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wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: DISSOLVED ORGANIC NITROGEN
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Synthetic strategies in construction of organic macromolecular carrier–drug conjugates
PublikacjaMany metabolic inhibitors, considered potential antimicrobial or anticancer drug candidates, exhibit verylimited ability to cross the biological membranes of target cells. The restricted cellular penetration ofthose molecules is often due to their highhydrophilicity. One of the possible solutions to this problem is aconjugation of an inhibitor with a molecular organic nanocarrier. The conjugate thus formed should beable to penetrate...
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Dissolved oxygen control for activated sludge processes
PublikacjaRegulatory do nadążania za trajektorią referencyjną stężenia tlenu w komorze reaktora biologicznego są proponowane i badane. W artykule badany jest nieliniowy regulator predykcyjny oraz regulator adaptacyjny z modelem referencyjnym. Uwzględniono zarówno usuwanie ze ścieków pożywki oraz fosforu za pomocą technologii osadu czynnego. Podejście do projektowania regulatora wykorzystuje strukturę dynamiki rozpuszczonego tlenu i jej dwie...
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Coupling transformation of carbon, nitrogen and sulfur in a long-term operated full-scale constructed wetland
PublikacjaThe coupling transformation of carbon, nitrogen and sulfur compounds has been studied in lab-scale and pilot-scale constructed wetlands (CWs), but few studies investigated full-scale CW. In this study, we used batch experiments to investigate the potentials of carbon, nitrogen and sulfur transformation in a long-term operated, full-scale horizontal subsurface flow wetland. The sediments collected from the HSFW were incubated for...
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An optimized dissolved oxygen concentration control in SBR with the use of adaptive and predictive control schemes
PublikacjaThis paper addresses the problem of optimizing control of the aeration process in a water resource recovery facility (WRRF) using sequencing batch reactor (SBR), one that affects the efficiency of wastewater treatment by stimulating metabolic reactions of microorganisms through dissolved oxygen (DO) level control, and accounts for the predominant part of operating costs. Two independent approaches to DO control algorithm design...
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Investigation of sensing mechanism of Nasicon electrocatalytic sensors in nitrogen dioxide and ammonia
PublikacjaIn this paper a sensing mechanism of Nasicon electrocatalytic sensor in nitrogen dioxide and ammonia is investigated. Both gases are environmentally hazardous and contain nitrogen atom in the molecule. However, it seems that their sensing mechanism in electrocatalytic sensor could be totally different. Namely, the maximum sensitivity for each gas was obtained at different temperatures. Also, different auxiliary layers are formed...
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Organic photovoltaics - chosen aspects
PublikacjaThere are many types of organic and organic/inorganic (hybrid) photovoltaic devices that possess many beneficial properties over inorganic solar cells. That makes the former suitable for a broad range of applications and hence so much attention is paid to their development. In spite of intensive research carried on this field of science and technology there are still many crucial problems that need to be solved. Extensive knowledge...
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Stochastic optimisation algorithm for optimisation of controller parameters for control of dissolved oxygen in wastewater treatment plant
PublikacjaWastewater treatment plants (WWTPs) are very important facilities for mankind. They enable the removal and neutralisation of man-made pollutants. Therefore, it is important for wastewater treatment plants to operate as efficiently as possible so that the level of pollutants in the treated wastewater meets specific requirements. This paper concerns the design of a hierarchical nonlinear adaptive control system for dissolved oxygen...
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Nitrogen mass balance and mathematical model of a Structured- Bed Reactor (SBRRIA)
PublikacjaAn up-flow structured-bed reactor subjected to recirculation and intermittent aeration (SBRRIA) was operated under varying influent conditions. The influent COD/N ratio was adjusted by maintaining a stable organic loading rate (average of 1.07 kgCOD m-3 d-1) and changing the nitrogen loading rate from 0.1 to 0.4 kg N m-3. Therefore, three different COD/N ratios were tested: 9.7±1 (Scenario 1); 7.6±1 (Scenario 2) and 2.9±1 (Scenario...
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Development of models for nitrogen-removal processes in subsurface flow constructed wetlands
PublikacjaThis paper summarizes recent progress in modelling approach of subsurface flow constructed wetlands (SSF CWs), focusing on nitrogen removal processes.
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Photo-oxidation of dissolved cyanide using TiO2 catalyst
PublikacjaZbadano utlenianie katalityczne jonów cyjankowych w układzie UV/TiO2. Szybkość utleniania zbadano dla różnego stężenia początkowego CN-, wartość pH, formy katalizatora, temperatury oraz wprowadzanej formy gazowej. Stwierdzono że szybkość degradacji cyjanków w układzie UV/TiO2/O2 wzrasta dwukrotnie, jakkolwiek jest niezależna od ciśnienia cząstkowego tlenu (0,2-1,0 atm.). Wzrost temperatury środowiska reakcji w zakresie od 20 do...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublikacjaMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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Organic Communications
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ORGANIC SYNTHESES
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Organic Farming
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ORGANIC LETTERS
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ORGANIC GEOCHEMISTRY
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Two-Step Model Based Adaptive Controller for Dissolved Oxygen Control in Sequencing Wastewater Batch Reactor
PublikacjaDissolved Oxygen (DO) concentration is a crucial parameter for efficient operation of biological processes taking place in the activated sludge Wastewater Treatment Plant (WWTP). High-quality DO control is difficult to achieve because of complex nonlinear behavior of the plant and substantial influent disturbances. A method to improve the Direct Model Reference Adaptive Control (DMRAC) technology in application to DO tracking for...
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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
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The results of the nitrogen adsorption/desorption measurements of CPMD and CPMH
Dane BadawczeThe results of the nitrogen adsorption/desorption measurements of CPMD and CPMH. The adsorption/desorption isothermswere carried out at 77 K using a Quantachrome Autosorb-1C-MS instrument. Sample abbreviations (CPMD, CPMH) are in agreement with the markings used in the linked publication.
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Fluctuation of nitrogen fraction during wastewater treatment in a multistage treatment wetland
PublikacjaFactors influencing COD and removal and transformation of N fractions have been investigatedin the conditions of horizontal (SSHF) and vertical (SSVF) flow reed beds. Multistage treatment wetlandin Wiklino ensured a stable and very effective removal of all the analysed pollutants. Based onthe resultsof investigation, it could be assumed that the working conditions of SSHF beds play an importantrole in the transformation of particulate...
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Electrochemical data for carbonized metal-organic framworks with cobalt
Dane BadawczeThe data includes the Metal-Organic Frameworks (MOF) measurements, where cobalt was added. The research focuses on the impact of aluminium on Oxygen Evolution Reaction (OER). The measurements were conducted on [EC Lab]. The techniques included are Linear Sweep Voltammetry (LSV), Tafel slope, Chronopotentiometry (CP) and Electrochemical Impedance Spectroscopy...
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Improving SBR Performance Alongside with Cost Reduction through Optimizing Biological Processes and Dissolved Oxygen Concentration Trajectory
PublikacjaAuthors of this paper take under investigation the optimization of biological processes during the wastewater treatment in sequencing batch reactor (SBR) plant. A designed optimizing supervisory controller generates the dissolved oxygen (DO) trajectory for the lower level parts of the hierarchical control system. Proper adjustment of this element has an essential impact on the efficiency of the wastewater treatment process as well...
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Incorporation of nitrogen in diamond films – A new way of tuning parameters for optical passive elements
PublikacjaThis paper investigates the impact of nitrogen incorporation in diamond films for the construction of an interferometric sensor to measure displacement. Diamond films with different nitrogen levels (0–5%) were deposited on silicon substrates by microwave plasma enhanced chemical vapor deposition. The structural characteristics of these samples are characterized using scanning electron microscopy (SEM), atomic force microscopy (AFM), confocal...
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NEW ORGANIC MATERIALS FOR PHOTOVOLTAICS
PublikacjaThis report presents the results of investigations carried out for polymer- and low-weightmolecular materials prepared in the form of thin films by various methods, namely the thermalvacuum evaporation and chemical vapour deposition. The influence of the technologicalconditions on the structure, surface morphology, and electronic properties of selected organic thinfilms, including polyazomethines, phthalocyanines, and perylene...
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Novel nitrogen precursors for electrochemically driven doping of titania nanotubes exhibiting enhanced photoactivity
PublikacjaNitrogen doped titania nanotubes were successfully sensitized by electrochemical method, i.e. as-anodized titania was immersed in different amine (diethyleneamine-DETA, triethyleneamine-TEA, ethylenediamine-EDA) and urea (U) solution and a constant potential was applied. The highly ordered morphology of fabricated N-TiO2 was investigated by using scanning electron microscopy. Spectroscopic techniques, i.e. UV-Vis spectroscopy,...
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Greener organic solvents in analytical chemistry
PublikacjaThe paper presents the most recent advances in analytical applications of greener organic solvents. Substitution of problematic solvents with more benign organic ones is much easier than shifting to technique applying alternative solvents, such as ionic liquids or supercritical fluids. In the area of liquid chromatography greener mobile phases, much attention is given to application ethanol or acetone instead of acetonitrile. Solvent-based...
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Incorporation of nitrogen in diamond films - A new way of tuning parameters for optical passive elements
PublikacjaThis paper investigates the impact of nitrogen incorporation in diamond films for the construction of an interferometric sensor to measure displacement. Diamond films with different nitrogen levels (0–5%) were deposited on silicon substrates by microwave plasma enhanced chemical vapor deposition. The structural characteristics of these samples are characterized using scanning electron microscopy (SEM), atomic force microscopy...
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Nitrogen-doped diamond thin films: potential application in Fabry-Pérot interferometer
PublikacjaIn this paper we present results of preliminary research of using nitrogen-doped diamond (NDD) films as reflective layer in Fabry-Pérot interferometer. NDD films were deposited on Si substrates by Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) with the use of CH4, H2 and N2 gas mixtures. During deposition process methane flow rate varied while nitrogen flow was constant. We performed series of measurements which showed...
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Optical Magnetometry Based on Nanodiamonds with Nitrogen-Vacancy Color Centers
PublikacjaNitrogen-vacancy color centers in diamond are a very promising medium for many sensing applications such as magnetometry and thermometry. In this work, we study nanodiamonds deposited from a suspension onto glass substrates. Fluorescence and optically detected magnetic resonance spectra recorded with the dried-out nanodiamond ensembles are presented and a suitable scheme for tracking the magnetic-field value using a continuous...
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Nitrogen pathways in the environment.
PublikacjaPraca stanowi wprowadzenie do zbioru artykułów poświęconych wielorakim aspektom badań nad ścieżkami przenoszenia związków azotu, zagrożeniami z tego wynikającymi oraz metodami przeciwdziałania tym zagrożeniom. Przedstawiono w niej bardzo problematykę obiegu kołowego azotu w przyrodzie, zwracając szczególną uwagę na zakłócenia w tym obiegu, będące rezultatem różnorodnej działalności człowieka. Na tle aktualnego stanu wiedzy, krótko...
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Sławomir Makowiec dr hab.
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Influence of the boron doping level on the electrochemical oxidation of raw landfill leachates: advanced pre-treatment prior to the biological nitrogen removal
PublikacjaThe electrochemical oxidative treatment of landfill leachates (LLs) containing high amounts of ammonia nitrogen and organic matter was used as a promising method, prior to biological processes, to achieve the final effluent quality that would be acceptable by current regulations. The deposited boron-doped diamond electrodes (BDDs) with different boron doping concentrations (10000, 5000 and 500 ppm of B) were applied as anodes....
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Electrooxidation of dissolved dsDNA backed by in situ UV-Vis spectroscopy
PublikacjaPrzeprowadzono badania elektrochemicznego utleniania dsDNA stosując metody cyklowoltametryczne na elektrodzie weglowej, platynowej, platynowej w formie siatki oraz z siatki platynowej osadzonej na węglu. Otrzymane wyniki analizy spektroelektrochemicznej wykazały, że wraz ze wzrostem potencjału i piku prądowego absorpcja roztworu dsDNA wzrasta w sposób zależny od typu elektrody. Jednak położenie maksimum absorpcji nie zmieniało...
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Dissolved oxygen tracking and control of blowers at fast time scale.
PublikacjaNapowietrzanie jest bardzo ważnym i drogim procesem w oczyszczalni ścieków. Tlen jest podstawowym składnikiem dla procesów biologicznych. System napowietrzania jest skomplikowanym, hybrydowym, nieliniowym, dynamicznym systemem z dynamiką szybszą w porównaniu z wewnętrzną dynamiką tlenu rozpuszczonego w reaktorze biologicznym. Obecnie stosowane systemy sterowania są dalekie od zadowalających. Koszt pompowania powietrza do reaktora...
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Hydrogen production from ethanol In nitrogen microwave plasma At atmospheric pressure
PublikacjaHydrogen seems to be one of the most promising alternative energy sources. It is a renewable fuel as it could be produced from e.g. waste or bio-ethanol. Furthermore hydrogen is compatible with fuel cells and is environmentally clean. In contrast to conventional methods of hydrogen production such as water electrolysis or coal gasification we propose a method based on atmospheric pressure microwave plasma. In this paper we present...
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CURRENT ORGANIC CHEMISTRY
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LETTERS IN ORGANIC CHEMISTRY
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Optical photoluminescent, and electroluminescent properties of organic solids
PublikacjaThis chapter discusses optical, photoluminescence and electroluminescence properties of organic materials. First, the spectral features of individual molecules and molecular solid states are analysed. Next, the excitonic processes in organic materials are discussed. The chapter reviews experimental methods leading to the determination of basic excitonic parameters. Finally, the electroluminescence phenomena in organic materials...
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A new approach to designing control of dissolved oxygen and aeration system in sequencing batch reactor by applied backstepping control algorithm
PublikacjaThe Wastewater Treatment Plant (WWTP) is a very complex system, due to its nonlinearity, time-variance, and multiple time scales in its dynamics among others. The most important control parameter in a WWTP is the Dissolved Oxygen (DO) concentration. The tracking problem of the DO concentration is one of the most fundamental issues in biological wastewater treatment. Proper DO concentration control is necessary to achieve adequate...
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Nitrogen pathways during sewage treatment in constructed wetlands in temporary climate
PublikacjaThe objectives of this paper is to estimate the role and quantity of the unit process responsible for removal or/and retention of nitrogen in different types of constructed wetlands in vegetation season and outside vegetation season. To estimate the role of the plant two objects inhabited one with willow and the other with reed were selected to assessment. Among anthers it was indicated that the concentrations of contamination...
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List of initial and final geometries of hybrid organic-inborganic perovskites
Dane BadawczeList of initial and optimized geometries of hybrid organic-inorganic perovskites. Calculations were performed on DFT level of theory. Those results were reported in the Influence of Orientational Disorder on the Optical Absorption Properties of the Hybrid Metal‐Halide Perovskite CH3NH3PbI3 publication. Geometries, HOMO, LUMO, Band gap energies are concatenated...
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Nitrogen-Doped Diamond Film for Optical Investigation of Hemoglobin Concentration
PublikacjaIn this work we present the fabrication and characterization of a diamond film which can be utilized in the construction of optical sensors for the investigation of biological samples. We produced a nitrogen-doped diamond (NDD) film using a microwave plasma enhanced chemical vapor deposition (MWPECVD) system. The NDD film was investigated with the use of scanning electron microscopy (SEM), atomic force microscopy (AFM) and Raman...
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Role of nitrogen in optical and electrical band gaps of hydrogenated/hydrogen free carbon nitride film
PublikacjaWe report the optical and electrical band gap energy of amorphous hydrogenated carbon nitride (a-HCNx) and carbon nitride (a-CNx) as a function of nitrogen concentration (N/C). The optical band gap of a-HCNx and a-CNx films has been determined by means of Ellipsometry and UV-VIS. Both optical and electrical band gaps increase with elevated nitrogen concentration. Experimentally obtained electrical band gap is compared with the...
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PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
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Biomass-Derived Nitrogen Functionalized Carbon Nanodots and Their Anti-Biofouling Properties
PublikacjaThe prevalence of the antibiotic resistant bacteria remains a global issue. Cheap, sustainable and multifunctional antibacterial membranes are at the forefront of filtrating materials capable of treating multiple flow streams, such as water cleansing treatments. Carbon nanomaterials are particularly interesting objects shown to enhance antibacterial properties of composite materials. In this article, amino-functionalized, photoluminescent...
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Application of mechanistic and data-driven models for nitrogen removal in wastewater treatment systems
PublikacjaIn this dissertation, the application of mechanistic and data-driven models in nitrogen removal systems including nitrification and deammonification processes was evaluated. In particular, the influential parameters on the activity of the Nitrospira activity were assessed using response surface methodology (RSM). Various long-term biomass washout experiments were operated in two parallel sequencing batch reactor (SBR) with a different...
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Influence of dipoles on the recombination in organic photovoltaic devices
PublikacjaAlthough organic compounds are promising materials to use them in photovoltaic devices, the efficiencies of organic solar cells are still lower in comparison to inorganic photocells. The recombination of charge carriers leads to the loss of photocurrent, therefore a detailed theoretical description of this process is required. In the present work, an influence of interface dipoles on the recombination process is discussed. We show...
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Effect of Functionalization of Reduced Graphene Oxide Coatings with Nitrogen and Sulfur Groups on Their Anti-Corrosion Properties
PublikacjaElectrophoretic production of anticorrosion carbonaceous coatings on copper could be successfully performed by anodic oxidation of negatively charged graphene platelets suspended in an aqueous solution. The various platelets were synthesized by Hummer’s method followed by a hydrothermal reduction in the presence of NH4SCN which was expected to substitute some parts of graphene structure with nitrogen and sulfur groups. X-ray photoelectron...
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Modeling the pH effects on nitrogen removal in the anammox-enriched granular sludge
PublikacjaThe aim of the study was to determine the pH effects on nitrogen removal in the anammox-enriched granular sludge. The experimental data were extracted from a 4L completely-mixed batch reactor with the granular sludge at different initial pH values (6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5) and constant temperature T=30℃. Simulations were run in GPS-X 6.4 using a comprehensive mechanistic model Mantis2. Two kinetic parameters, including...
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MODELING THE pH EFFECTS ON NITROGEN REMOVAL IN THE ANAMMOX-ENRICHED GRANULAR SLUDGE
PublikacjaThe aim of the study was to determine the pH effects on nitrogen removal in the anammox-enriched 10 granular sludge. The experimental data were extracted from a 4L completely-mixed batch reactor with the 11 granular sludge at different initial pH values (6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5) and constant temperature 12 T=30℃. Simulations were run in GPS-X 6.4 using a comprehensive mechanistic model Mantis2. Two 13 kinetic parameters,...