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Wyniki wyszukiwania dla: activation process
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Flow cytometry analysis of caspase 3/7 activation in A549, H460 and U2OS cells after exposure to TXT2 and TXT4
Dane BadawczeThe data contains flow cytometry analysis of caspase 3/7 activation in A549, H460 and U2OS cells after exposure to equitoxic concentrations of TXT2 and TXT4. DMSO and MTX were used as positive and negative controls, respectively. Caspase 3/7 activity was detected using CellEvent™ Caspase-3/7 Green Flow Cytometry Assay Kit (#C10427, Thermo Fisher Scientific)....
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Electrical and noise responses of carbon nanotube networks enhanced by UV light for nitrogen dioxide sensing
Dane BadawczeNetworks consisting of randomly oriented carbon nanotubes (CNN) were investigated toward nitrogen dioxide detection by means of electrical and low-frequency noise measurements. UV-activation of CNN layers improved gas sensitivity and reduced the limit of detection, especially by employing 275 nm-LED. This data set includes DC resistance measurements...
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The Efficacious Benefit of 25-Hydroxy Vitamin D to Prevent COVID-19: An In-Silico Study Targeting SARS-CoV-2 Spike Protein
PublikacjaThe environment has rapidly looked at proven specialist task forces in the aftermath of the COVID-19 pandemic to build public health policies and measures to mitigate the effects of emerging coronaviruses. According to the researchers, taking 10 μg of 25-hydroxy vitamin D daily is recommended to keep us safe. There have been several studies recently indicating that there is a reduced risk of contracting Coronavirus by 25-hydroxy...
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The effect of boron concentration on the electrical, morphological and optical properties of boron-doped nanocrystalline diamond sheets: Tuning the diamond-on-graphene vertical junction
PublikacjaIn this paper, the effect of boron doping on the electrical, morphological and structural properties of free-standing nanocrystalline diamond sheets (thickness ~ 1 μm) was investigated. For this purpose, we used diamond films delaminated from a mirror-polished tantalum substrate following a microwave plasma-assisted chemical vapor deposition process, each grown with a different [B]/[C] ratio (up to 20,000 ppm) in the gas phase....
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Microwave-Induced Processing of Free-Standing 3D Printouts: An Effortless Route to High-Redox Kinetics in Electroanalysis
Publikacja3D-printable composites have become an attractive option used for the design and manufacture of electrochemical sensors. However, to ensure proper charge-transfer kinetics at the electrode/electrolyte interface, activation is often required, with this step consisting of polymer removal to reveal the conductive nanofiller. In this work, we present a novel effective method for the activation of composites consisting of poly(lactic...
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Reactivation of seizure‐related changes to interictal spike shape and synchrony during postseizure sleep in patients
PublikacjaOBJECTIVE: Local field potentials (LFPs) arise from synchronous activation of millions of neurons, producing seemingly consistent waveform shapes and relative synchrony across electrodes. Interictal spikes (IISs) are LFPs associated with epilepsy that are commonly used to guide surgical resection. Recently, changes in neuronal firing patterns observed in the minutes preceding seizure onset were found to be reactivated during postseizure...
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Immittance Studies of Bi6Fe2Ti3O18 Ceramics
PublikacjaResults of studies focusing on the electric behavior of Bi6Fe2Ti3O18 (BFTO) ceramics are reported. BFTO ceramics were fabricated by solid state reaction methods. The simple oxides Bi2O3, TiO2, and Fe2O3 were used as starting materials. Immittance spectroscopy was chosen as a method to characterize electric and dielectric properties of polycrystalline ceramics. The experimental data were measured in the frequency range D = (101–107)...
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Electrical conductivity relaxation measurements - water uptake of BaCe0.6Zr0.2Y0.1Tb0.1O3-δ
Dane BadawczeFor Electrical Conductivity Relaxation (ECR) measurements, platinum reversible electrodes were applied in a four-probe arrangement and the BaCe0.6Zr0.2Y0.1Tb0.1O3-δ sample was measured in the ProboStat™ measurement system. The ECR measurements were performed in air in the temperature range of 450-800 ℃ after switching water partial pressure between...
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Activation of the operational ecohydrodynamic model (3D CEMBS) – the ecosystem module**The study was supported by the Polish State Committee of Scientific Research (grants: N N305 111636, N N306 353239). Partial support was also provided by the Satellite Monitoring of the Baltic Sea Environment – the SatBałtyk project funded by the European Union through the European Regional Development Fund contract No. POIG 01.01.02-22-011/09.
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Elderly persons professional activity - substantive issues and methodological challenges
PublikacjaPopulation ageing in Europe and mass withdrawal from professional activity leads to a number of adverse phenomena, such as increased public spending, reduced consumer demand and the growing problem of social exclusion. The study focuses on the problems of population ageing in Europe as well as on the feasible steps that may be taken with a view to professional activation of the elderly. The first part is concerned with the trends...
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Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics
PublikacjaIn the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18 (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz – 10MHz) within the temperature range ΔT=-100°C – 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found...
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Could thermal imaging supplement surface electromyography measurements for skeletal muscles?
PublikacjaAbstract—(1) Background: The aim of this study is to present the results of experiments in which surface electromyography (sEMG) and thermal imaging were used to assess muscle activation during gait and to verify the hypothesis that there is a relationship in the case of low fatigue level between sEMG measured muscle activation, assessed in the frequency domain, and thermal factors calculated as minimum, maximum, kurtosis, mean,...
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How do institutions from Pomerania Province support professional activity of people aged 50 and over?
PublikacjaThe article presents the solutions that were implemented in last years in the pomorskie province with regard to the economic activation of individuals aged 50+. The author presents the priorities in this area included in regional policy and specific initiatives of different types of institutions operating in the region.
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Electrochemical impedance spectroscopy measurements - conductivity vs. temperature and conductivity vs. oxygen partial pressure - BaCe0.6Zr0.2Y0.1Tb0.1O3-δ
Dane BadawczeThe dataset consists of two main catalogs consisting of measurement data: of the electrical conductivity of the BaCe0.6Zr0.2Y0.1Tb0.1O3-δ (BCZYTb) sample as a function of temperature and of the electrical conductivity as a function of oxygen partial pressure (pO2). Measurements as a function of temperature were carried out in dry and wet air (pH2O ~...
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Bio based PUR-PIR foams thermal degradation (TG) and isoconversional kinetics
Dane BadawczeIn the present work, we perform a thorough thermogravimetric (TG) analysis of the bio-based polyurethane – polyisocyanurate (PUR-PIR) foams in both nitrogen and oxygen atmosphere. A sustainable element of the foam was a biopolyol obtained via acid-catalyzed liquefaction of Zostera Marina and Enteromorpha Algae biomass. Based on isoconversional analysis...
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The role of electrolysis and enzymatic hydrolysis treatment in the enhancement of the electrochemical properties of 3D-printed carbon black/poly(lactic acid) structures
PublikacjaAdditive manufacturing, also known as 3D printing, is beginning to play an unprecedented role in developing many applications for industrial or personalized products. The conductive composite structures require additional treatment to achieve an electroactive surface useful for electrochemical devices. In this paper, the surfaces of carbon black/poly(lactic acid) CB-PLA printouts were activated by electrolysis or enzymatic digestion...
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Electrochemical impedance spectroscopy measurements - conductivity vs. temperature and conductivity vs. oxygen partial pressure for BaCe0.6Zr0.2Y0.2-xFexO3-δ (x = 0.02, 0.05, 0.1)
Dane BadawczeThe dataset consists of two main catalogs consisting of measurement data: of the electrical conductivity of the BaCe0.6Zr0.2Y0.18Fe0.02O3-δ (BCZYFe2), BaCe0.6Zr0.2Y0.15Fe0.05O3-δ (BCZYFe5), and BaCe0.6Zr0.2Y0.1Fe0.1O3-δ (BCZYFe10) samples as a function of temperature and of the electrical conductivity as a function of oxygen partial pressure (pO2)....
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The Ellenbogen’s “Matter as Software” Concept for Quantum Computer Implementation: IV. The X@C60 Molecular Building Blocks (MBBs) and Computing System Lifetime Estimation
PublikacjaThe problem of approximate lifetimes of individual X@C60 MBBs and tip-based nanofabricated quantum computing device systems is discussed under the conservative assumption of single-point failure. A single chemical transformation of the C60 cage into high-energy opened o-C60 isomer which forms the communication canal for the low energy transfer of an X atom from X@C60 MBB to the outside environment was studied. According to the...
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Thermal decomposition kinetics of dynamically vulcanized polyamide 6-acrylonitrile butadiene rubber-halloysite nanotube nanocomposites
PublikacjaThermally stable thermoplastic elastomer nanocomposites based on polyamide 6 (PA6), acrylonitrile butadiene rubber (NBR), and halloysite nanotubes (HNTs) were dynamically vulcanized, and their nonisothermal decomposition kinetics were examined. The Friedman, Kissinger–Akahira–Sunose (KAS), Ozawa–Wall–Flynn (FWO), and modified Coats–Redfern (m‐CR) isoconversional models were used to obtain information about the kinetics of the thermal...
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Genetic Determinants and Biofilm Properties Useful in Estimation of UTI Pathogenicity of the Escherichia coli Strains Isolated from Free-Living Birds
PublikacjaBackground/Objectives: According to the One Health concept, wild birds can be indicators of ecosystem pollution and disease incidence. Escherichia coli strains are widespread worldwide, but there are still few reports on the association of human infections with a potential reservoir of highly pathogenic human strains in wild birds. Fecal E. coli with uropathogenic potential (UPEC) can be transmitted between birds and humans and...
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Development of a Peptide Derived from Platelet-Derived Growth Factor (PDGF-BB) into a Potential Drug Candidate for the Treatment of Wounds
PublikacjaObjective: This study evaluated the use of novel peptides derived from platelet-derived growth factor (PDGF-BB) as potential wound healing stimulants. One of the compounds (named PDGF2) was subjected for further research after cytotoxicity and proliferation assays on human skin cells. Further investigation included evaluation of: migration and chemotaxis of skin cells, immunological and allergic safety, the transcriptional analyses...
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Phosphanylphosphaalkenes as precursors for metallaphosphaalkene complexes
PublikacjaWe synthesized phosphanylphosphaalkenes (biph)2C=P-P(tBu)2 (2), Ph2CvP-P(NEt2)2 (3), and (biph)2CvP-P(NEt2)2 (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions.
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Social activities in The Vistula Marshlands
PublikacjaSocial activities in The Vistula Marshlands favouring development in this part of the Pomeranian Voivodeship and preserving its specific character have recently been a domain of Local Activity Groups, clubs and societies, as well as cultural centres and local schools. The activation of local environment is supported by the possibility of gaining EU grants, particularly 4 LEADER Axis from the Rural Development Programme for years...
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Phosphinoborinium cation: a synthon for cationic B-P bond systems
PublikacjaHerein, we report access to phosphinoborinium cations via heterolytic cleavage of the boron-bromide bond in bromophosphinoborane. The product of the reaction was isolated as a dimeric dication possessing a planar P2B2 core. Activation of C-H and C-P bonds in the dication led to formation of the borinium-phosphaborene adduct. Reactivity studies revealed that title cation exhibits ambiphilic properties and intramolecular frustrated...
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Catalytic impact of alloyed Al on the corrosion behavior of Co50Ni23Ga26Al1.0 magnetic shape memory alloy and catalysis applications for efficient electrochemical H2 generation
PublikacjaThe electrochemical and corrosion behaviour of Co50Ni23Ga27-xAlx (x = 0 and 1.0 wt%) magnetic shape memory alloys (MSMAs) was studied in 0.5 M NaCl solutions using various electrochemical techniques. Results showed remarkable activation of the tested MSMA toward pitting corrosion upon alloying it with Al. XPS examination confirmed the activation influence of alloyed Al. It proved that the presence of Al in the alloy's matrix weakens...
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H2AX phosphorylation, its role in DNA damage response and cancer therapy
PublikacjaDouble-strand breaks (DSBs) are the most deleterious DNA lesions, which, if left unrepaired, may have severe consequences for cell survival, as they lead to chromosome aberrations, genomic instability, or cell death. Various physical, chemical, and biological factors are involved in DSB induction. Cells respond to DNA damage by activating the so-called DNA damage response (DDR), a complex molecular mechanism developed to detect...
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Spin-glass behavior in a binary Pr 3 Ir intermetallic compound
PublikacjaPolycrystalline Pr3Ir was synthesized by arc melting. Its cementite-type crystal structure (Pnma) was confirmed by powder X-ray diffraction and estimated lattice parameters are in agreement with literature. Physical properties were measured by means of the ac and dc magnetic susceptibility, electrical resistivity and heat capacity. Our results indicate spin-glass behavior in Pr3Ir with a freezing temperature Tf = 6.58 K and activation...
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Wczesny Mickiewicz jako zapowiadający się historiozof
PublikacjaThe paper shows young Mickiewicz’s family and historical experiences. It discussesthe knightly premises for his historiosophy and explains its radicalism and structureon the grounds of the knightly tradition. The study reveals the pre-Slavic deposits ofspiritual archeology in the Romantic poet. It proves that the activation of these depositsshaped Mickiewicz’s view on the collision between Poland and...
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A cryptic ribosome binding site, false signals in reporter systems and avoidance of protein translation chaos
PublikacjaThe expression of reporter gene may be induced by activation of cryptic signalling sequences, as we found while constructing the mutS-lacZ fusion gene. We cloned the Escherichia coli lacZ gene encoding beta-galactosidase into a plasmid vector carrying the Thermus thermophilus mutS gene. The clones expected to produce beta-galactosidase as the C-terminal fusion were selected for the complementation of beta-galactosidase activity...
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Self-Organising map neural network in the analysis of electromyography data of muscles acting at temporomandibular joint.
PublikacjaThe temporomandibular joint (TMJ) is the joint that via muscle action and jaw motion allows for necessary physiological performances such as mastication. Whereas mandible translates and rotates [1]. Estimation of activity of muscles acting at the TMJ provides a knowledge of activation pattern solely of a specific patient that an electromyography (EMG) examination was carried out [2]. In this work, a Self-Organising Maps (SOMs)...
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Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels
PublikacjaBiowaste chicken eggshell (ES) powder was applied as a potential cure modifier in epoxy/anhydride systems. Cure behaviour and kinetics of composites filled with very low content (0.1 wt% based on epoxy resin) of ES, calcium carbonate (CaCO3), and terpolymer-modified fillers, mES and mCaCO3, were discussed comparatively. Surface analysis was performed by X-ray photoelectron spectroscopy. Cure kinetics was investigated by differential...
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Electrical conductivity and relaxation processes in V2O5 nanorods prepared by sol–gel method
PublikacjaProperties of high purity V2O5 nanorods prepared by a sol – gel method are presented. The studied materials were characterized by: X-ray diffractometry (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The electrical impedance was measured as a function of temperature and frequency. The obtained results show that the electrical conductivity increases with increasing temperature. The d.c. conductivity...
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Electrical properties of A-site Ca-doped LaNb1-xAsxO4-δ ceramics
PublikacjaThe electrical properties of A-site Ca-doped LaNbO4 with the addition of As in the B-site, have been investigated. Total, grain- and specific grain boundary electric conductivities in different oxygen partial pressure, and water vapour partial pressure were determined. Additional conductivity measurements were performed in nitrogen, to suppress the possible p-type conductivity, focusing on protonic conductivity. The maximum measured...
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Kinetics study of the fully bio-based poly(propylene succinate) synthesis. Functional group approach
PublikacjaCurrently, the increasing importance of the bio-based chemical compounds development is visible in the polymer chemistry, chemical engineering and materials science. It is well-known that the various purity level and different contaminants characterize petrochemical-based compounds compared to their biobased counterparts. Therefore, it is necessary to find out the contaminants impact on the bio-based monomers synthesis. One of...
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Surface diffusion and cluster formation of gold on the silicon (111)
PublikacjaPurpose: Investigation of the gold atoms behaviour on the surface of silicon by molecular dynamics simulation method. The studies were performed for the case of one, two and four atoms, as well as incomplete and complete filling of gold atoms on the silicon surface. Design/methodology/approach: Investigations were performed by the method of molecular dynamics simulation using the Large-scale Atomic/Molecular Massively Parallel...
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Enhanced electrochemical activity of boron-doped nanocarbon functionalized reticulated vitreous carbon structures for water treatment applications
PublikacjaAn extraordinary charge transfer kinetics and chemical stability make a boron-doped diamond (BDD) a prom- ising material for electrochemical applications including wastewater treatment. Yet, with flat geometrical sur- faces its scaling options are limited. In this study, the reticulated Vitreous Carbon (RVC) served as a substrate for boron-doped diamondized nanocarbons (BDNC) film growth resulting with complex heterogeneity carbon structures...
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Increasing the conductivity of V2O5-TeO2 glass by crystallization: structure and charge transfer studies
PublikacjaIn the present paper, V 2 O 5 -TeO 2 glass was prepared by the melt-quenching technique. Crystallization of glass with a vanadium content higher than 35%mol results in an increase in electrical conductivity by a few orders of magnitude and a decrease in activation energy from ~0.40 to ~0.12 eV. In this work, a critical review of existing charge transfer models was presented on the example of V 2 O 5 -TeO 2 glass and glass–ceramics....
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Activation of the operational ecohydrodynamic model (3D CEMBS) – the hydrodynamic part **The original version of this paper appeared in the Geoscientific Model Development Discussion; here, we present the revised version, which takes all the reviewers’ comments into account.The study was supported by the Polish State Committee of Scientific Research (grants: N N305 111636, N N306 353239). Partial support was also provided by the Satellite Monitoring of the Baltic Sea Environment – SatBałtyk project funded by the European Union through the European Regional Development Fund contract No. POIG 01.01.02-22-011/09.
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Fully scalable one-pot method for the production of phosphonic graphene derivatives
PublikacjaGraphene oxide was functionalized with simultaneous reduction to produce phosphonated reduced graphene oxide in a novel, fully scalable, one-pot method. The phosphonic derivative of graphene was obtained through the reaction of graphene oxide with phosphorus trichloride in water. The newly synthesized reduced graphene oxide derivative was fully characterized by using spectroscopic methods along with thermal analysis. The morphology...
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Sensorless algorithm for sustaining controllability of IPMSM drive in electric vehicle after resolver fault
PublikacjaThis paper presents a sensorless algorithm designated for the emergency control of an interior permanent magnet synchronous motor (IPMSM) drive in electric or hybrid vehicle. The algorithm is based on analysing the derivatives of motor phase currents measured over the duration of particular inverter states. The method is computationally simple and does not require additional hardware since the derivatives are measured indirectly....
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Phase Separation and Electrical Properties of Manganese Borosilicate Glasses
PublikacjaThe structure and electrical properties of manganese borosilicate glasses of a composition of xMnO-(0.8-x)SiO2-(0.2)B2O3 (x=0.4, 0.5 and 0.6 in mol) were investigated by impedance spectroscopy, SEM, XRD and confocal microscopy methods. The influence of composition on the glass structure and electrical properties was discussed. A separation of two amorphous phases was observed and it was concluded that one phase is SiO2-rich and...
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The Pomerania Design Faktory as an Example of 50+ Entrepreneurship Promotion
PublikacjaThe article presents one of the programmes carried out by The Gdańsk Entrepreneurs' Foundation and The Gdansk Labor Office in 2013/14, dedicated to seniors. It is a great example of an innovative project aimed at the activation of individuals aged 50+ by using their own talents and interests in business. It also shows the results of intergenerational cooperation because the trainers — especially the designers — were much younger...
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Activated persulfate and peroxymonosulfate based advanced oxidation processes (AOPs) for antibiotics degradation – A review
PublikacjaSulfate radical AOPs (SR-AOP) were successfully utilized in degradation of antibiotics in water and wastewater treatment. The review discusses details on SR-AOPs mechanisms and applications for antibiotics degradation. The progress in this field was discussed, highlighting the most promising developments and remaining challenges. The applicability of SR-AOPs was summarized revealing the most susceptible and persistent to oxidation...
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Thermal-Resistant Polyurethane/Nanoclay Powder Coatings: Degradation Kinetics Study
PublikacjaIn the present study, thermal degradation kinetics of polyurethane (PU) powder coatings reinforced with organo-modified montmorillonite (OMMT) was investigated. PU nanocomposites were prepared in different concentrations of 1, 3, and 5 wt.% of OMMT via the extrusion method. The microstructure of the nanocomposites was observed by scanning electron microscope (SEM) illustrating uniform dispersion of OMMT nano-clay platelets in the...
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Serotonergic–Muscarinic Interaction within the Prefrontal Cortex as a Novel Target to Reverse Schizophrenia-Related Cognitive Symptoms
PublikacjaRecent studies revealed that the activation of serotonergic 5-HT1A and muscarinic M1, M4, or M5 receptors prevent MK-801-induced cognitive impairments in animal models. In the present study, the effectiveness of the simultaneous activation of 5-HT1A and muscarinic receptors at preventing MK-801-induced cognitive deficits in novel object recognition (NOR) or Y-maze tests was investigated. Activators of 5-HT1A (F15599), M1 (VU0357017),...
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Implementation of DEIS for reliable fault monitoring and detection in PEMFC single cells and stacks
PublikacjaDynamic Electrochemical Impedance Spectroscopy (DEIS) was presented as novel method for diagnostic and monitoring of PEMFC stack and single cells operation. Impedance characteristics were obtained simultaneously with current - voltage characteristics for stack and each individual cell. Impedance measurements were performed in galvanodynamic mode. It allowed to compare performance of each cell and identification of faulty cell operation...
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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Fe local structure in Pt-free nitrogen-modified carbon based electrocatalysts: XAFS study
PublikacjaThe paper presents a new results on the bonding environment (coordination number and geometry) and on oxidation states of Fe in nitrogen-modified Fe/C composites used as Pt-free catalysts for oxygen reduction in Direct Hydrogen Fuel Cells. Starting from glucose or fructose, two catalysts displaying different electrochemical performance were prepared and studied in the form of pristine powder and thin catalytic layer of electrode...
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Determination of the ionic conductivity of Sr-doped lanthanum manganite by modified Hebb–Wagner technique
PublikacjaThe Hebb–Wagne rpolarization method with the electron blocking electrode has been discussed in this paper in aim to determine a partial ionic conductivity of Sr-doped lanthanum manganite.The “limiting current” in the proposed system was measured using the two-point DC technique with additional Pt electrode between LSM and blocking electrode.The electrochemical model based on bulk diffusion processes and Boltzmann statistics has...
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Kinetics of cross-linking processes of fast-curing polyurethane system
PublikacjaThis work focuses on the application of thermal analysis and kinetics investigations to analyze chemical processes during cross-linking of the complex fast-curing polyurethane system. Non-isothermal Differential Scanning Calorimetry (DSC) measurements were performed for both stoichiometric mixtures of polyol and isocyanate component and for mixture with large isocyanate excess. Isoconversional methods were used to calculate initial...