Filters
total: 9102
filtered: 6520
-
Catalog
Chosen catalog filters
displaying 1000 best results Help
Search results for: high-pressure spectroscopy
-
Supine blood pressure normalised by daytime series values is independently associated with ischaemic wake-up stroke
Publication -
Ambulatory Blood Pressure Adds to Explaining Benefits of AT‐1 Receptor Blockade in the Treatment of Left Ventricular Hypertrophy
Publication -
Blood pressure lowering effect of renal sympathetic denervation or placebo? - building expectations for Symplicity-HTN 3
Publication -
Low temperature broad band dielectric spectroscopy of multiferroic Bi6Fe2Ti3O18 ceramics
PublicationIn the present research the tool of broadband dielectric spectroscopy was utilized to characterize dielectric behavior of Bi6Fe2Ti3O18 (BFTO) Aurivillius-type multiferroic ceramics. Dielectric response of BFTO ceramics was studied in the frequency domain (Δν=0.1Hz – 10MHz) within the temperature range ΔT=-100°C – 200°C. The Kramers-Kronig data validation test was employed to validate the impedance data measurements and it was found...
-
The Methodology for Determining the Theoretical Based on the Characteristics of Effective Absorbency Versus Pressure Drop in the Motor
PublicationThis article describes a method for determining the theoretical and actual working volume of a hydraulic motor. It has been shown that the actual working volume of the motor is the sum of the theoretical working volume and the additional volume that depends on the pressure drop in the working chambers of the motor. It was also shown that the volumetric losses in the hydraulic motor are not only a function of the pressure drop in...
-
Flow boiling of R1233zd(E) in a 3 mm vertical tube at moderate and high reduced pressures
PublicationThe results of flow boiling of R1233zd(E) in a 3 mm vertical stainless steel tube are presented at moderate and high saturation temperatures. Integral flow characteristics in the form of pressure drop and heat transfer coefficient are discussed for saturation temperatures ranging from 115 to 145 °C (corresponding reduced pressures from 0.2 to 0.7), mass velocity of 800 kg/m2s and heat flux of 20 kW/m2. All of the obtained heat...
-
Weak hydrogen bonding interaction S-H···O=C studied by FT-IR spectroscopy and DFT calculations
PublicationInteractions between the thiolate group of tri-tert-butoxysilanethiol (TBST) and carbonyl group of acetone are studied with the use of FT-IR spectroscopy and DFT calculations.
-
Enhanced capacitance of composite TiO2 nanotube / boron-doped diamond electrodes studied by impedance spectroscopy
PublicationWe report on the novel composite nanostructures based on boron-doped diamond thin film grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2...
-
New Method of Non-Linear Electrochemical Impedance Spectroscopy with an Amplitude-Modulated Perturbation Signal
PublicationThe paper presents a new method of non-linear electrochemical impedance spectroscopy (NLEIS), which allows fast and nondestructive evaluation of the corrosion rate and determination of the Tafel coefficients values for a corrosion system under investigation. This method employs amplitude modulation of the ac perturbation signal. The study demonstrated that it was possible to obtain impedance characteristic as a function of the...
-
Failure analysis of a high-speed induction machine driven by a SiC-inverter and operating on a common shaft with a high-speed generator
PublicationDue to ongoing research work, a prototype test rig for testing high-speed motors/generators has been developed. Its design is quite unique as the two high- speed machines share a single shaft with no support bearings between them. A very high maximum operating speed, up to 80,000 rpm, was required. Because of the need to minimise vibration during operation at very high rotational speeds, rolling bearings were used. To eliminate...
-
The influence of moderate pressure and subzero temperature on the shelf life of minced cod, salmon, pork and beef meat
PublicationThe effect of moderate pressure at subzero temperature on natural microflora of minced cod, salmony, pork and beef meat was studied. Pressure of 193 MPa at –20 °C caused reduction of total bacterial count in pork and beef meat by 1.1 and 0.6 log cycles, respectively, and by about 1.5 log cycles in fish meat. Under these conditions the psychrophilic and psychrotophic bacteria were below the detection limit (<10CFU/g of sample) in...
-
The influence of high temperature wood drying conditions using air-steam mixture on its properties
PublicationThe results of properties change of beech wood after drying process are presented. The wood taken to experiments was from northern part of Pomeranian region in Poland. Before the main high temperature drying process using air-steam mixture, wood was initially dried in an open air conditions. The high temperature drying process was conducted at temperature 120oC, humidity 48%, flow rate of drying medium 2.5m/s and atmospheric pressure....
-
Chemical and Mechanical Pressure-Induced Photoluminescence Tuning via Structural Evolution and Hydrostatic Pressure
Publication -
Contribution of arterial excess pressure and arterial stiffness to central augmentation pressure in healthy subjects
Publication -
Elevated ambulatory systolic-diastolic pressure regression index is genetically determined in hypertensive patients with coronary heart disease
Publication -
Twenty‐four‐hour and conventional blood pressure components and risk of preterm delivery or neonatal complications in gestational hypertension
Publication -
Urgent need to address quality control issues of out‐of‐office blood pressure measurement and patient risk assessment
Publication -
Application of vibrational spectroscopy, thermal analyses and X-Ray diffraction in the rapid evaluation of the stability in solid-state of ranitidine, famotidine and cimetidine
PublicationThis paper reports the study on applicability of Fourier transform infrared (FTIR), near-infrared (NIR) and Raman spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction (XRD) for the estimation of the chemical stability and photostability of histamine H2-receptor antagonist substances. Ranitidine hydrochloride (RAN), famotidine (FAM) and cimetidine (CIM) were tested and differences in sensitivity were measured...
-
X-Ray Diffraction, Mössbauer Spectroscopy and Magnetoelectric Effect Studies of Multiferroic Bi5Ti3FeO15 Ceramics
PublicationBi5Ti3FeO15 ceramics belongs to multiferroic class of materials. In this work it was prepared by solid-state sintering method and investigated by X-ray diffraction, Mössbauer spectroscopy, and magnetoelectric effect measurements. As it was proved by X-ray diffraction studies the single-phase Bi5Ti3FeO15 compound was obtained. The Mössbauer investigations revealed paramagnetic character of the compound at room temperature as well...
-
Study of Direct Methanol Fuel Cell Process Dynamics Using Dynamic Electrochemical Impedance Spectroscopy
PublicationA new technique, which was developed to characterize the direct methanol fuel cell under work conditions, has been presented in this paper. The impedance measurements were made using dynamic electrochemical impedance spectroscopy research technique in the galvanostatic mode, using multiple sinusoidal excitation. Obtained results show, that together with an increase of the temperature and working load, the global impedance...
-
Combined analysis of whole human blood parameters by Raman spectroscopy and spectral-domain low-coherence interferometry
PublicationIn this article the simultaneous investigation of blood parameters by complementary optical methods, Raman spectroscopy and spectral-domain low-coherence interferometry, is presented. Thus, the mutual relationship between chemical and physical properties may be investigated, because low-coherence interferometry measures optical properties of the investigated object, while Raman spectroscopy gives information about its molecular...
-
Synthesis, spectroscopy and computational studies of some biologically important hydroxyhaloquinolines and their novel derivatives
PublicationA series crystalline compounds of methyl and phosphinyl derivatives of 2-methylquinolin-8-ol (1a) and related 5,7-dichloro-2-methylquinolin-8-ol (1b) were quantitatively prepared and characterized by microanalysis, IR, UV-vis and multinuclear NMR spectroscopy. Five of them have been characterized by single crystal X-ray diffraction method. The known compounds, 8-methoxy-2-methylquinoline (2a) and 8-methoxyquinoline (2d), were synthesised...
-
Synthesis, spectroscopy and computational studies of some novelphosphorylated derivatives of quinoline-5,8-diones
PublicationThe neutral phosphorus nucleophiles such as R2P(=Y)M allowed the radical addition to 2-methyl-5,8-dioxo-5,8-dihydroquinoline-7-amine and N-(2-methyl-5,8-dioxo-5,8-dihydroquinolin-7-yl)acetamide giving exclusively O-phosphorylated products. All products were quantitatively prepared and characterized by microanalysis, and multinuclear NMR spectroscopy. Seven of them, have been characterized by single crystal X-ray diffraction method....
-
Pressure-induced superconductivity in CaFe2As2
PublicationNowo odkryty związek CaFe2As2 pod wpływem zewnętrznego ciśnienia 0.69 GPa przechodzi w stan nadprzewodnictwa z temperaturą krytyczną powyżej 10K.
-
Signature of Hydrodynamic Pressure Field
PublicationW artykule przedstawiono wyniki obliczeń pola hydrodynamicznego ciśnienia wokół statku jako funkcję przestrzenną, obliczoną metodą brzegowego rozkładu osobliwości. Obliczone pole ciśnienia hydrodynamicznego jest porównywane z pomierzonym polem ciśnienia wokół okrętu na akwenie specjalnym, opis kształtu kadłuba jest przybliżony. Przedstawione wyniki obliczeń uzyskano stosując pojedynczą warstwę o ciągłym rozkładzie źródłowości....
-
Signature of Hydrodynamic Pressure Field
PublicationW artykule przedstawiono wyniki obliczeń pola hydrodynamicznego ciśnienia wokół okrętu specjalnego jako funkcji przestrzennej, obliczonej metodą brzegową. Obliczone pola ćiśnienia hydrodynamicznego jest porównywane z pomierzonym polem okrętu na morzu, przy czym opis kształtu kadłuba okrętu jest przybliżony. Przedstawione wyniki obliczeń uzyskano stosując warstwę pojedynczą , którą stanowią źródła o rozkładzie ciągłym. Skonstruowany...
-
Pressure field in a plane layer
PublicationPraca prezentuje wyniki badań teoretycznych i numerycznych zagadnienia przejścia fal płaskich przez warstwę. Omówiono zagadnienie tworzenia i rozchodzenia się fal w poszczególnych warstwach. Zaproponowano model matematyczny opisujący zmiany ciśnienia wewnątrz warstwy. Analizowano ciśnienie wewnątrz warstwy, fale bieżące i odbite wewnątrz warstwy oraz w ośrodku otaczającym. Przedstawiono wyniki badań numerycznych.
-
Fluorescent spectroscopy of collagen as a diagnostic tool in medicine
Publication -
Instantaneous electrochemical impedance spectroscopy of electrode reactions
Publication -
Optical spectroscopy and scintillation mechanisms ofCexLa1−xF3
Publication -
Hydration of tetrahydrofuran derived from FTIR spectroscopy
PublicationZbadano hydratację THF na podstawie spektroskopii FTIR drgań HDO oraz H2O. Dane widmowe poddano analizie przy pomocy ilościowej metody widm różnicowych. Ustalono, że w roztworach rozcieńczonych hydratacja THF typu hydrofobowego dominuje nad hydratacją typu elektrofilowego. Scharakteryzowano wodę w otoczce hydratacyjnej THF poprzez jej porównanie z wodą czystą.
-
Evaluation of coating systems using impedance spectroscopy
PublicationTrwałość powłokowych systemów ochronnych zależy od oddziaływań środowiska i związana jest nieodwracalnymi procesami chemicznymi i fizycznymi. Zastosowanie spektroskopii impedancyjnej pozwala na określenie obszaru zastosowań danej powłoki i prognozowanie okresu jej trwałości. W pracy zamieszczono przykłady oceny trwałości systemów powłokowych stosowanych w strategicznych konstrukcjach.
-
Instantaneous electrochemical impedance spectroscopy of electrode reactions.
PublicationUstalona została ciągła transformata STFT sinusoidalnego sygnału pobudzeniai odpowiedzi prądowej dla pierwszorzędowej reakcji elektrodowej. Impedancja elektrodowa wyznaczona została w łącznej dziedzinie czasowo-częstotliwościowej. Wykonano pomiary reakcji redukcji Cd(II) na kapiącej elektrodzie rtęciowej w funkcji czasu. Zaprezentowano możliwość wyznaczania chwilowych widm impedancyjnych. Opisano czasowe charakterystyki rezystancji...
-
Noise sources in Raman spectroscopy of biological objects
PublicationWe present an overview of noise sources deteriorating the quality of the recorded biological Raman spectra and the ability to determine the specimen composition. The acquired Raman spectra exhibit intense additive noise components or drifts because of low intensity of the scattered light. Therefore we have to apply expensive or bulky measurement setups to limit their inherent noise or to apply additional signal processing to reduce...
-
How does stakeholder pressure influence CSR-practices? A construction industry model based on a European sample
PublicationThe stakeholder pressure is one of the most vital powers which determines CSR implementation and can provide organizations with the motivation to adopt corporate social responsibility (CSR) strategy, as the stakeholder theory claims. The current investigation replications Kowalczyk’s (2019) study, who examined the same structure of relations based on the Polish sample. The essence of this replication is to find out whether CSR-...
-
Relationships between stakeholder pressure, culture, and CSR-practices in the context of project management in the construction industry in Poland
PublicationThe study aims to investigate how CSR-stakeholder pressure, CSR-company culture, and CSR-practices are related to one another based on the example of the construction industry in Poland. This knowledge will make it possible to assess which of the two factors, i.e., stakeholder culture or the internal company culture have a stronger effect on the CSR-practices. To accomplish the goal of the study a sample composed of 216 cases was...
-
Weldability of high strength steel in underwater environment
PublicationThe article describes the problems with weldability of high-strength steels in the aquatic environment. The tendency of steel S355J2G3 and S500M to form cold cracks when welded in wet welding conditions has been experimentally evaluated. It was found that the tested steels have a high propensity to cracking. An experiment has been proposed and tested to evaluate the usefulness of the tempering bead technique as a method of improving...
-
The influence of stainless steels microstructure evolution on the mechanical properties of pressure installation elements
PublicationIn this paper results of FEM analysis performed for pipe and 90o elbow, made of super duplex stainless steel, after precipitation of sigma phase (),were presented. Heat treatment conditions simulate accidental overheating that can occur in nuclear installations after cooling circulation fails. For initial and modified microstructure tensile test was performed and numerical description of work hardening curves was done. Verification...
-
The influence of stainless steels microstructure evolution on the mechanical properties of pressure installation elements
PublicationIn this paper results of FEM analysis performed for pipe and 90o elbow, made of super duplex stainless steel, after precipitation of sigma phase (s), were presented. Heat treatment conditions simulate accidental overheating that can occur in nuclear installations after cooling circulation fails. For initial and modified microstructure tensile test was performed and numerical description of work hardening curves was done. Verification...
-
Investigation of the electrochemical behaviour of AA1050 aluminium alloy in aqueous alkaline solutions using Dynamic Electrochemical Impedance Spectroscopy
PublicationThe paper presents the electrochemical behaviour of aluminium alloy AA1050 in aqueous alkaline media in the pH range 14–8.5. Electrochemical study was applied in order to obtain comprehensive information on the mechanism and kinetics of the process of anodic dissolution of aluminium, supplemented by monitoring of surface topography using an electron microscope. The corrosion rate of AA1050 increases with increasing concentration...
-
Study of the NO2 sensing mechanism of PEDOT-RGO film using in situ Raman Spectroscopy
PublicationIn this work, the mechanism of the NO2 reaction with PEDOT-RGO composite film has been investigated via in situ Raman spectroscopy. Reduced graphene oxide (RGO), poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO) and poly(3,4-ethylenedioxytiophene)/ClO4− (PEDOT/ClO4−) films were fabricated using an electrodeposition method and used as resistance sensors of gaseous nitrogen dioxide. The experimental results indicate...
-
Validity of impedance spectra obtained by dynamic electrochemical impedance spectroscopy verified by Kramers-Kronig transformation.
PublicationArtykuł przedstawia weryfikację wiarygodności widm impedancyjnych otrzymanych za pomocą niedawno wprowadzonej techniki eksperymentalnej - Dynamicznej Elektrochemicznej Spektroskopii Impedancyjnej (Dynamic Electrochemical Impedance Spectroscopy, DEIS). Technika ta zakłada, że badany system jest pseudostacjonarny jeśli czas pomiaru jest odpowiednio krótki. Czas potrzebny na otrzymanie pojedynczego spektrum zależy od długości okna...
-
Chemical Pressure Tuning Magnetism from Pyrochlore to Triangular Lattices
PublicationGeometrically frustrated lattices combined with magnetism usually host quantum fluctuations that suppress magnetic orders and generate highly entangled ground states. Three-dimensionally (3D) frustrated magnets generally exist in the diamond and pyrochlore lattices, while two-dimensionally (2D) frustrated geometries contain Kagomé, triangular, and honeycomb lattices. In this work, we reported using chemical pressure to tune the magnetism...
-
High-throughput Evaluation of Lipophilicity and Acidity by New Gradient HPLC Methods
Publication -
Masked hypertension in type 2 diabetes: never take normotension for granted and always assess out-of-office blood pressure
Publication -
The J-curve phenomenon revisited again: SPRINT outcomes favor target systolic blood pressure below 120 mmHg
Publication -
Numerical analysis of high temperature minichannels heat exchanger performance
PublicationNowadays, the most difficult technological challenge in energy sector is connected with the gas micro-CHP units, dedicated to the distributed power generation. They are expected to be of high efficiency and at the same time of compact in size. Regarding the first reason, significant increase in microturbine efficiency can only be achieved by increase in the engine operating temperature. Therefore, one of the critical elements in...
-
Distribution of relaxation times as a method of separation and identification of complex processes measured by impedance spectroscopy
PublicationImpedance spectroscopy is one of the most commonly performed measurements to characterize electronic and electrochemical systems. Impedance spectra have limited resolution and many different processes may overlap what could be the reason of obstructions in its proper later analysis. Up to date, there are three approaches to solve this problem: examining impedance spectra itself, fitting spectra with equivalent circuits, and calculating...
-
Surface modification of PMMA polymer and its composites with PC61BM fullerene derivative using an atmospheric pressure microwave argon plasma sheet
PublicationThis paper presents the results of experimental investigations of the plasma surface modification of a poly(methyl methacrylate) (PMMA) polymer and PMMA composites with a [6,6]-phenyl-C61-butyric acid methyl ester fullerene derivative (PC61BM). An atmospheric pressure microwave (2.45 GHz) argon plasma sheet was used. The experimental parameters were: an argon (Ar) flow rate (up to 20 NL/min), microwave power (up to 530 W), number...
-
Detection of the Plant Pathogen Pseudomonas Syringae pv. Lachrymans on Antibody-Modified Gold Electrodes by Electrochemical Impedance Spectroscopy
PublicationThe present work describes an impedimetric immunosensor for Pseudomonas syringae pv. lachrymans (Psl) detection. This pathogen infects many crop species causing considerable yield losses, thus fast and cheap detection method is in high demand. In the assay, the gold disc electrode was modified with 4-aminothiophenol (4-ATP), glutaraldehyde (GA), and anti-Psl antibodies, and free-sites were blocked with bovine serum albumin (BSA)....