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Search results for: INFORMAL SETTLEMENTS

  • Golden artefacts, resin figurines, body adhesives and tomb sediments from the pre-Columbian burial site El Caño (Gran Coclé, Panamá): tracing organic contents using molecular archaeometry

    Publication
    • J. Kaal
    • M. Martín Seijo
    • C. Oliveira
    • E. Wagner-Wysiecka
    • V. E. McCoy
    • M. M. Solórzano Kraemer
    • A. Kerner
    • P. Wenig
    • C. Mayo
    • J. Mayo

    - Journal of Archaeological Science - Year 2020

    This research aimed to determine the origin of organic residues from funerary contexts in the El Ca~no settlement (Gran Cocl�e area, Panam�a, Central America) by means of multiple molecular probing techniques (GC-MS of organic solvent extracts and pyrolysis-GC-MS, THM-GC-MS and FTIR of solid samples). The samples include particles of precious resin figurines, fillings of golden objects, tomb sediments, plant exudates from extant...

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  • RAGE as a Novel Biomarker for Prostate Cancer: A Systematic Review and Meta-Analysis

    Publication
    • C. C. Applegate
    • M. B. Nelappana
    • E. A. Nielsen
    • L. Kalinowski
    • I. T. Dobrucki
    • L. W. Dobrucki

    - Cancers - Year 2023

    The receptor for advanced glycation end-products (RAGE) has been implicated in driving prostate cancer (PCa) growth, aggression, and metastasis through the fueling of chronic inflammation in the tumor microenvironment. This systematic review and meta-analysis summarizes and analyzes the current clinical and preclinical data to provide insight into the relationships among RAGE levels and PCa, cancer grade, and molecular effects....

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  • System for monitoring road slippery based on CCTV cameras and convolutional neural networks

    Publication

    The slipperiness of the surface is essential for road safety. The growing number of CCTV cameras opens the possibility of using them to automatically detect the slippery surface and inform road users about it. This paper presents a system of developed intelligent road signs, including a detector based on convolutional neural networks (CNNs) and the transferlearning method employed to the processing of images acquired with video...

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  • Political Parties in the Digital World

    Publication

    - Year 2017

    The aim of this report is to outline how digital technologies and digital media are redefining the way political parties fulfill their role as collective platforms for political participation of citizens, e.g. in relation to the parties’ decision-making processes, communication strategies, funding mechanisms, membership, information sharing, etc. and to highlight the existing international standards and good practices in this area....

  • Digital Government as Implementation Means for Sustainable Development Goals

    Publication

    - International Journal of Public Administration in the Digital Age - Year 2019

    One of the challenges for implementing Sustainable Development Goals (SDGs) is the measurement of indicators that represent progress towards such goals. Measuring such progress enables data-driven decision-making and management of SDG-relevant projects and strategies. The premise of this research is that measuring such indicators depends on measuring so-called means of implementation, i.e. activities that directly contribute to...

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  • Insight into heart regeneration

    Publication

    The mammalian heart is thought to be incapable of regeneration because of the limited ability of cardiomyocytes. to proliferate. However, it has been recently shown that the neonatal murine heart is able to restore its normal function after coronary artery ligation or even partial resection. Unfortunately, this feature is lost in a few days after birth, although lower vertebrates as zebrafish or newt, retain this ability until adulthood. Therefore,...

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  • Quantitative risk assessment of new ship designs in damage conditions

    Publication

    - Year 2015

    The paper is devoted to safety of ships in damage conditions. The novel contribution of the paper is connected with a new Multi-Task ship (MT-ship) design at the preliminary stage of design. There are a few problems at the preliminary stage that should be considered. One problem is connected with if the quantitative risk-based method is a reliable and formal method for safety assessment of such the new design (MT-ship) in damage...

  • Depolarisation Model for a BAN Indoor Scenario

    Publication
    • M. M. Ferreira
    • F. D. Cardoso
    • S. J. Ambroziak
    • M. Särestöniemi
    • K. Turbic
    • L. M. Correia

    - Year 2023

    In this paper, an analysis of depolarisation in Body Area Networks for Body-to-Infrastructure communications based on a measurement campaign in the 5.8 GHz band in an indoor environment is performed. Measurements were made with an offbody antenna transmitting linearly polarised signals and dualpolarised receiving antennas carried by the user on the body. A Normal Distribution with a mean of 2.0 dB and a standard deviation of 4.3...

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  • Modelling and Control of a Brushless Multiphase Doubly-Fed Induction Generator in a Stand-Alone Wind Generation System

    Publication

    The development of the novel multiphase brushless doubly-fed generator system and voltage controller for stand-alone mode configuration is proposed in this paper. The generator system is based on the new machine construction with multiphase control winding and traditional three-phase power winding. The dynamic model of multiphase brushless doubly-fed generator is presented, and the control strategy for voltage amplitude and frequency...

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  • Techniki chromatografii w rozdzielaniu i oznaczaniu ekdysteroidów w Rhaponticum carthamoides

    Rhaponticum carthamoides to syberyjska endemiczna wieloletnia bylina, od wieków wykorzystywana w medycynie ludowej, jako preparat wzmacniający organizm. Główną grupą związków chemicznych, występujących w roślinie oraz wzbudzających szczególne zainteresowanie, ze względu na wykazywaną aktywność, są ekdysteroidy. Dlatego też poznanie ich dokładnego składu oraz stężeń w tkankach roślinnych staje się istotnym elementem poznawczym oraz...

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  • Koncepcja platformy wymiany informacji o incydentach cyberbezpieczeństwa dla krajowego systemu elektroenergetycznego

    Artykuł opisuje wybrane zagadnienia związane z cyberbezpieczeństwem w sektorze elektroenergetyki. Jednym z elementów zapewniania bezpieczeństwa sieci elektro-energetycznej jest efektywna wymiana informacji o incydentach bezpieczeństwa. W jej ramach wszystkie zaangażowane podmioty systemu elektroenergetycznego, tj.: elektrownie, operatorzy systemów przesyłowych, operatorzy systemów dystrybucyjnych, dostawcy rozwiązań bezpieczeństwa,...

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  • INFLUENCE OF WRONGLY ASSUMED PROBABILITY DISTRIBUTION ON THE UNCERTAINTY OF RESISTANCE MEASUREMENT BY TECHNICAL METHOD

    The paper presents studies on the influence of probability distributions on the expanded uncertainty of the resistance measurement. Choosing the correct probability distribution is very important to estimate of measurement uncertainty. The most commonly used distribution is the rectangular distribution. The paper presents the results of analysis of the resistance measurement uncertainty using the technical method of two resistances:...

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  • Fractional Calculus Evaluation of Hyaluronic Acid Crosslinking in a Nanoscopic Part of Articular Cartilage Model System

    Publication
    • P. Bełdowski
    • P. Weber
    • T. De Leon
    • W. K. Auge
    • A. Gadomski

    - Year 2018

    This work presents a study of the mechanism of physical crosslinking of hyaluronic acid in the presence of common phospholipids in synovial joint organ systems. Molecular dynamic simulations have been executed to understand the formation of hyaluronan networks at various phospholipid concentrations. The results of the simulations suggest that the mechanisms exhibit subdiffusion characteristics. Transportation quantities derive...

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  • Systematic Management of Simulation State for Multi-Branch Simulations in Simulink

    Publication

    - Year 2013

    Systematic simulation is a technique related and motivated by the formal analysis of hybrid dynamic systems. It combines the exhaustive and conservative nature of traditional model checking with numerical simulation for providing efficient algorithms to manage simulations. Multi-branch simulation is the concept advancing simulation efficiency by reducing the number of state transitions. This paper introduces an approach to implement...

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  • Developing Prognostic Models of Organization Evolution

    Publication

    - Year 2011

    The work focuses on the problem of measuring evolution of IT organizations. Changes in business influence functioning of the IT organization. IT departments or companies must ensure that the needs of their parent company/customers will be met. Therefore they must constantly evolve. Following question can be raised: is it possible to support process of changes the IT organization to run it smoother, faster, easier but with reduced...

  • Towards the boundary between easy and hard control problems in multicast Clos networks

    In this article we study 3-stage Clos networks with multicast calls in general and 2-cast calls, in particular. We investigate various sizes of input and output switches and discuss some routing problems involved in blocking states. To express our results in a formal way we introduce a model of hypergraph edge-coloring. A new class of bipartite hypergraphs corresponding to Clos networks is studied. We identify some polynomially...

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  • Inhibitors of angiogenesis in cancer therapy – synthesis and biological activity

    Angiogenesis is the process of formation of new capillaries from preexisting blood vessels. Angiogenesis is involved in normal physiological processes, and plays an important role in tumor invasion and development of metastases. Vascular endothelial growth factor (VEGF) plays a key role in angiogenesis. VEGF is a mitogen for vascular endothelial cells and stimulates their proliferation. By inhibiting the biological activity of...

  • Microstructure and Electrical Properties of Fe,Cu Substituted (Co,Mn)3O4 Thin Films

    Publication

    - Crystals - Year 2017

    In this work, thin films (~1000 nm) of a pure MnCo2O4 spinel together with its partially substituted derivatives (MnCo1.6Cu0.2Fe0.2O4, MnCo1.6Cu0.4O4, MnCo1.6Fe0.4O4) were prepared by spray pyrolysis and were evaluated for electrical conductivity. Doping by Cu increases the electrical conductivity, whereas doping by Fe decreases the conductivity. For Cu containing samples, rapid grain growth occurs and these samples develop cracks...

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  • An Adaptive Network Model Simulating the Effects of Different Culture Types and Leader Qualities on Mistake Handling and Organisational Learning

    Publication

    - Year 2022

    This paper investigates computationally the following research hypotheses: (1) Higher flexibility and discretion in organizational culture results in better mistake management and thus better organizational learning, (2) Effective organizational learning requires a transformational leader to have both high social and formal status and consistency, and (3) Company culture and leader's behavior must align for the best learning effects....

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  • Computational Simulation of the Effects of Different Culture Types and Leader Qualities on Mistake Handling and Organisational Learning

    Publication

    - Year 2023

    This chapter investigates computationally the following research hypotheses: (1) Higher flexibility and discretion in organisational culture results in better mistake management and thus better organisational learning, (2) Effective organisational learning requires a transformational leader to have both high social and formal status and consistency, and (3) Company culture and leader’s behavior must align for the best learning...

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  • Source-related Wavefields in Fluids and Dielectrics: A new way of Thinking about Medium Dynamics

    Publication

    - HYDROACOUSTICS - Year 2013

    Acoustic and electromagnetic wave phenomena may seem to have a proper formal representation in field theory dating from the 19th century, founded on the mathematics of complex functions. This paper shows, however, that when replacing the classical spectrum-domain approach related to the assumption of harmonic timeform of signals, with a time-domain approach imposingnorestrictionastotheclassoftimeevolutionofsourceandfieldsignals,...

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  • An Adaptive Network Model Simulating the Effects of Different Culture Types and Leader Qualities on Mistake Handling and Organisational Learning

    Publication

    - Year 2023

    This paper investigates computationally the following research hypotheses: (1) Higher flexibility and discretion in organizational culture results in better mistake management and thus better organizational learning, (2) Effective organizational learning requires a transformational leader to have both high social and formal status and consistency, and (3) Company culture and leader’s behavior must align for the best learning effects....

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  • Ruthenium(II) and Iridium(III) Complexes as Tested Materials for New Anticancer Agents

    Publication
    • J. Masternak
    • A. Gilewska
    • B. Barszcz
    • I. Łakomska
    • K. Kazimierczuk
    • J. Sitkowski
    • J. Wietrzyk
    • A. Kamecka
    • M. Milczarek

    - Materials - Year 2020

    The oncological use of cisplatin is hindered by its severe side eects and a very important resistance problem. To overcome these problems, scientists have attempted to design new generation transition-metal anticancer complexes. In this study, we present new complexes, ruthenium(II) [(6-p-cymene)RuCl(py2CO)]PF6 (1), iridium(III) [(5-Cp)IrCl(py2CO)]PF6 (2), and NH4[IrCl4(py2CO)]H2O (3), based on di-2-pyridylketone (py2CO). The prepared...

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  • Smart Innovation Engineering: Toward Intelligent Industries of the Future

    Publication

    - CYBERNETICS AND SYSTEMS - Year 2018

    Knowledge-based Engineering Systems are founded upon integration of knowledge into computer systems and are one of the core requirements for the future Industry 4.0. This paper presents a system called Smart Innovation Engineering (SIE) capable of facilitating product innovation process semi-automatically. It enhances decision-making processes by using the explicit knowledge of formal decision events. The SIE system carries the...

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  • Fading Characteristics for Dynamic Body-to-Body Channels in Indoor and Outdoor Environments

    Publication

    - Year 2018

    This paper presents an analysis of the fading characteristics in dynamic body-to-body channels, based on measurements performed at 2.45 GHz in indoor and outdoor environments. The statistical analysis of the small- and large-scale fading shows that the Nakagami Distribution is the best model for the former and the Log-Normal one for the latter. An important influence of body shadowing...

  • Smart Virtual Product Development (SVPD): Experience Based Product Development System for Industry 4.0

    Publication

    - Year 2020

    This chapter presents the concept of smart virtual product development (SVPD) system capable of supporting industrial product development. It enhances the decision making process during various activities involved in product development i.e. product design, manufacturing, and inspection planning. This is achieved by using the explicit knowledge of past formal decision events, which are captured, stored, and recalled in the form...

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  • Decisional-DNA Based Smart Production Performance Analysis Model

    Publication

    - CYBERNETICS AND SYSTEMS - Year 2019

    n order to allocate resources effectively according to the production plan and to reduce disturbances, a framework for smart production performance analysis is proposed in this article. Decisional DNA based knowledge models of engineering objects, processes and factory are developed within the proposed framework. These models are the virtual representation of manufacturing resources, and with help of Internet of Things, are capable...

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  • Towards Experience-Based Smart Product Design for Industry 4.0

    Publication

    - CYBERNETICS AND SYSTEMS - Year 2019

    This paper presents the concept of smart virtual product development (SVPD) system capable of supporting industrial product development process. It enhances the decision making process during different stages and activities involved in product development i.e. product design, manufacturing, and its inspection planning. The enhancement is achieved by using the explicit knowledge of formal past decision events, which are captured,...

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  • CeIr3: superconductivity in a phase based on tetragonally close packed clusters

    Publication

    - SUPERCONDUCTOR SCIENCE & TECHNOLOGY - Year 2019

    We present the crystallographic analysis, superconducting and spectroscopic characterization, and theoretical modeling of CeIr3. Lattice parameters a = 5.2945(1) Å and c = 26.219(1) Å are found for the R-3m symmetry crystal structure, which are close to the literature values. CeIr3 is a moderate type-II superconductor (κ GL = 17, λ e–p = 0.65) below 2.5 K. Ce ions exhibit a strongly intermediate valence character as evidenced by...

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  • Discovering patterns of Web Page Visits from Associaton Rules Viewpoint

    Publication

    The popularity of the Internet results from the almost unlimited resources of information stored in it. At the same time, Internet portals have become a widespread source of information and note very large number of visits. The list of web pages opened by users is stored in web servers' log files. Extraction of knowledge on the navigation paths of users has become carefully analyzed problem. Currently, there are a number of algorithms...

  • Towards automating repairs of IT systems

    Publication

    - Year 2009

    This paper presents formal description of working principles of the repair library, being the essential component of the Repair Management Framework (RMF), which aims at automating the process of repairing IT systems, and consists also of the Repair Management Model (RMM) and the Repair Management System (RMS). RMM introduces two mathematical models (model of monitoring and model of repair processes), general enough to cover the...

  • Features of a radial user interface to search engines

    The paper is concerned with a new type of user interface to search engines. Instead of presenting search results in a form of a ranked list, the results are presented in radial arrangement. In the center of the interface the most relevant web page is presented. Other web pages are located around the central one. The location of a web page depends on two factors: its relevance to the query and its content. The relevance has influence...

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  • Scalar and Vector acoustic fields and sources: a new look

    Publication

    - Year 2011

    A study of fundamental problems of the wavefields that are the reaction of fluid continuum on two kinds of primary actions in fluid, then on two kinds of elementary point sources, is presented in this paper, based on the assumption of the physical duality of linear fluid mechanics and the formal symmetry of mathematical description. The two fundamental wavefields generated in fluid by physical point sources are discussed in detail,...

  • Applying Decisional DNA to Internet of Things: The Concept and Initial Case Study

    Publication

    - CYBERNETICS AND SYSTEMS - Year 2015

    In this article, we present a novel approach utilizing Decisional DNA to help the Internet of Things capture decisional events and reuse them for decision making in future operations. The Decisional DNA is a domain-independent, standard and flexible knowledge representation structure that allows its domains to acquire, store, and share experiential knowledge and formal decision events in an explicit way. We apply this approach...

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  • A spectroscopic study of the cis/trans-isomers of penta-2,4-dienoic acid attached to gold nanoclusters

    Publication

    - PHYSICAL CHEMISTRY CHEMICAL PHYSICS - Year 2015

    In this theoretical work, we present a spectroscopic analysis of the cis/trans-isomers of a molecular switch, penta-2,4-dienoic acid, attached to gold clusters of different size (1, 2 and 20 gold atoms). We have simulated 4 different spectroscopic techniques: Infrared spectroscopy, normal Raman scattering, absorption spectra and resonance Raman scattering. We discuss how the position and the conformation of the molecule determine...

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  • The methylome and transcriptome of fetal skin: implications for scarless healing

    Aim: Fetal skin is known to heal without scarring. In mice, the phenomenon is observed until the 16–17 day of gestation – the day of transition from scarless to normal healing. The study aims to identify key methylome and transcriptome changes following the transition. Materials & methods: Methylome and transcriptome profiles were analyzed in murine dorsal skin using microarray approach. Results & conclusion: The genes associated...

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  • The Evaluation of Use of Colors in Graphical User-Interfaces in Healthcare

    In this paper, color difference/contrast measures are investigated in reference to results of experiments with the participation of average, color-normal observers and with individuals with deuteranopia. Additionally, a new method for the automatic analysis of color contrast is proposed, which supports designers of graphical user- interfaces in healthcare. The method was verified using the GUI phantom of a vital signs monitor (the...

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  • Optimizing of target detection and tracking processes realized on consoles of passive sonar with linear towed antenna

    Publication

    - HYDROACOUSTICS - Year 2016

    The long-range passive towed sonar was first modernised a few years ago. Building on operator experience over that period, a concept was developed of optimising the tasks performed by sonar operators, and improving forms of imaging to inform about object detection and support object tracking. The concept was implemented and successfully tested during ships’ manoeuvres. The optimisation of operator tasks was designed to keep listening...

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  • The potential of Web-GIS and geovisual analytics in the context of marine cadastre

    Publication

    - SURVEY REVIEW - Year 2017

    The importance of the marine environment to human existence makes it imperative that information models represent the multidimensional nature of reality as closely as possible in order to facilitate good governance. Information regarding jurisdiction, as well as the effects of formal law and community interests on the marine environment (e.g. nature and spatial extents as well as rights, responsibilities, restrictions etc.) would...

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  • A Bayesian regularization-backpropagation neural network model for peeling computations

    Publication
    • S. Gouravaraju
    • J. Narayan
    • R. Sauer
    • S. S. Gautam

    - JOURNAL OF ADHESION - Year 2023

    A Bayesian regularization-backpropagation neural network (BRBPNN) model is employed to predict some aspects of the gecko spatula peeling, viz. the variation of the maximum normal and tangential pull-off forces and the resultant force angle at detachment with the peeling angle. K-fold cross validation is used to improve the effectiveness of the model. The input data is taken from finite element (FE) peeling results. The neural network...

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  • Influence of User Mobility on System Loss and Depolarization in a BAN Indoor Scenario

    Publication
    • M. M. Ferreira
    • F. D. Cardoso
    • S. J. Ambroziak
    • M. Särestöniemi
    • K. Turbić
    • L. M. Correia

    - IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION - Year 2024

    In this article, an analysis of system loss and depolarization in body area networks (BANs) for body-toinfrastructure (B2I) communications based on a measurement campaign in the 5.8 GHz band in an indoor environment is performed. Measurements were performed with an off-body antenna transmitting linearly polarized signals and dual-polarized receiving antennas carried by the user on the body. A normal distribution with a mean of...

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  • A model-based approach to analysis of authentication protocols.

    Publication

    - Year 2004

    W referacie przedstawiono zintegrowane podejście do analizy protokołów uwierzytelniania o nazwie Object-oriented Formal Authentication Protocol Security Analysis Framework (OF-APSAF). Podejście to jest zaprojektowane na bazie sprawdzonej metody formalnej CSP wraz z narzędziami ją wspierającymi: Casper oraz FDR. Jego integralną częścią jest półformalna zorientowana obiektowo technika modelowania protokołów, ich kontekstu oraz wymagań...

  • PROBLEMY RACJONALNEGO ZASTOSOWANIA SYSTEMÓW DIAGNOZUJĄCYCH DO PODEJMOWANIA DECYZJI W FAZIE EKSPLOATACJI URZĄDZEŃ ENERGETYCZNYCH Z UWZGLĘDNIENIEM ZAGADNIEŃ KWANTOWYCH

    Publication

    - Year 2015

    W rozdziale przedstawiono najistotniejsze problemy pojawiające się w fazie projektowania, wytwarzania i eksploatacji systemów diagnozujących (SDG) urządzeń energetycznych (będących systemami diagnozowanymi – SDN), w przypadku przysposabiania ich do opracowania finalnej diagnozy eksploatacyjnej. Przestawiono opisową i formalną interpretację pojęcia systemu diagnozującego (SDG). Zaproponowano modele procesu diagnozowania urządzeń...

  • Wybrane elementy projektowania budynków wielofunkcyjnych stanowiących miejskie centra logistyczne

    Publication

    - Logistyka - Year 2014

    Celem artykułu jest przedstawienie wybranych aspektów dotyczących projektowania budynków wielofunkcyjnych stanowiących miejskie centra logistyczne. Centrum logistyczne lokalizowane w obszarze zurbanizowanym jest formalnie obiektem, który ma na celu zaspokojenie wielu potrzeb funkcjonalnych względem potencjalnych użytkowników. Miejskie centrum logistyczne stanowi swego rodzaju system, którego podstawą jest sprawna obsługa procesów...

  • How to model ROC curves - a credit scoring perspective

    Publication

    - Year 2018

    ROC curves, which derive from signal detection theory, are widely used to assess binary classifiers in various domains. The AUROC (area under the ROC curve) ratio or its transformations (the Gini coefficient) belong to the most widely used synthetic measures of the separation power of classification models, such as medical diagnostic tests or credit scoring. Frequently a need arises to model an ROC curve. In the biostatistical...

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  • Economic Integration and Foreign Direct Investment: Review of Main Theoretical Concepts

    The objective of the article is to present key theoretical relationships between economic integration and FDI flows. The research method used is a comprehensive literature review. Most influential publications, including books, articles, working papers, etc. contributing to the subject were identified. The review consists of two essential parts: theory of FDI, and theoretical relationships between economic integration and FDI flows....

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  • Wybrane metody optymalizacji podatkowej w sektorze MSP w Polsce

    Z każdą działalnością gospodarczą związane jest rozliczanie i płacenie podatków zarówno bezpośrednich jak i pośrednich. Jak podaje serwis dla księgowych infor.pl Polscy przedsiębiorcy nie zawsze są świadomi, że pomimo, iż podatki są obowiązkową daniną na rzecz państwa, można legalnie zmniejszyć ich należną kwotę poprzez wykorzystanie narzędzi dostępnych w polskim prawie podatkowym. Narzędzia te popularnie nazywa się optymalizacjami...

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  • High resolution optical and acoustic remote sensing datasets of the Puck Lagoon

    Publication
    • L. Janowski
    • D. Skarlatos
    • P. Agrafiotis
    • P. Tysiąc
    • A. Pydyn
    • M. Popek
    • A. M. Kotarba-Morley
    • G. Mandlburger
    • Ł. Gajewski
    • M. Kolakowski... and 2 others

    - Scientific Data - Year 2024

    The very shallow marine basin of Puck Lagoon in the southern Baltic Sea, on the Northern coast of Poland, hosts valuable benthic habitats and cultural heritage sites. These include, among others, protected Zostera marina meadows, one of the Baltic’s major medieval harbours, a ship graveyard, and likely other submerged features that are yet to be discovered. Prior to this project, no comprehensive high-resolution remote sensing...

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  • Towards a Framework for Context Awareness Based on Textual Process Data

    Publication

    - Year 2023

    Context awareness is critical for the successful execution of processes. In the abundance of business process management (BPM) research, frameworks exclusively devoted to extracting context from textual process data are scarce. With the deluge of textual data and its increasing value for organizations, it be-comes essential to employ relevant text analytics techniques to increase the awareness of business process (BP) workers,...

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  • Similarities and differences in d6 low-spin ruthenium, rhodium and iridium half-sandwich complexes: synthesis, structure, cytotoxicity and interaction with biological targets

    Publication
    • A. Gilewska
    • B. Barszcz
    • J. Masternak
    • K. Kazimierczuk
    • J. Sitkowski
    • J. Wietrzyk
    • E. Turlej

    - JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY - Year 2019

    In this paper, we discussed the similarities and diferences in d6 low-spin half-sandwich ruthenium, rhodium and iridium complexes containing 2,2′-biimidazole (H2biim). Three new complexes, {[RuCl(H2biim)(η6 -p-cymene)]PF6}2·H2O (1), [(η5 - Cp)RhCl(H2biim)]PF6 (2), and [(η5 -Cp)IrCl(H2biim)]PF6 (3), were fully characterized by CHN, X-ray difraction analysis, UV–Vis, FTIR, and 1 H, 13C and 15N NMR spectroscopies. The complexes exhibit...

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