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Search results for: PHYSICO-CHEMICAL VARIABLES
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DNA structure and integrity checkpoints in the cell cycle and their role in drug targeting and resistance of tumor cells to anticancer treatment
PublicationW artykule dokonaliśmy przeglądu literatury dotyczącej różnych typów uszkodzeń DNA indukowanych przez różne czynniki terapeutyczne w komórkach nowotworowych. Omówiliśmy także w jaki sposób aktywują różne typy punktów kontrolnych w cyklu komórkowym i w jaki sposób punkty te są regulowane przez inne szlaki sygnalizacji wewnątrzkomórkowej takie jak szlaki naprawy uszkodzeń DNA, stresu komórkowego i śmierci-przeżycia. W szczególności...
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Calcium sulphate scaling in membrane distillation process
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Separation of saline oily wastewater by membrane distillation
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Application of vacuum membrane distillation for concentration of organic solutions‡
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Effect of carbon nanotube modification on poly (butylene terephthalate)-based composites
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The long-term studies of osmotic membrane distillation
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Fouling of nanofiltration membranes used for separation of fermented glycerol solutions
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The application of polypropylene membranes for production of fresh water from brines by membrane distillation
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The application of ultrafiltration for treatment of ships generated oily wastewater
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Microfiltration of post-fermentation broth with backflushing membrane cleaning
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Membrane processes used for separation of effluents from wire productions
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Production of process water using integrated membrane processes
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Treatment of effluents from a membrane bioreactor by nanofiltration using tubular membranes
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Effect of flow-rate on ethanol separation in membrane distillation process
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Studies of membrane scaling during water desalination by membrane distillation
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Biosynthesis of methanol from methane by Methylosinus trichosporium OB3b
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Ethanol production in a bioreactor with an integrated membrane distillation module
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Wettability of polypropylene capillary membranes during the membrane distillation process
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Cubane Like Structure of a Silanethiol Primary Amine Assembly a Novel, Unusual Hydrogen Bond Pattern.
PublicationMetodą rentgenowskiej analizy strukturalnej wyznaczono struktury krystaliczne i cząsteczkowe trzech soli amoniowych: (t-BuO)3SiS(-)H3N(+)Bu-t, (i-PrO)3SiS(-)H3N(+)Bu-t i (t-BuO)3SiS(-)H3N(+)(CH2)2CH(CH3)2. Wszystkie trzy związki w ciele stałym tworzą tetramery w których atomy S i N wyznaczają w przybliżeniu naroża sześcianu. Trwałość tych agregatów, oprócz sił elektrostatycznego przyciągania, zapewnia sieć wiązań wodorowych N-H
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Oscillatory Phenomena in System with Bulk Luquid Membranes
PublicationOscylatory z grubowarstwowymi membranami ciekłymi zawierające jonowe surfakanty mogą być użyte do modelowania zjawisk oscylacyjnych zachodzących w membranach biologicznych. Stwierdzono, że zmiany temperatury mają silny wpływ na charakterystyki oscylacyjne. Zmienia się częstotliwość oscylacji i ukazują się nowe piki w układach zawierających nitrometan. Zbadano wpływ składu faz wodnych (stężenie surfaktanta i alkoholu) oraz materiału...
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The nature of emitting states in electroluminescence of polymeric films do-ped with anthracene andanthracene-based supramolecules
PublicationZaobserwowano nową odmianę bi-molekularnych stanów wzbudzenia elektronowego w polimerowych jednowarstwowych diodach EL z molekułami antracenu wbudowanymi bezpośrednio w matrycę poliwęglanową, jak i pośrednio przez ich włączenie jako grup chromoforowych w dużych makromolekułach rotaxanowych. Stwierdzono, że obok typowej emisji ekscymerowej pojawia się długofalowe pasmo elektromerowe. Pasmo to związane jest z emisją kolumbowsko związanych...
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Kinetics of photochromic reactions in a 10-membered dibenzoazo crown ether
PublicationPrzedstawiono rezultaty pomiarów kinetyki fotochromowych reakcji dla jednego z serii eterów koronowych zawierających fragment azobenzenowy. Badano 10-członową dibenzoazokoronę, która ulega odwracalnej foto i termicznej izomeryzacji, podobnie jak macierzysty azobenzen. Eksperymenty były prowadzone w matrycy pMMA. Reakcja izomeryzacji monitorowana była spektrofotometrycznie. Czynnik przedwykładniczy dla termicznej izomeryzacji cis-trans...
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Advantageous conditions of saccharification of lignocellulosic biomass for biofuels generation via fermentation processes
PublicationProcessing of lignocellulosic biomass includes four major unit operations: pre-treatment, hydrolysis, fermentation and product purifcation prior to biofuel generation via anaerobic digestion. The microorganisms involved in the fermentation metabolize only simple molecules, i.e., monosugars which can be obtained by carrying out the degradation of complex polymers, the main component of lignocellulosic biomass. The object of this...
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Engineering TADF, Mechanochromism, and Second Harmonic Up- conversion Properties in Regioisomeric Substitution Space
PublicationThis research article explores the distinct TADF efficiency of three donor-acceptor based regio-isomers: DPAOCN (ortho- isomer), DPAMCN (meta-isomer), and DPAPCN (para-isomer). DPAPCN exhibits maximum TADF efficiency in both solution and solid-state with an impressive reverse inter-system crossing (RISC) rate of ~ 106 s-1; the underlying cause being the minimum singlet-triplet splitting energy or ∆EST and maximum SOC (spin-orbit...
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Calculation of adiabatic potentials of Li2
PublicationInformujemy o adiabatycznych krzywych energii potencjalnej cząsteczki litu. Nasze krzywe są stabelowane według odległości międzyatomowej od 3,2 a0 do 88a0. Porównujemy nasze wyniki teoretyczne z wynikami obliczonymi przez innych autorów oraz krzywymi energii potencjalnej wyprowadzonymi z eksperymentów. W naszym podejściu używamy metody konfiguracji wzajemnego oddziaływania, gdzie tylko elektrony walencyjne atomu Li są traktowane...
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Exploring of electronic structure of nitrogen-modified TiO2 photocatalysts through photocurrent and surface photovoltage studies
PublicationPrzeprowadzono pomiary fotonapięcia powierzchniowego i fotoprądu w obecności różnych reduktorów celem otrzymania eksperymentalnego potwierdzenia położenia pasma walencyjnego w strukturze elektronowej tlenku tytanu(IV) modyfikowanego azotem. Zaobserwowano silne sprzężenie poziomów N 2p i O 2p, którego konsekwencją jest powstanie nowego pasma walencyjnego
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Internal electric fields in vacuum-evaporated films as studied by electroabsorption spectroscopy
PublicationMierzono sygnały elektroabsorpcji na I-szej harmonicznej częstości przykładanego sinusoidalnego pola elektrycznego w komórkach sandwiczowych Al/warstwa organiczna/Al. Wyznaczono elektryczne pola wewnętrzne (Fi) dla materiałów stosowanych w organicznych diodach elektroluminescencyjnych (TPD, TAPC, MTDATA, QAC, Alq3, Ir(ppy)3, PtOEP). Mechanizm powstawania pól Fi powiązano z pułapkowaniem ładunku w obszarach przyelektrodowych.
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Electroabsorption in triphenylamine-based hole-transporting materials for organic light-emitting diodes
PublicationMetodą elektroabsorpcji (EA) badano stany wzbudzenia elektronowego w próżniowo naparowanych warstwach diamin (TPD, TAPC) i dendrymeru aminowego m-MTDATA. Widma EA amin złożonych porównano z widmem monomeru trifenylaminy (TPA). Kształt widm EA świadczy o obecności zdegenerowanych i quasi-zdegenerowanych stanów elektronowych.
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Electromodulation of photoluminescence in vacuum-evaporated films of fac-tris(2-phenylpyridine)iridium(III)
PublicationZaobserwowano silne wygaszenie fosforescencji w komórkach sandwiczowych Al/Ir(ppy)3/Al/kwarc, które w polu elektrycznym o natężeniu 3 MV/cm dochodzi do 30%. Mechanizm wygaszania jest związany z dysocjacją ekscytonów trypletowych pod działaniem zewnętrznego pola elektrycznego w obszarach zdefektowanych sieci krystalicznej.
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Visible light-induced photocatalytic reaction of gold-modified titanium(IV) oxide particles: action spectrum analysis
PublicationAnalizy spektrum działania wykazały, ze wzbudzenie powierzchniowego plazmonu złota inicjuje utlenianie 2-propanolu w świetle widzialnym w napowietrzonej zawiesinie tlenku(IV) tytanu zmodyfikowanego zlotem. Badania przeprowadzone z użyciem światła polichromatycznego wykazały, ze szybkość reakcji foto-utleniania zależy od właściwości tlenku(IV) tytanu, takich jak rozmiar ziaren, pola powierzchni właściwej, formy krystalicznej (anataz...
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Phosphinoborinium cation: a synthon for cationic B-P bond systems
PublicationHerein, we report access to phosphinoborinium cations via heterolytic cleavage of the boron-bromide bond in bromophosphinoborane. The product of the reaction was isolated as a dimeric dication possessing a planar P2B2 core. Activation of C-H and C-P bonds in the dication led to formation of the borinium-phosphaborene adduct. Reactivity studies revealed that title cation exhibits ambiphilic properties and intramolecular frustrated...
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A non-adiabatic wavepacket dynamical study of the low energy chargetransfer process in the S3+ + H collision
PublicationThe collisional system S3+ + H?S2+ + H+ has been studied using a time-dependent wavepacket methodologyin two-dimensions. Using available potential energy surfaces and coupling matrix elementsobtained from multireference ab initio calculations, five non-adiabatically coupled electronic states of1P symmetry have been included in the dynamical simulations. The collision has been studied in thelow energy regime of 1-10 eV. The wavepacket...
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Understainding solid-phase microextraction: key factors influencing the extraction process and trends in improving the technique
PublicationAnalytical chemists are faced with the daunting challenges of accurately monitoring the state of the environment and the processes taking place in it and of determining an enormous range of analytes often present in trace and ultratrace amounts in sample matrixes with complex or variable compositions. Further challenges are presented by the need to introduce new methodologies into current analytical practice and equipment to comply...
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New bulk liquid membrane oscillator composed of two coupled oscillators with diffusion-mediated physical coupling
PublicationA new type of bulk liquid membrane system, which represents the first example of a bulk liquid membrane oscillator characterised by the presence of two coupled oscillators, is described. When the benzyldimethyltetradecylammonium chloride surfactant undergoes an oscillatory mass transfer through a nitromethane liquid membrane, a new liquid layer (phase X) appears between the membrane and the acceptor phase. Kinetic analysis provides...
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Photovoltaic properties of cadmium selenide–titanyl phthalocyanine planar heterojunction devices
PublicationPhotovoltaic phenomenon taking place in cadmium selenide (CdSe)/titanyl phthalocyanine (TiOPc) planar heterojunction devices is described. Mechanisms of free charge carrier generation and their recombination in the dark and under illumination are analyzed, chosen photovoltaic parameters are presented.
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Detoxification of the tricyclic antidepressant opipramol and its analog – IS-noh by UGT enzymes before and after activation by phase I enzymes in rat liver microsomes
PublicationThe present studies were carried out to evaluate the simultaneous one-pot metabolism of opipramol (IS-opi) and analog (IS-noh) by phase I and phase II enzymes present in rat liver microsomes (RLM) as an alternative to separate testing with recombinant enzymes. This approach allows for more time-saving and cost-effective screening of the metabolism of newly discovered drugs. We also considered that the lack of results for phase...
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Synthesis and properties of new 'N,'N-phenyltetrazole podand
PublicationThe synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity...
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Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid
PublicationThe first example of CO2 diphosphination is described. Reactions of unsymmetrical diphosphanes with CE2 (E = O, S) catalyzed by BPh3 insert a CE2 molecule into the P-P bond with formation of the products of the general formula R2P-E-C(=E)-PR2. The obtained CO2 adducts arise from synergistic interaction of diphosphane and borane with CO2 molecule.
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Multi-state vibronic interactions in the fluorobenzene radical cation: The importance of quadratic coupling terms
PublicationThe multi-mode multi-state vibronic interactions in the set of X^2B_1 - D^2A_1 electronic states of the monofluoro benzene radical cation are investigated theoretically, based on a quadratic vibronic coupling approach. The underlying ionization potentials and coupling constants are obtained from ab initio coupled-cluster calculations. Previous investigations (relying on the linear coupling approach) are extended by including all...
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Multi-mode vibronic interactions in the five lowest electronic states of the fluorobenzene radical cation
PublicationThe multi-mode vibronic interactions between the five lowest electronic states of the fluorobenzene radical cation are investigated theoretically, based on ab initio electronic structure data, and employing the linear vibronic coupling model. Low-energy conical intersections, and strong vibronic couplings are found to prevail within the set of X-A and B-C-D cationic states, while the interactions between these two sets of states...
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Synthesis of reduced graphene oxide nanosheets using nanofibers from methane and biogas thermal decomposition with various catalysts
PublicationReduced graphene oxide and graphene oxide (rGO, GO) were synthesised from carbon nanofibers, which were formed in catalytic thermal decomposition of methane (CDM) and biogas with different catalysts used in the process. The aim of the work was valorization of CDM carbon nanofiber products. The samples were characterized using Raman spectra, a scanning electron microscope and a transmission electron microscope. As a result, we observe...
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Quasirelativistic potential energy curves and transition dipole moments of NaRb
PublicationWe report on extensive calculations of quasi-relativistic potential energy curves and, for the first time, transition dipole moments including spin-orbit and scalar-relativistic effects of the NaRb molecule. The calculated curves of the 0+, 0-, 1, 2 and 3 molecular states correlate for large internuclear separation with the fourteen lowest atomic energies up to the Na(3s ^2S_{1/2}) + Rb(7s ^2S_{1/2}) atomic limit. Several new features...
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Influence of excitons interaction with charge carriers on photovoltaic parameters in organic solar cells
PublicationWe report on theoretical analysis of excitons annihilation on charge carriers in organic solar cells. Numerical calculations based on transient one-dimensional drift-diffusion model have been carried out. An impact of three quantities (an annihilation rate constant, an exciton mobility and a recombination reduction factor) on current density and concentrations of charge carriers and excitons is investigated. Finally, we discuss...
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Integration of protein tethering in a rapid and label-free SERS screening platform for drugs of abuse
PublicationSurface enhanced Raman spectroscopy (SERS) has emerged as a promising technique for the rapid and ultrasensitive detection of molecular species such as drugs of abuse in biofluids. Yet, it remains a significant challenge to create a viable screening tool for multiple drug classes, owing to the lack of affinity of certain species for the SERS substrate and to the matrix interference in complex media. Here we report a protein tethering...
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Synthesis, structural and spectroscopic properties of asymmetric schiff bases derived from 2,3-diaminopyridine
PublicationTwo Schiff base derivatives, 4-(2-amino-3-pyridyliminomethyl)phenol (I) and 3-(2-amino-3- pyridyliminomethyl)nitrobenzene (II ), were synthesised and characterised by spectroscopy. The structure of I was determined by single crystal X-ray diffraction studies. The asymmetric Schiff base derived from 2,3-diaminopyridine selectively recognise transition and heavy metal cations, and some anion. Ligands I and II form stable complexes...
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Sano-Tachiya-Noolandi-Hong versus Onsager modelling of charge photogeneration in organic solids
PublicationW pracy obliczono numerycznie charakterystyki polowe wydajności fotogeneracji nośników ładunku na gruncie różnych wesrsji modeli Onsagera i Noolandiego-Honga. Wyznaczone krzywe teoretyczne porównano z wynikami doświadczalnymi uzyskanymi metodą elektromodulacji (foto)luminescencji (EML) dla próżniowo naparowanych warstw organicznych kompleksów Alq3 i Ir(ppy)3.
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Reversible energy transfer between monomers and fluorescent dimers of rhodamine S in polyvinyl alcohol films
PublicationBezpromienisty transfer energii i jej pułapkowanie jest analizowane dla rodaminy S domieszkowanej w foliach PVA. Z analizy wynika że fluoryzujące dimery rodaminy S grają rolę niedoskonałych pułapek energii wzbudzenia. Dla najwyższych koncentracji barwnika wyniki doświadczalne wydajności kwantowej i anizotropii emisji nie mogą być wyjaśnione przy pomocy modelu pomijającego transfer powrotny energii do monomerów. Uwzględnienie transferu...
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Endangering of Groundwater on the Municipal Intakes in Gdańsk
PublicationGroundwater from the Quaternary aquifer on the marine terrace in Gdańsk has been exploited for almost a century, supplying the town with water of good quality. However intensive exploitation in the past and development of the urban area influenced the chemical composition of the water. Hydrogeochemical background for such ions as chlorine, sulphate and ammonia has changed and also some organic micro compounds appeared in single...
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Analisys of the failure of fixator used in bone surgery
PublicationThe Gamma nail (fixator) made of stainless steel, which has broken in the body, was subjected to examination. The fixator was removed from the patient femur. The fracture occurred in the area of the nail hole after two months' stay in the organism. The research included chemical composition, hardness of the Gamma nail material and the observation and analysis of the type of fracture. The research showed the fatigue failure of the...
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Application, design and operation of constructed wetland systems: case studies of systems in the Gdańsk region, Poland
PublicationDifferences in operation result from physical, chemical and biological conditions, which directly influence transformations in the whole aquatic-matrix-plants environment. Depending on the quantity of inflowing organic matter load and the rate of biochemical processes, the contaminations could be removed or/and retuned in the system. From this point of view the facility should be designed and operated in such way that the highest...