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Search results for: AZEOTROPIC MIXTURES
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Towards azeotropic MeOH-MTBE separation using pervaporation chitosan-based deep eutectic solvent membranes
PublicationDeep eutectic solvents (DESs) are a new class of solvents that can offset some of the major drawbacks of common solvents and ionic liquids. When dealing with the preparation of dense membranes, the use of DESs is still challenging due to their low compatibility with the polymer phase. In this research, a novel L-proline:sulfolane (molar ratio 1:2) DES was synthesized and used for the preparation of more sustainable bio-based membranes...
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Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures
PublicationDeep eutectic solvents have quickly attracted the attention of researchers because they better meet the requirements of green chemistry and thus have the potential to replace conventional hazardous organic solvents in some areas. To better understand the nature of these mixtures, as well as expand the possibilities of their use in different industries, a detailed examination of their physical properties, such as density, viscosity,...
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Preferential solvation in (amide+alcohol) binary mixtures. Part 2. The N-methylpyrrolidinone+methanol mixture at T = 313.15 K: thermodynamic resultsand molecular dynamics calculations.
PublicationBadano zjawisko preferencyjnej solwatacji amidu (N-metylopyrrolidonu) przez metanol wykorzystując dwie uzupełniające się metody: bezpośrednich pomiarów własności termodynamicznych roztworu oraz symulacji komputerowych. W metodzie pierwszej dokonano pomiarów wielkości termodynamicznych takich jak: nadmiarowa energia swobodna mieszania, nadmiarowa objętość mieszania oraz współczynnika ściśliwości izotermicznej mieszaniny,...
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Preferential solvation in (amide+alcohol) binary mixtures. Part 1. The N- methylpyrrolidinone+ethanol mixture at T = 313.15 K: thermodynamic resultsand molecular dynamics calculations.
PublicationBadano zjawisko preferencyjnej solwatacji amidu (N-metylopyrrolidonu) przez etanol wykorzystując dwie uzupełniające się metody: bezpośrednich pomiarów własności termodynamicznych roztworu oraz symulacji komputerowych. W metodzie pierwszej dokonano pomiarów wielkości termodynamicznych takich jak: nadmiarowa energia swobodna mieszania, nadmiarowa objętość mieszania oraz współczynnika ściśliwości izotermicznej mieszaniny,...
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Antioxidant properties of ferrous flavanol mixtures
PublicationInteraction of metal, especially iron ions with flavanols is considered as an important feature of these compounds and is believed to contribute to their both antioxidant and prooxidant properties. The aim of this study was to examine how Fe2+ binding to form a 4:1 (flavanol:Fe2+) mixtures affects the antioxidant properties of flavanols. ABTS∗ scavenging, protection against fluorescence bleaching induced by AAPH and hypochlorite,...
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Devices for the production of reference gas mixtures
PublicationFor many years there has been growing demand for gaseous reference materials, which is connected with development in many fields of science and technology. As a result, new methodological and instrumental solutions appear that can be used for this purpose. Appropriate quality assurance/quality control (QA/QC) must be used to make sure that measurement data are a reliable source of information. Reference materials are a significant...
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Development of techniques of generation of gaseous standard mixtures
PublicationW pracy przedstawiono informacje dotyczące: klasyfikacji znanych technik sporządzania gazowych mieszanin wzorcowych oraz omówienia technik najszerzej wykorzystywanych wraz z przedstawieniem odpowiednich schematów zestawów aparaturowych. Przedstawiono również informacje na temat nowego podejścia do zagadnienia sporządzania gazowych mieszanin wzorcowych. W tym przypadku strumień składnika mierzonego (analitu) jest otrzymywany w procesie...
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Strength characteristics of tyre chips-sand mixtures.
PublicationBadania w aparacie trójosiowego ściskania przy różnej zawartości wagowej kawałków zużytych opon oraz różnym ich ułożeniu w próbce piasku. Badania prowadzono przy dowolnym ułożeniu tych elementów, umieszczeniu ich poziomo oraz w systemie mieszanym. Wyznaczono optymalną zawartość kawałków opon w próbce piasku, przy której występowała maksymalna wytrzymałość na ściskanie.
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Heterogeneous soil behavior. Mechanical study of mixtures
PublicationW pracy opisano właściwości gruntu niejednorodnego w postaci mieszaniny budowanej ze żwiru i piasku w różnych proporcjach. Mieszanina ma właściwości typowe ośrodków ziarnistych. Badania przeprowadzono w aparacie trójosiowego ściskania. Jako wynik uzyskano, że wraz ze wzrostem procentowej zawartości żwiru rośnie kąt tarcia wewnętrznego mieszaniny i jej zagęszczenie oraz wartość jej wytrzymałości na ścinanie.
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Laboratory assessment of permeability of sand and biopolymer mixtures
PublicationLaboratory assessment of permeability of sand and biopolymer mixtures. This research presents a method of creating seepage barriers in a sandy soil using biopolymer additives (biosubstance), which consist of polysaccharides and water. Polysaccharides strongly interact with water to produce a viscous suspension. The paper aims to investigate the infl uence of a biosubstance employed in a highly permeable sandy soil. Amount of the...
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Selectivity of amperometric gas sensors in multicomponent gas mixtures
PublicationIn recent years smog and poor air quality became a growing environmental problem. There is a need to continuously monitor the quality of air. The lack of selectivity is one of the most important problems limiting the use of gas sensors for this purpose. In this study, a selectivity of the six amperometric gas sensors is being investigated. Calibration of sensors has been performed in order to find a correlation between concentration...
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Flow boiling of oil-refrigerant mixtures in smooth tubes
PublicationPrzedstawiono wyniki badań współczynnika przejmowania ciepła i spadku ciśnienia podczas wrzenia czynników R 22, R 134a i R 407C i ich mieszanin z olejem w rurach gładkich. Opisano procedurę badawczą. Udział masowy oleju w mieszaninie z czynnikiem wynosił 0,1% i 5%. Zaobserwowano negatywny wpływ obecności środka smarnego we wrzącym czynniku chłodniczym.
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Influence of aggregates angularity on the locking point of asphalt mixtures
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The long-term properties of mineral-cement-emulsion mixtures
PublicationThis publication presents evaluation of long-term behavior of mineral-cement-emulsion (MCE) mixtures. MCE mixtures are among the major products of cold recycling of old asphalt pavements. They are composed by binding of the old materials reclaimed from the pavement and new mineral aggregate using two different binding agents – cement and bituminous emulsion. While bituminous emulsion dissolutes and binds materials quite fast, it...
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Adsorption study of surfactants and biosurfactants mixtures at different interfaces
PublicationZbadano napięcia powierzchniowe i międzyfazowe roztworów mieszaniny surfaktantów niejonowych (Rokanol L7 i Rokanol NL8) i biosurfaktantu (JBR 425) i ich mieszanin. Olejową fazę stanowił dodekan oraz olej bazowy PAO. Wykazano synergizm wartości napięcia międzyfazowego przy CMC jedynie w przypadku mieszaniny Rokanolu L7 i JBR 425 i tylko dla granicy faz olej/woda.
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Wetting of different solid materials with solutions of surfactants mixtures
PublicationBadanie zdolności zwilżających mieszanin niejonowego surfaktantu gemini S-10 z surfaktantami anionowymi CsDS (dodecylosiarczan cezu) i LiDS (dodecylosiarczan litu). Badane powierzchnie różniły się stopniem hydrofobowości (szkło, stal, polimetakrylan metylu). Niektóre mieszaniny wykazywały synergizm w procesie zwilżania.
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EFFICIENCY OF GAS MIXTURES DETECTION BY RESISTIVE GAS SENSORS
PublicationResistive gas sensors are very popular and are commonly used to detect various gases and their mixtures. Their main disadvantage is very limited selectivity. Practical use of gas sensors in environmental applications (e.g., in sewage systems to protect workers, in air conditioning systems to monitor atmosphere quality) requires determination of concentration of a few mixed gases at the same time. We would like to present recent...
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Efficiency of gas mixtures detection by resistive gas sensors
PublicationResistive gas sensors are very popular and are commonly used to detect various gases and their mixtures. Theeir main disadvantage is very limited selectivity. Practical use of gas sensors in environenmental applications requires determination of concentration of a few mixed gases at the same time. We would like to present recent results of gas detection improvement by utilizing a single gas sensor and additional measurements to...
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New developments in preparation and use of standard gas mixtures
PublicationStandard gas mixtures are commonly applied in all stages of analytical work related to the analysis of gaseous samples. Numerous techniques for generating standard gas mixtures are in use. In this article, we present new developments regarding the production of standard gas mixtures, with particular focus on improvements in the application of dynamic techniques for generating them. Furthermore, we describe the application of new...
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Evaluation of Low Temperature Properties of Rubberized Asphalt Mixtures
PublicationThe paper presents low-temperature test results of asphalt mixtures designed with use of bitumen modified by crumb rubber and also SBS polymer. Laboratory tests were conducted on two types of asphalt mixtures for wearing course – stone matrix asphalt (SMA 8) and porous asphalt (PA 8). This paper presents results of the following laboratory tests at low temperatures: TSRST test, three point bending creep test, fracture toughness...
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Effect of strain level on the stiffness of cold recycled bituminous mixtures
PublicationCold recycling is a sustainable technology for the rehabilitation of bitumi-nous pavements. This study investigates the stiffness response of cement-bitumen treated materials (CBTM)manufactured with 80% reclaimed asphalt and treated with 2.0% Portland cement and 4.0% bitumen emulsion. Indirect tensile stiffness modulus tests were carried out to assess the strain dependence of stiffness at target horizontal deformation levels between...
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Polyurethane Glycerolysate as a Modifier of the Properties of Natural Rubber Mixtures and Vulcanizates
PublicationChemical recycling of polyurethanes can be realized in several different ways, but the most important methods are glycolysis and glycerolysis. Both methods permit recovery of polyols (when the process is realized with the mass excess of depolymerizing agent) or substitutes of polyols, which contain urethane moieties in the main chains and terminate mainly in hydroxyl groups (when the process is realized with the mass excess of...
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Prediction of adsorption equilibria for mixtures of pesticides present in industrial wastewater
PublicationOpierając się na właściwościach termodynamicznych roztworów w równowadze ciecz-ciało stałe, przeprowadzono analizę wybranych modeli matematycznych znanych z literatury, na wyrażenie izoterm adsorpcji cieczowej. Korelację danych przeprowadzono dla dziewięciu modeli matematycznych, w formie znanego zmodyfikowanego równania Freundlich'a. Wykorzystano doświadczalne wyniki badań nad usuwaniem zanieczyszczeń pestycydowych ze ścieków...
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Gaseous standard mixtures - the challenge of obtaining small amounts of measurands.
PublicationOpisano wykorzystanie techniki termicznego rozkładu związków powierzchniowych do sporządzania gazowych mieszanin wzorcowych. Przedstawiono wyniki własnych badań ukazujących możliwości uzyskiwania szerokiego zakresu ilości składników mierzonych. Opisano także sposoby wykorzystania otrzymanych mieszanin wzorcowych do kalibracji urządzeń kontrolno-pomiarowych.
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Test of an Optimised Exact-Diagonalization Approach for Trapped Fermionic Mixtures
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Gaseous standard mixtures – the challenge of obtaining small amounts of measurands
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Generation of standard gaseous mixtures by thermal decomposition of surface compounds
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Characteristics of tyre chips-sand mixtures from triaxial tests
PublicationAnaliza parametrów wytrzymałościowych i odkształcalności mieszanek piasku i kawałków zużytych opon. Powtórne użycie tego materiału, odpowiednio przetworzonego na skrawki i elementy o kształcie kołowym pozwala po odpowiednim zmieszaniu z gruntem niespoistym na uzyskanie materiału o zwiększonej wytrzymałości na ścinanie zachowywanej również przy dużych odkształceniach. Analizowano mieszanki o różnej zawartości opon przy naprężeniach...
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FT-IR studies of molecular interactions in formamide-methanol mixtures
PublicationTechniką ATR zmierzono widma FT-IR roztworów metanolu(MeOH) i formamidu(FA) w całym zakresie ich składu. Przeprowadzono analizę faktorową widm, która wykazała obecność dwóch kompleksów molekularnych matanolu z formamidem. Na podstawie profilów stężeniowych indywiduów absorbujących wyznaczono średni skład kompleksów w zależności od składu mieszaniny. Przeprowadzono również analizę pasma CO formamidu metodą widm różnicowych. Wyniki...
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Sound velocity and parameter of nonlinearity in the two-component relaxing mixtures
PublicationRozpatruje się własności akustyczne mieszanki dwuskładnikowej zawierającej gaz doskonały i parę cieczy bądź pył ciała stałego. Dokładne obliczenia pozwoliły na wyprowadzenie prędkości dźwięku i parametru nieliniowości jako funkcji koncentracji jednej ze składowych mieszaniny przy zadanych warunkach równowagowych. Przedstawiono wzory ogólne oraz symulacje numeryczne.
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The effect of surfactants mixtures composition on wetting of different solid materials
PublicationThe wetting properties of surfactants mixtures were investigated. Three types of compounds were used: nonionic gemini α, α'-[2,4,7,9-tetramethyl-5-decyne-4,7-diyl]bis[ω-hydroxyl-olioxyethylene] (S-10), anionic sodium dodecyl sulphates (SDS) and cationic dodecyl trimethyl ammonium bromide (DTAB). The materials used in wetting experiments were steel and methyl polymethacrylate. These materials differ...
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The Influence of Binding Agents on Stiffness of Mineral-cement-emulsion Mixtures
PublicationThis paper attempts to determine the behavior of mineral-cement-emulsion mixture (MCE) under load, whether is it similar to asphalt mixtures (viscoelastic behavior) or to cement treated materials (elastic behavior). To answer this question nine mineral- cement-emulsion mixtures with different combinations of cement and emulsion content were tested in laboratory using Simple Performance Test (SPT). For each mixture stiffness moduli...
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Effect of polymer fibres reinforcement on selected properties of asphalt mixtures
PublicationThe paper presents selected results of the research program concerning fibre reinforced asphalt concrete. Aramid-polyalphaolefin fibres was used in this study. Selected properties responsible for low temperature cracking and resistance to permanent deformation are presented in this paper. Low temperature cracking susceptibility was evaluated with the results obtained from bending test of rectangular beams with constant rate of...
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A material model of asphalt mixtures based on Monte Carlo simulations
PublicationThe paper aims to numerically reflect mineral-asphalt mixture structure by a standard FEM software. Laboratory test results are presented due to bending tests of circular notched elements. The result scatter is relatively high. An attempt was made to form a random aggregate distribution in order to obtain various results corresponding to laboratory tests. The material structure calibration, its homogenization and finite element...
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Assessment of Tensile Strength Reserve of Asphalt Mixtures at Low Temperatures
PublicationDuring winter conditions, low-temperature cracks develop at the surface of the asphalt pavement when tensile thermal stress induced in the asphalt layer during cooling equals and exceeds the tensile strength of the material. The paper presents the results of tensile strength reserve assessment of asphalt mixtures with neat and SBS-polymer modified bitumen application. The tensile strength reservewas calculated as difference between...
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Numerical simulation of asphalt mixtures fracture using continuum models
PublicationThe paper considers numerical models of fracture processes of semi-circular asphalt mixture specimens subjected to three-point bending. Parameter calibration of the asphalt mixture constitutive models requires advanced, complex experimental test procedures. The highly non-homogeneous material is numerically modelled by a quasicontinuum model. The computational parameters are averaged data of the components, i.e. asphalt, aggregate...
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Gas-steam mixture wood drying
PublicationBadania skuteczności suszenia wysokotemperaturowego suszenia drewna w komorze suszarniczej - wstępne wyniki.
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Characterization of Modified Silica Gel as a Source of Ethene for Standard Gaseous Mixtures
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Investigation into Locking Point of Asphalt Mixtures Utilizing Superpave and Marshall Compactors
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Noble metal–TiO2 supported catalysts for the catalytic ozonation of parabens mixtures
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Performance evaluation of temperature effect on hot in-place recycling asphalt mixtures
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Non-matrix reference matrials- chalanges in the preparation of standard gas mixtures
PublicationIn the last few years particularly great pressure is exerted on quality control and assurance of analytical measurement results. An invaluable role in this process is played by reference materials. The paper presents the characteristics of basic types of reference materials, with particular attention to gaseous reference materials. In addition, a review of literature on techniques of preparation of gaseous standard materials, published...
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Analysis of odor interactions in ternary gas mixtures using electronic nose
PublicationIn recent years there has been a noticeable increase in interest in the use of electronic noses in analytical chemistry. These devices perform a holistic analysis of the gas mixtures composition, without the separation and identification of its individual components. For this reason e-noses are increasingly replacing the conventional olfactometers, due to the significantly shorter analysis time and possible automation. In the work...
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Binary Mixtures of Selected Bisphenols in the Environment: Their Toxicity in Relationship to Individual Constituents
PublicationBisphenol A (BPA) is one of the most popular and commonly used plasticizer in the industry. Over the past decade, new chemicals that belong to the bisphenol group have increasingly been used in industrial applications as alternatives to BPA. Nevertheless, information on the combined effects of bisphenol (BP) analogues is insufficient. Therefore, our current study aimed to find the biological response modulations induced by the...
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MECHANICAL PROPERTIES OF BOTTOM ASH – DREDGED MATERIAL MIXTURES IN LABORATORY TESTS
PublicationBottom ash from EC Gdańsk and dredged material taken from the mouth of The Vistula were mixed to form an engineering material used for dike construction. Mixtures with different bottom ash content were tested in laboratory to determine its basic physical and mechanical properties. The optimum bottom ash–dredged material mixture, built in the corps of the test dike, contains 70% of ash. The optimum bottom ash content in the mixture...
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Standard gas mixtures- indispensable reference materials in the analysis of gaseous media
PublicationIn recent years the need for the quality control and assurance of analytical measurement results has been particularly strongly emphasised. Certified reference materials play an invaluable role in this process. The article characterises the basic types of reference materials, focusing in particular on those in the gaseous state. It also reviews the literature on the techniques of preparing standard gas mixtures over the last ten...
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Predicting sulfanilamide solubility in the binary mixtures using a reference solvent approach
PublicationBackground. Solubility is a fundamental physicochemical property of active pharmaceutical ingredients. The optimization of a dissolution medium aims not only to increase solubility and other aspects are to be included such as environmental impact, toxicity degree, availability, and costs. Obtaining comprehensive...
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Influence of Aggregate Gradation on the Compactability of Asphalt Mixtures Utilizing Locking Point
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Influence of Asphalt Binder on the Compactability of Asphalt Mixtures Using Locking Point
PublicationCompaction is an important process for the asphalt mixture service life. A properly compacted mixture is crucial for long-lasting pavement. The objective of this study was to evaluate the influence of asphalt binders on the compactability of the asphalt mixtures by utilizing the concept of the locking point. To achieve this objective, two compaction methods (impact and gyration), different temperatures and asphalt content, and...
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Detonations in hydrogen-methane-air mixtures in semi confined flat channels
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