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Search results for: WEGLIKI TIC
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Fatal intoxication with U-47700 in combination with other NPS (N-ethylhexedrone, adinazolam, 4-CIC, 4-CMC) confirmed by identification and quantification in autopsy specimens and evidences
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Toward Mechanosynthesis of Diamondoid Structures: IX Commercial Capped CNT Scanning Probe Microscopy Tip as Nowadays Available Tool for Silylene Molecule and Silicon Atom Transfer
PublicationAccording to K. E. Drexler, advanced mechanosynthesis will employ advanced nanomachines, but advanced nanomachines will themselves be product of advanced mechanosynthesis. This circular relationship must be broken in SPM technology development. In the article, the possibility of use easy available commercial CNT tips to assembly silicon-based intermediate generations of nano-devices is considered. Mechanosynthesis of a target class...
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Phenolic composition and antioxidant properties of polish blue-berried honeysuckle genotypes by HPLC-DAD-MS, HPLC postcolumn derivatization with ABTS or FC, and TLC with DPPH visualization
PublicationIn this study, different Polish cultivars of blue-berried honeysuckles (Lonicera caerulea L.), wild and bog bilberry, were analyzed for bioactive compounds. The chemical properties verified included composition of anthocyanins and other polyphenols, antioxidant activity, and profiles of antioxidants by HPLC postcolumn derivatization or TLC. The antioxidant activities of different blue-berried honeysuckle cultivars were similar...
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Chromium‑based metal organic framework for pipette tip micro‑solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
PublicationAbstract Background A chromium-based metal organic framework was synthesized and employed as an efficient sorbent for pipette tip micro-solid phase extraction and preconcentration of parabens from wastewater and shampoo samples up to sub-ppb level before their spectrophotometric analysis. Results Factors affecting preconcentration including volume and type of solvent, amount of sorbent, number of extraction, and volume and pH of...
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Rozwój materiałów tytanowych na implanty aloplastyczne = Development of Ti-based materials for alloplastic implants
PublicationThe article is aimed at demonstraiting the previous results and current research work in the area made by Advanced Biomaterials Research Group at the Faculty of Mechanical Engineering. The paper concentrated on the developement of Ti-based biomaterials with improved biocompatibility and bioactivity.
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Manipulating Electrical Properties of Nanopatterned Double-Barrier Schottky Junctions in Ti/TiOx/Fe Systems
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The isomerization of α-pinene over the Ti-SBA-15 catalyst—the influence of catalyst content and temperature
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Influence of the Titanium Content in the Ti-MCM-41 Catalyst on the Course of the α-Pinene Isomerization Process
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Growth and properties of Ti-Cu films with respect to plasma parameters in dual-magnetron sputtering discharges
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Initial stage of (Bi-Pb)2Sr2Ca1Cu2Ox high Tc superconductor crystallisation from the amorphous phase.
PublicationWysokotemperaturowe nadprzewodniki bizmutowe 2201, 2212 i 2223 były wytwarzane metodą krystalizacji w fazie stałej. Zmiany struktury i mikrostruktury badano metodą dyfrakcji rentgenowskiej oraz skanningowej mikroskopii elektronowej. Zbadano kinetykę krystalizacji oraz przedyskutowano jej przebieg.
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Improvement of machinability of Ti and its alloys using cooling-lubrication techniques: a review and future prospect
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Crystal structure and physical properties of Mg6Cu16Si7-typeM6Ni16Si7, for M = Mg, Sc, Ti, Nb, and Ta
PublicationW pracy dyskutowana jest synteza i struktura krystalograficzna, określona poprzez proszkową dyfrakcję rentgenowską, dla pięciu związków M6Ni16Si7, gdzie M = Mg, Sc, Ti, Nb, and Ta. Wszystkie te związki krystalizują w strukturze typu Mg6Cu16Si7.
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Modelling of ic engine coolant system with permanent magnet brushless motor - bond graphs approach
PublicationW pierwszej części referatu przedstawiono strukturę i podstawy modelowania w ujęciu grafów wiązań nowoczesnego (nowej generacji) systemu chłodzenia silnika spalinowego. Istotną cechą rozważnego systemu chłodzenia jest zastosowanie zintegrowanego układu: pompa cieczy chłodzącej-bezszczotkowy silniki prądu stałego (BSPS, ang. BDCM). W kolejnych częściach referatu przedstawiono: podstawy modelowania całego systemu chłodzenia, model...
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THE USE OF THE Ti-13Zr-13Nb ALLOY POWDER FOR MANUFACTURING OF PROSTHETIC PARTS BY SELECTIVE LASER MELTING
PublicationThe 3D printing is a manufacturing technique belonging to the additive methods able to prepare the designed parts for various purposes. The present reasearch was aimed to fabricate the prosthetic foundations and bridges made of the new Ti-13Zr-13Nb alloy by the selective laser melting (SLM) of a metal powder. The scanning electron examinations and micro scanning tomography were used to investigate the surface quality and intrinsic...
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A Flexible Nafion Coated Enzyme‐free Glucose Sensor Based on Au‐dimpled Ti Structures
PublicationThe detection of glucose at low concentrations using electrochemical sensors is of great importance due to the possibility of using different human body fluids than blood, such as e.g. urine, saliva, sweat or tears. The interest behind those biofluids is related to their utility in non-invasive sugar determination. In this work, we present flexible, fully biocompatible electrode material based on Au nanoparticles immobilized onto...
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Fluorine ions in photocatalysts’ synthesis: an obstacle or an ally? The investigation of photocatalysts in Ti-O-F system
PublicationTitanium(IV) oxide (TiO2) is one of the most promising photocatalysts, which is expected to be applied in the photocatalytic degradation of xenobiotics. For sustainable development and green chemistry approach recently, much effort has been paid to enhance TiO2 photocatalytic activity in UV-vis light by modifying its structure. The photocatalytic process’s complexity cannot be simply described as electron-hole pairs generations...
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Proton-Electron Hole Interactions in Sr(Ti,Fe)O3−δ Mixed-Conducting Perovskites
PublicationOxides in which total electrical conductivity is determined by the partial conductivities of three types of charge carriers i.e. holes/ electrons, oxygen ions, and protons are key components of well-functioning proton ceramic fuel cells. Apart from electrochemical properties also easily modified microstructure is an important feature of the electrodes. In the paper, a group of SrTi1−xFexO3−δ (STF, x = 0.2–0.8) perovskites prepared...
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Enhanced Charge Storage Mechanism And Long-Term Cycling Stability In Diamondized Titania Nanocomposite Supercapacitors Operating In Aqueous Electrolytes
PublicationThe long cycle life stability jointly with high energy density are limiting broader feasible applications of supercapacitors. The novel diamondized titania nanocomposite supercapacitors deliver high power and energy densities along with high capacitance retention rates. Supercapacitor electrodes were fabricated utilizing a combination of Ti anodization followed by chemical vapor deposition resulting in simultaneous growth of complex...
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Elementy analizy RAMS i cyklu życia napędów nowej generacji w układzie e-transformatora realizowanych w technologii SiC do elektrycznych zespołów trakcyjnych
PublicationTransport kolejowy podlega ciągłej presji, aby zwiększać dostępność połączeń i obniżać koszty przejazdów. Konstruktorzy pociągów i przewoźnicy, w odpowiedzi na stawiane oczekiwania, starają się wdrażać pojawiające się na rynku nowe innowacyjne rozwiązania. Europejski program Shift2Rail stawia ambitne cele w stosunku do kluczowych wskaźników wydajności (z ang. KPI - Key Performance Indicators) systemu kolejowego obejmującego infrastrukturę,...
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Surface-enhanced Raman scattering (SERS) and tip-enhanced Raman scattering (TERS) in label-free characterization of erythrocyte membranes and extracellular vesicles at the nano-scale and molecular level
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Correction to: Chromium‑based metal organic framework for pipette tip micro‑solid phase extraction: an effective approach for determination of methyl and propyl parabens in wastewater and shampoo samples
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Effect of particle size and weight fraction of SiC on the mechanical, tribological, morphological, and structural properties of Al-5.6Zn-2.2Mg-1.3Cu composites using RSM: fabrication, characterization, and modelling
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Water and chemical properties of hydrometeors over central european mountains
PublicationAtmospheric pollutants are transferred to the groundby the contribution of various types of hydrometeors. Because ofthe different techniques of measurement, comparative analysesbetween them are often neglected. Hence, the main goal is tocompare water volume and chemistry of different types ofhydrometeors and their role in both: water balance and pollutantsdeposition. The results of water input and atmospheric depositschemistry...
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Fabrication and characterization of composite TiO2 nanotubes/ boron-doped diamond electrodes towards enhanced supercapacitors
PublicationThe composite TiO2 nanotubes / boron-doped diamond electrodes were deposited using Microwave Plasma Enhanced Chemical Vapor Deposition resulting in the improved electrochemical performance. This composite electrode can deliver high specific capacitance of 7.46 mF cm‐− 2 comparing to boron-doped diamond (BDD) deposited onto flat Ti plate (0.11 mF cm‐− 2).The morphology and composition of composite electrode were characterized...
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Development of UV/H 2 O 2 /TiO 2 –LECA hybrid process based on operating cost: Application of an effective fixed bed photo-catalytic recycled reactor
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The Mesoporous Porphyrinic Zirconium Metal-Organic Framework for Pipette-Tip Solid-Phase Extraction of Mercury from Fish Samples Followed by Cold Vapor Atomic Absorption Spectrometric Determination
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Experimental validation and comparison of a SiC MOSFET based 100 kW 1.2 kV 20 kHz three-phase dual active bridge converter using two vector groups
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Analysis of size and shape of abrasive micrograins in lapping of assembly joints
PublicationPrzedstawiono skomputeryzowana analizę wielkości i kształtu mikroziaren ściernych. W badaniach mikroziaren węglika boru, węglika krzemu i elektrokorundu zastosowano mikroskopie optyczna oraz specjalistyczne oprogramowanie MultiScan v.6.08
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Determinants of the surface quality, density and dimensional correctness in selective laser melting of the Ti-13Zr-13Nb alloy
PublicationSelective laser melting is widely used for custom-designed elements. Successful manufacturing depends on laser treatment parameters and material features. This research aimed to determine the effects of laser power, scan time and hatch distance on surface quality, relative density and dimensional precision for cuboids made of the Ti-13Zr-13Nb alloy. The influence of energy density, energy flux and pre-heating was seen to be decisive...
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Yield surface identification of CP-Ti and its evolution reflecting pre-deformation under complex loading
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Core/shell structured Ti/Si/C composite for high-performance zinc-ion hybrid capacitor
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Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications
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Tailoring the Stability of Ti-Doped Sr2Fe1.4TixMo0.6−xO6−δ Electrode Materials for Solid Oxide Fuel Cells
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Fatigue resistance investigation of the IC engine MB11 bearings, working under conditions of dynamic unidirectional loadings
PublicationThe slide bearing material MB11 fatigue resistance has been investigated with the application of SMOK - test stand in which dynamic unidirectional loadings to the test bearing is generated. Slide bearing layer consists of the bronze MB11 ( Cu Pb22 Sn 3 ) sintered to the steel shell. Each of the tested bearing has been subject to the standard 20-hour test, under conditions of the full fluid lubrication. Methodology of the experiments,...
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Korozyjne pękanie naprężeniowe stali 18Cr-10Ni-Ti w systemie chłodzenia za wodorowym reaktorem.
PublicationPrzedstawiono mechanizm korozyjnego pękania napręzeniowego stali austenitycznej 18Cr-10Ni-Ti w systemie chłodzenia za reaktorem instalacji hydrorafinacji olejów przepracowanych.
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Novel composite of Zn/Ti-layered double hydroxide coupled with MXene for the efficient photocatalytic degradation of pharmaceuticals
PublicationIn the present study, a hybrid photocatalyst of Zn/Ti layered double hydroxide (LDH) coupled with MXene – Ti3C2 was synthesized for the first time and applied in photocatalytic degradation of acetaminophen and ibuprofen, two commonly present in the natural environment and prone to accumulate in the aquatic ecosystem pharmaceuticals. The effect of MXene content (0.5 wt%, 2.5 wt%, and 5 wt%) on the photocatalytic activity of LDH/MXene...
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Crystal structure and physical properties of Mg6Cu16Si7-type M6Ni16Si7, for M=Mg, Sc, Ti, Nb, and Ta
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Toward Mechanosynthesis of Diamondoid Structures: VI. Quantum-Chemical Molecular Dynamics Comparison of Conditions for the STM Tip Driven Mechanosynthesis on Hydrogenated Si(111), Si(110) and Si(100) Surfaces.
Publicationmożliwość prototypowania przejściowych generacji nano-urządzeń otrzymanych drogą pozycjonowanej mechanosyntezy za pomocą stm wyposażonego w ostrze typu swcnt są analizowane metodą kwantowo-chemicznej dynamiki molekularnej. proponowana strategia syntezy polega na insercji atomów si oraz cząsteczek sih2 we wiązania si-h na uwodornionej powierzchni si(111), si(110) oraz si(100) kryształu krzemu. rezultaty modelowania sugerują, że...
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Application of Box-Behnken design in response surface methodology for the molecularly imprinted polymer pipette-tip solid phase extraction of methyl red from seawater samples and its determination by spectrophotometery
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Separation and determination of ciprofloxacin in seawater, human blood plasma and tablet samples using molecularly imprinted polymer pipette‐tip solid phase extraction and its optimization by response surface methodology
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Tool wear, surface roughness, cutting temperature and chips morphology evaluation of Al/TiN coated carbide cutting tools in milling of Cu–B–CrC based ceramic matrix composites
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The Ellenbogen's “Matter as Software” Concept for Quantum Computer Implementation. C60 and X@C60 Molecules as Available Molecular Building Blocks (MBBs) for Tip-Based Nanofabrication (TBN) of Quantum Computing Devices
PublicationThe TBN bottom-up strategy of building quantum devices from C60 and X@C60 MBBs is proposed as an extension of the Ellenbogen's “Matter as Software” idea to quantum information processing. The capped SW or DW CNT STM tip is considered as device for manipulating C60 and X@C60 molecules. In this article, the possibility of using easily available on the market C60 Fullerene and endohedral X@C60 molecules together with commercial CNT...
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Pollutant deposition via dew in urban and rural environment, Cracow, Poland
PublicationThis study is a comparative analysis of dew in rural and urban environment. Dew samples were collected between May and October, 2009 in two reference stations in southern Poland: Cracow and Gaik-Brzezowa. The investigation included comparison of volume and chemistry of the collected samples. Due to its formation mechanisms, dew is a good indicator of air pollution. Following parameters were analyzed in 159 collected samples: pH,...
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Protective properties of the chromium - titanium carbonitryde composite coatings.
PublicationZbadano właściwości ochronne warstw chromowych zawierających dodatki węglika tytanu poprawiającego właściwości mechaniczne warstw. badania ditycżą roztworów kwasu siarkowego. Badania przeprpwadzono metodą spektroskopii impedamncyjnej. Wykazano ze właściwosci ochronne warswt są lepsze dzięki sdyspergowanym cząstkowm węglika tytanu.
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Epoxidation of natural limonene extracted from orange peels with hydrogen peroxide over Ti-MCM-41 catalyst
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Characterization and Wear Response of Magnetron Sputtered W–B and W–Ti–B Coatings on WC–Co Tools
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Adhesion of AlCrN coating deposited on TiB2/Ti composites sintered by SPS dedicated for high temperature tribological applications
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Optimization of biocorrosion resistance and mechanical properties of PM Ti–XAl–2Fe–3Cu alloys by response surface methodology
PublicationIn the current study, the biocorrosion resistance and mechanical properties of the Ti–XAl–2Fe–3Cu (wt%) (X = 6, 4, 2 wt%) alloy produced by powder compact extrusion of blended elemental powders were optimized by using the response surface methodology in order to gain the best combination of processing parameters. To run the optimization process, central composite design with three equal levels of oxygen, hydrogen and aluminum was...
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Zbadanie właściwości strukturalnych i elektrycznych niestechiometrycznych, domieszkowanych związków typu Srx(Ti,Fe)O3-δ
PublicationNiniejsza rozprawa doktorska zatytułowana: „Zbadanie właściwości strukturalnych i elektrycznych niestechiometrycznych, domieszkowanych związków typu Srx(Ti,Fe)O3-δ” przedstawia wyniki badań właściwości fizykochemicznych domieszkowanego tytanianu strontu wykazującego mieszane przewodnictwo jonowo-elektronowe, w celu poszerzenia o nim wiedzy i określenia jego przydatności w urządzeniach elektrochemicznych. Przebadano szereg związków...
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Synthesis and properties of porous Sr 0.96 Y 0.04 Ti 1−x Nb x O 3
PublicationA series of porous, single phase Sr0.96Y0.04Ti1-xNbxO3 samples was obtained using a wet synthesis method (modified citrate sol-gel) method. Temperature-programmed reduction (TPR) and temperature-programmed oxidation (TPO) measurements have shown high stability of the obtained material in variable (oxidizing/reducing) atmospheres. All samples exhibit high conductivity in hydrogen atmosphere with the highest value (around 1S/cm)...