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Agent System for Managing Distributed Mobile Interactive Documents
PublikacjaThe MIND architecture of distributed mobile interactive document is a new processing model defined for facilitate informed decision-making in non-algorithmic decision-making processes carried out by knowledge-based organizations. The aim of this architecture is to change the static document to mobile agents, which are designed to implement the structure of the organization through autonomous migration between knowledge workers...
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Evaluation of Professional Demands and Financial Reward Through the Perception of Police Managers
PublikacjaThe aim of the study was to examine the relationship between job demands and salary in the subjective perception of mid-level police managers. An occupational stress model in which effort spent on job demands are not balanced by the received reward, was adopted. The study comprised 51 police officers (4 women). The partial least squares method was used for the analysis, and the SmartPLS 2.0 program was applied. The income and...
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Model otwartej architektury rozproszonych dokumentów elektronicznych wspierającej proces podejmowania decyzji w trybie obliczeń zespołowych
PublikacjaModel otwartej architektury mobilnych dokumentów interaktywnych MIND, został opracowany w celu efektywnego zarządzania informacją w procesach podejmowanych przez organizacje oparte na wiedzy. Architektura ta stanowi całościowy opis struktury i funkcjonalności dokumentu, zaprojektowanego w celu realizacji rozproszonego przetwarzania zespołowego i pracy grupowej. Umożliwia automatyczne przejście od statycznej postaci dokumentów...
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From Creative Thinking Techniques to Innovative Design Solutions - The Educators' Perspective
PublikacjaThe article presents a structure and basic tasks of a new original academic course, which was inaugurated in 2015 at the Faculty of Architecture in Gdańsk University of Technology and organized for the first year students of Spatial Planning.The title of the course was ‘Garden Cities and the Gardens in the Cities. A Course with Elements of Training Creativity’. The aim of the course was to encourage the participants to develop...
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A convenient and efficient alfa-sulfenylation of carbonyl compounds
PublikacjaA method for alfa-sulfenylation of carbonyl compounds by a 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane-2-disulfanyl derivatives has been developed. Readily available reagents, mild reaction conditions, and excellent yields with high selectivity makes this method quite simple, convenient and practical.
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Qualia: About Personal Emotions Representing Temporal Form of Impressions - Implementation Hypothesis and Application Example
PublikacjaThe aim of this article is to present the new extension of the xEmotion system as a computerized emotional system, part of an Intelligent System of Decision making (ISD) that combines the theories of affective psychology and philosophy of mind. At the same time, the authors try to find a practical impulse or evidence for a general reflection on the treatment of emotions as transitional states, which at some point may lead to the...
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Narzędzia treningu twórczości jako pomoc w kształceniu projektantów
PublikacjaKreatywność rozwijać. Na tym założeniu opiera się międzynarodowy program edukacyjny Odyssey of the Mind (Odyseja Umysłu). W programie zespoły młodych osób pracują metodą projektową, wykorzystując różnorodne techniki treningu twórczości, nad rozwiązaniem abstrakcyjnego problemu rozbieżnego. Część absolwentów programu wybiera kierunki kreatywne jako naturalną kontynuację procesu edukacji. Elementy treningu twórczości można wykorzystać...
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Convenient and Efficient Diastereoselective Preparation of Functionalized Z -Alkenyl Sulfides
PublikacjaWe have developed an efficient and convenient regio‐ and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)‐alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.
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Convenient and Efficient Synthesis of Functionalized 2-Sulfenylindoles
PublikacjaA simple, efficient, and practical sulfenylation at the C2 position of N-tosylindoles under mild conditions was developed. The designed transformation is based on the reaction of N-tosylindoles with BuLi and S-alkyl, and S-aryl phosphorodithioates or thiotosylates to produce 2-sulfenylindoles in moderate to high yields. The presence of additional hydroxy, carboxy, or amino functionalities did not disturb the formation of products
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Convenient and efficient synthesis of functionalized unsymmetrical Z-alkenyl disulfanes
PublikacjaWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical Z-alkenyl disulfanes under mild conditions in moderate to good yields. The designed method is based on the reaction of Z-alkenyl thiotosylates with thiols in the presence of base. The developed method allows the preparation of unsymmetrical Z-alkenyl disulfanes bearing additional hydroxy, carboxy, or amino functionalities.
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Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides
PublikacjaWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical alkynyl sulfides under mild conditions in good yields. The designed method is based on the reaction of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-disulfanyl derivatives with lithium acetylides. The developed method allows the preparation of unsymmetrical alkynyl sulfides bearing additional hydroxyl, carboxyl, or amino functionalities.
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Diastereoselective Synthesis of Z‐Alkenyl Disulfides from α‐Thiophosphorylated Ketones and Thiosulfonates
PublikacjaWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical Z‐alkenyl disulfides under mild conditions in moderate to good yields. The designed method is based on the reaction of α‐thiophosphorylated carbonyl compounds with thiotosylates in the presence of a base. The developed method allows the preparation of unsymmetrical Z‐alkenyl disulfides bearing additional hydroxy, carboxy, or ester functionalities
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Boron Difluoride Complexes of Carbamoyl Meldrum's Acids
Publikacja5-[Hydroxy(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-diones react with BF3•Et2O in mild conditions leading to the formation of boron difluoride complexes of carbamoyl Meldrum's acids. The X-ray structure has been obtained for one representative complex. The obtained new compounds are fairly stable at standard ambient conditions and easily isolable.
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Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2
PublikacjaThe monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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DDQ-mediated synthesis of functionalized unsymmetrical disulfanes
PublikacjaWe developed a simple and efficient method for the synthesis of functionalized unsymmetrical disulfanes under mild conditions in good yields. The designed method is based on the reaction of bis(5,5- dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfane with thiols in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). The developedmethod allows the preparation of unsymmetrical disulfanes bearing additional hydroxy, carboxy,...
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The organophosphorus sulfenyl bromides as versatile reagents for cysteine derivatives functionalization by unsymmetrical disulfide bond formation
PublikacjaWe have developed a convenient method for the synthesis of L-cysteine unsymmetrical disulfides under mild conditions with good to excellent yields. Described method is based on the straightforward preparation of the organophosphorus sulfenyl bromide readily available from bis-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl) disulfide. The unsymmetrical disulfides can be obtained for L-cysteine derivatives and thiols bearing neutral...
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Application of nonmetallic frustrated cations in the activation of small molecules
PublikacjaThe concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated...
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Efficient Method for the Synthesis of Functionalized Basic Maleimides
PublikacjaA three-step procedure involving Diels-Alder condensation of maleic anhydride with furane, formation of N-substituted imide upon reaction with appropriate diamine and a final retro Diels-Alder regeneration of the maleic carbon-carbon double bond is proposed for an unequivocal synthesis of N-substituted basic maleimides. The novel method is characterized by mild reaction conditions, easy work-up, high yields and no need for additional...
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A convenient method for the preparation of functionalized N-acylsulfenamides from primary amides.
PublikacjaWe have developed a convenient method for the synthesis of functionalized N-acylsulfenamides under mild conditions and in moderate to good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with nitrogen nucleophiles generated from primary amides or imides and sodium hydride. The developed method allows for the preparation of N-acylsulfenamides bearing...
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Politiceskaja pressa o rosijsko-ukrainskich otnoszenijach i sobytiach w Krymu = Polish press covering russian- ukrainian relations and events in Crimea
PublikacjaThe paper made a review of opinions expressed by the most widely read Polish newpapers on the issue of Ukraine-Russian relations and events in Crimea in the period from early December 2013 till late March 2014. The author has brought to light attitudes to the events in Ukraine perceived while having in mind preserving security of Poland in political, economic and societal aspects. The EC policy towards the Russian Federation and...
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Phosphorylation of glucosamine-6-phosphate synthase is important but not essential for germination and mycelial growth of Candida albicans.
PublikacjaStosując mutagenezę ukierunkowaną dla genu gfa1 kodującego syntazę glukozamino-6-fosforanu Candida albicans otrzymano zmutowaną wersję GFA1S208A. Produkt zmutowanego genu, który utracił miejsce fosforylacji dla kinazy A, wykazywał wszystkie właściwości identyczne do dzikiego enzymu, jednakże nie był substratem dla kinazy. Brak fosforylacji syntazy glukozamino-6-fosforanu przez kinazęA prowadził do redukcji lecz nie eliminował...
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Safeguarding democracy during pandemics. Social distancing, postal, or internet voting—the good, the bad, or the ugly?
PublikacjaDuring a pandemic, many countries and organizations must decide whether to postpone upcoming elections or to hold them (Krimmer et al., 2020a). If the decision is made to hold the election, three main scenarios come to mind: continue using the existing system but include measures to ensure the health of participants; or look for alternatives among remote voting channels which could ensure social distancing is guaranteed either...
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Ring Opening of Triflates Derived from Benzophospholan-3-one Oxides by Aryl Grignard Reagents as a Route to 2‑Ethynylphenyl(diaryl)phosphine Oxides
PublikacjaA new simple method for the synthesis of 2-ethynylphenyl(diaryl)phosphine oxides via ring opening of benzophosphol-3-yl triflates has been developed. This process occurs via nucleophilic attack of a Grignard reagent at the phosphorus center, which results in ring opening and cleavage of a leaving group. The reaction proceeds under mild conditions and, within 15−60 min, leads to a library of previously unavailable 2-ethynylphenylphosphine...
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An efficient and convenient synthesis of unsymmetrical disulfides from thioacetates
PublikacjaWe have developed convenient methods for the synthesis of functionalized unsymmetrical dialkyl disulfides under mild conditions in very good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives 1 with functionalized alkyl thiolate anions, generated in situ from thioacetates2and sodium methoxide or butylamine. The developed method allows the preparation...
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Efficient Synthesis of Functionalized Unsymmetrical Dialkyl Trisulfanes
PublikacjaWe have developed a convenient method for the synthesis of functionalized unsymmetrical dialkyl trisulfanes under mild conditions in very good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with alkyl disulfanyl anions generated in situ from S-acetyl disulfanyl derivatives and sodium methoxide. The developed method allows for the preparation of...
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Novel and Efficient Synthesis of Unsymmetrical Trisulfides
PublikacjaWe have developed a convenient method for the synthesis of unsymmetrical trisulfides under mild conditions in very good yields. The designed method is based on the straightforward preparation of 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)trisulfanyl]dodecane from readily available 5,5-dimethyl-2-sulfanyl-2-thioxo-1,3,2-dioxaphosphorinane, sulfur dichloride (SCl2) and dodecane-1-thiol. The unsymmetrical trisulfides can...
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Determination of modifier contents in polymer-modified bitumens and in samples collected from the roads using high performance gel permeation/size exclusion chromatography
PublikacjaThis paper describes application of high performance gel permeation/size exclusion chromatography (HP-GPC/SEC) for the determination of content of polymer modifiers in modified road bitumens. The obtained results were compared with the measurements based on the procedure recommended by the American Association of State Highway and Transportation Officials, which employs Fourier transform mid-infrared spectroscopy (mid-IR FTIR)....
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TBAF Promoted Formation of Symmetrical Trisulfides
PublikacjaWe have developed a new method for the synthesis of functionalized symmetrical trisulfides based on (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorin-2-yl)disulfanyl derivatives prepared from readily available 5,5-dimethyl-2-sul-fanyl-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The symmetrical trisulfides can be obtained from aliphatic and aromatic thiols andL-cysteine derivatives...
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Novel and Efficient Methods for the Synthesis of Symmetrical Trisulfides
PublikacjaWe have developed a convenient methods for the synthesis of symmetrical trisulfides under mild conditions in very good yields. The described methods are based on the straightforward preparation of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane-2-disulfanyl derivatives from readily available 5,5-dimethyl-2-sulfanyl-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The symmetrical...
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Just Let Me Think: Designing Against Acquired Illiteracy.
PublikacjaThis article concerns the relatively new problem of illiteracy relating to persons previously being literate, which is caused by too intensive using of so-called digital media (TV, computers, tablets, smartphones, e-book readers, portable media players, etc.). The problem has been observed for several years mainly in countries with high economic and technological development. The widespread use of digital media and the ease of...
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Convenient Synthesis of Functionalized Unsymmetrical Vinyl Disulfides and Their Inverse Electron-Demand Hetero-Diels-Alder Reaction
PublikacjaThe simple, convenient, and efficient methods for the preparation of unsymmetrical vinyl disulfides with additional functional groups under mild conditions with moderate to high yields were designed. The developed methods include the reaction of S-vinyl phosphorodithioate with thiotosylates or S-vinyl thiotosylate with thiols. The designed methods allow for the synthesis of unsymmetrical vinyl disulfides with additional functionalities...
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A versatile and convenient preparation of unsymmetrical diaryl disulfides
PublikacjaWe have developed a convenient method for the synthesis of unsymmetrical diaryl disulfides under mild conditions in excellent yields. The described method is based on the straightforward preparation of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinane-2-sulfenyl bromide from readily available 5,5-dimethyl-2-thiolo-2-thioxo-1,3,2-dioxaphosphorinane or bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl) disulfide. The unsymmetrical...
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Toward Intelligent Recommendations Using the Neural Knowledge DNA
PublikacjaIn this paper we propose a novel recommendation approach using past news click data and the Neural Knowledge DNA (NK-DNA). The Neural Knowledge DNA is a novel knowledge representation method designed to support discovering, storing, reusing, improving, and sharing knowledge among machines and computing systems. We examine our approach for news recommendation tasks on the MIND benchmark dataset. By taking advantages of NK-DNA, deep...
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Primum non necere, czyli jak uczyć, żeby nie szkodzić
PublikacjaNiezbędna dla projektanta znajomość teorii kompozycji, stylów, kierunków,mód architektonicznych musi stanowić element wspomagający wciąż kształconą i pielęgnowana wrażliwość i umiejętność ekspresyjnego wyrażania emocji, przy użyciu form przestrzennych. Każdy student jest jedynym właścicielem i dysponentem swojej osobowości. To ona określa wrażliwość, ustala granice prywatności, rządzi emocjami i kreuje sposób ekspresji.
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Level and trend uncertainties of Kyoto relevant greenhouse gases in Poland.W: IIASA Home page. Mid-Summer Workshop of Young Scientists Summer Program. 18-19 July 2002, Laxenburg, Austria. Laxenburg: Int. Inst. Applied Syst.** 2002. Dostępny z Internetu: http://www.iiasa.ac.at IIASA - Publications Catalog [s. 1-38, 1 rys. 13 tab. bibliogr. 27 poz.] Poziom i trend niepewności oszacowania emisji gazów cieplarnianych w Polsce
PublikacjaScharakteryzowano metody określania niepewności szacowania emisji gazów cie-plarnianych z różnych źródeł. Wykonano badania i skomentowano wyniki.
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Variability of relationship between cities and nature in landscape architecture= Zmienność relacji miedzy miastem a naturą na przykładzie architektury krajobrazu miast
PublikacjaInterpreting and creating the relations between nature and city are the process of learning which is a subject of permanent conceptualization. It is characterized by the culutrality due to human nature and own ability to perceive oneself in the context of the relationship between own environmental and cultural nature. The way of interpreting the nature and providing it with different features affected significantly the development...
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Układy sterowania pojazdem wykonującym określone trajektorie z zastosowaniem w programie Odysei Umysłu
PublikacjaW ramach programu Odysei Umysłów prowadzonego na Wydziale Mechanicznym Politechniki Gdańskiej grupa studentów startowała w Finałach Światowych konkursu ''Odyssey of the Mind''. Autor był uczestnikiem tej grupy i wraz z nią zdobył pierwsze miejsce na Finałach Światowych. Referat prezentuje cele i zakres działania Odysei oraz koncepcję analizy trajektorii ruchu pojazdu w celu przyszłego jej odtwarzania w trakcie prezentacji ''odysejowych''....
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Reliable Document-Centric Processing in Loosely Coupled Email-Based Systems
PublikacjaEmail is a simple way to exchange digital documents of any kind. The Mobile INteractive Document architecture (MIND) enables self-coordination and self-steering of document agent systems based on commonly available email services. In this paper, a mechanism for providing integrity and reliability of such an email based agent system is proposed to cope with message soft or hard bounces, user interrupts, and other unexpected events....
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Flexomagneticity in Functionally Graded Nanostructures
PublikacjaFunctionally graded structures have shown the perspective of materials in a higher efficient and consistent manner. This study reports a short investigation by concentrating on the flexomagnetic response of a functionally graded piezomagnetic nano-actuator, keeping in mind that the converse magnetic effect is only taken into evaluation. The rule of mixture assuming exponential composition of properties along with the thickness...
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Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublikacjaThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
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Complexes of silanethiolate ligands: Synthesis, structure, properties and application
PublikacjaThe purposeful syntheses of silanethiolate complexes started approximately in the mid-eighties of the 20th century but no summary of the synthetic efforts has been reported till now. The synthetic methods and the resulting complexes have some common features, which are emphasized throughout the review. Thereby specific difficulties during synthesis are outlined and the structures, properties and possible applications of the resulting...
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A method to assess transverse vibration energy of ship propeller shaft for diagnostic purposes
PublikacjaThe article discusses a key problem of ship propulsion system vibration diagnostics, which concerns assessing this part of mechanical energy transmitted from the main engine to the ship propeller which is dissipated due to propeller shaft vibration. A simplified calculation model is proposed which allows the total energy of the generated torsional vibration to be assessed from the shaft deflection amplitude measured at the mind-span...
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Between Descriptive Geometry and CAD 3D
PublikacjaDescriptive geometry provides methods to analyse three-dimensional space through two-dimensional drawings and prepares to create technical documentation. Geometric form of an engineering project is presented by the means of projection methods based on a 3D model, which is present in designer’s imagination. The forthcoming era of Building Information Modelling (BIM) brings changes in the way the engineer works, as the vision is...
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(Vapour and liquid) equilibrium in (N,N-dimethylacetamide+methanol+water) at the temperature 313.15 K.
PublikacjaPraca zawiera wyniki pomiarów całkowitej prężności pary dla tytułowego układu trójskładnikowego oraz dla ''składowych'' układów binarnych. Wyniki obliczeń nadmiarowej energii swobodnej mieszania dla układów (N,N-dimetyloaceta-mid+woda) i (N,N-dimetyloacetamid+metanol) porównane zostały z rezultatami uzyskanymi wcześniej dla innych układów (amid+metanol) oraz (amid+woda). Znaleziono interesującą zależność wartości nadmiaru...
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On the use of uniaxial one-parameter damage laws for estimating fatigue life under multiaxial loading
PublikacjaThe goal of this paper is to evaluate the capabilities of different one-parameter fatigue laws to estimate crack initiation in notched components under multiaxial loading. Fatigue damage is accounted for through stress-based, strain-based, and energy-based approaches while the cyclic plasticity at the notch-controlled process zone is estimated using linear-elastic simulations. The results show that energy-based formulations established...
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Water uptake in protective organic coatings and its reflection in measured coating impedance
PublikacjaWater uptake in commercially available epoxy coating on mild steel using impedance spectroscopy and gravimetry was studied. The water content in the coating was determined using the Brasher-Kingsbury equation and various methods of coating capacitance calculation used in the literature. The obtained results were compared with reference gravimetric data. An overestimation of values obtained from impedance data in relation to gravimetric...
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A New Geodetic Method of Examination of Geometrical Conditions of a Crane Bridge
PublikacjaSafety is one of the key aspects related to crane-based material transport. In order to ensure safe crane operation and material transport, it is necessary to meet certain geometrical conditions. The authors addressed the geometrical conditions of a crane bridge, a substantial crane component. The paper presents the method to compute displacement components of points on the top of a bridge crane relative to their design position....
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Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids
PublikacjaThis manuscript presents results from the investigation on the synthesis of alkyl xylosides by the novel, very efficient and promising protocol of the Fischer synthesis from unprotected xylose and aliphatic alcohol. The use of 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids as the catalysts with dual functionality (surfactant + acid catalyst) and micellar reaction system are the main novelty of described method. It has...
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Development of dynamic method for evaluation of inhibition efficiency on the example of 8-hydroxyquinolin
PublikacjaSelection of a proper inhibitor should be based on the evaluation of its mechanism and effective concentrations. Mechanism of inhibition usually has dynamic character due to changing physicochemical conditions of the environment and corroding metal surface. Most of actually used methods are stationary or contain assumptions which highly influences obtained values. Development of new dynamic method, based on modified EIS, allows...
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Launch of the Immersive 3D Visualization Laboratory
PublikacjaThe paper presents the concept of Immersive 3D Visualization Laboratory, formed at the Faculty of Electronics, Telecommunications and Informatics at Gdańsk University of Technology under the project Gdańsk University of Technology's Modern auditoriums. The basic unit of this laboratory will be cubic CAVE (Cave Automatic Virtual Environment) enriched with spherical walk simulator. This device will allow the user unlimited walking,...