction nodes that after breaking the boundary layer it could be restored without any wear occurring. therefore, an idea has been devised of introducing to friction nodes, with the lubrication oils, of new substances (operational preparations) modifying...
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Remote command and control capabilities for data acquisition systems provided by delay-tolerant network mechanisms
PublikacjaThe paper presents an assessment of a remote device reconfiguration service employing a Delay Tolerant Network (DTN) mechanisms. This service has been implemented as a part of a communication appliance dedicated to marine data transfer in off-shore and open sea areas. The service has been successfully deployed and validation test have been completed. The practical use-case has been defined as remote access to the equipment operating...
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Production of singlet oxygen atoms by photodissociation of oxywater
PublikacjaQuantum chemical calculations are reported for the energies of the few lowest electronic singlet states of oxywater along dissociation of the oxygen-oxygen bond into water and singlet oxygen using multistate multireference second-order Møller–Plesset perturbation theory. We compute an energy of 21 kcal/mol to remove one oxygen atom in the lowest singlet state. The two lowest excited singlet states have vertical excitation energies...
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Cold Cracking Of Underwater Wet Welded S355G10+N High Strength Steel
PublikacjaWater as the welding environment determines some essential problems influencing steel weldability. Underwater welding of high strength steel joints causes increase susceptibility to cold cracking, which is an effect of much faster heat transfer from the weld area and presence of diffusible hydrogen causing increased metal fragility. The paper evaluates the susceptibility to cold cracking of the high strength S355G10+N steel used,...
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Music Genre Recognition in the Rough Set-Based Environment
PublikacjaThe aim of this paper is to investigate music genre recognition in the rough set-based environment. Experiments involve a parameterized music data-base containing 1100 music excerpts. The database is divided into 11 classes cor-responding to music genres. Tests are conducted using the Rough Set Exploration System (RSES), a toolset for analyzing data with the use of methods based on the rough set theory. Classification effectiveness...
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Oddziaływanie portali intranetowych na zarządzanie wiedzą w nowoczesnych organizacjach
PublikacjaArtykuł przedstawia wyniki badania przeprowadzonego wśród ekspertów ds. komunikacji wewnętrznej i intranetu na temat postrzeganego w ich praktyce oddziaływania portali intranetowych na zarządzanie wiedzą w organizacjach. Zdaniem ekspertów-respondentów portale intranetowe najsilniej oddziaływają na transfer wiedzy i wykorzystywanie wiedzy, a w mniejszym, ale zauważalnym stopniu na ewaluację i rozwój wiedzy, innowacyjność w organizacji...
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Education at the Faculty of Mechanical Engineering of the Gdańsk University of Technology
PublikacjaFaculty of Mechanical Engineering is one of the largest departments of the Gdańsk University of Technology (GUT), currently educating about 3 000 student. Lectures are conducted in five Chairs, which include 18 Divisions. In 2000 GUT introduced the European Credit Transfer and Accumulation System (ECTS). Each student should get during one academic year 60 ECTS points. Obtaining a diploma of BEng requires the acquisition of no less...
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Education at the Faculty of Mechanical Engineering of the Gdańsk University of Technology
PublikacjaFaculty of Mechanical Engineering is one of the largest departments of the Gdańsk University of Technology (GUT), currently educating about 3 000 student. Lectures are conducted in five Chairs, which include 18 Divisions. In 2000 GUT introduced the European Credit Transfer and Accumulation System (ECTS). Each student should get during one academic year 60 ECTS points. Obtaining a diploma of BEng requires the acquisition of no less...
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New trends in development of micro heat exchangers for ORC's
PublikacjaIn the paper, new trends in development of micro heat exchangers for CHP are presented. Main attention is concentrated on the question, how channels size and thermal development lenght affect the heat transfer. New types of micro heat exchangers developed at the Institute of Fluid-Flow Machinery PAS and the methoda of their design are presented. The new experimental testing methods of the micro-channel heat exchangers, new algorithms...
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Knowledge-Based Management as the Key Success Factor for Research and Development Organizations
PublikacjaA key to achieving success in project organizations lies in exemplary management of processes within those organizations, while the ongoing projects are mainly characterized by their uniqueness. The situation is no different in commercial research and development organizations (R&D) where accuracy and repeatability of elementary processes guarantees efficient and productive realization of all enterprises. R&D organizations are...
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The Influence of Titania Electrode Modification with Lanthanide Ions Containing Thin Layer on the Performance of Dye-Sensitized Solar Cells
PublikacjaThe lanthanide and scandium groups ions (except Pm and Ac) have been used as dopants of TiO2 film in dye-sensitized solar cells. The X-ray diffraction spectra show that the modification has no influence on the structure of the electrode; however, the diffuse reflectance UV-Vis measurements exhibit significant changes in the electronic properties of modified electrodes. The appearance of energy barrier preventing photoexcited electron...
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Impact of thermal loading into the structural performance of ships: A review
PublikacjaThe presented study reviews the recent advances done regarding the impact of thermal loading on the structural performance of ships. Firstly, the studies related to the mechanical and thermal properties of typical materials used in shipbuilding are outlined. Secondly, a brief introduction to the heat transfer analysis, Finite Element modelling and thermal stresses is provided. Finally, the review of papers dealing with the structural...
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Characterization of Bioactivity of Selective Molecules in Fruit Wines by FTIR and NMR Spectroscopies, Fluorescence and Docking Calculations
PublikacjaFourier transform infrared (FTIR) and proton nuclear magnetic resonance (1H NMR) spectroscopies were applied to characterize and compare the chemical shifts in the polyphenols’ regions of some fruit wines. The obtained results showed that FTIR spectra (1800–900 cm−1) and 1H NMR (δ 6.5–9.3 ppm) of different fruit wines can be used as main indices of the year of vintage and quality of fruit wines. In addition to the classical determination...
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Influence of iron content on water uptake and charge transport in BaCe0.6Zr0.2Y0.2−xFexO3−δ triple-conducting oxides
PublikacjaIn this work, we studied the BaCe0.6Zr0.2Y0.2−xFexO3−δ system which belongs to the triple-conducting oxides (TCOs) group. The electrochemical properties of BaCe0.6Zr0.2Y0.2−xFexO3−δ were investigated using electrochemical impedance spectroscopy (EIS) and the water uptake was analyzed using thermogravimetry (TG). All investigated materials exhibited water uptake, with proton concentration increasing with decreasing iron content....
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[soft skills] Commercialization of scientific outcomes
Kursy Online{mlang pl} Dyscyplina: wszystkie dyscypliny Zajęcia obowiązkowe dla doktorantów II roku Prowadzący: Damian Kuźniewski, Agnieszka Krawczyk-Kłos, Centrum Transferu Wiedzy i Technologii na PG Liczba godzin: 5 Forma zajęć: wykład {mlang} {mlang en} Discipline: all disciplinesObligatory course for the 2nd-year PhD students Academic teacher: Damian Kuźniewski, Agnieszka Krawczyk-Kłos, Centre for Knowledge and Technology Transfer...
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Efficiency of acoustic heating in the Maxwell fluid
PublikacjaThe nonlinear effects of sound in a fluid describing by the Maxwell model of the viscous stress tensor is the subject of investigation. Among other, viscoelastic biological media belong to this non-newtonian type of fluids. Generation of heating of the medium caused by nonlinear transfer of acoustic energy, is discussed in details. The governing equation of acoustic heating is derived by means of the special linear combination...
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Modelling and analysis of beam/bar structure by application of bond graphs
PublikacjaThe paper presents an uniform, port-based approach to modelling of beam/bar systems (trusses). Port-based model of such distributed parameter system has been defined by application of the bond graph methodology and the distributed transfer function method (DTFM). The proposed method of modelling enables to formulate input data for computer analysis by application of the DTFM. The constructed computational package enables the frequency...
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Efficiency of acoustic heating in the Maxwell fluid
PublikacjaThe nonlinear effects of sound in a fluid describing by the Maxwell model of the viscous stress tensor is the subject of investigation. Among other, viscoelastic biological media belong to this non-newtonian type of fluids. Generation of heating of the medium caused by nonlinear transfer of acoustic energy, is discussed in details. The governing equation of acoustic heating is derived by means of the special linear combination...
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Nonlinear Influence of Sound on the Vibrational Energy of Molecules in a Relaxing Gas
PublikacjaDynamics of a weakly nonlinear and weakly dispersive flow of a gas where molecular vibrational relaxation takes place is studied. Variations in the vibrational energy in the field of intense sound is considered. These variations are caused by a nonlinear transfer of the acoustic energy into energy of vibrational degrees of freedom in a relaxing gas. The final dynamic equation which describes this is instantaneous, it includes a...
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Modelling of Mechatronic Systems with Distributed Parameter Components
PublikacjaThe paper presents an uniform, port-based approach to modelling of both lumped and distributed parameter systems. Port-based model of distributed system has been defined by application of the bond graph methodology and the distributed transfer function method (DTFM). The proposed method of modelling enables to formulate input data for computer analysis by application of the DTFM. The computational package for the analysis of complex...
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Calculation method for flow boiling and flow condensation of R134a and R1234yf in conventional and small diameter channels
PublikacjaThe paper presents the results of calculations performed using the authors’ model to predict the heat transfer coefficient during flow boiling for two refrigerants R134a and R1234yf. The experimental data from various past studies have been collected and the calculations have been conducted for the full range of quality variation and a wide range of mass velocity. The aim of the study was to test the sensitivity of the in-house...
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The modelling method of discrete-continuous systems
PublikacjaThe paper introduces a method of discrete-continuous systems modelling. In the proposed method a three-dimensional system is divided into finite elements in only two directions, with the third direction remaining continuous. The thus obtained discrete-continuous model is described by a set of partial differential equations. General difference equations of discrete system are obtained using the rigid finite element method. The limit...
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Experimental study of the multi-disc negative brake for a hydraulic motor
PublikacjaThis paper describes the methodology for experimental testing of a multi-disc brake. The construction of this brake was also present. The brake is dedicated to hydraulic motors with a small working volume. Experimental tests were carried out on a brake with plates immersed in oil and, for comparison, tests were carried out on a dry brake. As a result of the tests, the permissible torque (load) that is able to transfer the brake...
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Dyskretno-ciągła metoda modelowania układów dynamicznych
PublikacjaW artykule przedstawiono oryginalną metodę modelowania układów dyskretno-ciągłych. Metoda polega na dyskretyzowaniu układu trójwymiarowego jedynie w dwóch wybranych kierunkach. W trzecim z kierunków układ pozostaje ciągły. Otrzymany w ten sposób model jest modelem dyskretno-ciągłym. Opisany jest za pomocą równań różniczkowych cząstkowych. Ogólne równania różnicowe układu dyskretnego otrzymano, wykorzystując metodę sztywnych elementów...
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Pompownie dużej mocy z falownikiem wędrującym średniego napięcia
PublikacjaArtykuł zawiera rys rozwoju napędów przekształtnikowych w stacjach pomp, w szczególności regulacji wydatku kilku pomp, po kolei, przez jeden przemiennik częstotliwości. Omówiono podstawy teoretyczne zjawiska pola niestłumionego i napięcia resztkowego silników, które utrudniają szybkie przełączania silnika pompy pomiędzy zasilaniem regulowanym przez falownik a zasilaniem z sieci. Przedstawiono zasady transferu (przełączania) synchronicznego...
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Preliminary results from HEDGEHOG REXUS Project - sounding rocket experiment on accelerations, vibrations and heat flow
PublikacjaAs access to space conditions becomes more available, both technically and economically, scientists' interest in launching finer and more sophisticated experiments grows. This applies now more than ever to fragile by nature biological and chemical experiments. To be qualified for launch, such experiments need to be carefully tested prior to the event. The tests should represent actual launch conditions as closely and in as detailed...
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Design and material selection for a patient transport device in field hospitals
PublikacjaACKGROUND: A major cause of patient and hospital worker injuries occurs transferring patients between two planes. The main aim of this paper was to propose a design of patient’s lift and transfer apparatus for use in field hospitals. The assumption was to design lightweight, durable and ergonomic device using innovative material. The authors concentrated on partial elimination of manual lifting in order to device could work both...
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Exploring the cocrystallization potential of urea and benzamide
PublikacjaThe cocrystallization landscape of benzamide and urea interacting with aliphatic and aromatic carboxylic acids was studied both experimentally and theoretically. Ten new cocrystals of benzamide were synthesized using an oriented samples approach via a fast dropped evaporation technique. Information about types of known bi-component cocrystals augmented with knowledge of simple binary eutectic mixtures was used for the analysis...
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The Ellenbogen's “Matter as Software” Concept for Quantum Computer Implementation. C60 and X@C60 Molecules as Available Molecular Building Blocks (MBBs) for Tip-Based Nanofabrication (TBN) of Quantum Computing Devices
PublikacjaThe TBN bottom-up strategy of building quantum devices from C60 and X@C60 MBBs is proposed as an extension of the Ellenbogen's “Matter as Software” idea to quantum information processing. The capped SW or DW CNT STM tip is considered as device for manipulating C60 and X@C60 molecules. In this article, the possibility of using easily available on the market C60 Fullerene and endohedral X@C60 molecules together with commercial CNT...
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Data augmentation for improving deep learning in image classification problem
PublikacjaThese days deep learning is the fastest-growing field in the field of Machine Learning (ML) and Deep Neural Networks (DNN). Among many of DNN structures, the Convolutional Neural Networks (CNN) are currently the main tool used for the image analysis and classification purposes. Although great achievements and perspectives, deep neural networks and accompanying learning algorithms have some relevant challenges to tackle. In this...
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Forced vibrations in a dynamic system that is damped by a mechanism that trans-pass through its singular position
PublikacjaIn the paper, vibrations of a hybrid multibody-continuous system are investigated. For all the mechanical devices, effective damping methods are crucial in the design process. To obtain it, installation of viscous dampers or elasto-viscous elements is dominant. In the paper, an alternative method is investigated. It is based on modal disparity. To describe the method briefly, when structural damping is present in continuous systems,...
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Numerical analysis of high temperature minichannels heat exchanger performance
PublikacjaNowadays, the most difficult technological challenge in energy sector is connected with the gas micro-CHP units, dedicated to the distributed power generation. They are expected to be of high efficiency and at the same time of compact in size. Regarding the first reason, significant increase in microturbine efficiency can only be achieved by increase in the engine operating temperature. Therefore, one of the critical elements in...
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Deep learning for ultra-fast and high precision screening of energy materials
PublikacjaSemiconductor materials for energy storage are the core and foundation of modern information society and play important roles in photovoltaic system, integrated circuit, spacecraft technology, lighting applications, and other fields. Unfortunately, due to the long experiment period and high calculation cost, the high-precision band gap (the basic characteristic parameter) of semiconductor is difficult to obtain, which hinders the...
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Beyond Antioxidant Activity: Redox Properties of Catechins May Affect Changes in the DNA Methylation Profile—The Example of SRXN1 Gene
PublikacjaThe role of catechins in the epigenetic regulation of gene expression has been widely studied; however, if and how this phenomenon relates to the redox properties of these polyphenols remains unknown. Our earlier study demonstrated that exposure of the human colon adenocarcinoma HT29 cell line to these antioxidants affects the expression of redox-related genes. In particular, treatment with (−)-epigallocatechin (EGC) downregulated...
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Cavitation-based technologies for pretreatment and processing of food wastes: Major applications and mechanisms – A review
PublikacjaConversion of food wastes to valuable products is an important topic for sustainable development. Feedstock hydrolysis is a stage strongly affecting the anaerobic digestion process, and resistance of food waste towards hydrolysis causes a decrease in product yield. Such as biomethane, biohydrogen, biohythane, VFAs, and lactic acids. Moreover, mass transfer is a serious limitation of transesterification for the production of biodiesel....
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Evaluating the impact of ZnO doping on electrical and thermal properties of calcium-aluminosilicate oxynitride glass-ceramics
PublikacjaThis study aimed to investigate the impact of ZnO content on the structure, thermal, and electrical properties of oxynitride glass-ceramic(s) within the Ca–Al–Si–O–N (CASON) system. The base glass had the composition of Ca7Al14Si17O52N7, with ZnO additions ranging from 3 to 15 % by weight. A pristine Ca7Al14Si17O52N7 glass was successfully prepared by melt-quenching technique followed by converted into glass-ceramic by incorporating various...
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Benchmarking overlapping communication and computations with multiple streams for modern GPUs
PublikacjaThe paper presents benchmarking a multi-stream application processing a set of input data arrays. Tests have been performed and execution times measured for various numbers of streams and various compute intensities measured as the ratio of kernel compute time and data transfer time. As such, the application and benchmarking is representative of frequently used operations such as vector weighted sum, matrix multiplication etc....
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Tests of bond between concrete and steel bars – literature background and program of own research
PublikacjaThis article deals with the issue of the bond between concrete and reinforcement. The bond is crucial for reinforced concrete elements because it is possible to transfer forces (stresses) from concrete to the reinforcement. Basic information related to the cooperation of concrete and rebars was recalled in the article. Selected issues concerning theoretical and numerical analysis as well as experiments of the bond phenomenon were...
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New Method of Non-Linear Electrochemical Impedance Spectroscopy with an Amplitude-Modulated Perturbation Signal
PublikacjaThe paper presents a new method of non-linear electrochemical impedance spectroscopy (NLEIS), which allows fast and nondestructive evaluation of the corrosion rate and determination of the Tafel coefficients values for a corrosion system under investigation. This method employs amplitude modulation of the ac perturbation signal. The study demonstrated that it was possible to obtain impedance characteristic as a function of the...
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Analiza i ocena smarności olejów w ujęciu energetycznym i działania układu tribologicznego = Analysis and evaluation of oil lubricity from the viewpoint of energy apects and of the tribological system action
PublikacjaBased on measurement results, an interpretation is presented of the tribological system boundary layer action in the form of a four-ball tester friction node. The evaluation was performed of the boundary layer action understood as transfer of energy Ep resulting from loading the tribological system in a determined time t with work Lp, which may lead to breaking the boundary layer. That energy and time are the values unequivocally...
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Monitoring system of the road embankment
PublikacjaThe paper presents the monitoring system of the embankment supported on concrete columns and overlaid by a load transfer platform (LTP) with the embedded steel grid. This field investigation was to study the complex inter-action between the columns, the LTP layer, and steel reinforcement via full-scale in situ measurements during erection of the embankment. The study was focused on the behaviour of steel reinforcement and the behaviour...
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Experimental study of pressure rise at the evaporator of capillary pumped loop with acetone and water as working fluids
PublikacjaIn this work studied is the possibility of fluid pumping using capillary forces in the capillary pumped loop. Experimental and theoretical studies have been performed to understand the phenomena associated with heat transfer in porous structure of the evaporator. The capillary effect was studied during operation of two different capillary porous structures with two different working fluids, namely water and acetone. The results...