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Search results for: OXIDATION AND REDUCTION REACTIONS
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Nitroreductase reactions of Arabidopsis thaliana thioredoxin reductase
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Reactions on the surface of the implant under the influence of biofilm
PublicationThe contact of a biomaterial with the biological environment in in vitro and in vivo tests leads to the production of a particular ecosystem in which the active roles perform both, the material surface and the extracellular matrix protein forming a biofilm. Proteins affect cell and bacteria adhesion processes, biological activity of cells and activation of inflammatory response.The knowledge of the reaction mechanisms active on...
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Instantaneous electrochemical impedance spectroscopy of electrode reactions.
PublicationUstalona została ciągła transformata STFT sinusoidalnego sygnału pobudzeniai odpowiedzi prądowej dla pierwszorzędowej reakcji elektrodowej. Impedancja elektrodowa wyznaczona została w łącznej dziedzinie czasowo-częstotliwościowej. Wykonano pomiary reakcji redukcji Cd(II) na kapiącej elektrodzie rtęciowej w funkcji czasu. Zaprezentowano możliwość wyznaczania chwilowych widm impedancyjnych. Opisano czasowe charakterystyki rezystancji...
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Electrodes criticality: the impact of CRMs in the leachate electrochemical oxidation
Publication. Landfill leachate possesses high concentrations of ammonia, micropollutants, and heavy metals, and are characterised for low biodegradability. For this reason, conventional treatment technologies may result ineffective for complete pollutant removal. Electrochemical oxidation allows most of the of recalcitrant pollutants to be oxidised effectively within an easy operational and acceptable retention time, without the need to provide...
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Efficient model order reduction for FEM analysis of waveguide structures and resonators
PublicationAn efficient model order reduction method for three-dimensional Finite Element Method (FEM) analysis of waveguide structures is proposed. The method is based on the Efficient Modal Order Reduction (ENOR) algorithm for creating macro-elements in cascaded subdomains. The resulting macro-elements are represented by very compact submatrices, leading to significant reduction of the overall number of unknowns. The efficiency of the model...
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Application of persulfate-based oxidation processes to address diverse sustainability challenges: A critical review
PublicationOver the past years, persulfate (PS) is widely applied due to their high versatility and efficacy in decontamination and sterilization. While treatment of organic chemicals, remediation of soil and groundwater, sludge treatment, disinfection on pathogen microorganisms have been covered by most published reviews, there are no comprehensive and specific reviews on its application to address diverse sustainability challenges, including...
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Chracteristics of anaerobic ammonium oxidation initated by anaerobic granular sludge
PublicationTwo different mixed sludge, anaerobic granular sludge(R1) and anaerobic granular sludge with mature anaerobic ammonium oxidation (ANAMMOX) sludge (R2 )were used as the inocula in two up-flow reactors to enrich anaerobic ammonia-oxidizing bacteria (AnAOB),respectively.The total nitrogen removal rate of R1 reached 74% in 99 days, while R2 remained above 70% in only 48 days.The content of extracellular polymeric substance (EPS) in...
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Testing the Effect of Bathymetric Data Reduction on the Shape of the Digital Bottom Model
PublicationDepth data and the digital bottom model created from it are very important in the inland and coastal water zones studies and research. The paper undertakes the subject of bathymetric data processing using reduction methods and examines the impact of data reduction according to the resulting representations of the bottom surface in the form of numerical bottom models. Data reduction is an approach that is meant to reduce the size...
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Synergistic effect of TiO2 photocatalytic advanced oxidation processes in the treatment of refinery effluents
PublicationDifferent types of photolytic and photocatalytic advanced oxidation processes (AOPs) were used for treatment of refinery effluents from bitumen production. The treatment efficiency was evaluated by analyzing chemical oxygen demand (COD), biological oxygen demand (BOD5), volatile organic compounds (VOCs) and sulfide ions concentration. The studies revealed a synergistic effect of application of external oxidants (O3, H2O2, O3/H2O2)...
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The Effectiveness of Polymer Damper in Damage Reduction of Temporary Steel Grandstand
PublicationA large number of accidents involving damage of temporary grandstands during different types of events were observed in the past. The aim of the paper is to analyse numerically the effectiveness of a polymer damper in damage reduction of a temporary steel scaffolding grandstand exposed to dynamic load due to jumping. The element has been installed as a diagonal one at the back part of the structure. The method has been compared...
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Advanced Oxidation Processes for the Treatment of Contaminants of Emerging Concern
PublicationThe application of contaminants of emerging concern (CEC) such as pharmaceuticals and personal care products (PPCPs), pesticides, plasticizers, endocrine disruptors, surfactants, flame retardants and polycyclic aromatic hydrocarbons (PAHs) became an indispensable requirement of the current era. Although the CEC are useful for wide-spectrum purposes, they can also result in undesirable effects on human health and other animals....
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Deflated Preconditioned Solvers for Parametrized Local Model Order Reduction
PublicationOne of steps in the design of microwave filters is numerical tuning using full-wave simulators. Typically, it is a time-consuming process as it uses advanced computational methods, e.g. the finite-element method (FEM) and it usually requires multiple optimization steps before the specification goals are met. FEM involves solving a large sparse system of equations at many frequency points and therefore its computational cost is...
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The importance of the bottom layer in double-layer porous asphalt for noise reduction
PublicationDouble-layer porous asphalt concrete (DPAC) surfaces are generally considered to be the acoustically most effective low noise road surfaces ready for implementation. While DPAC used on highways in warm climates may have an average life of around 8 years, in Scandinavia with severe winter climate DPAC usually survive only about 3 years; partly due to wear of studded tyres. An ongoing project in Sweden, applying DPAC and single-layer...
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Electrochemical simulation of metabolism for antitumor-active imidazoacridinone C-1311 and in silico prediction of drug metabolic reactions
PublicationThe metabolism of antitumor-active 5-diethylaminoethylamino-8-hydroxyimidazoacridinone (C-1311) has been investigated widely over the last decade but some aspects of molecular mechanisms of its metabolic transformation are still not explained. In the current work, we have reported a direct and rapid analytical tool for better prediction of C-1311 metabolism which is based on electrochemistry (EC) coupled on-line with electrospray...
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Styrene Oxidation by Copper(II) Complexes Salen-Type Encapsulated into Nay Zeolite
PublicationThe copper(II) complex with a Schiff-base salen-type ligand has been encapsulated in the nanopores of a NaY zeolite by using two different methodologies, the flexible ligand and in situ complex preparation methods. The encapsulated and non-encapsulated copper(II) complexes were screened as catalysts for styrene oxidation by using TBHP as the oxygen source in acetonitrile solvent. Under the optimized conditions, the catalysts exhibited...
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A Review of Reduction Methods of Impact of Common-Mode Voltage on Electric Drives.
PublicationIn this survey paper, typical solutions that focus on the reduction in negative effects resulting from the common-mode voltage influence in AC motor drive applications are re-examined. The critical effectiveness evaluation of the considered methods is based on experimental results of tests performed in a laboratory setup with an induction machine fed by an inverter. The capacity of a common-mode voltage level reduction and voltage...
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Reduction of road traffic noise by source measures — present and future strategies
PublicationThe current trend worldwide is less focused on reducing road traffic noise. This is in strong contrast to the severe impact of traffic noise to the general health and quality of life. A more holistic and combined strategy is needed. Current international rules and regulations regarding vehicles and tyres are not sufficient to reduce traffic noise levels in an effective way. Calculations show that these regulations will only yield...
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Experiences and Challenges in Fatality Reduction on Polish Roads
PublicationAccording to the UN, road safety is the key to achieving sustainable development goals, yet the complexity of how road accidents happen makes this a difficult challenge leaving many countries struggling with the problem. For years, Poland has infamously been one of the EU’s top countries for road-accident fatality rates. Despite that, it has made significant progress in the last thirty years with a fatality reduction of more than...
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Thermohydraulic maldistribution reduction in mini heat exchangers
PublicationA detailed numerical investigation has been carried out to analyze the flow maldistribution in 50 parallel 1 mm × 1 mm rectangular minichannels and 1 mm depth minigap section with rectangular, trapezoidal, triangular or concave manifolds in Z-type flow configuration. The working medium was ethanol and the mass flow rate was 5 × 10−4 kg/s. Both sections were heated from the bottom side. Heat flux of 10 000 W/m2 and 5000 W/m2 was...
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Treatment of bitumen post oxidative effluents by sulfate radicals based advanced oxidation processes (S-AOPs) under alkaline pH conditions
PublicationSulfate radicals based Advanced Oxidation Processes (S-AOPs), namely Persulfate and peroxymonosulfate, were used for the treatment of post oxidative effluents from a production of petroleum bitumens under alkaline pH. Studies on the identification and monitoring of the volatile organic compounds (VOCs) along with COD, BOD and sulfide ions reduction were performed. Persulfate with a ratio between the oxygen from the oxidant and...
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The Method of reduction of aerodynamic forces generated in turbine blade seals
PublicationThe distibution of pressure in the seal gaps does not only affect the so called '' leakage losses'' and the turbine stage overall efficiency but also plays an important role in the generation of aerodynamic forces which may cause self-excited rotor vibrations. The paper describes a chamber seal applied for the reduction of the aerodynamic forces created in shroud seals. This kind of turbine seal was patented and tested.
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Sulfate reducing ammonium oxidation (SULFAMMOX) process under anaerobic conditions
PublicationSulfate (SO42-) can be an electron acceptor for ammonium nitrogen (NH4+) oxidation under anaerobic conditions. The process is known as sulfammox and can be a viable alternative to conventional, nitrite (NO2-) dependent, anammox. Two bacterial species, including Bacillus Benzoevorans and Brocadia Anammoxoglobus Sulfate, can perform that process. With sulfammox, an economically inefficient pre-nitration step (due to aeration) is...
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Application of polymer element in reduction of temporary steel grandstand vibrations
PublicationThe numerical analysis focused on reduction of vibrations of a temporary steel scaffolding grandstand has been conducted in this paper. These types of structures are regularly subjected to dynamic loads which, in conjunction with light and quite slender structural members, may induce dangerous vibrations. To increase their safety, temporary steel grandstands are usually strengthened with the diagonal stiffeners of tubular cross...
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Size Reduction of Microwave Couplers by EM-Driven Optimization
PublicationThis work addresses simulation-driven design optimization of compact microwave couplers that explicitly aims at circuit footprint area reduction. The penalty function approach allows us to minimize the area of the circuit while ensuring a proper power division between the output ports and providing a sufficient bandwidth with respect to return loss and isolation around the operating frequency. Computational cost of the optimization...
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Wastewater treatment by means of Advanced Oxidation Processes at basic pH conditions: A review
PublicationAdvanced oxidation processes (AOPs) have been used as an alternative and effective option for treatment of industrial wastewater, especially in the case of the non-biodegradable compounds. Despite of several well developed AOPs, the majority of them are effective only at acidic or neutral pH, namely Fenton related processes, making the list of available effective advanced oxidation technologies strongly limited. In many cases,...
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High-Temperature Oxidation of Heavy Boron-Doped Diamond Electrodes: Microstructural and Electrochemical Performance Modification
PublicationIn this work, we reveal in detail the effects of high-temperature treatment in air at 600 °C on the microstructure as well as the physico-chemical and electrochemical properties of boron-doped diamond (BDD) electrodes. The thermal treatment of freshly grown BDD electrodes was applied, resulting in permanent structural modifications of surface depending on the exposure time. High temperature affects material corrosion, inducing...
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Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
PublicationSurface oxidation processes play a key role in understanding electrochemical properties of boron-doped diamond (BDD) electrodes. The type of surface termination groups, which create the potential window of electrolytic water stability or hydrophobicity, influences such properties. In this study the kinetics of oxidation process under anodic polarization were studied in situ by means of Dynamic Electrochemical Impedance Spectroscopy...
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Domain Reduction in Hybrid Technique for Electromagnetic Wave Scattering Problems
PublicationThis paper proposes a combination of the field matching technique, finite element method and generalized impedance matrix, the main idea of which is to reduce the computational domain by surrounding a scatterer with the smallest convex shape and applying the field matching technique. This approach can be applied for arbitrary shaped scatterers and types of materials and allows for the reduction of the computational domain. In order...
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Fundamental-harmonic impedance of first-order electrode reactions
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The reactions occuring on the implant as a result of contact with human tissue
PublicationObecnosc implantu w ciele czlowieka powoduje liczne, czesto nieprzewidywalne skutki. Powodem takiej sytuacji jest duza roznorodnosc interakcji materialu medycznego z kontaktujaca sie z nim tkanka. Stwierdzenie to dotyczy glownie oddzialywan i skutkow zachodzacych na poziomie molekularnym w poszczegolnych komorkach kontaktujacej sie tkanki.
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3D imaging of nuclear reactions using GEM TPC
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Reactions of parylenes with double bonds: An ab initio study
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublicationThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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The reduction of auxiliaries power demand: The challenge for electromobility in public transportation
PublicationAn important role in the consumption of electric energy in urban transport are non-traction needs (auxiliaries), the main part of which is heating and air condition (HVAC). Auxiliaries are responsible for almost half of total energy consumption (normal weather conditions) and in the winter (or hot summer) it reaches up to 70% in daily scale. The reduction of energy used for non-traction needs is currently the main challenge related...
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Synergistic effects of hybrid advanced oxidation processes (AOPs) based on hydrodynamic cavitation phenomenon – A review
PublicationHigh-performance water treatment systems based on cavitational processes have received an increasing interest of scientific community in the past few decades. Numerous studies indicated the advantageous application of hydrodynamic cavitation as an alternative, reagent-free treatment method of various pollutants in water. Both approaches were proved as an effective method to achieve mineralization of many organic contaminants as...
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Improving Clairvoyant: reduction algorithm resilient to imbalanced process arrival patterns
PublicationThe Clairvoyant algorithm proposed in “A novel MPI reduction algorithm resilient to imbalances in process arrival times” was analyzed, commented and improved. The comments concern handling certain edge cases in the original pseudocode and description, i.e., adding another state of a process, improved cache friendliness more precise complexity estimations and some other issues improving the robustness of the algorithm implementation....
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Effect of Vascular Lumen Reduction on the Performance and Energy Consumption of an Innovative Implantable LVAD
PublicationThis paper presents the results of a study on the effect of vascular lumen reduction on the performance of an innovative implantable LVAD (left ventricular assist device). It details the pressures in the individual cardiac chambers as a function of device frequency. In addition, mass flow rates and energy consumption of the device are examined, varying with lumen reduction and operating frequency. While the lumen reduction of the...
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Stock Markets’ Reactions to the Announcement of the Hosts. An Event Study in the Analysis of Large Sporting Events in the Years 1976–2032
PublicationThis study attempts to estimate the impact of the announcements of hosts of large sporting events on domestic stock markets. The research problem is to establish a connection between the uniqueness of a sporting event and investors’ beliefs through stock price behavior. Using appropriate estimation windows, 13 different sporting events classified as large, including mega and major events, were tested. The obtained results show...
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Reliable Greedy Multipoint Model-Order Reduction Techniques for Finite-Element Analysis
PublicationA new greedy multipoint model-order reduction algorithm for fast frequency-domain finite-element method simulations of electromagnetic problems is proposed. The location of the expansion points and the size of the projection basis are determined based on a rigorous error estimator. Compared to previous multipoint methods, the quality of the error estimator is significantly improved by ensuring the orthogonality of the projection...
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Surrogate-Assisted Design of Checkerboard Metasurface for Broadband Radar Cross-Section Reduction
PublicationMetasurfaces have been extensively exploited in stealth applications to reduce radar cross section (RCS). They rely on the manipulation of backward scattering of electromagnetic (EM) waves into various oblique angles. However, arbitrary control of the scattering properties poses a significant challenge as a design task. Yet it is a principal requirement for making RCS reduction possible. This article introduces a surrogate-based...
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Low-Cost Behavioral Modeling of Antennas by Dimensionality Reduction and Domain Confinement
PublicationBehavioral modeling has been rising in importance in modern antenna design. It is primarily employed to diminish the computational cost of procedures involving massive full-wave electromagnetic (EM) simulations. Cheaper alternative offer surrogate models, yet, setting up data-driven surrogates is impeded by, among others, the curse of dimensionality. This article introduces a novel approach to reduced-cost surrogate modeling of...
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A Reduction Method for Bathymetric Datasets that Preserves True Coastal Water Geodata
PublicationWater areas occupy over 70 percent of the Earth’s surface and are constantly subject to research and analysis. Often, hydrographic remote sensors are used for such research, which allow for the collection of information on the shape of the water area bottom and the objects located on it. Information about the quality and reliability of the depth data is important, especially during coastal modelling. In-shore areas are liable...
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The effectiveness of polymer adhesive in reduction of vibrations of structural members
PublicationIn this paper, the idea of using polymer adhesive as a damping layer is proposed. An experimental study of two aluminium cantilevered beams has been conducted. One of them presents a plain cantilevered beam, while the second one considers two aluminium beams bonded with a polymer adhesive of different thickness (0,5; 1,2; 1,75; 3,1 and 5 mm). The polymer adhesive considered in the study is a specially designed flexible...
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Reduction of measurement data before Digital Terrain Model generation vs. DTM generalisation
PublicationModern data acquisition technologies provide large datasets that are not always necessary in its entirety to properly accomplish the goal of the study. In addition, such datasets are often cumbersome for rational processing, and their processing is time and labour consuming. Therefore, methods that enable to reduce the size of the measurement dataset, such as the generalization of the Digital Terrain Model (DTM) or the reduction...
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Impedance monitoring of corrosion degradation of plasma electrolytic oxidation coatings (PEO) on magnesium alloy
PublicationImpedance technique based on continuous multisinusoidal current perturbation was used to explain degradation process of plasma electrolytic oxidation coatings (PEO) on magnesium alloy. An obtained impedance spectrum was fitted by electrical equivalent circuit to describe properties of conversion layer on magnesium alloy. Additionally, galvanostatic mode maintained during experiment, with DC current equal to zero, allowed to achieve...
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Synthesis of bimetallic Co–Pt/cellulose nanocomposites for catalytic reduction of p-nitrophenol
PublicationIn this study, bimetallic nanoparticles (NPs) of Co–Pt anchored on cellulose nanofibers (CNFs) for catalytic applications were synthesized via a sonochemical approach. The electro-spinning technique was employed for the synthesis of CNFs from cellulose acetate. The thorough characterization of synthesised Co–Pt/CNF nanocomposites was performed with the help of scanning electron microscopy (SEM), Fourier transform infra-red (FT-IR)...
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A Model-Order Reduction Approach for Electromagnetic Problems With Nonaffine Frequency Dependence
PublicationThe aim of this paper is to present a novel model-order reduction (MOR) technique for the efcient frequency-domain nite-element method (FEM) simulation of microwave components. It is based on the standard reduced-basis method, but the subsequent expansion frequency points are selected following the so-called sparsied greedy strategy. This feature makes it especially useful to perform a fast-frequency sweep of problems that lead...
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Heterogeneous oxidation of highly boron-doped diamond electrodes and its influence on the surface distribution of electrochemical activity
PublicationThe electrochemical active surface area (EASA) of polycrystalline boron-doped diamond (BDD) electrodes is heterogeneous and can be affected by numerous factors. There is a strong need for proper consideration of BDD heterogeneity in order to improve this material's range of application in electrochemistry. Localized changes in surface termination due to the influence of oxidation agent result in increased surface resistance. The...
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A grey box model of glucose fermentation and syntrophic oxidation in microbial fuel cells
PublicationIn this work, the fermentative and oxidative processes taking place in a microbial fuel cell (MFC) fed with glucose were studied and modeled. The model accounting for the bioelectrochemical processes was based on ordinary, Monod-type differential equations. The model parameters were estimated using experimental results obtained from three H-type MFCs operated at open or closed circuits and fed with glucose or ethanol. The experimental...
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Activated persulfate and peroxymonosulfate based advanced oxidation processes (AOPs) for antibiotics degradation – A review
PublicationSulfate radical AOPs (SR-AOP) were successfully utilized in degradation of antibiotics in water and wastewater treatment. The review discusses details on SR-AOPs mechanisms and applications for antibiotics degradation. The progress in this field was discussed, highlighting the most promising developments and remaining challenges. The applicability of SR-AOPs was summarized revealing the most susceptible and persistent to oxidation...