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Search results for: SAMPLE PREPARATION, GREEN ANALYTICAL CHEMISTRY, SOLID PHASE MICROEXTRACTION, NON-FIBER SPME TECHNIQUES
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Determination of selenium by X-ray fluorescence spectrometry using dispersive solid-phase microextraction with multiwalled carbon nanotubes as solid sorbent
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Novel fast analytical method for indirect determination of MCPD fatty acid esters in edible oils and fats based on simultaneous extraction and derivatization
PublicationA novel method for indirect determination of MCPD esters levels in lipid samples has been developed. The method is based on combination of extraction and derivatisation in the same sample preparation step. It is achieved by the application of diethyl ether as extraction solvent for isolation of released from esterified forms analytes from water phase and dilution solvent for solid PBA – derivatisation agent. It is a noteworthy...
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Determination of volatile fatty acid ethyl esters in raw spiritsusing solid phase microextraction and gas chromatography
PublicationPrzedstawiono opracowanie i opymalizację metody analitycznej oznaczania estrów etylowych kwasów tłuszczowych w destylatach rolniczych różnej jakości lub wyprodukowanych z różnych surowców. W badaniach wykorzystywano technikę mikroekstrakcji do fazy stacjonarnej (HS-SPME) oraz kapilarnej chromatografii gazowej (CGC) z detektorem płomieniowo-jonizacyjnym (FID). Ekstrakcja związków lotnych prowadzona była według opracowanej procedury,...
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Solid State Phenomena
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Solid-phase microextraction and ion chromatographic analysis of anions based on polypyrrole electrode
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Static headspace sampling and solid-phase microextraction for assessment of edible oils stability
PublicationStatyczna analiza fazy nadpowierzchniowej i mikroekstrakcja do fazy stacjonarnej z fazy nadpowierzchniowej zostały zastosowane do oznaczenia niskocząsteczkowych aldehydów - markerów procesu utleniania olejów roślinnych. Zoptymalizowano parametry izolacji i ekstrakcji analitów dla obu technik. Wyznaczono granice oznaczalności i wykrywalności oraz powtarzalność dla badanych związków. Obie metody zastosowano w analizie próbek olejów...
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Head-Space SPME for the Analysis of Organophosphorus Insecticides by Novel Silica IL-Based Fibers in Real Samples
PublicationThis work demonstrates the suitability of a newly developed ionic liquid (IL)-based silica SPME fiber for the determination of seven organophosphorus insecticides in cucumber and grapefruit samples by headspace solid-phase microextraction (HS-SPME) with a gas chromatography–flame ionization detector (FID). The sol-gel method released four different sorbent coatings, which were obtained based on a silica matrix containing ILs immobilized...
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Analytical procedures for determination of cocaine and its metabolites in biological samples
PublicationThe dangerous effects and increased usage of illicit drugs have inspired the development of analytical methodologies. We based our review of analytical procedures for determination of cocaine (COC) and its metabolites on literature from the past two decades. Our main aim was to compare the capabilities of different analytical techniques. The diversity of matrices from which COC is determined (e.g., blood, hair, saliva, plasma,...
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Computational modeling of molecularly imprinted polymers as a green approach to the development of novel analytical sorbents
PublicationThe development of novel molecularly imprinted polymers (MIP) sorbents for specific chemical compounds require a lot of tedious and time-consuming laboratory work. Significant quantities of solvents and reagents are consumed in the course of the verification of appropriate configurations of polymerization reagents. Implementation of molecular modeling in the MIP sorbent development process appears to provide a solution to this...
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JOURNAL OF NON-CRYSTALLINE SOLIDS
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Miniaturized methods of sample preparation
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Greening procedures and analytical parameters. The polychlorinated naphthalenes analysis in complex matrices as proof of concept
PublicationDue to the complexity of analytical procedures employed for the determination of wide spectrum of persistent organic pollutants (POPs), it is important to consider the green character of the applied protocols and propose the greenest solutions. In this review, the green aspects of several analytical procedures used for the determination of polychlorinated naphthalenes (PCNs) (as a representatives of POPs) in different types of...
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Preconcentration and Analytical Methods for Determination of Methyl Tert-Butyl Ether and Other Fuel Oxygenates and Their Degradation Products in Environment: A Review
PublicationFuel oxygenates (FOs) are mainly ethers or alcohols which are added to gasoline either to boost the octane number or to make the fuel burning process more "cleaner" with increasing the oxygen content, or to obtain a combination of both effects. FOs are water soluble with high mobility in the environment which presence even at very low concentrations lower the quality of water making it unsafe or unpleasant due to their objectionable...
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Green Analytical Chemistry
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Green chromatography
PublicationAnalysis of organic compounds in samples characterized by different composition of the matrix is very important in many areas. A vast majority of organic compound determinations are performed using gas or liquid chromatographic methods. It is thus very important that these methods have negligible environmental impact. Chromatographic techniques have the potential to be greener at all steps of the analysis, from sample collection...
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A standard analytical method as the common good and pollution abatement measure
PublicationA standard method can be considered as a common-good “resource,” and the solution to “the commons” problems usually lies in societal self-organization. The multi-criteria decision analysis (MCDA) was applied to model complex phenomena, such as the standard selection for imidacloprid determination. In this process, the standard was self-selected by the analytical chemistry society. The results show that analytical chemistry is a...
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Pre-analytical aspects in metabolomics of human biofluids – sample collection, handling, transport, and storage
PublicationMetabolomics is the field of omics research that offers valuable insights into the complex composition of biological samples. It has found wide application in clinical diagnostics, disease investigation, therapy prediction, monitoring of treatment efficiency, drug discovery, or in-depth analysis of sample composition. A suitable study design constitutes the fundamental requirements to ensure robust and reliable results from the...
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Marek Biziuk prof. dr hab. inż.
PeopleCURRICULUM VITAE Marek BIZIUK Born 1947 MSc 1969 GUT PhD 1977 GUT DSc 1994 GUT Professor 2001 Membership of scientific society - Gdansk Scientific Society - Romanian Society of Analytical Chemistry - Engineers and Techniques of...
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Non-matrix reference matrials- chalanges in the preparation of standard gas mixtures
PublicationIn the last few years particularly great pressure is exerted on quality control and assurance of analytical measurement results. An invaluable role in this process is played by reference materials. The paper presents the characteristics of basic types of reference materials, with particular attention to gaseous reference materials. In addition, a review of literature on techniques of preparation of gaseous standard materials, published...
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Sample preparation and chromatographic analysis of acidic herbicides in soils and sediments
PublicationW pracy przedstawiono różne techniki przygotowania próbek i oznaczania herbicydów z grupy pochodnych fenoli i pochodnych kwasów karboksylowych w próbkach gleby. Opisano wybrane metody wzbogacania i izolacji analitów, m. in.: ekstrakcję za pomocą wodnych roztworów zasad i rozpuszczalników organicznych płynem w stanie nadkrytycznym, wodą w stanie podkrytycznym, cieczą pod zwiększonym ciśnieniem, cieczą wspomaganą mikrofalami. Niski...
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New insights into the application of MSPD in various fields of analytical chemistry
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Magnetic Covalent Organic Frameworks—Fundamentals and Applications in Analytical Chemistry
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Current Analytical Chemistry
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Investigation of use of hydrophilic/hydrophobic NADESs for selective extraction of As(III) and Sb(III) ions in vegetable samples: Air assisted liquid phase microextraction and chemometric optimization
PublicationIn this paper, a green, cost-effective sample preparation method based on air assisted liquid phase microextraction (AA-LPME) was developed for the simultaneous extraction of As(III) and Sb(III) ions from vegetable samples using hydrophilic/hydrophobic natural deep eutectic solvents (NADESs). Central composite design was used for the optimization of extraction factors including NADES volume, extraction cycle, pH, and curcumin concentration....
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TALANTA.The International Journal of Pure and Applied Analytical Chemistry
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Comparison of Headspace Solid-phase Microextraction, Headspace Single-drop Microextraction and Hydrodistillation for Chemical Screening of Volatiles in Myrtus Communis L
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Multi-residue method for the determination of 16 recently used pesticides from various chemical groups in aqueous samples by using DI - SPME coupled with GC-MS
PublicationA simple and solvent-free multi-residue method has been optimized to determine 16 currently used pesticides from different chemical groups in aqueous samples. The extraction of analytes was carried out with direct immersion solid-phase microextraction (DI-SPME) and for the identification and quantitative determination gas chromatography coupled with mass spectrometry (GC-MS) was applied. Two commonly used adsorbent coatings have...
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A new dilution-enrichment sample preparation strategy for expanded metabolome monitoring of human breast milk that overcomes the simultaneous presence of low- and high-abundance lipid species
PublicationThe complex nature of human breast milk (HBM) makes samples difficult to analyze, requiring several extraction techniques and analytical platforms to obtain high metabolome coverage. In this work, we combined liquid-liquid extraction (LLE) and solid-phase extraction (SPE) techniques to prepare HBM samples to overcome the challenge of low- and high-abundance lipid species, enabling the semiquantitative analysis of total HBM lipids...
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Perspectives on the replacement of harmful organic solvents in analytical methodologies: a framework toward the implementation of a generation of eco-friendly alternatives
PublicationVolatile organic solvents derived from non-renewable fossil feedstocks are commonplace in analytical laboratories. In spite of their convenient performance in countless unit operations, their environmental, health and safety issues represent a major area of concern. The progressive replacement of organic solvents obtained from fossil resources by eco-friendly alternatives would involve remarkable advances within the framework of...
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Determination of Surfactants in Environmental Samples. Part III. Non-Ionic Compounds
PublicationNon-ionic surface active agents are a diverse group of chemicals which have an uncharged polar head and a non-polar tail. They have different properties due to amphiphilic structure of their molecules. Commercial available non-ionic surfactants consist of the broadest spectrum of compounds in comparison with other types of such agents. Typically, non-ionic compounds found applications in households and industry during formulation...
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Nanoconfined Ionic Liquids. Properties and analytical applications
PublicationThe synergistic combination of ionic liquids (ILs) and solid‐like matrices involves a powerful coupling towards the development of new sustainable analytical methodologies. Here we survey the literature regarding such ionic liquid‐based hybrid materials, including a database on relevant physicochemical properties of ionic liquids confined in a solid network. Furthermore, this chapter presents the strategies implemented to combine...
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Introductory Chapter: Evolution of Sample Preparation
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Introductory Chapter: Evolution of Sample Preparation
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Validation and Regulatory Issues for Sample Preparation
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Evaluation of the Greenness of Analytical Procedures
PublicationThis contributions introduces the need to develop the methods to evaluate analytical procedures in the light of green analytical chemistry. Green chemistry metrics are not applicable in analytical chemistry because they refer to the mass of product and no product with mass is generated during analytical determination. Analytical greenness evaluations are based on scoring - such as NEMI or Eco-scale or comparative analysis as it...
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Botanical and geographical origin characterization of polish honeys by headspace SPME-GCxGC-TOFMS
PublicationVolatile organic compounds (VOCs) composition of Polish honeys obtained from various geographical regions was studied. Headspace solid phase microextraction (HS-SPME) using Divinylbenzene/Carboxen/Polydimethylsiloxane-coated fibers was used in combination with comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GC× GC-TOFMS) because of the complexity of the samples. Acacia, linden, rapeseed, buckwheat...
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Bartłomiej Cieślik dr inż.
PeopleBorn on April 21, 1988 in Płock January 2012 - Eng. Environmental Protection Technologies at the Faculty of Chemistry of the Gdańsk University of Technology June 2013 - MSc. - Environmental Protection Technologies at the Faculty of Chemistry of the Gdańsk University of Technology May 2018 - Ph.D. - Field: chemical sciences, discipline: Chemistry, Faculty of Chemistry of the Gdańsk University of Technology September 2018 employed...
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Surface Chemistry & Experimental Techniques
e-Learning Courseswykłady prowadzone przez prof. G. Jerkiewicza
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Piotr Jamroz dr hab. inż.
PeoplePiotr Jamroz graduated from Wroclaw University of Technology, Faculty of Chemistry in 1998 and obtained his PhD from the same university in 2003. Currently he works as an associate professor at Wroclaw University of Science and Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy. His research interests are related to generation and diagnostics of different kinds of plasma sources, including...
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Evaluation of headspace solid-phase microextraction for the analysis of volatile carbonyl compounds in spirits and alcoholic beverages
PublicationOpracowano metodę oznaczania C1-C6 związków karbonylowych w układzie GC-ECD w roztworach alkoholowych poprzez derywatyzację pentafluorobenzylohydroksy-aminą i mikroekstrakcję w fazie stacjonarnej z fazy nadpowierzchniowej. Zoptymalizowano warunki eksperymantalne: zawartość alkoholu, czas ekspozycji, temperaturę i sposób mieszania próbki. W metodzie tej najpierw przeprowadza się rozcieńczenie spirytusu lub napojów alkoholowych do...
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New Technique of preparation of standard gas mixtures needed for validation of analytical procedures used in environmental studies
PublicationStandard gas mixtures are indispensable reference materials for ensuring the reliability of analytical work. Paper presents one novel approach in the field of production of gaseous reference materials based on the application of thermal decomposition process of proper surface compound for obtaining the desired gaseous analyte. The main fields of application of reference materials are presented. The field of application of thermal...
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Validation of SPME-GC and HS-GC procedures for the determination of selected solvent residues in edible oil matrices
PublicationW pracy przedstawiono przebieg procesu walidacji, przeprowadzonej zgodnie ze wskazaniami ICH (International Conference on Harmonization), procedur wykorzystywanych do oznaczania pozostałości wybranych rozpuszczalników w olejach jadalnych i preparatach farmaceutycznych. W celu izolacji i wzbogacania analitów wykorzystano dwie bezrozpuszczalnikowe techniki ekstrakcyjne: ekstrakcję do fazy nadpowierzchniowej (HS) i mikroekstrakcję...
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Application of TOPSIS for Selection and Assessment of Analytical Procedures for Ibuprofen Determination in Wastewater
PublicationThis paper describes the possible implementation of the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) as green analytical chemistry metrics tools. TOPSIS is one of the multi-criteria decision analysis (MCDA) tools that is applied in the selection of the best alternative from many possible. In this case we have applied it to assess the nineteen analytical procedures for ibuprofen determination in wastewater...
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Phase Change Thermal Energy Storage – The Experience of the Materials Preparation for the Specific Applications.
PublicationThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat storage, latent heat storage and reversible chemical reaction heat storage. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. The amount of heat...
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Volatile Organohalogen Compounds Determination with Dispersive Liquid-Liquid Microextraction Applying Solvent Lighter than Water
PublicationBackground: Volatile organohalogen compounds (VOX) are a group of environmental pollutants that risk the quality of drinking water. These compounds are characterized by certain acute and chronic toxicities, possessing mutagenic properties. Because of these potential risks factors that these compounds cause, the maximum allowable concentrations (MACs) have been established by respective organizations. The abundance of VOX, their...
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Solid Phase Synthesis and Biological Activity of Tuftsin Conjugates
PublicationNew tuftsin/retro-tuftsin conjugates were designed and synthesized using a classical fluorenylmethoxycarbonyl (Fmoc) solid phase procedure. All the peptide conjugates were divided into three series: 1,4-dihydroxyanthraquinone (type A), 1-nitroacridine (type B), and 4-carboxyacridone (type C) derivatives. In type A conjugates, the N-terminal group of the peptide chain is directly connected to the anthraquinone ring at C1 (Scheme...
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Experimental Evaluation of ND: YAG Laser Parameters and Sample Preparation Methods for Texturing Thin AISI 316L Steel Samples
PublicationIn mechanical and material engineering, the effect of laser texturing depends on many factors besides device specification, primarily the properties of the materials being processed, and, secondly, the preparation of the sample. Laser texturing of thin (<5 mm) samples is mostly performed utilizing short-pulse lasers, but depending on the power of the laser beam, the process can also be performed by using continuous operation lasers....
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Multi-objective optimization of microextraction procedures
PublicationOptimization of extraction process requiresfinding acceptable conditions for many analytes and goodperformance in terms of process time or solvent consumption. These optimization criteria are oftencontradictory to each other, the performance of the system in given conditions is good for some criteriabut poor for others. Therefore, such problems require special assessment tools that allow to combinethese contradictory criteria into...
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Headspace solid-phase microextraction and gas chromatography-olfactometry analysis of raw spirits of different organoleptic quality
PublicationCelem pracy było określenie, ktore związki wnoszą wkład w aromat destylatów rolniczych i wskazać te z nich które mogą powodować obniżenie ich właściwości organoleptycznych. W badaniach zastosowano ekstrakcję lotnych analitów z fazy nadpowierzchniowej techniką mikroekstrakcji do fazy nadpowierzchniowej w połączeniu z chromatografia gazową z detekcja olfaktometryczną . Znaleziono 40 zsubstancji, które mogą być markerami jakości organoleptycznej
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Opportunities and shortcomings of ionic liquids in single-drop microextraction
PublicationThe synergistic combination of ionic liquids (ILs) and single-drop microextraction (SDME) involves a powerful coupling toward the development of sustainable analytical methodologies. This overview provides a survey of the literature regarding the IL-SDME, including a database on relevant physicochemical properties of ILs for their application in SDME, the strategies implemented to combine IL-based SDME methods efficiently with...