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Search results for: CHLORIDE-INDUCED CORROSION
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Tailoring the electrochemical degradation of iron protected with polypyrrole films for biodegradable cardiovascular stents
PublicationThe degradation of polypyrrole (PPy) coated iron is studied in phosphate buffer saline solution at 37 °C by odd random phase multisine electrochemical impedance spectroscopy (ORP-EIS). PPy is electropolymerized with anti-inflammatory salicylates incorporated in the film, as a drug release system. The modelling of EIS over time provides the quantitative description of the corrosion behaviour of the material. Thus, the reliable...
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Study of anticorrosion and microwave absorption properties of NiZn ferrite pigments
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The effect of the temperature change rate on determination of the critical pitting temperature of stainless steels
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The impedance method of monitoring the degradation of rubber linings in applications where progressive deterioration is the predominant failure mechanism
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Durability evaluation of Ni‐Cr‐Mo super alloys in a simulated scrubbed flue gas environment
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Evaluation and characterisation of the condition of individual components of cathodic protection systems
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Electrochemical investigations of stainless steels used in flue‐gas desulphurization units
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The temperature dependencies of susceptibility of 654SMO and 316L stainless steels to pitting
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The determination and identification of stray current source influences on buried pipelines using time/frequency analysis
PublicationZaprezentowano metodę detekcji źródła interferencji prądów błądzących na rurociągach podziemnych w aglomeracjach miejskich z wykorzystaniem łącznej analizy czasowo-częstotliwościowej mierzonych sygnałów. Badania przeprowadzono na rurociągu podziemnym zlokalizowanym w sąsiedztwie dwóch trakcji elektrycznych: tramwajowej i kolejowej. Wyniki analiz zaprezentowano w formie spektrogramów, które ilustrują zmiany spektralnej gęstości...
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Localized impedance measurements of AA2024 and AA2024‐T3 performed by means of AFM in contact mode
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Detection and time/frequency analysis of electric fields in the ground
PublicationThis paper sets out to detect and characterize electric fields in the ground (such as stray current fields) using a tandem time/frequency method of signal analysis. Results were obtained from investigations performed in the presence of a generated electric field with controlled variable characteristics, and in the presence of an electric field generated by a tramline. The analysis of measurement registers was performed using Short‐Time...
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Cyclic analysis of thermal impedance of a passive layer of aluminium in a neutral borate buffer solution
PublicationW pracy przedstawiono wyniki badań warstwy pasywnej tworzącej się na stopie 1050 A w warunkach zmieniającej się temperatury. Zmiany realizowano w sposób cykliczny zwiększając a następnie zmniejszając temperaturę. W czasie zmian temperatury prowadzono badania metodę dynamicznej elektrochemicznej spektroskopii impedancyjnej. Stwierdzono największe zmiany parametrów elektrycznego schematu zastępczego w czasie pierwszego cyklu zmian....
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Studying the effectiveness of a modernized cathodic protection system for an offshore platform
PublicationPrzedstawiono dokonaną modernizację starego systemu ochrony katodowej nóg platformy morskiej oraz omówiono wykonane badania skuteczności przeciwkorozyjnej zastosowanego rozwiązania. Modernizacja polegała na podłączeniu do nóg platformy układów anod galwanicznych umieszczonych na dnie morza. Skuteczność działania systemu oceniono na podstawie pomiarów profili potencjałowych nóg platformy. Po podłączaniu kolejnych układów anod...
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Study of anticorrosion and microwave absprption properties of NiZn ferrite pigments
PublicationPurpose - The purpose of this paper is to report the electrochemical verification of anticorrosive properties of NiZn ferrites as pigments in protective coatings and evaluation of their microwave absorbing properties. Design/methodology/approach - Ferrites, represented by formula NixZn(1-x)Fe2O4, where x=0, 0.2, 0.4, 0.6, 0.8, 1.0, were synthesized using a ceramic method. The samples of ferrites were examined by X-ray diffraction...
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Study of the formation of calcareous deposits on cathodically protected steel in Baltic sea water
PublicationPurpose – The purpose of this paper is to investigate whether the sedimentation of calcareous deposits occurs on cathodically protected steel in Baltic sea water. Design/methodology/approach – Steel electrodes were cathodically polarized in natural Baltic sea water at potential þ0.150 V vs Zn electrode in potentiostatic mode. During exposure chronoamperometric measurements were carried out. After the exposure, the electrode’s surface...
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AFM-assisted investigation of conformal coatings in electronics
PublicationPurpose – This paper aims to presents a new method of investigation of local properties of conformal coatings utilized in microelectronics. Design/methodology/approach – It is based on atomic force microscopy (AFM) technique supplemented with the ability of local electrical measurements, which apart from topography acquisition allows recording of local impedance spectra, impedance imaging and dc current mapping. Potentialities...
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The effect of the temperature change rate on determination of the criticalpitting temperature of stainless steels
PublicationPrzedstawiono wyniki badań wpływu szybkości zmian temperatury na wyznaczaną krytyczną temperaturę korozji wżerowej. Badania stali 316L przeprowadzono metodą termometrii cyklicznej. Stwierdzono, że zwiększenie szybkości zmian temperatury związane jest ze zwiększeniem wyznaczonej temperatury krytycznej. Zależność krytycznej temperatury korozji wżerowej od szybkości korozji ma charakter liniowy. Wartości krytycznej temperatury korozji...
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The stationarity characteristics of electrochemical current noise
PublicationPrzedstawiono rezultaty analizy szumu elektrochemicznego generowanego podczas korozji stali 0H18N9 w roztworze 0.1 M H2SO4+0,006 M Cl-. Rejestry uzyskano w warunkach potencjostatycznych. W szumie zaobserwowano trendy i sygnały przejściowe, charakterystyczne dla korozji wżerowej. Trend został usunięty za pomocą aproksymacji wielomianem trzeciego stopnia. Analiza statystyczna wykazała niestacjonarny bądź słabo stacjonarny charakter...
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Conducting composites as cable anodes in cathodic protection: a literature summary
PublicationPrzedstawiono podstawową charakterystykę systemu ochrony katodowej z wykorzystaniem anod kablowych. Anody kablowe różnią się od klasycznych systemów anodowych sposobem instalacji anod. System anodowy oparty na anodach kablowych nie jest instalowany punktowo; anoda umieszczana jest w niewielkiej odległości od chronionej konstrukcji i biegnie wzdłuż trasy konstrukcji. Materiałem anodowym proponowanego rozwiązania jest elastyczny...
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Numerical Analysis of the Unsteady Propeller Performance in the Ship Wake Modified by Different Wake Improvement Devices
PublicationThe paper presents summary of numerical analysis of the unsteady propeller forces and induced pressure pulses generated by the selected real propeller of 7000 tons product tanker, operating in five different wakefields including four inflenced by the different wake improvement devices. The results of the analysis are partly compared with experimental data and univocal conclusions about the optimum wake improvement device are presented.
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Effect of temperature and composition on physical properties of deep eutectic solvents based on 2-(methylamino)ethanol – measurement and prediction
PublicationNovel deep eutectic solvents were synthesized using 2-(methylamino)ethanol as hydrogen bond donor with tetrabutylammonium bromide or tetrabutylammonium chloride or tetraethylammonium chloride as hydrogen bond acceptors. Mixtures were prepared at different molar ratios of 1:6, 1:8 and 1:10 salt to alkanolamine and then Fourier Transform Infrared Spectroscopy measurements were performed to confirm hydrogen bonds interactions between...
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Visible light photocatalytic activity of ionic liquid-TiO2 spheres: effect of the ionic liquid's anion structure
PublicationThe effect of the ionic liquid’s (IL) anion type ([BIMIM][X], where X= [Br], [PF6] or [OctSO4]) and content on the morphology, surface properties and photoactivity of TiO2 obtained by solvothermal method has been systematically investigated. Our results revealed that the presence of [Br], [OctSO4] anions favors formation of anatase phase, while presence of [PF6] anion causes formation of mixture of anatase and Ti(OH)PO4 phases....
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Numerical study on pounding between two adjacent buildings under earthquake excitation
PublicationSeismic excitation, which results in large horizontal relative displacements, may cause collisions between two adjacent structures due to insufficient separation distance between them. Such collisions, known as earthquake-induced structural pounding, may induce severe damages. In this paper, the case of pounding between two adjacent buildings is studied by the application of single degree-of-freedom structural models. Impact is...
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Comparison of calculated and measured thermal stresses in asphalt concrete
PublicationThe paper presents the comparison of calculated and measured thermal stresses induced in restrained asphalt concrete specimens by cooling. Thermal stresses were measured in the Thermal Stress Restrained Specimen Test. The calculations of thermal stresses were performed with the use of a theoretical formula based on the temperature dependent stiffness modulus. The novel approach applied in this paper was that the stiffness modulus...
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Investigations of Titanium Implants Covered with Hydroxyapatite Layer
PublicationTo reduce unfavorable phenomena occurring after introducing an implant into human body various modifications of the surface are suggested. Such modifications may have significant impact on biocompatibility of metallic materials. The titanium and it's alloys are commonly used for joint and dental implants due to their high endurance, low plasticity modulus, good corrosion resistance as well as biocompatibility. Special attention...
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Copper-based 2D-coordination polymer as catalyst for allylation of aldehydes
PublicationA copper-tartrate, [Cu2(Tart)2(H2O)2]·4H2O, was synthesized at room temperature in aqueous media using copper chloride and D-tartaric acid. The compound crystallizes in the monoclinic system P21 space group and was characterized by infrared spectroscopy, thermogravimetry, X-ray powder diffraction and the results are in good agreement with the single crystal...
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New bulk liquid membrane oscillator composed of two coupled oscillators with diffusion-mediated physical coupling
PublicationA new type of bulk liquid membrane system, which represents the first example of a bulk liquid membrane oscillator characterised by the presence of two coupled oscillators, is described. When the benzyldimethyltetradecylammonium chloride surfactant undergoes an oscillatory mass transfer through a nitromethane liquid membrane, a new liquid layer (phase X) appears between the membrane and the acceptor phase. Kinetic analysis provides...
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Validation of atmospheric aerosols sampling in equivalent fractions
PublicationPhysical properties and chemical composition of atmospheric aerosols are of extreme importance, in many fields of interest, namely the Environment even with legal implications. Atmospheric sampling poses inherent problems with consequent demands on sampling optimisation, with sampling strategies requiring validation. In this work a study was conducted aiming at validating the collection of atmospheric aerosols in equivalent fractions....
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Trwałość spawanych instalacji wodnych wykonanych z nierdzewnych stali austenitycznych
PublicationW artykule przedstawiono dwa przypadki przedwczesnych uszkodzeń spawanych instalacji wodnych wykonanych ze stali odpornych na korozję. W celu ustalenia przyczyn uszkodzenia instalacji przeprowadzono badania metalograficzne, makro - i mikroskopowe oraz mikroanalizę składu chemicznego EDS na próbkach pobranych z reprezentatywnych miejsc. Wykazano, że głównymi przyczynami awarii rurociągów wody pitnej były niezgodności spawalnicze,...
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Korozja i zniszczenia kształtowników stalowych o przekrojach zamkniętych
PublicationW artykule przedstawiono spotykany na obiektach budowlanych problem rozwoju korozji na wewnętrznych powierzchniach kształtowników zamkniętych eksploatowanych w środowisku zewnętrznym. Zachodzące wewnętrzne procesy korozyjne oraz towarzyszące im siły niszczące w związku z zamarzającą wewnątrz profili wodą, powodują utratę nośności i obniżenie bezpieczeństwa eksploatacji, przez co przyczyniają się do powstawania stanów awaryjnych....
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Ocena stanu technicznego konstrukcji zgarniaczy będących na wyposażeniu osadników wstępnych Grupowej Oczyszczalni Ścieków „DĘBOGÓRZE
PublicationOsadniki wstępne typu DORRA – 4 szt., o pojemności 1830 m3, wyposażone są w elementy mechaniczne do kierunkowego przemieszczania się osadu w kierunku leja centralnego. Celem pracy jest ocena stany technicznego części mechanicznej, a w szczególności: - konstrukcji zespołu zgarniania części pływających oraz osadu. - zespołu napędu i sterowania, - zespołu napędu i jazdy. Pierwsze dwa zespoły będą oceniane również z punktu widzenia...
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Biocompatibility and Bioactivity of Load-Bearing Metallic Implants
PublicationThe main objective of here presented research is to develop the titanium (Ti) alloy base composite materials possessing better biocompatibility, longer lifetime and bioactivity behaviour for load-bearing implants, e.g. hip joint and knee joint endoprosthesis. The development of such materials is performed through: modeling the material behaviour in biological environment in long time and developing of new procedures for such evaluation;...
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Adhesion of organic coatings to hot-dip galvanized steel
PublicationDuplex systems provide long-time corrosion protection, much longer than the sum of the lifetimes of zinc and paint used individually. However loss of adhesion between coating and zinc substrate is often found in practice. Different methods of zinc surface preparations are used in the fi eld. The aim of this study was to examine and compare coating protection when the old zinc surface, stored during long-time period (15 years) in...
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Deterioration and Protection of Concrete Elements Embedded in Contaminated Soil: A Review
PublicationCoating materials are considered one of the most antique materials of human civilization; they have been used for decoration and the protection of surfaces for millennia. Concrete structures—due to their permanent exposure to different types of environments and contaminants—require the use of coatings that contribute to its preservation by reducing the corrosion of its components (steel and aggregates). This article intends to...
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Chromatographic analyses of Lavandula angustifolia and Rosmarinus officinalis extracts and their biological effects in mammalian cells and cell-free systems
PublicationKnowledge of biological properties of natural compounds allows to understand their therapeutic value, efficacy and security. We investigated: composition of Lavandula angustifolia (LA) and Rosmarinus officinalis (RO) extracts, their antioxidant capacity, cytotoxicity and genotoxicity, their DNA-protective potential against DNA damage induced in hamster V79 cells by several genotoxins or in plasmid DNA by Fe2+ ions and activity...
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EXPERIMENTAL ANALYSIS OF RUBBER AND STYROFOAM BUMPERS INFLUENCE ON THE COLLIDING STRUCTURES
PublicationPast and recent investigations of colliding structures under seismic excitation confirmed that pounding may have a significant influence on the structural response. Interactions between adjacent buildings may cause serious damage to the structures, leading even to its total collapse. The main reason of earthquake-induced pounding, besides insufficient distance between structures, are differences in stiffness or mass of colliding structures....
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QRS Morphology-Based EDR Signal—Factors Determining its Properties
PublicationRespiration-induced signals contain a clinically significant information. It could be obtained utilizing both direct and indirect methods. ECG-Derived Respiration (EDR) method is the latter one. However, in this case, two approaches could be distinguished. First one is based on determining changes in the morphology of QRS complexes while the second one is based on the Respiratory Sinus Arrhythmia (RSA) mechanism. The former approach...
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Experimental and Theoretical Insights into the Intermolecular Interactions in Saturated Systems of Dapsone in Conventional and Deep Eutectic Solvents
PublicationSolubility is not only a crucial physicochemical property for laboratory practice but also provides valuable insight into the mechanism of saturated system organization, as a measure of the interplay between various intermolecular interactions. The importance of these data cannot be overstated, particularly when dealing with active pharmaceutical ingredients (APIs), such as dapsone. It is a commonly used anti-inflammatory and...
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A Reaction of Thioamides with Zinc Ammoniates Leading to Simple Amidines. Discovery of a New Zwitterionic Monomethylamidine
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
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Convenient Syntheses of N-Methylthioamides: A Migration of the H2S Molecule in the Thioamide-nitrile System
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
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A dipole-driven path for electron and positron attachments to gas-phase uracil and pyrimidine molecules: a quantum scattering analysis
PublicationElectron and positron scattering processes in the gas-phase are analysed for uracil and pyrimidine molecules using a multichannel quantum approach at energies close to threshold. The special effects on the scattering dynamics induced by the large dipole moments in both molecules on the spatial features of the continuum leptonic wavefunctions are here linked to the possible bound states of the Rydberg-like molecular anions or ‘positroned’...
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Experimental and Machine-Learning-Assisted Design of Pharmaceutically Acceptable Deep Eutectic Solvents for the Solubility Improvement of Non-Selective COX Inhibitors Ibuprofen and Ketoprofen
PublicationDeep eutectic solvents (DESs) are commonly used in pharmaceutical applications as excellent solubilizers of active substances. This study investigated the tuning of ibuprofen and ketoprofen solubility utilizing DESs containing choline chloride or betaine as hydrogen bond acceptors and various polyols (ethylene glycol, diethylene glycol, triethylene glycol, glycerol, 1,2-propanediol, 1,3-butanediol) as hydrogen bond donors. Experimental...
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Experimental and Machine-Learning-Assisted Design of Pharmaceutically Acceptable Deep Eutectic Solvents for the Solubility Improvement of Non-Selective COX Inhibitors Ibuprofen and Ketoprofen
PublicationDeep eutectic solvents (DESs) are commonly used in pharmaceutical applications as excellent solubilizers of active substances. This study investigated the tuning of ibuprofen and ketoprofen solubility utilizing DESs containing choline chloride or betaine as hydrogen bond acceptors and various polyols (ethylene glycol, diethylene glycol, triethylene glycol, glycerol, 1,2-propanediol, 1,3-butanediol) as hydrogen bond donors. Experimental...
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Hybrid analogues of SFTI-1 modified in P1 position by β- and γ-amino acids and N-substituted β-alanines
PublicationA series of compounds containing either non-proteinogenic beta-/gamma-amino acids or N-substituted beta-alanine residues (beta-peptoid units) in P-1 specificity position were synthesized based on the structure of sunflower trypsin inhibitor 1 (SFTI-1). The compounds were synthesized on a solid support; the N-substituted beta-alanines (beta Nhlys and beta Nhphe) were introduced into a peptidomimetic chain via a two-step approach...
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Microporous N-Doped Carbon Obtained from Salt Melt Pyrolysis of Chitosan toward Supercapacitor and Oxygen Reduction Catalysts
PublicationThe direct carbonization of low-cost and abundant chitosan biopolymer in the presencesalt eutectics leads to highly microporous, N-doped nanostructures. The microporous structureeasily manufactured using eutectic mixture (ZnCl2 -KCl) and chitosan. Potassium ions here can act as an intercalating agent, leading to the formation of lamellar carbon sheets, whereas zinc chloride generates significant porosity. Here, we present an efficient...
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Studies on the utilization of post-distillation liquid from Solvay process to carbon dioxide capture and storage
PublicationIn this work, a method of precipitated calcium carbonate production from the post-distillation liquid created in the Solvay process and waste carbon dioxide was proposed and investigated. Precipitation was carried out in a model solution of calcium chloride containing ammonia at various molar ratios in relation to Ca2+ ions, while gaseous carbon dioxide was supplied to the reactor as a pure gas or as a mixture with air. It was...
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Electrophoretic co-deposition of Fe2O3 and Mn1,5Co1,5O4: Processing and oxidation performance of Fe-doped Mn-Co coatings for solid oxide cell interconnects
PublicationThe “in-situ” Fe-doping of the manganese cobalt spinel was achieved by electrophoretic co-deposition of Mn1,5Co1,5O4 and Fe2O3 powders followed by a two-step reactive sintering treatment. The effects on the coating properties of two different Fe-doping levels (5 and 10 wt.% respectively) and two different temperatures of the reducing treatment (900 and 1000 °C) are discussed. Samples with Fe-doped coatings demonstrated a lower...
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A study on diagnosing both isotropic and orthotropic, intentionally damaged laminates
PublicationBeing the most detrimental mode in laminated structures, delamination initially degrades local structural strength, and lastly causes global structural failure, thus necessitating delamination identification at its incipient stages. For identification purposes, a comprehensive numerical and experimental study on delamination within both the laminated isotropic acrylic-glass and orthotropic epoxyglass plates is presented. As the...
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Influence of separation gap on the response of colliding models of steel structures under seismic and paraseismic excitations
PublicationAs a result of high urbanization, the need to erect closely-spaced buildings forces designers to consider collisions between structures taking place during ground motions. Experimental and numerical studies have confirmed that such collisions (often referred to as structural pounding) may cause serious damage to the structural elements and even lead to total collapse of colliding structures. The main reason of earthquake-induced...
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The Processing Procedure for the Interpretation of Microseismic Signal Acquired from a Surface Array During Hydraulic Fracturing in Pomerania Region in Poland
PublicationHydraulic fracturing is a procedure of injecting high pressure fluid into the wellbore in order to break shell rock and facilitate gas flow. It is a very costly procedure and, if not conducted properly, it may lead to environmental pollution. To avoid costs associated with pumping fluid outside the perspective (gas rich) zone and improve one’s knowledge about the reservoir rock, microseismic monitoring can be applied. The method...