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Photoelectrochemical properties of BIMEVOX (ME=Cu, Zn, Mn) electrodes in contact with aqueous electrolyte
PublikacjaLayered oxide Bi4O2O11 and mixed oxides of bismuth, vanadium and a third metal (ME = Cu, Zn, Mn) were synthesized and characterized using XRD, Raman and SEM. The energy band gap (Eg) of samples determined using UV–VIS reflectance spectra equals to 2.46, 2.34, 2.27 and 2.18 eV for Bi4V2O11, BICUVOX (Bi2V1 − xCuxO5.5 − 3x/2), BIZNVOX (Bi2V1 − xZnxO5.5 − 3x/2) and BIMNVOX (Bi2V1 − xMnxO5.5 − x/2) (x = 0.1), respectively. Open circuit...
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Modeling of multi-cavity Fabry-Perot optical fiber sensors
PublikacjaReflectance characteristics of a two-cavity extrinsic Fabry-Perot optical fiber sensor were investigated using computer modeling. Calculations were performed using a plane wave-based approach, selected for clarity of results. Based on the modeling results, it can be concluded that the two-cavity Fabry-Perot interferometer can be used to measure two different quantities, such as refractive index and temperature, independently. It...
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Determination of the refractive index and wavelength‐dependent optical properties of few‐layer CrCl3 within the Fresnel formalism
PublikacjaBased on previous reports on the optical microscopy contrast of mechanically exfoliated few layer CrCl3 transferred on 285 nmand 270 nmSiO2 on Si(100), we focus on the experimental determination of an effective mean complex refractive index via a fitting analysis based on the Fresnel equations formalism. Accordingly, the layer and wavelength-dependent absorbance and reflectance are calculated. Layer and wavelength-dependent optical...
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A Parallax Shift Effect Correction Based on Cloud Height for Geostationary Satellites and Radar Observations
PublikacjaThe effect of cloud parallax shift occurs in satellite imaging, particularly for high angles of satellite observations. This study demonstrates new methods of parallax effect correction for clouds observed by geostationary satellites. The analytical method that could be found in literature, namely the Vicente et al./Koenig method, is presented at the beginning. It approximates a cloud position using an ellipsoid with semi-axes...
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Rare earth ions doped K 2 Ta 2 O 6 photocatalysts with enhanced UV–vis light activity
PublikacjaNew rare earth-doped K2Ta2O6 photocatalysts were successfully synthesized by hydrothermal method. The effect of dopant type (Y,Yb,Ho,Pr,Er) and amount of rare earth precursor (2,4,8 and 10 mol%) on the physicochemical and photocatalytic properties of RE-K2Ta2O6 have been investigated. All as-prepared materials were characterized by UV–vis diffuse reflectance spectroscopy, Brunauer-Emmett-Teller specific surface area measurement,...
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Short Term Monitor of Photodegradation Processes in Ranitidine Hydrochloride Observed by FTIR and ATR FTIR
PublikacjaThe effects of degradation of ranitidine hydrochloride exposed to UVB radiation (l = 310 nm) and oxygen in a weathering chamber were studied by Fourier Transform Infrared spectroscopy (FTIR) and Attenuated Total Reflectance Fourier Transform Infrared spectroscopy (ATR-FTIR). ATR-FTIR profile indicated that the degradation was spatially heterogeneous. Significant amounts of photoproducts were detected only in a directly...
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Porous Phantoms Mimicking Tissues—Investigation of Optical Parameters Stability Over Time
PublikacjaOptical phantoms are used to validate optical measurement methods. The stability of their optical parameters over time allows them to be used and stored over long-term periods, while maintaining their optical parameters. The aim of the presented research was to investigate the stability of fabricated porous phantoms, which can be used as a lung phantom in optical system. Measurements were performed in multiple series with an interval...
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Determination of leakage inductances of multi-winding and single-phase transformer
PublikacjaThis paper presents the method for determination of leakage inductances of single-phase and multi-winding transformer. The matrix of leakage inductances takes into account leakage self and also leakage mutual magnetic couplings. It is assumed that there is a flux common to all windings and several leakage fluxes referred to a particular winding. The flux linkages of each coil needed fo calculation of leakage inductances was computed...
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Selected dynamic properties of adaptive proportional observer of induction motor state variables
PublikacjaThis paper presents problems related to the design and the stability of adaptive proportional observer which is used for estimation of magnetic flux and motor speed in sensorless control systems of induction motor. The gain matrix of the observer was chosen by genetic algorithm and alternatively by pole placement method. It has been shown that adaptive proportional observer is stable if the...
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Magnetization reversal process in flat and patterned exchange-biased CoO/[Co/Pd] thin films
PublikacjaNanostructured magnetic materials have gained great interest due to their possible technological applications in electronic and spintronic devices or in medicine as drug carriers. The key issue which decides on their potential industrial utilization is an exhibited type of a magnetization reversal process. Two main approaches used to describe the switching mechanism are the domain wall motion and coherent magnetization rotation,...
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Compensation Topologies in IPT Systems: Standards, Requirements, Classification, Analysis, Comparison and Application
PublikacjaWireless power transfer devices are becoming more relevant and widespread. Therefore, an article is devoted to a review, analysis and comparison of compensation topologies for an inductive power transfer. A new classification of topologies is developed. A lot of attention is paid to the problems of the physical fundamentals of compensation work, standards, safety, and five main topology requirements. It is determined, that topologies...
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Iridium 5d -electron driven superconductivity in ThIr3
PublikacjaA polycrystalline sample of superconducting ThI r 3 was obtained by arc-melting Th and Ir metals. Powder x-ray diffraction revealed that the compound crystalizes in a rhombohedral crystal structure (R-3m, s.g. #166) with the lattice parameters: a = 5.3394 ( 1 ) Å and c = 26.4228 ( 8 ) Å . Normal and superconducting states were studied by magnetic susceptibility, electrical resistivity, and heat capacity measurements. The results...
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New Architecture of Solid-State High-Voltage Pulse Generators
PublikacjaThe application of the nanosecond pulsed electric field (nsPEF) for biomedical treatments has gained more interest in recent decades due to the development of pulsed power technologies which provides the ability to control the electric field dose applied during tests. In this context, the proposed paper describes a new architecture of solid-state high-voltage pulse generators (SSHVPG) designed to generate fully customised sequences...
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The Assessment of the Influence of Low-Frequency Electromagnetic Fields Originated from the Power Infrastructure on Humans’ Health
PublikacjaThe objective of this study is to assess the impact of low-frequency electromagnetic fields (LF EMFs) generated by power infrastructure on the nearby environment. Measurements of electric (E) and magnetic (H) field intensities were conducted around high-voltage power lines, transformer stations and facilities related to them. Numerical simulations were also performed to model the distribution of the field values around real buildings...
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Chemical Characteristics and Thermal Oxidative Stability of Novel Cold-Pressed Oil Blends: GC, LF NMR, and DSC Studies
PublikacjaPlant oils contain a high content of unsaturated fatty acids. Studies of food products have revealed a considerable disproportion in the ratio of ω6 to ω3. This article presents information on the healthful qualities of eight new oil blends that contain a beneficial proportion of ω6 to ω3 fatty acids (5:1), as well as their degradation during heating at 170 and 200 °C. The fatty acid profile was analyzed by gas chromatography (GC),...
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Chemical Origins of Optically Addressable Spin States in Eu2(P2S6) and Eu2(P2Se6)
PublikacjaLanthanide materials with a 4f7 electron configuration (8S7/2) offer an exciting system for realizing multiple addressable spin states for qubit design. While the 8S7/2 ground state of 4f7 free ions displays an isotropic character, breaking degeneracy of this ground state and excited states can be achieved through local symmetry of the lanthanide and the choice of ligands. This makes Eu2+ attractive as it mirrors Gd3+ in exhibiting...
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Koncepcja i modelowanie silnika o wirującym tworniku oraz magneśnicy do zastosowania w napędzie miejskiego samochodu elektrycznego
PublikacjaW artykule zaprezentowano koncepcję, model oraz prototyp silnika z wirującym twornikiem oraz magneśnicą. Opisano historię powstania i zastosowania tego typu silników w motoryzacji. Przedstawiono nowoczesne rozwiązania konstrukcyjne i zastosowania we współczesnych samochodach elektrycznych i hybrydowych. Opracowano model silnika z wirującym twornikiem i magneśnicą oraz przedstawiono wybrane wyniki symulacji przeprowadzone w programie...
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Floodplain inundation Mapping using SAR Scattering Coefficient Thresholding and Observed Discharge Data
PublikacjaInundation area time series are important for wetlands monitoring and hydrological model validation. This study is conducted in Biebrza floodplain, which is a natural wetland with complex inundation generation processes. In order to map 2014-2018 series of inundation in the floodplain we test our automatic thresholding method on Sentinel 1 data. The threshold value is optimized using correlation of the inundation area with observed...
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Superconducting properties of vn-sio 2 sol-gel derived thin films
Publikacjain this work studies of structure and superconducting properties of vnsio2 films are reported. the films were obtained through thermal nitridation (ammonolysis) of solgel derived v2o3sio2 coatings (in a proper v2o3/sio2 ratio) at 1200 ◦c. this process leads to the formation of disordered structure with vn metallic grains dispersed in the insulating sio2 matrix. the structural transformations occurring in the lms as a result...
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SSFR Test of Synchronous Machine for Different Saturation Levels using Finite-Element Method
PublikacjaIn this paper the StandStill Frequency Response characteristics (SSFR) of saturated synchronous generator (SG) have been calculated using Finite Element Method (FEM) analysis. In order to validate proposed approach for unsaturated conditions FEM simulation from Flux2D software has been compared with the measurements performed on the 10 kVA, 4- poles synchronous machine ELMOR GCe64a of salient rotor construction, equipped with a...
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Modelling and analysis of medium frequency transformers for power converters
PublikacjaThe evolutions in power systems and electric vehicles, related to the economic opportunities and the environmental issues, bring the need of high power galvanically isolated DC-DC converter. The medium frequency transformer (MFT) is one of its key components, enabled by the increasing switching frequency of modern power semiconductors like silicon carbide transistors or diodes. The increased operating frequency offers small...
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What are the true volumes of SEGA tumors? Reliability of planimetric and popular semi-automated image segmentation methods
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Application of titanium dioxide thin films in fiber optic sensors
PublikacjaThe advance in the nanotechnology and fabrication of micro- and nanostructures has significant impact on development of new optical sensors. Presented study focuses on the applications of the titanium dioxide (TiO2) thin films in fiber optic sensors. The concept of a sensing fiber optic interferometer integrating TiO2 thin film is presented. The cavity of this interferometer is delimited by a 80 nm film fabricated on the end-face...
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Software tool for modelling of mechatronic systems with elastic continua
PublikacjaThe paper presents a systematic computational package for modelling and analysis of complex systems composed of multiple lumped and distributed parameter subsystems. The constructed computer program enables the frequency domain analysis of a class of linear systems and to obtain reduced order model in the form of bond graph. Obtained modal bond graph can be directly exported into 20-Sim package to further processing including nonlinear...
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EHV transmission lines wires location on line operation issues - case studies
PublikacjaTransmission lines towers construction affects the line parameters and influences on its operation in the future. Misguided design of the tower can lead to serious problems such as overvoltages, electric arc extinction difficulties, voltage asymmetry, resonance phenomena or increasing of magnetic field near the line. The paper points out those threats on example of 400 kV double circuit overhead transmission line with shunt reactors....
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Magnetosonic Excitation of the Entropy Perturbations in a Plasma with Thermal Conduction Depending on Temperature
PublikacjaNonlinear excitation of the entropy perturbations by magnetosonic waves in a uniform and infinite plasma model is considered. The wave vector of slow or fast mode forms an arbitrary angle (0 B B ) with the equilibrium straight magnetic field, and all perturbations are functions of the time and longitudinal coordinate. Thermal conduction is the only factor which destroys isentropicity of wave perturbations and causes the nonlinear...
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Charge density wave and crystalline electric field effects in TmNiC2
PublikacjaSingle crystals of TmNiC2 were grown by the optical floating-zone technique and were investigated by x-ray diffraction (XRD), thermal expansion, electrical resistivity, specific heat, and magnetic susceptibility measurements. Single-crystal XRD reveals the formation of a commensurate charge density wave (CDW) characterized by a CDW modulation vector q2c = (0.5, 0.5, 0.5), which is accompanied by a symmetry change from the orthorhombic...
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Kinetics of Intermetallic Phase Precipitation in Manual Metal Arc Welded Duplex Stainless Steels
PublikacjaThe article presents the influence of heat treatment on the kinetics of transformations in lean duplex LDX2101 steel and a weld made of standard duplex 2209 material, which was welded by manual metal arc welding. Changes in the microstructure, hardness, and magnetic phase content were analyzed after heat treatment was conducted at a temperature of 800 °C for a period ranging from 15 to 1440 min. Light and scanning microscopy, Vickers...
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Support Materials of Organic and Inorganic Origin as Platforms for Horseradish Peroxidase Immobilization: Comparison Study for High Stability and Activity Recovery
PublikacjaIn the presented study, a variety of hybrid and single nanomaterials of various origins were tested as novel platforms for horseradish peroxidase immobilization. A thorough characterization was performed to establish the suitability of the support materials for immobilization, as well as the activity and stability retention of the biocatalysts, which were analyzed and discussed. The physicochemical characterization of the obtained...
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Elastic electron scattering and vibrational excitation of isoxazole molecules in the energy range from 2 to 20 eV
PublikacjaDifferential cross sections for elastic electron scattering and the excitation of the C-H vibrational modes of isoxazole molecules were measured in the energy range from 2 to 20 eV and over the scattering angle range from 10◦ to 180◦. The cross sections at the scattering angles of and above 90◦ were accessible with the use of a magnetic angle changer. The differential cross sections were integrated to yield integral and momentum...
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Parameter selection of an adaptive PI state observer for an induction motor
PublikacjaThe paper discusses problems connected with the parameters selection of the proportional-integral observer, designed for recon- struction of magnetic fluxes and angular speed of an induction motor. The selection is performed in several stages that are focused on different criteria. The first stage consists in selecting observer’s gains and provides desired dynamical properties, taking into consideration immunity to disturbances and...
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Crystal growth and properties of a binary intermetallic ZrBi2 compound
PublikacjaSingle crystals of ZrBi2 were grown by a self-flux method. The material adopts TiAs2 structure type with lattice parameters: a = 10.233(4) Å, b = 15.581(2) Å, c = 3.994(5) Å. Crystals of ZrBi2 were studied by means of magnetic susceptiblity, specific heat and resistivity measurements. The compound reveals a metallic-like behavior (RRR = 30). The Sommerfeld coefficient equals γ = 1.59(16) mJ mol-1 K-2 and Debye temperature ΘD =...
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Nonlinear Excitation of the Non-Wave Perturbations by the Magnetoacoustic Waves in the Non-Isentropic Plasma
PublikacjaNonlinear excitation of slow modes by the planar magnetosonic perturbations in a plasma is discussed. Plasma is an open system due to radiation and external heating. This may stipulate enhancement of wave perturbations and hence the acoustical activity of plasma. Plasma is assumed to be a homogeneous ideal gas with infinite electrical conductivity. The straight magnetic field is orthogonal to the velocity of fluid’s...
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Larmor diamagnetism and Van Vleck paramagnetism in relativistic quantumtheory: the Gordon decomposition approach
PublikacjaWe consider a charged Dirac particle bound in a scalar potential perturbed by a classical magnetic field derivable from a vector potential A(r). Using a procedure based on the Gordon decomposition of a field-induced current, we identify diamagnetic and paramagnetic contributions to the second-order perturbationtheory correction to the particle's energy. In contradiction to earlier findings, based on the sum-over-states approach,...
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Nonlinear Interaction of Magnetoacoustic Modes in a Quasi-Isentropic Plasma Flow
PublikacjaThe nonlinear interaction of magnetoacoustic waves in a plasma is analytically studied. A plasma is an open system. It is affected by the straight constant equilibrium magnetic flux density forming constant angle with the wave vector which varies from 0 till . The nonlinear instantaneous equation which describes excitation of secondary wave modes in the field of intense magnetoacoustic perturbations is derived by use of projecting....
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Projektowanie, synteza i charakterystyka fotokatalizatorów nowej generacji na bazie związku Ti3C2Tx do usuwania aktywnych substancji farmaceutycznych
PublikacjaCelem niniejszej pracy było zastosowanie materiałów nowej generacji na bazie związku Ti3C2Tx w procesach fotokatalitycznej degradacji aktywnych substancji farmaceutycznych: karbamazepiny, acetaminofenu i ibuprofenu. Zakres prac badawczych obejmował syntezę fotokatalizatorów, charakterystykę ich właściwości fizykochemicznych, oraz ocenę aktywności fotokatalitycznej. Przedstawiono możliwość zastosowania węglika tytanu jako kokatalizatora...
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Measurements of fundamental properties of homogeneous tissue phantoms
PublikacjaWe present the optical measurement techniques used in human skin phantom studies. Their accuracy and the sources of errors in microscopic parameters’ estimation of the produced phantoms are described. We have produced optical phantoms for the purpose of simulating human skin tissue at the wavelength of 930 nm. Optical coherence tomography was used to measure the thickness and surface roughness and to detect the internal inhomogeneities....
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Implementation of spatial information for monitoring and analysis of the area around the port using laser scanning techniques
PublikacjaNowadays, maritime infrastructure is heavily exploited, which requires monitoring. The article presents the implementation of spatial information which are point clouds for monitoring and analysis of the area around the port (buildings and wharves). For this study, point clouds coming from terrestrial (TLS) and airborne laser scanning (ALS), each of them having different accuracy, were used. An important part of the analysis was...
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Enhancement of fiber-optic low-coherence Fabry-Pérot interferometer with ZnO ALD films
PublikacjaIn this paper investigation of the enhanced fiber-optic low coherence Fabry-Pérot interferometer with zinc oxide (ZnO) film deposited by atomic layer deposition (ALD) was presented. Model of the interferometer, which was constructed of single-mode optical fiber with applied ZnO ALD films, was built. The interferometer was also examined by means of experiment. Measurements were performed for both reflective and transmission modes,...
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Optical recognition elements: macrocyclic imidazole chromoionophores entrapped in silica xerogel
PublikacjaMaterials containing new chromoionophores consisting of crown residue and azole moiety as partsof macrocycles were encapsulated by the sol-gel procedure in silica xerogel matrices and proposed aschemical recognition elements especially for such metal ions as Li+, Cs+ and Cu2+. Action of these recognition elements is in principle based on changes of reflectance. The recognition elements containing 21-membered chromogenic...
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Hydrothermal Cobalt Doping of Titanium Dioxide Nanotubes towards Photoanode Activity Enhancement
PublikacjaDoping and modification of TiO2 nanotubes were carried out using the hydrothermal method. The introduction of small amounts of cobalt (0.1 at %) into the structure of anatase caused an increase in the absorption of light in the visible spectrum, changes in the position of the flat band potential, a decrease in the threshold potential of water oxidation in the dark, and a significant increase in the anode photocurrent. The material...
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Obrazowanie perfuzji mózgu z wykorzystaniem modelowania parametrycznego danych DSC-MRI
PublikacjaPomiary DSC-MRI (Dynamic Susceptibility Contrast Magnetic Resonance Imaging) zostały wykorzystane w pracy do estymacji parametrów perfuzji mózgu: przepływu krwi mózgowej (cerebral blood flow, CBF), objętości krwi mózgowej (cerebral blood volume, CBV) oraz średniego czasu przejścia (mean transit time, MTT). Zaproponowano model trzykompartmentowy. Przedstawiono i porównano dwa podejścia do identyfikacji modelu na podstawie danych...
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Microstructure and electrical properties of manganese borosilicate glasses
PublikacjaThe structure, optical and electrical properties of manganese borosilicate glasses of the composition xMnO–(80 − x)SiO 2 –20B 2 O 3 (x = 40, 50, and 60 mol%) were investigated. The dependence of the glass structure on its composition was discussed and related to electrical properties. A separation of two amorphous phases was observed. It was suggested that one phase is MnO-rich and the other is SiO 2 -rich. It was found that...
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Correlation between charge density waves and antiferromagnetism in Nd1−xGdxNiC2 solid solutions
PublikacjaWe report a study on the evolution of a charge density wave and antiferromagnetism in the series of the polycrystalline solid solution Nd1−xGdxNiC2 (0 _ x _ 1) by means of magnetic and transport properties measurements. The experimental results reveal the violation of the de Gennes law and a strong correlation between the Peierls, Néel, and Curie-Weiss temperatures, which strongly suggests a cooperative interaction between the...
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Synthesis and characterization of mononuclear Zn(II), Co(II) and Ni(II) complexes containing a sterically demanding silanethiolate ligand derived from tris(2,6-diisopropylphenoxy)silanethiol
PublikacjaFour heteroleptic complexes of zinc(II), cobalt(II) and nickel(II) containing a monodentate silanethiolate ligand derived from tris(2,6-diisopropylphenoxy)silanethiol (TDST), were prepared and characterized. The geometries of ligands in the complexes are typical: distorted tetrahedral in zinc and cobalt(II) complexes and square planar in nickel(II) compound. Magnetic studies performed for Ni(II) and Co(II) compounds confirm the...
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Application of Barkhausen effect in the impact assessment of welding to internal stress distribution in steel
PublikacjaThe paper presents identification method of internal stresses in plane steel elements in the chase of deliverance and welding assembly. The assessment was made by means of a non-destructive experimental method based on measurements incorporating local external magnetic field and the measurement of induced voltage, including Barkhausen noise. This method allows a degradation assessment due to internal and external actions, causing...
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Application of Barkhausen effect in the impact assessment of welding to internal stress distribution in steel
PublikacjaThe paper presents identification method of internal stresses in plane steel elements in the chase of deliverance and welding assembly. The assessment was made by means of a non-destructive experimental method based on measurements incorporating local external magnetic field and the measurement of induced voltage, including Barkhausen noise. This method allows a degradation assessment due to internal and external actions, causing...
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Functional phase bistability in a nanocrystalline RbMn[Fe(CN)6] thin film fabricated by matrix-assisted laser evaporation
PublikacjaOne of the main barriers hindering applications of Prussian blue metal assemblies is their poor processability, which makes the fabrication of intact thin films very difficult. In this work, a nanocrystalline RbMn[Fe(CN)6]·xH2O film on silicon substrate was obtained for the first time via laser-stimulated deposition and investigated. Temperature-induced phase transition and bistability within broad hysteresis loop (120 K), along...
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Nanosorbents as Materials for Extraction Processes of Environmental Contaminants and Others
PublikacjaThe aim of this work focuses on the application of nanomaterials (NMs) in different sorp- tive extraction techniques for the analysis of organic contaminants from environmental samples of distinct matrix compositions. Without any doubt, the integration of specific NMs such as carbona- ceous nanomaterials, magnetic nanoparticles (MNPs), metal–organic frameworks (MOFs), silica na- noparticles, and ion-imprinted NPs with so lid-phase...
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A comparative performance assessment of a hydrodynamic journal bearing lubricated with oil and magnetorheological fluid
PublikacjaThis work presents the investigation results of a journal bearing lubricated with magnetorheological fluid that is activated by a local constant magnetic field to vary both the local flow resistance and pressure. The bearing performance is assessed via Finite Element Modelling (FEM) and results are corroborated by experiments. The FEM model uses the Bingham model to describe the fluid film. A dedicated test rig is used to assess...