Filtry
wszystkich: 276
wybranych: 226
Wyniki wyszukiwania dla: HEMODYNAMICS
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On thermal stability of piezo-flexomagnetic microbeams considering different temperature distributions
PublikacjaBy relying on the Euler–Bernoulli beam model and energy variational formula, we indicate critical temperature causes in the buckling of piezo-flexomagnetic microscale beams. The corresponding size-dependent approach is underlying as a second strain gradient theory. Small deformations of elastic solids are assessed, and the mathematical discussion is linear. Regardless of the pyromagnetic effects, the thermal loading of the thermal...
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Sensitivity analysis of free torsional vibration frequencies of thin-walled laminated beams under axial load
PublikacjaThe paper addresses sensitivity analysis of free torsional vibration frequencies of thin-walled beams of bisymmetric open cross-section made of unidirectional fibre-reinforced laminate. The warping effect and the axial end load are taken into account. The consideration is based upon the classical theory of thin-walled beams of non-deformable cross-section. The first-order sensitivity variation of the frequencies is derived with...
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Adaptation of the arbitrary Lagrange–Euler approach to fluid–solid interaction on an example of high velocity flow over thin platelet
PublikacjaThe aim of this study is to analyse the behaviour of a thin plate with air flow velocities of 0.3–0.9 Ma. Data from the experiment and numerical tools were used for the analysis. For fluid–solid interaction calculations, the arbitrary Lagrange–Euler approach was used. The results of the measurements are twofold. The first one is the measurement of the flow before and after vibrating plate, i.e. pure flow plate, and the second consists...
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Studies on the solid-liquid equilibria and intermolecular interactions Urea binary mixtures with Sulfanilamide and Sulfacetamide
PublikacjaThe binary phase diagrams of Sulfanilamide-Urea (SN-U) and Sulfacetamide-Urea (SC-U) were measured using differential scanning calorimetry technique (DSC). Both examined mixtures were found to form simple binary eutectics. The limited miscibility in the solid state observed by DSC, proving inability of co-crystallization in new multi-molecular form, was also confirmed using PXRD and FTIR-ATR measurements of solid dispersions...
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On the correspondence between two- and three-dimensional Eshelby tensors
PublikacjaWe consider both three-dimensional (3D) and two-dimensional (2D) Eshelby tensors known also as energy–momentum tensors or chemical potential tensors, which are introduced within the nonlinear elasticity and the resultant nonlinear shell theory, respectively. We demonstrate that 2D Eshelby tensor is introduced earlier directly using 2D constitutive equations of nonlinear shells and can be derived also using the throughthe-thickness...
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Robust four-node elements based on Hu–Washizu principle for nonlinear analysis of Cosserat shells
PublikacjaMixed 4-node shell elements with the drilling rotation and Cosserat-type strain measures based onthe three-field Hu–Washizu principle are proposed. In the formulation, apart from displacement and rotationfields, both strain and stress resultant fields are treated as independent. The elements are derived in the frame-work of a general nonlinear 6-parameter shell theory dedicated to the analysis of multifold irregular shells.The...
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A continual model of a damaged medium used for analyzing fatigue life of polycrystalline structural alloys under thermal–mechanical loading
PublikacjaThe main physical laws of thermal–plastic deformation and fatigue damage accumulation processes in polycrystalline structural alloys under various regimes of cyclic thermal–mechanical loading are considered. Within the framework of mechanics of damaged media, a mathematical model is developed that describes thermal–plastic deformation and fatigue damage accumulation processes under low-cycle loading. The model consists of three...
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On existence and uniqueness of weak solutions for linear pantographic beam lattices models
PublikacjaIn this paper, we discuss well-posedness of the boundary-value problems arising in some “gradientincomplete” strain-gradient elasticity models, which appear in the study of homogenized models for a large class ofmetamaterials whosemicrostructures can be regarded as beam lattices constrained with internal pivots. We use the attribute “gradient-incomplete” strain-gradient elasticity for a model in which the considered strain energy...
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Excess molar volume and viscosity deviation for binary mixtures of gamma-butyrolactone with dimethyl sulfoxide
PublikacjaThe densities of binary liquid mixtures of dimethyl sulfoxide and gamma-butyrolactone at (293.15, 298.15, 303.15 and 313.15) K and viscosity at T=298.15 K have been measured at atmospheric pressure over theentire range of concentration. From these data the excess molar volumes VE at (293.15, 298.15, 303.15 and 313.15) K and the viscosity deviation, the excess entropy, and the excess Gibbs energy of activation for viscous flow at...
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A model of damaged media used for describing the process of non-stationary creep and long-term strength of polycrystalline structural alloys
PublikacjaThe main laws of the processes of creep and long-term strength of polycrystalline structural alloys are considered. From the viewpoint of continuum damaged media (CDM), a mathematical model is developed that describes the processes of viscoplastic deformation and damage accumulation under creep. The problem of determining material parameters and scalar functions of the developed constitutive relations based on the results of specially...
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Cavity-expansion approximation for projectile impact and penetration into sand
PublikacjaA one-dimensional problem of a spherical cavity expanding at a constant velocity from zero initial radius in an infinite granular medium, which has the first-kind self-similar solution, is considered. We are solving this dynamic spherical cavity-expansion problem to model rigid spheres penetrating into a granular media. Elastic–plastic deformation of the granular media is described in a barotropic approximation, using the high-pressure...
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Nonlinear free and forced vibrations of a dielectric elastomer-based microcantilever for atomic force microscopy
PublikacjaThe majority of atomic force microcode (AFM) probes work based on piezoelectric actuation. However, some undesirable phenomena such as creep and hysteresis may appear in the piezoelectric actuators that limit their applications. This paper proposes a novel AFM probe based on dielectric elastomer actuators (DEAs). The DE is modeled via the use of a hyperelastic Cosserat model. Size effects and geometric nonlinearity are included...
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Extended micropolar approach within the framework of 3M theories and variations thereof
PublikacjaAs part of his groundbreaking work on generalized continuum mechanics, Eringen proposed what he called 3M theories, namely the concept of micromorphic, microstretch, and micropolar materials modeling. The micromorphic approach provides the most general framework for a continuum with translational and (internal) rotational degrees of freedom (DOF), whilst the rotational DOFs of micromorphic and micropolar continua are subjected...
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Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide
PublikacjaIn this work, densities, speeds of sound, refractive indices and viscosities of three binary mixtures containing the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexyl-ammonium bis(trifluoromethylsulfonyl)imide, mixed with 2-propanol at wide temperature and composition ranges at atmospheric pressure have been measured. From these...
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Structural response of existing spatial truss roof construction based on Cosserat rod theory
PublikacjaPaper presents the application of the Cosserat rod theory and newly developed associated finite elements code as the tools that support in the expert-designing engineering practice. Mechanical principles of the 3D spatially curved rods, dynamics (statics) laws, principle of virtual work are discussed. Corresponding FEM approach with interpolation and accumulation techniques of state variables are shown that enable the formulation...
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Nonlinear finite element modeling of vibration control of plane rod-type structural members with integrated piezoelectric patches
PublikacjaThis paper addresses modeling and finite element analysis of the transient large-amplitude vibration response of thin rod-type structures (e.g., plane curved beams, arches, ring shells) and its control by integrated piezoelectric layers. A geometrically nonlinear finite beam element for the analysis of piezolaminated structures is developed that is based on the Bernoulli hypothesis and the assumptions of small strains and finite...
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Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies
PublikacjaDensity and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl- morpholinium cations: N-ethyl- -methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-Nmethylmorpholinium bis(trifluoromethanesulfonyl)imide, N-octyl-N-methyl -morpholinium bis(trifluor omethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in N, N-dimethylformamide and N,N-dimethylacetamide were...
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Pantographic metamaterials: an example of mathematically driven design and of its technological challenges
PublikacjaIn this paper, we account for the research efforts that have been started, for some among us, already since 2003, and aimed to the design of a class of exotic architectured, optimized (meta) materials. At the first stage of these efforts, as it often happens, the research was based on the results of mathematical investigations. The problem to be solved was stated as follows: determine the material (micro)structure governed by those...
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Selected local stability problems of channel section flanges made of aluminium alloys
PublikacjaThe paper addresses the issue of local buckling of compressed flanges of cold-formed thin-walled channel columns and beams with nonstandard flanges composed of aluminium alloys. The material behaviour follows the Ramberg–Osgood law. It should be noted that the proposed solution may be also applied for other materials, for example: stainless steel, carbon steel. The paper is motivated by an increasing interest in nonstandard cold-formed...
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Limiting Partial Molar Volumes of Tetra-n-Alkylammonium Perchlorates in N,N-dimethylacetamide, Triethylphosphate and Dimethyl Sulfoxide at 298.15 K
PublikacjaThe densities of tetraalkylammonium perchlorates R4NClO4(R = methyl, or ethyl, or propyl, or butyl) and ammonium perchlorate solutions in N, N - dimethylacetamide, dimethyl sulfoxide, and triethylphosphate have been measured over the whole composition range atT = 298.15 K. From these densities, apparent and limiting partial molar volumes of the electrolytes and ions...
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublikacjaDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Copper(II) coordination properties of GxG peptides: Key role of side chains of central residues on coordination of formed systems; combined potentiometric and ITC studies
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Apparent molar volumes and compressibilities of selected electrolytes in dimethylsulfoxide
PublikacjaDensities at T = (293.15, 298.15, 303.15, 313.15, 323.15, and 333.15) K and sound velocities at T = 298.15 K of tetraphenylphosphonium bromide, sodium tetraphenylborate, sodium bromide, and sodium perchlorate in dimethylsulfoxide have been measured over the composition range from (0 to 0.3) mol kg1. From these data, apparent molar volumes and apparent molar isentropic compressibilitiesat infinite dilution as well as the expansibilities...
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Apparent molar volumes and compressibilities of alkaline earth metal ions in methanol and dimethylsulfoxide
PublikacjaTemperature dependencies of density of magnesium (II), calcium (II), strontium (II), barium (II) perchlorates as well as beryllium (II), and sodium trifluoromethanesulfonates in methanol and dimethylsulfoxide have been determined over the composition range studied. From density data the apparent molar volumes and partial molar volumes of the salts at infinite dilution as well as the expansibilities have been evaluated. The apparent...
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Apparent molar volumes and compressibilities of tetrabutyl-ammonium bromide in organic solvents
PublikacjaW oparciu o pomiary gęstości i szybkości rozchodzenia się dźwięku w niewodnych roztworach bromku czterobutyloamoniowego obliczono pozorne objętości molowe w przedziale temperatur od 288,15 K do 323,15 K oraz pozorne ściśliwości w temperaturze 298,15 K. Graniczne wielkości pozornej objętości molowej i ściśliwości wyznaczono w oparciu o równanie Massona, jak i równanie Redlicha, Rosenfelda i Mayera oraz z wykorzystaniem teorii Pitzera....
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Solvation of multivalent cations in methanol - apparent molar volumes, expansibilities, and isentropic compressibilities
PublikacjaWyznaczono gęstości roztworów trifluorometanosulfonianów galu, itru, lantanu, gadolinu i lutetu w metanolu w zakresie temperatur (283.15 to 313.15) K. Zmierzono prędkości dźwięku dla tych układów w temperaturze T = 298.15 K. Z uzyskanych danych wyznaczono standardowe cząstkowe objętości molowe i ich pochodne temperaturowe oraz standardowe cząstkowe molowe ściśliwości adiabatyczne badanych jonów. Wyniki omówiono stosując klasyczny...
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Excess volumes of mixing in (N,N-Dimethylacetamide+methanol+water) and (N,N-Dimethylacetamide+ethanol+water) at the temperature 313.15 K
PublikacjaW pracy podane są rezultaty precyzyjnych pomiarów namiarowych objętości molowych dla dwóch układów trójskładnikowych zawierających wodę, amid alifatyczny (N,N-dimetyloacetamid) oraz alkohol: metanol lub etanol. Dla wszystkich badanych układów obserwowane są duże i ujemne wartości nadmiarowych objętości mieszania, wskazujące na obecność silnych oddziaływań międzycząsteczkowych.
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(Vapour + liquid) equilibrium in (n,n-dimethylacetamide + ethanol + water) at the temperature 313.15 K
PublikacjaW pracy prezentowane są pomiary całkowitej prężności pary dla tytułowego układu trójskładnikowego oraz dla składowych układów binarnych. Uzyskane w pracy wyniki porównane zostały z wcześniejszymi danymi dla podobnych układów. Znaleziono w przybliżeniu liniową zależność pomiędzy wartościami nadmiarowej entalpii swobodnej Gibbsa a objętością molową amidu, spełnianą w układach dwuskładnikowych: amid + alkohol alifatyczny.
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Limiting partial molar volumes and expansibilities of ammonium perchlorate, tetraalkylammonium perchlorates, and tetrabutylammonium tetraphenylborate in N,N-dimethylformamide
PublikacjaWyniki pomiarów gęstości i szybkości rozchodzenia się dźwięku w roztworach nadchloranu amonu, nadchloranów alkiloamoniowych i tetrafenyloboranu tetrabutylomoniowego w N,N-dimetyloformamidzie wyznaczono wartości graniczne cząstkowych molowych objętości i rozszerzalności. Dokonano rozdziału tych wartości na udziały jonowe. Przeanalizowano wpływ temperatury oraz długości łańcucha na te wielkości.
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Thermophysical properties and phase equilibria study of the binary systems {N-hexylquinolinium bis(trifluoromethylsulfonyl)imide+aromatic hydrocarbons, or an alcohol}
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Excess Gibbs energies and excess molar volumes for binary mixtures: (2-pyr-rolidone+water), (2-pyrrolidone+methanol), and (2-pyrrolidone+ethanol) at the temperature 313.15K
PublikacjaZmierzono całkowite prężności pary oraz zmiany objętości mieszania dla tytułowych układów dwuskładnikowych w temperaturze 313.15K. Rezultaty zostały porównane z wynikami uzyskanymi poprzednio dla pozostałych amidów N-metylofor-mamidu, N,N-dimetyloformamidu oraz N-metyloacetamidu.
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(Vapour and liquid) equilibrium in (N,N-dimethylacetamide+methanol+water) at the temperature 313.15 K.
PublikacjaPraca zawiera wyniki pomiarów całkowitej prężności pary dla tytułowego układu trójskładnikowego oraz dla ''składowych'' układów binarnych. Wyniki obliczeń nadmiarowej energii swobodnej mieszania dla układów (N,N-dimetyloaceta-mid+woda) i (N,N-dimetyloacetamid+metanol) porównane zostały z rezultatami uzyskanymi wcześniej dla innych układów (amid+metanol) oraz (amid+woda). Znaleziono interesującą zależność wartości nadmiaru...
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Bending analysis of functionally graded nanoplates based on a higher-order shear deformation theory using dynamic relaxation method
PublikacjaIn this paper, bending analysis of rectangular functionally graded (FG) nanoplates under a uniform transverse load has been considered based on the modified couple stress theory. Using Hamilton’s principle, governing equations are derived based on a higher-order shear deformation theory (HSDT). The set of coupled equations are solved using the dynamic relaxation (DR) method combined with finite difference (FD) discretization technique...
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Understanding the interactions between protein stabilizers and the peptide bond through the analysis of the volumetric and compressibility properties for the model systems
PublikacjaThis work confirms our earlier supposition, that volumetric and acoustic parameters for simple model proposed by us are directly related to stabilizing/destabilizing effect of osmolytes on proteins structure. The apparent molar volumes, V and the apparent molar isentropic compressions, KS,, of glycine and N,N,N –trimethylglycine (betaine) were determined from densities and speed of sound measurements in aqueous solution of N-methylacetamide...
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Computational analysis of an infinite magneto-thermoelastic solid periodically dispersed with varying heat flow based on non-local Moore–Gibson–Thompson approach
PublikacjaIn this investigation, a computational analysis is conducted to study a magneto-thermoelastic problem for an isotropic perfectly conducting half-space medium. The medium is subjected to a periodic heat flow in the presence of a continuous longitude magnetic field. Based on Moore–Gibson–Thompson equation, a new generalized model has been investigated to address the considered problem. The introduced model can be formulated by combining...
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On nonlinear dilatational strain gradient elasticity
PublikacjaWe call nonlinear dilatational strain gradient elasticity the theory in which the specific class of dilatational second gradient continua is considered: those whose deformation energy depends, in an objective way, on the gradient of placement and on the gradient of the determinant of the gradient of placement. It is an interesting particular case of complete Toupin–Mindlin nonlinear strain gradient elasticity: indeed, in it, the...
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Flexomagneticity in buckled shear deformable hard-magnetic soft structures
PublikacjaThis research work performs the first time exploring and addressing the flexomagnetic property in a shear deformable piezomagnetic structure. The strain gradient reveals flexomagneticity in a magnetization phenomenon of structures regardless of their atomic lattice is symmetrical or asymmetrical. It is assumed that a synchronous converse magnetization couples both piezomagnetic and flexomagnetic features into the material structure....
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Thermal buckling of functionally graded piezomagnetic micro- and nanobeams presenting the flexomagnetic effect
PublikacjaGalerkin weighted residual method (GWRM) is applied and implemented to address the axial stability and bifurcation point of a functionally graded piezomagnetic structure containing flexomagneticity in a thermal environment. The continuum specimen involves an exponential mass distributed in a heterogeneous media with a constant square cross section. The physical neutral plane is investigated to postulate functionally graded material...
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On the exact equilibrium conditions of irregular shells reinforced by beams along the junctions
PublikacjaThe exact, resultant equilibrium conditions for irregular shells reinforced by beams along the junctions are formulated. The equilibrium conditions are derived by performing direct integration of the global equilibrium conditions of continuum mechanics. New, exact resultant static continuity conditions along the singular curve modelling reinforced junction are presented. The results do not depend on shell thickness, internal through-the-thickness...
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Influence of temperature and anion type on thermophysical properties of aqueous solutions of morpholine based amino acid ionic liquids
PublikacjaDensities and sound velocities of aqueous solutions of N-butyl-N-methylmorpholine based amino acid ionic liquids (AAILs), including N-acetyl-L-alanine, N-acetyl-Lvalinate, N-acetyl-L-leucinate, and N-acetyl-L-izoleucinate anions were measured at a temperature from 293.15 to 313.15 K at 5 K intervals and atmospheric pressure. These data were used to calculate the apparent molar volumes and the apparent molar compressibilities in...
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Thermomagnetic behavior of a semiconductor material heated by pulsed excitation based on the fourth-order MGT photothermal model
PublikacjaThis article proposes a photothermal model to reveal the thermo-magneto-mechanical properties of semiconductor materials, including coupled diffusion equations for thermal conductivity, elasticity, and excess carrier density. The proposed model is developed to account for the optical heating that occurs through the semiconductor medium. The Moore–Gibson–Thompson (MGT) equation of the fourth-order serves as the theoretical framework...
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Fluid–solid interaction on a thin platelet with high-velocity flow: vibration modelling and experiment
PublikacjaThe paper concerns the nonlinear behaviour of a thin platelet that is streamlined in an aerodynamic tunnel. The air velocity in the aerodynamic tunnel was at 858.9 km/h or 0.7 Ma (Ma—Mach number is a dimensionless quantity in fluid dynamics representing the ratio of flow velocity past a boundary to the local speed of sound). This experiment was numerically simulated using FSI (fluid–solid interaction) tools, namely the coupling...
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Densimetric and ultrasonic characterization of pentaerythritol in water and in aqueous NaCl and MgCl2 solutions at different temperatures
PublikacjaZmierzono gęstości dla serii roztworów pentaerytritolu w czystej w wodzie jak i w wodnych roztworach NaCl i MgCl2 zawierających stałą ilość soli. Pomiary wykonano dla trzech różnych zawartości NaCl i MgCl2 w sześciu rożnych temperaturch w przedziale od 20oC do 40oC. Ponadto wyznaczono szybkości rozchodzenia się dźwięku w przygotowanych roztworach dla dwóch temperatur (25 i 37oC). W oparciu o uzyskane wielkości obliczono pozorne...
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Apparent molar volumes and compressibilities of electrolytes and ions in gamma-butyrolactone
PublikacjaW oparciu o zmierzone wartości gęstości roztworów i rozpuszczalnika w temperaturach od 15 do 40oC wyznaczono pozorne molowe objętości bromku litu, nadchloranu litu, nadchloranu sodu, tetrafenyloboranu sodu oraz bromku tetrafenylofosfoniowego w gamma-butyrolaktonie. Ponadto, wyznaczone prędkości rozchodzenia się dźwięku w 25oC w badanych układach pozwoliły obliczyć pozorne molowe ściśliwości wybranej grupy soli. Uzyskane (w wyniku...
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Solvation of ionic liquids based on N-methyl-N-alkyl morpholinium cations in dimethylsulfoxide – volumetric and compressibility studies
PublikacjaThe density and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octyl-morpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in dimethylsulfoxide were measured at T = (298.15 to 318.15)...
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Effect of temperature and ionic strength on volumetric and acoustic properties of solutions of urea alkil derivatives in aqueous NaCl
PublikacjaThe present work was undertaken to study volumetric and acoustic properties for diluted solutions of tetramethylurea in pure water and for urea, n-propylurea, n-butylurea and tetramethylurea in 0.5 or 1 moldm3 aqueous solutions of sodium chloride. This paper presents measured values of densities and sound velocities at T = (288.15, 298.15 and 308.15) K. From these data the apparent molar volumes, , adiabatic compressibilities,...
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Solvation of ionic liquids based on N-alkyl-N-methylmorpholinium cations in N,N-dimethylformamide and dimethyl sulfoxide – A volumetric and acoustic study
PublikacjaApparent molar volumes and molar isentropic compressibilities for N-ethyl-N-methylmorpholinium and N-decyl-N-methylmorpholinium tetrafluoroborates in N,N-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) have been determined from density and speed of sound measurements over the temperature range T = (298.15, 303.15, 308.15, 313.15, 318.15 and 328.15) K at experimental pressure p = 0.1 MPa. This data has been used to calculate...
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Densimetric and ultrasonic characterization of urea and its derivatives in water
PublikacjaW oparciu o pomiary gęstości dla serii roztworów jak i rozpuszczalnika wykonanych w temperaturach 15, 20, 25, 30 i 35oC wyznaczono pozorne molowe objętości mocznika, N-metylomocznika, N,N'-dimetylomocznika, N,N,N',N'-tetrametylomocznika, N-etylomocznika, N,N'-dietylomocznika jak i N-butylomocznika w wodzie. Dodatkowe pomiary szybkości dźwięku przeprowadzone w temperaturze 25oC pozwoliły obliczyć ściśliwości adiabatyczne, pozorne...
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Apparent molar volumes and compressibilities of lanthanum, gadolinium, lutetium and sodium trifluoromethanesulfonates in N,N-dimethylformamide and N,N-dimethylacetamide
PublikacjaZmierzono gęstości roztworów trifluorometanosulfonianów lantanu, gadolinu i lutetu w N,N-dimetyloformamidzie i N,N-dimetyloacetamidzie w szerokim zakresie temperatur. W oparciu o uzyskane wartości gęstości wyznaczono pozorne objętości molowe, cząstkowe objętości molowe oraz rozszerzalności izobaryczne. Dodatkowo zmierzono szybkości rozchodzenia się dźwięku w badanych roztworach w 298,15 K i wyznaczono pozorne ściśliwości molowe...
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Apparent Molar Volumes and Compressibilities of Lanthanum, Gadolinium and Lutetium trifluoromethanesulfonates in Dimethylsulfoxide
PublikacjaZmierzono gęstości roztworów trifluorometanosulfonianów lantanu, gadolinu i lutetu w dimetylosulfotlenku w zakresie temperatur 293,15 -333,15 K. W oparciu o uzyskane wartości gęstości wyznaczono pozorne objętości molowe, cząstkowe objętości molowe oraz rozszerzalności izobaryczne. Dodatkowo zmierzono szybkości rozchodzenia się dźwięku w badanych roztworach w 298,15 K i wyznaczono pozorne ściśliwości molowe trifluorometanosulfonianów...