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Wyniki wyszukiwania dla: KOŚCIÓŁ GOTYCKI
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Studies of the complex formation between some proton sponges and Cu(II) cations
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Anthropopressure’s intensification with reference to Arctic ecosystems
PublikacjaThis paper concerns issue of long range atmospheric transport of pollutants to polar areas and intensification of their toxic effect on biota in the face of climate change. Arctic which was for years seen as a pristine and not affected by antropopressure region became a sink of xenobiotics. Atmospheric circulation facilitates transport of chemicals from Eurasia to Arctic. Influence of climate change on crucial balance of polar...
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Organic Pollution in Surface Waters from the Fuglebekken Basin in Svalbard, Norwegian Arctic
PublikacjaThe Fuglebekken basin is situated in the southern part of the island of Spitsbergen (Norwegian Arctic), on the Hornsund fjord (Wedel Jarlsberg Land). Surface water was collected from 24 tributaries (B1-B24) and from the main stream water in the Fuglebekken basin (25) between 10 July 2009 and 30 July 2009. The present investigation reveals the results of the analysis of these samples for their PAH and PCB content. Twelve of 16 PAHs...
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Helicene Monomers and Dimers: Chiral Chromophores Featuring Strong Circularly Polarized Luminescence
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Bypassing the stereoselectivity issue: transformations of Kinugasa adducts from chiral alkynes and non-chiral acyclic nitrones
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Zarządzanie zapasami dla praktyków Jak mądrze redukować zapasy w systemie KANBAN I MRP
PublikacjaDążenie do redukcji zapasów jest naturalnym trendem wszystkich przedsiębiorstw dbających o dostęp do tzw. wolnej gotówki. 11 lat prowadzonych przeze mnie obserwacji w toku realizowanych kilkuset projektów wskazuje, że tylko ok 0,5% przedsiębiorstw (w danym momencie) nie zajmuje się pracą nad obniżeniem zapasów. Jak ta redukcja zapasów zazwyczaj się odbywa? Szef stawia cel swojemu zespołowi: „dziś rotacja naszego zapasu wynosi...
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Ku zeroemisyjnej energetyce gazowej
PublikacjaW pracy krótko omówiono trendy wprowadzane w obiegach gazowych z zastosowaniem oksyspalania. Następnie przed-stawiono rozwiązanie nowego układu opartego na wykorzystaniu dwóch urządzeń o wzmożonej konwersji energii, a mia-nowicie „mokrej komory spalania” i „skraplacza natryskowo-strumieniowego”. Zaproponowany obieg gazowo-parowy realizowany jest w jednej turbinie, która ma zalety zarówno turbiny gazowej (wysokie temperatury wlotowe)...
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Chemometric analysis of rainwater and throughfall at several sites in Poland.
PublikacjaPróbki pobrano w stacjach w różnych rejonach Polski. Stacje te były umieszczone na terenach specjalnie chronionych (Wielkopolski Park Narodowy i Ojcowski Park Narodowy) oraz na niechronionych formacjach leśnych (leśnictwo Stara Piła). Celem badań było porównanie parametrów występujących w opadach atmosferycznych pod względem podobieństwa charakterystyki miejsca a także podobieństw i różnic związanych z przejściem wody opadowej...
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Botanical and geographical origin characterization of polish honeys by headspace SPME-GCxGC-TOFMS
PublikacjaVolatile organic compounds (VOCs) composition of Polish honeys obtained from various geographical regions was studied. Headspace solid phase microextraction (HS-SPME) using Divinylbenzene/Carboxen/Polydimethylsiloxane-coated fibers was used in combination with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC× GC-TOFMS) because of the complexity of the samples. Acacia, linden, rapeseed, buckwheat...
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Metabolic activity of tree saps of different origin towards cultured human cells in the light of grade correspondence analysis and multiple regression modeling
PublikacjaTree saps are nourishing biological media commonly used for beverage and syrup production. Although the nutritional aspect of tree saps is widely acknowledged, the exact relationship between the sap composition, origin, and effect on the metabolic rate of human cells is still elusive. Thus, we collected saps from seven different tree species and conducted composition-activity analysis. Saps from trees of Betulaceae, but not from...
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Comprehensive Chiroptical Study of Proline-Containing Diamide Compounds
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Synthesis and Comprehensive Structural and Chiroptical Characterization of Enones Derived from (−)-α-Santonin by Experiment and Theory
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Atropoisomerism in Mono- and Diaryl-Substituted 4-Amino-2,6-lutidines
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Steroidal Molecular Rotors with 1,4-Diethynylphenylene Rotators: Experimental and Theoretical Investigations Toward Seeking Efficient Properties
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In Depth Analysis of Chiroptical Properties of Enones Derived from Abietic Acid
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Electronic circular dichroism imaging (CDi) maps local aggregation modes in thin films of chiral oligothiophenes
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Phytotoxic Activity of Metabolites Isolated from Rutstroemia sp.n., the Causal Agent of Bleach Blonde Syndrome on Cheatgrass (Bromus tectorum)
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Chiral crystals from porphyrinoids possessing a very low racemization barrier
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Distance between the Basic Group of the Amino Acid Residue's Side Chain in Position P1of Trypsin Inhibitor CMTI-III and Asp189in the Substrate Pocket of Trypsin Has an Essential Influence on the Inhibitory Activity
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Green chromatography
PublikacjaAnalysis of organic compounds in samples characterized by different composition of the matrix is very important in many areas. A vast majority of organic compound determinations are performed using gas or liquid chromatographic methods. It is thus very important that these methods have negligible environmental impact. Chromatographic techniques have the potential to be greener at all steps of the analysis, from sample collection...
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Crystal structure and physical properties of new Ca2TGe3 (T = Pd and Pt) germanides
PublikacjaThe crystallographic, electronic transport and thermal properties of Ca2PdGe3 and Ca2PtGe3 are reported. The compounds crystalize in an ordered variant of the AlB2 crystal structure, in space group P6/mmm, with the lattice parameters a = 8.4876(4) Å/8.4503(5) Å and c = 4.1911(3) Å/4.2302(3) Å for Ca2PdGe3 and Ca2PtGe3, respectively. The resistivity data exhibit metallic behavior with residual-resistivity-ratios (RRR) of 13 for...
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HPLC-DAD in identification and quantification of selected coumarins in crude extracts from plant cultures of Ammi majus and Ruta graveolens.
PublikacjaW pracy opisano wyniki badań nad opracowaniem metody rozdzielania, identyfikacji i oznaczania wybranych kumaryn i funarokumaryn w surowych ekstraktach roślinnych z Ammi majus i Ruta graveolens hodowanych pojedynczo lub w kokulturach. Zbadano przydatność trzech głównych składników eluentu, stosowanych w układach faz odwróconych i różnych programów elucji: woda- acetonitryl(ACN)- metanol (MeOH)- tetrahydrofuran (THF). W optymalnej...
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Structure and the Biochemical Potential of the Bacterial Community in Wastewater Treatment Plant Effluent and in Receiving Waters: Northern Poland Case Study
PublikacjaWastewater treatment processes are monitored mainly in terms of biogenic substance removal efficiency. Little is known about the treated wastewater microbiome and its influence on the recipient. In this study, a wide range of methods (cultivation, microscopic analysis, New Generation Sequencing and Real Time PCR) were employed to determine the bacterial community composition of the treated wastewater and its receiver. Preliminary...
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The role of atmospheric precipitation in introducing contaminants to the surface waters of the Fuglebekken catchment, Spitsbergen.
PublikacjaAlthough the Svalbard Archipelago is located at a high latitude, far from potential contaminant sources, it is not free from anthropogenic impact. Towards the Fuglebekken catchment, in the southern part of Spitsbergen, north of Hornsund fjord, contaminants can be transported from mainland pollution sources. In the precipitation and surface water collected in the catchment, the following elements were detected and quantified: Ag,...
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Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions
PublikacjaAg-based plasmonic nanostructures were manufactured by thermal annealing of thin metallic films. Structure and morphology were studied using scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). SEM images show that the formation of nanostructures is influenced by the initial layer thickness as well as the...
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Tuning of the plasmon resonance location in Au nanostructures coated with a ultrathin film of Al2O3 – Optical measurements and FDTD simulations
PublikacjaThe Au nanostructures have been coated with an ultra-thin films of amorphous aluminium oxide. Optical absorption spectra show the influence of the thickness of Al2O3 on plasmon resonance wavelength. The observed red-shift of the resonance location with the increase of the thickness of the Al2O3 film, can be explained by the change in the dielectric function of this film. It allows control of the optical spectra of the coated particles....
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Sea spray as a secondary source of chlorinated persistent organic pollutants? - Conclusions from a comparison of seven fresh snowfall events in 2019 and 2021
PublikacjaSecondary sources of persistent organic pollutants (POPs) gain in importance worldwide as primary sources decline. In this work, we aim to determine whether sea spray may be a secondary source of chlorinated POPs to the terrestrial Arctic, since a similar mechanism was proposed there only for the more water-soluble POPs. To this end, we have determined polychlorinated biphenyls and organochlorine pesticides concentrations in fresh...
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Adaptative Potential of the Lactococcus Lactis IL594 Strain Encoded in Its 7 Plasmids
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Potential ofLactobacillus plantarumIBB3036 andLactobacillus salivariusIBB3154 to persistence in chicken afterin ovodelivery
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Isolation and Self-Association Studies of Beta-Lactoglobulin
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Amine-Catalyzed Direct Aldol Reactions of Hydroxy- and Dihydroxyacetone: Biomimetic Synthesis of Carbohydrates
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Phytotoxic Metabolites from Three Neofusicoccum Species Causal Agents of Botryosphaeria Dieback in Australia, Luteopyroxin, Neoanthraquinone, and Luteoxepinone, a Disubstituted Furo-α-pyrone, a Hexasubstituted Anthraquinone, and a Trisubstituted Oxepi-2-one from Neofusicoccum luteum
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Zewnętrzna stolarka drzwiowa Gdańska-Wrzeszcza na przełomie XIX i XX wieku
PublikacjaDzielnica Gdańska Wrzeszcz ukształtowała się na przełomie XIX i XX w. Liczba mieszkańców Wrzeszcza wzrosła z około 2500 w 1884 r. do około 35 000 w 1914 r. W tym czasie powstało kilkaset jednorodzinnych i wielorodzinnych budynków mieszkalnych oraz najważniejsze obiekty użyteczności publicznej, jak zespół Politechniki, szkoły, szpitale i kościoły. Wrzeszcz – w odróżnieniu od śródmieścia Gdańska – w niewielkim tylko stopniu ucierpiał...
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Rainwater chemistry composition in Bellsund: Sources of elements and deposition discrepancies in the coastal area (SW Spitsbergen, Svalbard)
PublikacjaDiscrepancies in rainfall chemistry in Bellsund were found to be influenced by the orographic barrier and related to the variability in the inflow of air masses as well as to the distance of sampling sites from the sea and thus the extent of sea spray impact. This study covers measurements of rainfall (P) and air temperature (T), physicochemical parameters (pH, specific electrolytic conductivity (SEC), major ions (Cl , NO3 , SO4...
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Transformation of bimetallic Ag–Cu thin films into plasmonically active composite nanostructures
PublikacjaFormation of plasmonically active silver, copper and composite silver-copper nanostructures were studied in this paper. Metallic nanostructures were fabricated by thermal disintegration, so called dewetting, of the thin films in an argon atmosphere. The formation process of the nanostructures was in-situ observed by a novel method, based on resistance measurements. The influence of the material and thickness of the initial thin...
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Reemission of inorganic pollution from permafrost? A freshwater hydrochemistry study in the lower Kolyma basin (North-East Siberia)
PublikacjaPermafrost regions are under particular pressure from climate change resulting in widespread landscape changes, which impact also freshwater chemistry. We investi- gated a snapshot of hydrochemistry in various freshwater environments in the lower Kolyma river basin (North-East Siberia, continuous permafrost zone) to explore the mobility of metals, metalloids and non-metals resulting from permafrost thaw. Partic- ular attention...
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Evaluation of the use of reindeer droppings for monitoring essential and non-essential elements in the polar terrestrial environment
PublikacjaExcess or toxic metals, non-metals and metalloids can be eliminated from the organism by deposition in inert tissue (e.g. fur) or excretion with body secretions, urine and faeces. Droppings are one of the main routes for the elimination of multiple elements and they can be collected without direct contact with the animal. Contaminant concentration has been examined in non-lethally collected tissues of several species (especially...
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Modyfikacja cementu kostnego w celu uzyskania długotrwałej ochrony antybakteryjnej
PublikacjaNiniejsza rozprawa doktorska stanowi przewodnik po jednotematycznym cyklu publikacji, dotyczącym modyfikacji akrylowego cementu kostnego celem uzyskania długotrwałej i efektywnej ochrony antybakteryjnej. W ramach niego przeprowadzono badania eksperymentalne polegające na opracowaniu technologii wytwarzania modyfikowanego cementu kostnego oraz procedury medycznej jego stosowania. Cement kostny był modyfikowany przez zastosowanie...
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Comprehensive Spectroscopic Characterization of Finasteride Polymorphic Forms. Does the Form X Exist?
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Structure – chiroptical properties relationship of cisoid enones with an α-methylenecyclopentanone unit
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Cover Feature: Electronic Circular Dichroism Imaging (ECD i ) Casts a New Light on the Origin of Solid‐State Chiroptical Properties (Chem. Eur. J. 4/2022)
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Higginsianins D and E, Cytotoxic Diterpenoids Produced by Colletotrichum higginsianum
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Chromane helicity rule – scope and challenges based on an ECD study of various trolox derivatives
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Circular Dichroism Imaging: Mapping the Local Supramolecular Order in Thin Films of Chiral Functional Polymers
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New chiral discotics with helical organization of the mesophase—liquid crystalline derivatives of dibenzotetraaza[14]annulene
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Rabenchromenone and Rabenzophenone, Phytotoxic Tetrasubstituted Chromenone and Hexasubstituted Benzophenone Constituents Produced by the Oak-Decline-Associated Fungus Fimetariella rabenhorstii
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Unique Aggregation of Sterigmatocystin in Water Yields Strong and Specific Circular Dichroism Response Allowing Highly Sensitive and Selective Monitoring of Bio-Relevant Interactions
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Electronic Circular Dichroism Imaging (ECD i ) Casts a New Light on the Origin of Solid‐State Chiroptical Properties
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Pochodne oleju makowego jako związki biologicznie czynne
PublikacjaW pracy przebadano skład kwasów tłuszczowych oleju makowego z nasion maku niskomorfinowego (Michałko, Agat, Mieszko, Zambo, Rubin i Przemko) i wysokomorfinowego (Lazur). Do dalszych badań wybrano olej makowy odmiany Michałko ze względu na wysoką zawartość kwasu linolowego (72,8%), niską zawartość kwasu oleinowego (12,6%) i kwasu linolenowego (0,8%). Kwasy nasycone głównie palmitynowy (11,3%) mogą być usunięte w odrębnym postępowaniu....
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Global Prevalence and Drivers of Dental Students’ COVID-19 Vaccine Hesitancy
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