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Chemical investigation on the mechanism and kinetics of the atmospheric degradation reaction of Trichlorofluoroethene by OH⋅ and Its subsequent fate in the presence of O2/NOx
PublicationThe M06-2X/6-311++G(d,p) level of theory was used to examine the degradation of Trichlorofluoroethene (TCFE) initiated by OH⋅ radicals. Additionally, the coupled-cluster single-double with triple perturbative [CCSD(T)] method was employed to refine the single-point energies using the complete basis set extrapolation approach. The results indicated that OH-addition is the dominant pathway. OH⋅ adds to both the C1 and C2 carbons,...
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In-situ FTIR study of reaction mechanism and chemical kinetics of a Xundian lignite during non-isothermal low temperature pyrolysis
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Bifunctional sulfur-silicon podands as new nucleophilic ionophores in acyl transfer reactions. Influence of monovalent cations on the reaction kinetics
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The reaction of substituted N-phenacyl-pyridinium bromides in the pyridine ring with DABCO and DBU in water and DMSO. Kinetics and DFT studies
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The kinetics of phenol decomposition under UV irradiation with and without H2O2 on TiO2, Fe–TiO2 and Fe–C–TiO2 photocatalysts
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Heteroleptic cadmium(II) complex, potential precursor for semiconducting CdS layers. Thermal stability and non-isothermal decomposition kinetics
PublicationW ramach pracy zweryfikowano stabilność termiczną [Cd{SSi(OBut)3}(S2CNEt2)]2 - potencjalnego prekursora do otrzymywania warstw półprzewodnikowych CdS. Równocześnie przeprowadzono analizę kinetyki rozkładu za pomocą różnych metod izokonwersyjnych zaproponowanych przez Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose i Friedmanna w wyniku czego wyznaczono całkowity tryplet kinetyczny dla omawianego kompleksu.
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Adsorption Kinetics of Acid Dye Acid Red 88 onto Magnetic Multi‐Walled Carbon Nanotubes‐Fe3C Nanocomposite
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Development, characterization and evaluation of composite adsorbent for the adsorption of crystal violet from aqueous solution: Isotherm, kinetics, and thermodynamic studies
PublicationThe purpose of this work focuses on the production and investigations of a new composite material as alternative low-cost adsorbent for the removal of crystal violet (CV) dye from waste solution. The production method was performed by in-situ thermal activation technology via extrusion process of polymer wastes containing tire rubber (50 wt%) and polyurethane foam (50 wt%) using single-screw extruder under processing temperature...
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublicationNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Erratum to: Pro-Cognitive Properties of the Immunomodulatory Polypeptide Complex, Yolkin, from Chicken Egg Yolk and Colostrum-Derived Substances: Analyses Based on Animal Model of Age-Related Cognitive Deficits
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Panax quinquefolium L. Ginsenosides from Hairy Root Cultures and Their Clones Exert Cytotoxic, Genotoxic and Pro-Apoptotic Activity towards Human Colon Adenocarcinoma Cell Line Caco-2
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Structure-activity relationship study of a small cyclic peptide H-c[Lys-Pro-Glu]-Arg-OH: a potent inhibitor of Vascular Endothelial Growth Factor interaction with Neuropilin-1
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Synthesis of 3-(2-Alkylthio-4-chloro-5-methylbenzenesulfonyl)-2-(1-phenyl-3-arylprop-2-enylideneamino)guanidine Derivatives with Pro-Apoptotic Activity against Cancer Cells
PublicationThe untypical course of reaction between chalcones and benzenesulfonylaminoguanidines led to the new 3-(2-alkylthio-4-chloro-5-methylbenzenesulfonyl)-2-(1-phenyl-3-arylprop-2- enylideneamino)guanidine derivatives 8–33. The new compounds were tested in vitro for their impact on the growth of breast cancer cells MCF-7, cervical cancer cells HeLa and colon cancer cells HCT-116 by MTT assay. The results revealed that the activity of...
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Plants of the Genus Terminalia: An Insight on Its Biological Potentials, Pre-Clinical and Clinical Studies
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Jubileusz 75-lecia prof. zw. dr hab. inż. Karola Franciszka Macheja
PublicationPrzedstawiono drogę zawodową Profesora Karola Macheja. Scharakteryzowano kierunki badań rozwijane przez Profesora. Wskazano osiągnięcia z zakresu badań przenikania masy w wypełnionych aparatach kolumnowych, osiągnięcia w zakresie zastosowań rachunku krakowianowego do zagadnień inżynierii chemicznej, osiągnięcia w zakresie badań równoczesnej wymiany ciepła i masy, osiągniecia z zakresu badań nad krystalizacją masową.
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Single‐walled carbon nanotubes modified by PFO: An optical absorption and Raman spectroscopic investigation
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Nuclear retention of pre-mRNA involving Cajal bodies during meiotic prophase in plants
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublicationThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Optimization of Saccharification Conditions of Lignocellulosic Biomass under Alkaline Pre-Treatment and Enzymatic Hydrolysis
PublicationPre-treatment is a significant step in the production of second-generation biofuels from waste lignocellulosic materials. Obtaining biofuels as a result of fermentation processes requires appropriate pre-treatment conditions ensuring the highest possible degree of saccharification of the feed material. An influence of the following process parameters were investigated for alkaline pre-treatment of Salix viminalis L.: catalyst concentration...
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Hydrogen Production from Energy Poplar Preceded by MEA Pre-Treatment and Enzymatic Hydrolysis
PublicationThe need to pre-treat lignocellulosic biomass prior to dark fermentation results primarily from the composition of lignocellulose because lignin hinders the processing of hard wood towards useful products. Hence, in this work a two-step approach for the pre-treatment of energy poplar, including alkaline pre-treatment and enzymatic saccharification followed by fermentation has been studied. Monoethanolamine (MEA) was used as the...
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Impedance monitoring of corrosion degradation of plasma electrolytic oxidation coatings (PEO) on magnesium alloy
PublicationImpedance technique based on continuous multisinusoidal current perturbation was used to explain degradation process of plasma electrolytic oxidation coatings (PEO) on magnesium alloy. An obtained impedance spectrum was fitted by electrical equivalent circuit to describe properties of conversion layer on magnesium alloy. Additionally, galvanostatic mode maintained during experiment, with DC current equal to zero, allowed to achieve...
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Pre-analytical aspects in metabolomics of human biofluids – sample collection, handling, transport, and storage
PublicationMetabolomics is the field of omics research that offers valuable insights into the complex composition of biological samples. It has found wide application in clinical diagnostics, disease investigation, therapy prediction, monitoring of treatment efficiency, drug discovery, or in-depth analysis of sample composition. A suitable study design constitutes the fundamental requirements to ensure robust and reliable results from the...
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Selection of an artificial pre-training neural network for the classification of inland vessels based on their images
PublicationArtificial neural networks (ANN) are the most commonly used algorithms for image classification problems. An image classifier takes an image or video as input and classifies it into one of the possible categories that it was trained to identify. They are applied in various areas such as security, defense, healthcare, biology, forensics, communication, etc. There is no need to create one’s own ANN because there are several pre-trained...
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Effect of modified soybeen oil amount on rheological characteriza-tion of polyurethane pre-polymers
PublicationPolyurethanes (Pu’s) are the polymeric materials which have got urethane groups in the structure. The properties of Pu’s depend both on the method of preparation and monomers used. Polyurethanes are produced by two methods known as one step or two step method called as “pre-polymers method”, especially for the case of segmented polyurethanes (SPU’s). These materials are thermoplastic block copolymers of the (AB)n type consisting...
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Professor Janusz Rachon official address at the University of Karlsruhe
PublicationWystąpienie na uroczystości 25−lecia współpracy i 10−lecia podwójnego dyplomu Uniwersytetu w Karlsruhe i Politechniki Gdańskiej, Karlsruhe, 9 lipca 2007
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A modified static equivalency method for roll-on/roll-off vessels
PublicationPrzedstawiono zmodyfikowaną metodę statycznej równoważności dla statków ro-ro, opartą na wypiętrzaniu się wody na pokładzie samochodowym w wypadku wystąpienia otworu w burcie, do oceny bezpieczeństwa statku.
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Application of gas chromatography to the study of the kinetics of reactionsin solution. Ring opening reactions for á-lactams studied using internal standard
PublicationW pracy przedstawiono metodę badania kinetyki reakcji otwarcia pierścienia á-laktamu, wykorzystującą technikę chromatografii gazowej. Na podstawie badań kinetyki reakcji w różnych temperaturach wyznaczono wartości energii aktywacji dwóch badanych reakcji. Podstawowym celem pracy było pokazanie możliwości wykorzystania GC w badaniach kinetyki reakcji prowadzonych w mikroskali.
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Degradation Efficiency and Kinetics Analysis of an Advanced Oxidation Process Utilizing Ozone, Hydrogen Peroxide and Persulfate to Degrade the Dye Rhodamine B
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WITHDRAWN: The kinetics of phenol decomposition under UV irradiation with and without H2O2 on TiO2, Fe-TiO2 and Fe-C-TiO2 photocatalysts
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Process Control and Investigation of Oxidation Kinetics of Postoxidative Effluents Using Gas Chromatography with Pulsed Flame Photometric Detection (GC-PFPD)
PublicationThis article presents the results of investigations on the use of headspace analysis and gas chromatography with pulsed flame photometric detection (HSA-GC-PFPD) to evaluate the effectiveness of oxidation of postoxidative effluents from the production of bitumens. Samples of effluents from the bitumen oxidation unit were used in the experiments. In addition, the kinetics of effluent oxidation was also investigated. The content...
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Kinetics of adsorption of hydrocarbon chloro-derivatives from seven-component aqueous solution onto a thin layer of DTO-activated carbon
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Evaluation of citric acid corrosion inhibition efficiency and passivation kinetics for aluminium alloys in alkaline media by means of dynamic impedance monitoring
PublicationA novel approach is proposed for constructing the adsorption isotherm in corrosion studies, based on a well-known interaction between citric acid and aluminium in alkaline electrolytes. Our approach utilizes the instantaneous impedance measurements via Dynamic Electrochemical Impedance Spectroscopy in galvanostatic mode (g-DEIS). Unlike other common tools, g-DEIS delivers exact information about the concentration required for full...
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Release Kinetics Studies of Early-Stage Volatile Secondary Oxidation Products of Rapeseed Oil Emitted during the Deep-Frying Process
PublicationThe research concerns the use of proton transfer reaction mass spectrometer to track real-time emissions of volatile secondary oxidation products released from rapeseed oil as a result of deep-frying of potato cubes. Therefore, it was possible to observe a sudden increase of volatile organic compound (VOC) emissions caused by immersion of the food, accompanied by a sudden release of steam from a potato cube and a decrease of the...
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Mathematical modelling of two-step nitrification-denitrification for treatment of sludge digester liquors: influence of nitrite (NO2-N) on the process kinetics
PublicationSeparate treatment of the sludge digester liquors is an alternative for expansion of the mainstream treatment line. In order to reduce the oxygen demand for nitrification and organic carbon demand for denitrification, a shortcut in the nitrogen conversion pathway has been promoted in recent years, i.e. nitrification-denitrification via NO2-N instead of NO3-N. Although NO2-N is a common intermediate product of nitrification and...
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Kamienica gdańska po 1945 r.
PublicationPrzedmiotem artykułu jest syntetyczna charakterystyka zespołu kamienic Głównego Miasta w Gdańsku, odbudowanych po 1945 roku. Wychodząc od opisu struktury przestrzennej kamienicy i jej przekształceń przed rokiem 1945 - autor opisuje stan zniszczeń, założenia i praktykę odbudowy; podejmuje próbę krytycznej systematyki powstałych form architektonicznych oraz subiektywnej oceny wyników całego przedsięwzięcia.
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Wprowadzenie :Inteligentne miasta po polsku
PublicationW rozdziale zostały opisane przedmiot, cel oraz metoda przeprowadzonych badań porównawczych między miastami. Na podstawie praktycznego zastosowania różnych form planowania w Glasgow wskazane zostały aspekty różnicujące planowanie w Polsce i Szkocji.
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zaduszki miejskie PRZYSTANEK PO ZMROKU
Publication„Miasto potrzebuje przystanków. Są w nim potrzebne jako miejsca refleksji nad tym, co zaniedbane, co szczęśliwie dopełnione, co trwa i co może jeszcze się wydarzyć. Przystanek może stać się przestrzenią do rozmyślań nad tym, co bezpowrotnie minione. Może pomóc utrzymać wgląd w perspektywę dawnych, ważnych zamierzeń, także, by przywołać ich wartość w codziennej wędrówce. Wystawa PRZYSTANEK PO ZMROKU dedykowana jest miejscom pozbawionym...
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LCF behavior of 2024AA under uni- and biaxial loading taking into account creep pre-deformation
PublicationThis study presents the results of experimental low-cycle fatigue (LCF) tests of aluminum 2024 alloy T3511 temper in uni- and biaxial loading states. Tests were carried out on both the as-received material (hardened extruded rods) and material with different pre-deformation histories. These deformations were carried out in the creep process at 200 °C and 300 °C for two different levels of at each temperature. The pre-deformed material’s...
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Importance of sign conventions on analytical solutions to the wave-induced cyclic response of a poro-elastic seabed
PublicationThis paper discusses the influence of different sign conventions for strains and stresses, i.e. the solid mechanics sign convention and the soil mechanics sign convention, on the form of governing partial differential equations (the static equilibrium equations and the continuity equation) used to describe the wave-induced cyclic response of a poro-elastic seabed due to propagation of a sinusoidal surface water-wave. Some selected...
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Umysł otwarty. Z dr. hab. Zbigniewem Kaźmierczykiem, prof. UG, rozmawia Anna Burzyńska
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Impact of Pre-Sowing Red Light Treatment of Sweet Corn Seeds on the Quality and Quantity of Yield
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Dr hab. inż. Roman J. Wasielewski prof. nadzw. PG (1951-2012) - Wspomnienie
PublicationPrzedstawiono sylwetkę naukową zmarłego prof. nadzw. PG dr hab. inż. Romana J. Wasielewskiego, długoletniego pracownika Wydziału Mechanicznego PG. Profesor Roman Wasielewski był kontynuatorem długoletnich tradycji naukowych z zakresu mechanicznej technologii drewna.
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Injectable Platelet-Rich Fibrin (I-PRF) Administered to Temporomandibular Joint Cavities: A Scoping Review
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High-performance polylactic acid compressed strawboard using pre-treated and functionalised wheat straw
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Pre‐exascale HPC approaches for molecular dynamics simulations. Covid‐19 research: A use case
PublicationExascale computing has been a dream for ages and is close to becoming a reality that will impact how molecular simulations are being performed, as well as the quantity and quality of the information derived for them. We review how the biomolecular simulations field is anticipating these new architectures, making emphasis on recent work from groups in the BioExcel Center of Excellence for High Performance Computing. We exemplified...
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Application of the 3D DEM in the modelling of fractures in pre-flawed marble specimens during uniaxial compression
PublicationPrzedstawiono w tym artykule wyniki modelowania pęknięć w cylindrycznych próbkach marmurowych ze wstępnymi nacięciami w czasie jednoosiowego ściskania . Zastosowano metodę elementów dyskretnych (DEM). Zbadano propagację i koalescencję pęknięć w próbkach marmuru z istniejącymi otwartymi nacięciami pod różnymi kątami do poziomu. Wyniki numerycznych symulacji trójwymiarowych (3D) zostały bezpośrednio porównane z badaniami laboratoryjnymi....
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The effect of pressure on luminescence properties of Cr3+ ions in LiSc(WO4)2 crystals—Part II: Pressure- and temperature-dependent luminescence kinetics
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Adsorption of anionic dye Direct Red 23 onto magnetic multi-walled carbon nanotubes-Fe3C nanocomposite: Kinetics, equilibrium and thermodynamics
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Kinetics and thermodynamics of the reaction of iminodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2′-bipyridine in aqueous, anionic, cationic and nonionic surfactants solutions
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The role of structural factors in the kinetics of cellular uptake of pyrazoloacridines and pyrazolopyrimidoakridines. Implications for overcoming multidrug resistance towards leukaemia K562/DOX cells.
PublicationOtrzymano dwie grupy związków: pyrazoloakrydony (PAC) i pyrazolopirymidoakrydony (PPAC). Zbadano molekularne podstawy różnic w aktywności cytotoksycznej otrzymanych związków na poziomie komórkowym wobec komórek opornych linii ludzkiej erytroleukemii K562/DOX z nadekspresją P-glikoproteiny. Zastosowano spektrofluorymetryczną metodę badania transportu związków, która pozwala obserwować zarówno dyfuzję fluoryzujących cząsteczek związku...