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Search results for: high pressure chemistry
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Deep eutectic solvents microbial toxicity: Current state of art and critical evaluation of testing methods
PublicationDeep eutectic solvents (DESs) were described at the beginning of 21st century and they consist of a mixture of two or more solid components, which gives rise to a lower melting point compared to the starting materials. Over the years, DESs have proved to be a promising alternative to traditional organic solvents and ionic liquids (ILs) due to their low volatility, low inflammability, easy preparation, and usually low cost of compounds...
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Deep eutectic solvents – A new platform in membrane fabrication and membrane-assisted technologies
PublicationDeep eutectic solvents (DESs) are a new class of solvents that can offset some of the primary drawbacks of typical solvents and ionic liquids (ILs). Since DESs fall into the guidelines of “Twelve Principles of Green Chemistry”, their implementation in several types of applications has exponentially increased over the last years. The usage of DESs has been directed to the designing, manufacture and purification of new materials...
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Twenty‐four‐hour and conventional blood pressure components and risk of preterm delivery or neonatal complications in gestational hypertension
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Urgent need to address quality control issues of out‐of‐office blood pressure measurement and patient risk assessment
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Elevated ambulatory systolic-diastolic pressure regression index is genetically determined in hypertensive patients with coronary heart disease
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Influence of hydrogen on a nanocrystalline high-entropy oxide with application potential in hydrogen technologies
PublicationThe influence of hydrogen on a (Co0⋅2Cu0⋅2Mg0⋅2Ni0⋅2Zn0.2)O HEO with a rock salt structure was studied. Two forms of this HEO (nanopowder and sinter) were prepared via mechanochemical synthesis (MS) and additional heat treatment, respectively. The chemical stability of the synthesized samples in a pure hydrogen atmosphere was investigated using Sievert’s technique. High-pressure hydrogenation at 250 ◦C had no noticeable effect...
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Pressure-induced superconductivity in CaFe2As2
PublicationNowo odkryty związek CaFe2As2 pod wpływem zewnętrznego ciśnienia 0.69 GPa przechodzi w stan nadprzewodnictwa z temperaturą krytyczną powyżej 10K.
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Signature of Hydrodynamic Pressure Field
PublicationW artykule przedstawiono wyniki obliczeń pola hydrodynamicznego ciśnienia wokół okrętu specjalnego jako funkcji przestrzennej, obliczonej metodą brzegową. Obliczone pola ćiśnienia hydrodynamicznego jest porównywane z pomierzonym polem okrętu na morzu, przy czym opis kształtu kadłuba okrętu jest przybliżony. Przedstawione wyniki obliczeń uzyskano stosując warstwę pojedynczą , którą stanowią źródła o rozkładzie ciągłym. Skonstruowany...
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Pressure field in a plane layer
PublicationPraca prezentuje wyniki badań teoretycznych i numerycznych zagadnienia przejścia fal płaskich przez warstwę. Omówiono zagadnienie tworzenia i rozchodzenia się fal w poszczególnych warstwach. Zaproponowano model matematyczny opisujący zmiany ciśnienia wewnątrz warstwy. Analizowano ciśnienie wewnątrz warstwy, fale bieżące i odbite wewnątrz warstwy oraz w ośrodku otaczającym. Przedstawiono wyniki badań numerycznych.
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Signature of Hydrodynamic Pressure Field
PublicationW artykule przedstawiono wyniki obliczeń pola hydrodynamicznego ciśnienia wokół statku jako funkcję przestrzenną, obliczoną metodą brzegowego rozkładu osobliwości. Obliczone pole ciśnienia hydrodynamicznego jest porównywane z pomierzonym polem ciśnienia wokół okrętu na akwenie specjalnym, opis kształtu kadłuba jest przybliżony. Przedstawione wyniki obliczeń uzyskano stosując pojedynczą warstwę o ciągłym rozkładzie źródłowości....
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How does stakeholder pressure influence CSR-practices? A construction industry model based on a European sample
PublicationThe stakeholder pressure is one of the most vital powers which determines CSR implementation and can provide organizations with the motivation to adopt corporate social responsibility (CSR) strategy, as the stakeholder theory claims. The current investigation replications Kowalczyk’s (2019) study, who examined the same structure of relations based on the Polish sample. The essence of this replication is to find out whether CSR-...
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Relationships between stakeholder pressure, culture, and CSR-practices in the context of project management in the construction industry in Poland
PublicationThe study aims to investigate how CSR-stakeholder pressure, CSR-company culture, and CSR-practices are related to one another based on the example of the construction industry in Poland. This knowledge will make it possible to assess which of the two factors, i.e., stakeholder culture or the internal company culture have a stronger effect on the CSR-practices. To accomplish the goal of the study a sample composed of 216 cases was...
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Weldability of high strength steel in underwater environment
PublicationThe article describes the problems with weldability of high-strength steels in the aquatic environment. The tendency of steel S355J2G3 and S500M to form cold cracks when welded in wet welding conditions has been experimentally evaluated. It was found that the tested steels have a high propensity to cracking. An experiment has been proposed and tested to evaluate the usefulness of the tempering bead technique as a method of improving...
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The influence of stainless steels microstructure evolution on the mechanical properties of pressure installation elements
PublicationIn this paper results of FEM analysis performed for pipe and 90o elbow, made of super duplex stainless steel, after precipitation of sigma phase (),were presented. Heat treatment conditions simulate accidental overheating that can occur in nuclear installations after cooling circulation fails. For initial and modified microstructure tensile test was performed and numerical description of work hardening curves was done. Verification...
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The influence of stainless steels microstructure evolution on the mechanical properties of pressure installation elements
PublicationIn this paper results of FEM analysis performed for pipe and 90o elbow, made of super duplex stainless steel, after precipitation of sigma phase (s), were presented. Heat treatment conditions simulate accidental overheating that can occur in nuclear installations after cooling circulation fails. For initial and modified microstructure tensile test was performed and numerical description of work hardening curves was done. Verification...
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Masked hypertension in type 2 diabetes: never take normotension for granted and always assess out-of-office blood pressure
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The J-curve phenomenon revisited again: SPRINT outcomes favor target systolic blood pressure below 120 mmHg
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Numerical analysis of high temperature minichannels heat exchanger performance
PublicationNowadays, the most difficult technological challenge in energy sector is connected with the gas micro-CHP units, dedicated to the distributed power generation. They are expected to be of high efficiency and at the same time of compact in size. Regarding the first reason, significant increase in microturbine efficiency can only be achieved by increase in the engine operating temperature. Therefore, one of the critical elements in...
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FEM simulations applied to the failure analysis of RC structure under the influence of municipal sewage pressure
PublicationThe paper discusses a failure mechanism of reinforced concrete (RC) structure with steel cover that failed under the influence of municipal sewage pressure. To explain the reasons of failure, in-situ measurements, laboratory experiments and comprehensive Finite Element Method (FEM) computations were performed. Non-destructive in-situ scanning tests were carried out to determine quantity and cover thickness of embedded reinforcement...
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Application of chemometric approach in studies of dew chemistry (on the basis of samples collected in Poland)
PublicationPrzedstawiono wyniki badań wybranych związków chemicznych (aniony, kationy, formaldehyd, nadtlenek wodoru, suma fenoli, TC, TIC, TOC) oznaczonych w próbkach rosy zebranych z różnych obszarów na terenie Polski (Gdynia, Gdańsk, Sopot, Mława, Kraków). Zastosowano analizę funkcji dyskryminacyjnej aby dokonać klasyfikacji poszczególnych próbek w zależności od miejsca pobierania oraz wykryć podstawowe zależności pomiędzy poszczególnymi...
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Development of sensitive cathepsin G fluorogenic substrate using combinatorial chemistry methods
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A simple method for selection of trypsin chromogenic substrates using combinatorial chemistry approach
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Intermolecular Interactions of Edaravone in Aqueous Solutions of Ethaline and Glyceline Inferred from Experiments and Quantum Chemistry Computations
PublicationEdaravone, acting as a cerebral protective agent, is administered to treat acute brain infarction. Its poor solubility is addressed here by means of optimizing the composition of the aqueous choline chloride (ChCl)-based eutectic solvents prepared with ethylene glycol (EG) or glycerol (GL) in the three different designed solvents compositions. The slurry method was used for spectroscopic solubility determination in temperatures...
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A coordination chemistry study of hydrated and solvated cationic vanadium ions in oxidation states +III, +IV, and +V in solution and solid state
PublicationPrzedmiotem studiów jest chemia koordynacyjna solwatów jonów wanadu(III), oksowanadu(IV) jaki i dioksowanadu(V) w rozpuszczalnikach tlenowo-donorowych takich jak: woda, dimetylosulfotlenek (DMSO) oraz N,N'-dimetylopropylenomocznik (DMPU). Badania prowadzone były w roztworach ciekłych jak i w fazie stałej z wykorzystaniem absorpcji (EXAFS), rozproszenia (LAXS) jak i dyfrakcji promieniowania X. Analiza uzyskanych wyników wskazuje,...
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The innovative experimental rig for wood steam drying at atmospheric pressure
PublicationThe high cost of fossil fuel and soaring consumer interest have encouraged people in the wood industry to look for faster and more energy-efficient methods to dry lumber. The air-steam mixture as medium of drying process was used in a laboratory kiln especially arranged for that reason. Experimental rig is based on automatic control system. At the time of drying measurements of the internal temperature, wood temperature, moisture...
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublicationNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Solventless and solvent-minimized sample preparation techniques for determining currently used pesticides in water samples: A review
PublicationThe intensification of agriculture means that increasing amounts of toxic organic and inorganic compounds are entering the environment. The pesticides generally applied nowadays are regarded as some of the most dangerous contaminants of the environment. Their presence in the environment, especially in water, is hazardous because they cause human beings to become more susceptible to disease. For these reasons, it is essential to...
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High temperature proton conduction in LaSbO4
PublicationLanthanum orthoantimonate was synthesized using a solid‐state synthesis method. To enhance the possible protonic conductivity, samples with the addition of 1 mol% Ca in La‐site, were also prepared. The structure was studied by the means of X‐ray diffraction, which showed that both specimens were single phase. The materials crystallized in the space group P2 1 /n. Dilatometry revealed that material expands non‐linearly with the...
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Biological Effects of Cold Atmospheric Pressure Plasma on Skin Cancer
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H2O˙+ and OH+ reactivity versus furan: experimental low energy absolute cross sections for modeling radiation damage
PublicationRadiotherapy is one of the most widespread and efficient strategies to fight malignant tumors. Despite its broad application, the mechanisms of radiation-DNA interaction are still under investigation. Theoretical models to predict the effects of a particular delivered dose are still in their infancy due to the difficulty of simulating a real cell environment, as well as the inclusion of a large variety of secondary processes. This...
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Continuous blood pressure monitoring by photoplethysmography - signal preprocessing requirements based on blood flow modelling
PublicationObjective. The aim of the study is to investigate the effect of the signal sampling frequency and low-pass filtering on the accuracy of the localisation of the fiducial points of the photoplethysmographic signal (PPG), and thus on the estimation of the blood pressure (i.e. the accuracy of the estimation). Approach. Statistical analysis was performed on 3,799 data samples taken from a publicly available database. Four PPGfiducial...
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Non-invasive hemodynamic monitoring as a guide to drug treatment of uncontrolled hypertensive patients: effects on home blood pressure in the BEAUTY study
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A novel in vivo approach to assess strains of the human abdominal wall under known intraabdominal pressure
PublicationThe study concerns mechanical behaviour of a living human abdominal wall. A better mechanical understanding of a human abdominal wall and recognition of its material properties is required to find mechanically compatible surgical meshes to significantly improve the treatment of ventral hernias. A non-invasive methodology, based on in vivo optical measurements is proposed to determine strains of abdominal wall corresponding to...
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Review on mechanisms and efficiency of removal of microbiological contaminants in constructed wetlands
PublicationConstructed wetlands (CW) have been considered as a waste and a stormwater treatment systems for small communities or for areas with unsteady sewage flow conditions. Several investigations were undertaken for estimation suspended solids, organic matter and nutrients efficiency removal but only few focused on retention of microorganisms in constructed wetlands. In this review mechanisms of elimination of viruses, indicator bacteria...
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Molecular Design Using Selected Concentration Effects in Optically Activated Fluorescent Matrices
PublicationMolecular physics plays a pivotal role in various fields, including medicine, pharmaceuticals, and broader industrial applications. This study aims to enhance the methods for producing specific optically active materials with distinct spectroscopic properties at the molecular level, which are crucial for these sectors, while prioritizing human safety in both production and application. Forensic science, a significant socio-economic...
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Application of Nanomaterials for Cadmium Adsorption for Sustainable Treatment of Wastewater: a Review
PublicationMany heavy metals, particularly cadmium, are detrimental to both people and the environment when present in large quantities. In wastewater treatment plants, several conventional approaches are employed for cadmium abatement to restore the ecosystem, food supplies, and health of people and animals. Ion exchange, coagulation, membrane filtration, and chemical precipitation are a few examples of ways for removing heavy metals from...
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Exploring thiophene-2-acetate and thiophene-3-acetate binding modes towards the molecular and supramolecular structures and photoluminescence properties of Pb(ii) polymers
PublicationTo evaluate the impact of the flexible positional isomeric ligands thiophene-2-acetate (2tpacCOO) andthiophene-3-acetate (3tpacCOO) on the construction and self-assembly process of Pb(II) polymers, twonovel compounds, [Pb(2tpacCOO)2(H2O)]n(1) and [Pb(3tpacCOO)2]n(2), were preparedviaanonhydro-thermal method with respect to green chemistry rules. The obtained polymers were fully characterized byelemental analysis, TG/DTG and PXRD,...
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An experimental study of high-hydrogen welding processes
PublicationThis paper presents investigation results of determination of the diffusible hydrogen content in deposited metal obtained by means of two most often used methods-the glycerin method and the mercury method. Relation has been defined between results of those methods in the area characteristic of low-hydrogen as well as high-hydrogen welding processes. Relations available in the literature do not include the diffusible hydrogen content...
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Foreign Entry Modes of High-tech Firms in Poland
PublicationThe main objective of the article is to present the role and importance of foreign entry modes in internationalization process and their key determinants. Research methods: A quantitative research design was used. A survey was conducted on the sample of 263 firms operating in...
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Pressure evolution of LiBaF3:Eu2+luminescence
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Pressure dependence of the Sr2Si5N8:Eu2+ luminescence
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Pressure dependence of the emission in CaF2 : Yb2+
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Aging of silicone pressure-sensitive adhesives
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Blood pressure in acute ischemic stroke
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Noninvasive Measurement of Intracranial Pressure: Is It Possible?
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Taylor type predictor for pressure changes
PublicationCelem pracy jest ocena predykcji ciśnienia za pomocą rozwinięcia funkcji w szereg Taylora. Przewidywana wartość ciśnienia jest obliczana jako iloczyn wcześniejszych wartości mnożonych przez współczynniki wagowe wyznaczone w oparciu o szereg Taylora. Zaletą takiego podejścia jest możliwość analizy danych próbkowanych nierównomiernie. Podstawową wadą jest założenie, że ciśnienie jest dobrze aproksymowane przez wielomian niskiego...
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Transversal Pressure Effect in Circulative Separators
PublicationPrzeanalizowano podobieństwa i różnice między podstawowymi kategoriami separatorów odśrodkowych (wirówki, cyklony, separatory wirowe). Zaproponowano model pola prędkości w separatorze. Wyznaczono rozkład ciśnienia i obliczono siłę dryfu poprzecznego (efekt poprzecznej zmiany ciśnienia). Przeprowadzono pomiary ciśnienia w separatorze laboratoryjnym, uzyskując pozytywną weryfikację przedstawionego modelu.
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Systolic blood pressure control prevents cognitive decline and slows development of white matter lesions in the brain: the SPRINT MIND study outcomes
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HIGH TEMPERATURE HEAT PUMPS – PERSPECTIVE HEATING SYSTEMS?
PublicationIn the paper presented are authors own concepts of high temperature compressor heat pumps for the utilisation of medium and low temperature sources of heat. Working fluids for use in high temperature heat pumps are discussed, as well as the criteria for their selection. Analyses are presented for the production of in the upper steam source at 130 °C. One-stage systems and cascade systems were analyzed. An analysis of the coefficient...
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Elastic-contractile model proteins: Physical chemistry, protein function and drug design and delivery
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