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Search results for: BIOPOL
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Study of thermal property changes of biopol/polyamide 11 blends during biodegradation in compost.
PublicationPrzeprowadzone badania dotyczą zmian struktury krystalicznej podczas biodegradacji mieszanin polimerowych z udziałem PHBV, gdzie zależność między strukturą a podatnością na biodegradację związane są nie tylko ze stopniem krystaliczności PHBV ale także z budową faz składników mieszaniny. Wyniki pozwalają stwierdzić, że mieszaniny PA11/PHBV zawierające 60% kopoliestru PHBV(otrzymane przy użyciu wytłaczarki dwuślimakowej) charakteryzują...
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Study of thermal property changes of biopol/polyamide 11 blends during biodegradation in compost
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BIOPOLYMERS
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Biopolimery w konstrukcji nowoczesnych materiałów medycznych o aktywności antydrobnoustrojowej. Cz. I. Biopolimerowe materiały medyczne - kolagen, chitozan
PublicationArtykuł stanowi przegląd literatury dotyczącej możliwości wykorzystania biopolimerów do otrzymywania materiałów opatrunkowych o aktywności antydrobnoustrojowej. Opisano potencjał tkwiący w biopolimerach, takich jak kolagen i chitozan. Omówiono możliwości unieruchomienia w nich a następnie kontrolowanego uwalniania substancji aktywnych, nadających materiałom opatrunkowym właściwości bakteriobójcze, bakteriostatyczne oraz wspomagające...
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Biopolymers in designing modern antimicrobial medical materials. Part I. Biopolymer medical materials - collagen, chitosan
PublicationThe article is a review of the literature concerning the possible use of biopolymers for the preparation of dressings with antimicrobial activity. Authors show the potential of biopolymers: collagen and chitosan - which have the ability to immobilize and control the release of various active compounds - for providing the appropriate antibacterial, bacteriostatic and wound healing properties. Types of threats, for which the dressing...
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Wpływ budowy chemicznej na zmiany właściwości mechanicznych i termomechanicznych elastomerów biopoliuretanowych = The influence of chemical structure on mechanical and thermomechanical properties of cast biopolyurethane elastomers
PublicationPrzedmiotem niniejszej pracy są elastomery biopoliuretanowe otrzymywane metodą dwuetapową, tzw. prepolimerową, z wykorzystaniem surowców bio-pochodnych. Zbadano wpływ różnych małocząsteczkowych przedłużaczy łańcucha prepolimerowego: 1,2-biopropanodiolu oraz 1,3-biopropanodiolu na strukturę chemiczną i właściwości mechaniczne (warunki statyczne i dynamiczne) elastomerów biopoliuretanowych. Ponadto, wykorzystano również inny surowiec...
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Biopolymers and Cell
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Badania wpływu dodatku biopolimeru na przepuszczalność piasku średniego
PublicationW artykule przedstawiono wyniki badań współczynnika filtracji mieszaniny piasku średniego i gumy ksantanowej, dla różnych stężeń biopolimeru oraz różnych czasów utwardzania próbek. Badania wykonano w nowoczesnym Permeametrze wyposażonym w komorę trójosiową na stanowisku do badań przepuszczalności gruntów zanieczyszczonych w Centrum Wodnym SGGW. Badania potwierdziły, że dodatek biopolimeru do gruntu niespoistego powoduje znaczne...
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Preparation and characterization of biopolymeric films with magnetic properties
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Biopolymers and Their Composites for Drug Delivery: A Brief Review
PublicationIn recent years, excipient development has become a core area of research in pharmaceutical drug delivery because it influences the formulation development and drug delivery process in various ways. Polymeric drug delivery systems have been of great interest for controlled delivery as they show the great advantage in drug delivery systems because of optimized drug loading and releasing property. Then, the side effects of synthetic...
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Termoplastyczne elastomery biopoliuretanowe otrzymywane z dwóch substratów pochodzenia roślinnego
PublicationCelem niniejszej pracy było zbadanie wpływu monomerów pochodzenia roślinnego na wybrane właściwości nowych termoplastycznych elastomerów poliuretanowych. Przygotowane w pracy materiały otrzymano metodą dwuetapową (prepolimerową) z wykorzystaniem petrochemicznego diizocyjanianu oraz dwóch monomerów pochodzenia roślinnego (odnawialnego): biopoliolu i bioglikolu. Zbadano także wpływ stosunku molowego grup izocyjanianowych [NCO] do...
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Hydraulic conductivity of a biopolymer treated sand
PublicationThis paper presents results of laboratory assessment of creating seepage barriers in a sandy soil using biopolymer additives (bio substance), which consist of polysaccharides and water. Polysaccharides strongly interact with water to produce a viscous suspension. The aim of the conducted work was to investigate the influence of a biosubstance employed in a highly permeable sandy soil. The amount of the biopolymer used in a sample...
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Możliwości wykorzystania modyfikowanych olejów sojowego i palmowego w syntezie biopoliuretanów
PublicationArtykuł stanowi przegląd literatury obejmujący możliwości wykorzystania naturalnych modyfikowanych olejów: sojowego lub palmowego w syntezie materiałów poliuretanowych. Opisane także zostały metody modyfikacji chemicznej epoksydowanych olejów roślinnych.
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The mechanical properties of biopolyether-urethanes synthesized from bioglycols and hydroxylated soybean oil
PublicationArtykuł zawiera informcje dotyczące syntezy biopolietero-uretanów z uzyciem biokomponentów oraz porównanie wpływu przedłużaczy łańcucha polimerowego na właściwości mechaniczne i termomechaniczne wytworzonych materiałów.
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The Biocompatibility and Self-Healing Effect of a Biopolymer’s Coating on Zn Alloy for Biomedical Applications
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Evaluation of sorption capabilities of biopolymeric microspheres by the solid-phase extraction
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Laboratory assessment of permeability of sand and biopolymer mixtures
PublicationLaboratory assessment of permeability of sand and biopolymer mixtures. This research presents a method of creating seepage barriers in a sandy soil using biopolymer additives (biosubstance), which consist of polysaccharides and water. Polysaccharides strongly interact with water to produce a viscous suspension. The paper aims to investigate the infl uence of a biosubstance employed in a highly permeable sandy soil. Amount of the...
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Effect of surface modification on starch biopolymer wettability
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Właściwości mechaniczne i morfologia kompozytów biopoliuretanowych wzmocnionych modyfikowanymi włóknami sizalowymi
PublicationOmówiono wyniki badań właściwości mechanicznych i morfologii kompozytów biopoliuretanowych (bio-PUR) zawierających 5-15% mas. krótkich włókien sizalu. Materiały te wytworzono z systemu poliuretanowego, w którym zdyspergowano włókno poddane wcześniej merceryzacji lub silanizacji. Charakterystykę wytrzymałościową w warunkach statycznych uzyskano z krzywych naprężenie-odkształcenie, a morfologię kompozytów oceniono na podstawie zdjęć...
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Is Dialdehyde Chitosan a Good Substance to Modify Physicochemical Properties of Biopolymeric Materials?
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A novel hybrid composites based on biopolyamide 10.10 with basalt/aramid fibers: Mechanical and thermal investigation
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Biopolymer based nanomaterials in drug delivery systems: A review
PublicationDrug delivery systems (DDS) are used to achieve a higher therapeutic effects of a pharmaceutical drug or natural compound in a specific diseased site with minimal toxicological effect and these systems consists of liposomes, microspheres, gels, prodrugs and many. Nanotechnology is a rapidly developing multi-disciplinary science that ensures the fabrication of the polymers to nanometer scale for various medical applications. Uses...
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Some geomechanical properties of a biopolymer treated medium sand
PublicationSome geomechanical properties of a biopolymer treated medium sand. This paper presents a laboratory assessment of geomechanical properties of sandy soil improved by biopolymer application. Additives (biosubstance) consist of polysaccharides and water. Biosubstance used in the project was xanthan gum, which comes from bacteria Xanthomonas campestris. Triaxial shear compression tests and unconfi ned compression tests were carried...
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Maillard-reaction (glycation) of biopolymeric packaging films; principles, mechanisms, food applications
PublicationBackground The biodegradable, biocompatible, sustainable, and renewable nature of biomaterials has led to increased interest in developing biopolymeric food packaging films (BFPFs) with green ingredients and strategies. To enhance the performance of these films, biopolymer molecules can be modified or combined with additives like nanomaterials, cross-linkers, bioactive compounds, and other polymers, particularly with Maillard-reaction...
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Liquefaction of macroalgae Enteromorpha biomass for the preparation of biopolyols by using crude glycerol
PublicationThis article describes the liquefaction process of macroalgae Enteromorpha with the use of crude glycerol as a solvent and a reagent, aimed at obtaining of new bio-polyols, which are characterized with respect to their chemical structure, physical and thermal properties. Six different biopolyols were prepared. In order to optimize the liquefaction of algal biomass for the best bio-polyol properties, two catalysts (sulfuric or orthophosphoric...
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Konkurencja czy współpraca? Koegzystencja miast aglomeracji gdańskiej. Bipolarny rozwój aglomeracji-kierunki rozwoju układów biopolarnych
PublicationW artykule zwrócono uwagę na tendencje dezintegracyjne w aglomeracji gdańskiej oraz wskazano w jaki sposób należy im zapobiegać.
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Valorization of Bioplastic Waste: A Review on Effective Recycling Routes for the Most Widely Used Biopolymers
PublicationPlastics-based materials have a high carbon footprint, and their disposal is a considerable problem for the environment. Biodegradable bioplastics represent an alternative on which most countries have focused their attention to replace of conventional plastics in various sectors, among which food packaging is the most significant one. The evaluation of the optimal end-of-life process for bioplastic waste is of great importance...
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Biopolymers based paper coating with promoted grease resistivity, bio-degradable and mechanical properties
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Biopolymer-based composites for tissue engineering applications: A basis for future opportunities
PublicationBiomimetic scaffolds supporting tissue regeneration are complex materials with multifunctional characteristics. The unique biocompatibility and biodegradability of biopolymers make them excellent candidates for tissue engineering and regenerative medicine. Biopolymers, which have a wide range of properties, can be obtained from different natural sources. Depending on the target tissue, biopolymers can be engineered to meet a series...
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
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Study on the Structure-Property Dependences of Rigid PUR-PIR Foams Obtained from Marine Biomass-Based Biopolyol
PublicationThe paper describes the preparation and characterization of rigid polyurethane-polyisocyanurate (PUR-PIR) foams obtained with biopolyol synthesized in the process of liquefaction of biomass from the Baltic Sea. The obtained foams differed in the content of biopolyol in polyol mixture (0–30 wt%) and the isocyanate index (IISO = 200, 250, and 300). The prepared foams were characterized in terms of processing parameters (processing...
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Scale-consistent approach to the derivation of coarse-grained force fields for simulating structure, dynamics, and thermodynamics of biopolymers
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Biopolyols obtained via microwave-assisted liquefaction of lignin: structure, rheological, physical and thermal properties
PublicationThe present study examined the application of polyols obtained via microwave-assisted liquefaction of lignin in the production of rigid polyurethane foam. Lignin was liquefed in crude glycerol and 1,4-butanediol at diferent temperatures (130–170 °C), without a catalyst and using various biomass concentrations (15 and 30 wt%). The physicochemical properties, process yield, and FTIR-based identifcation of the obtained polyols were...
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Biopolyols obtained via crude glycerol-based liquefaction of cellulose: their structural, rheological and thermal characterization
PublicationIn this work lignocellulose biomass liquefaction was used to produce biopolyols suitable for the manufacturing of rigid polyurethane foams. In order to better evaluate the mechanism of the process, pure cellulose was applied as a raw material. The effect of time and temperature on the effectiveness of liquefaction and the parameters of resulting biopolyols were characterized. The prepared materials were analyzed in terms of their...
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Rapid communication: Computational simulation and analysis of a candidate for the design of a novel silk-based biopolymer
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Biopolimery w konstrukcji nowoczesnych materiałów medycznych o aktywności antydrobnoustrojowej. Cz. II. Metody aktywacji antydrobnoustrojowej materiałów medycznych
PublicationArtykuł stanowi Cz. II publikacji poświęconej konstrukcji nowoczesnych materiałów medycznych o aktywności antydrobnoustrojowej. Przedstawiono strategie nadawania właściwości antydrobnoustrojowych biopolimerowym materiałom medycznym. Omówiono wykorzystanie różnych, aktualnie stosowanych czynników antydrobnoustrojowych oraz mechanizmy odpowiadające za kontrolowane ich dostarczanie w miejscu zranienia. Szczególną uwagę poświęcono...
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Synthesis and characterization of biopolyols through biomass liquefaction of wood shavings and their application in the preparation of polyurethane wood composites
PublicationThe sustainability of production systems in wood processing, wood industry, and wooden waste disposal is an important issue for European industry and society. Proper development of products based on renewable wood resources gives an opportunity to provide materials with long-term environmental, social, and economic sustainability. This study aims to establish a new way of forestry and agricultural waste materials utilization by...
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Effects of Xanthan Gum Biopolymer on the Permeability, Odometer, Unconfined Compressive and Triaxial Shear Behavior of a Sand
PublicationBiopolymers, which are microbially induced polymers, can be used as an alternative material to improve engineering performance of soils. In this paper, a laboratory study of 0.075-1.0 mm size sand and biopolymer (i.e., xanthan gum) mixtures with various mix ratios (0%, 0.5%, 1.0%, and 1.5%) was performed. The materials, specimen preparation, and test methods are described, as are the results of a suite of permeability, odometer, unconfined...
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Chemical structures, rheological and physical properties of biopolyols prepared via solvothermal liquefaction of Enteromorpha and Zostera marina biomass
PublicationIn this work, liquefied biomass from the Baltic Sea was used for the preparation of rigid polyurethane (PUR) foams. The biomass contained 10 wt% of Enteromorpha macroalgae and 90 wt% of Zostera marina seagrass characterized by a high content of cellulose. The influence of time, temperature and the type of solvent on the efficiency of the liquefaction process and properties of biopolyols was determined. Obtained materials were analyzed...
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The study on application of biopolyols obtained by cellulose biomass liquefaction performed with crude glycerol for the synthesis of rigid polyurethane foams
PublicationIn this work rigid polyurethane foams (PUR) were obtained by replacement of 0–70 wt% of petrochemical polyol with bio-polyol obtained via cellulose liquefaction in presence of crude glycerol. The foams with different content of a bio-polyol were prepared by single step method for NCO/OH ratio equals 1.5. The prepared materials were analyzed in terms of their morphology, chemical structure, thermal stability and basic physical and...
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Two-step Conversion of Crude Glycerol Generated by Biodiesel Production into Biopolyols: Synthesis, Structural and Physical Chemical Characterization
PublicationIn this work biopolyols were synthesized via two-step process from crude glycerol and castor oil. For better evaluation of analyzed process, the impact of its time and temperature on the structure and properties of biopolyols was determined. Obtained results fully justified conducting of synthesis in two steps. Prepared materials were characterized by hydroxyl value and water content comparable to polyols industrially applied in...
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Effective assessment of biopolymer-based multifunctional sorbents for the remediation of environmentally hazardous contaminants from aqueous solutions
PublicationPersistent contaminants in wastewater effluent pose a significant threat to aquatic life and are one of the most significant environmental concerns of our time. Although there are a variety of traditional methods available in wastewater treatment, including adsorption, coagulation, flocculation, ion exchange, membrane filtration, co-precipitation and solvent extraction, none of these have been found to be significantly cost-effective...
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Effects of Surface Pretreatment of Titanium Substrates on Properties of Electrophoretically Deposited Biopolymer Chitosan/Eudragit E 100 Coatings
PublicationThe preparation of the metal surface before coating application is fundamental in determining the properties of the coatings, particularly the roughness, adhesion, and corrosion resistance. In this work, chitosan/Eudragit E 100 (chit/EE100) were fabricated by electrophoretic deposition (EPD) and both their microstructure and properties were investigated. The present research is aimed at characterizing the effects of the surface...
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Rheological properties, oxidative and thermal stability, and potential application of biopolyols prepared via two-step process from crude glycerol
PublicationIn this work, previously synthesized biopolyols were analyzed in terms of their rheological and thermal properties, very important from the technological point of view. For better evaluation of performed synthesis, the influence of its time and temperature on the properties of biopolyols was determined. In the end, obtained materials were used to prepare rigid polyurethane-polyisocyanurate (PUR-PIR) foams, to evaluate their potential...
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One- and two-photon induced fluorescence of Pacific Blue-labeled human serum albumine deposited on different core size silver colloids
PublicationPublikacja opisuje jedno i dwufotonowo indukowaną Fluorescencje znakowanej barwnikiem ''Pacific Blue'' ludzkiej albuminy osadzonej na srebrnych koloidach różnych rozmiarów
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Hybrid analogues of SFTI-1 modified in P1 position by β- and γ-amino acids and N-substituted β-alanines
PublicationA series of compounds containing either non-proteinogenic beta-/gamma-amino acids or N-substituted beta-alanine residues (beta-peptoid units) in P-1 specificity position were synthesized based on the structure of sunflower trypsin inhibitor 1 (SFTI-1). The compounds were synthesized on a solid support; the N-substituted beta-alanines (beta Nhlys and beta Nhphe) were introduced into a peptidomimetic chain via a two-step approach...
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Fluorescent analogs of trypsin inhibitor SFTI-1 isolated from sunflower seeds-synthesis and applications
PublicationThis article describes the synthesis and enzymatic study of newly synthesized analogs of trypsin inhibitors SFTI-1 that were fluorescent labeled on their N-terminal amino groups. Two fluorescent derivatives of benzoxazole (3-[2-(4-diphenylaminophenyl) benzoxazol-5-yl]-L-alanine[(4NPh(2)) Ph] Box-Ala and 3-[2-(2', 4', 5'-trimethoxyphenyl) benzoxazol-5-yl]-l-alanine-[2,4,5-(OMe)3Ph] Box-Ala) were used as efficient fluorescent labels....
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Molecular dynamics insights into protein‐glycosaminoglycan systems from microsecond‐scale simulations
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Local and long range potentials for heparin‐protein systems for coarse‐grained simulations
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Conformational stability of the full-atom hexameric model of the ClpB chaperone fromEscherichia coli
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