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Search results for: SPEKTROSKOPIA LAXS
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Bioassays as one of the Green Chemistry tools for assessing environmental quality: A review
PublicationFor centuries, mankind has contributed to irreversible environmental changes, but due to the modern science of recent decades, scientists are able to assess the scale of this impact. The introduction of laws and standards to ensure environmental cleanliness requires comprehensive environmental monitoring, which should also meet the requirements of Green Chemistry. The broad spectrum of Green Chemistry principle applications should...
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Fighting Administrative Corruption with Digital Government in Sub-Saharan Africa
PublicationAdministrative corruption is a pervasive problem and a major threat to economic and social development around the world, especially in Sub-Saharan Africa which lags behind other regions in various development indicators and is seen as one of the most corrupt regions globally. This paper examines a hypothesis that digital government – the use of digital technology to transform public administration organizations and their relationships...
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Global Approaches to Reduce Light Pollution from Media Architecture and Non-Static, Self-Luminous LED Displays for Mixed-Use Urban Developments
PublicationUrban environments have become significantly brighter and more illuminated, and cities now consider media architecture and non-static, self-luminous LED displays an essential element of their strategy to attract residents, visitors, and tourists in the hours after dark. Unfortunately, most often, they are not designed with care, consideration, and awareness, nor do they support the visual wellbeing and circadian rhythms of humans....
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A global multinational survey of cefotaxime-resistant coliforms in urban wastewater treatment plants
PublicationThe World Health Organization Global Action Plan recommends integrated surveillance programs as crucial strategies for monitoring antibiotic resistance. Although several national surveillance programs are in place for clinical and veterinary settings, no such schemes exist for monitoring antibiotic-resistant bacteria in the environment. In this transnational study, we developed, validated, and tested a low-cost surveillance and...
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Studies on Aryl-Substituted Phenylalanines: Synthesis, Activity, and Different Binding Modes at AMPA Receptors
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QUEUE II Winter School
e-Learning CoursesQUEUE = QUantum and molEcUlEsIt's a school organized for all those young scientists and students who wish to learn on the basics and advances in quantum ideas and methodologies and its practical applications for living problems in chemistry, electrochemistry and material sciences. The students will learn on how to perform the quantum-chemical computations, because we have planned a big block of laboratories, aside from lectures,...
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QUEUE I Summer School
e-Learning CoursesQUEUE = QUantum and molEcUlEsIt's a school organized for all those young scientists and students who wish to learn on the basics and advances in quantum ideas and methodologies and its practical applications for living problems in chemistry, electrochemistry and material sciences. The students will learn on how to perform the quantum-chemical computations, because we have planned a big block of laboratories, aside from lectures,...
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QUEUE III Summer School
e-Learning CoursesQUEUE = QUantum and molEcUlEsIt's a school organized for all those young scientists and students who wish to learn on the basics and advances in quantum ideas and methodologies and its practical applications for living problems in chemistry, electrochemistry and material sciences. The students will learn on how to perform the quantum-chemical computations, because we have planned a big block of laboratories, aside from lectures,...
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Zastosowanie techniki NIR w analizie jakościowej surowców kosmetycznych i farmaceutycznych
PublicationW ramach współpracy pomiedzy Katedrą Technologii Leków i Biochemii Wydziału Chemicznego PG, a zakładem produkcji kosmetyków i farmaceutyków Ziaja Ltd. podjęto prace badawcze nad opracowaniem nowych metod analitycznych stosując spektroskopię w bliskiej podczerwieni (NIR). Metoda ta wykorzystuje absorpcję promieniowania elektromagnetycznego w zakresie 12 000 - 4 000 cm-1 (780-2500 nm). Absorpcja w zakresie NIR pochodzi głównie nod...
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ATR FT-IR H2O spectra of acidic aqueous solutions. Insights about proton hydration
PublicationW artykule podjęto próbę ilościowej analizy widm oscylacyjnych H2O w wodnych roztworach kwasów. Widma H2O dostarczają głównie informacji o stanie strukturalnym cząsteczek wody, wynikającym ze sprzężeń oscylatorów w układzie. Są jednak znacznie trudniejsze w interpretacji niż widma HDO. Widma wodnych roztworów kwasów jednoprotonowych (HCl, HClO4, HPF6) zmierzono posługując się spektroskopią FT-IR w technice osłabionego wewnętrznego...
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Instantaneous impedance evaluation of dissolution of aisi 304 stainless steel during intergranular corrosion
PublicationCelem pracy było uzyskanie informacji dotyczących zróżnicowania parametrów elektrycznych uzyskanych na podstawie zarejestrowanych chwilowych widm impedancyjnych w zakresie aktywacji i reaktywacji roztwarzania wysokostopowej stali austenitycznej AISI podczas postępującego procesu korozji międzykrystalicznej. Badania prowadzono z wykorzystaniem dynamicznej elektrochemicznej spektroskopii impedancyjnej (DEIS). Pomiary wykonywano ''on-line''...
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Charge Distribution and Hyperfine Interactions in GdBa2Cu3O7 from First Principles
PublicationW rozdziale przedstawiono wyniki obliczeń "z zasad pierwszych" (''ab initio'') struktury elektronowej, rozkładu ładunku i struktury nadsubtelnej, w szczególności gradientu pola elektrycznego (EFG) i składnika kontaktowego pola nadsubtelnego (HFF), nadprzewodnika wysokotemperaturowego o wzorze GdBa2Cu3O7 (Gd123). Do obliczeń wykorzystano metodę FP-LAPW (full-potential linearized augmented plane wave). Efekty związane z oddziaływaniami...
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Badanie degradacji powłok organicznych metodą EIS w warunkach podwyższonych temperatur
PublicationPomimo nieustannego rozwoju zaawansowanych technik antykorozyjnych oraz imponująco wysokiej odporności współczesnych warstw i pokryć ochronnych problem zabezpieczenia powierzchni metalicznych jak i niemetalicznych jest nadal aktualny. Wciąż rosnące zapotrzebowanie na nowe metody ochrony antykorozyjnej oraz dążenie do jak najmniejszej degradacji środowiska naturalnego wytyczają współczesne trendy rozwoju przemysłu antykorozyjnego....
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Termoplastyczne elastomery poli(estro-uretanowe) otrzymywane z udziałem bio-glikolu poddane dwukrotnemu przetwórstwu
PublicationRecykling materiałów polimerowych w istotny sposób wpływa na zmniejszenie ilości odpadów z tworzyw sztucznych składowanych na wysypiskach śmieci. Jedną z metod recyklingu jest recykling mechaniczny, stosowany szczególnie w przypadku materiałów o właściwościach termoplastycznych. W pracy zbadano wpływ dwukrotnego przetwórstwa termoplastycznych elastomerów poli(estro-uretanowych), TPU, otrzymywanych z udziałem bio-glikolu na strukturę...
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Integration, Processing and Dissemination of LiDAR Data in a 3D Web-GIS
PublicationThe rapid increase in applications of Light Detection and Ranging (LiDAR) scanners, followed by the development of various methods that are dedicated for survey data processing, visualization, and dissemination constituted the need of new open standards for storage and online distribution of collected three-dimensional data. However, over a decade of research in the area has resulted in a number of incompatible solutions that offer...
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Analiza trwałości zmęczeniowej asfaltów drogowych i modyfikowanych z wykorzystaniem testu liniowego zwiększania amplitudy / Analysis of the fatigue life of neat and modified bitumens using linear amplitude sweep test
PublicationThe paper presents an evaluation of the fatigue resistance of selected Polish bituminous binders: neat bitumen 50/70, polymer modified bitumen PMB 45/80-55 and polymer highly modified bitumen PMB 45/80-80. The linear amplitude sweep (LAS) test, which is a new bitumen performance grading test developed in the USA, and was used to assess the fatigue life of the bitumens. Highly modified bitumen 45/80-80 showed 10-20 times higher...
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Nontoxic Goiter (NTG) and Radioiodine: What Do Patients Think About It? Quality of Life in Patients with NTG Before and After 131-I Therapy
PublicationObjective Despite numerous publications regarding nontoxic goiter (NTG) treatment and an increasing interest in patients’ quality of life, few studies present the outcome of 131-I treatment from the patients’ perspective. Our study’s main aim was to verify whether there is any improvement in life quality following 131-I treatment. Materials and methods Thirty-five patients with NTG qualified to participate in the study. All patients...
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US not bright but right method of thyroid volume estimation even in large and substernal extended goitres. Comparison of US and three methods of CT thyroid evaluation - prospective study.ON LINE
PublicationBackground Ultrasound is nowadays a method of choice for thyroid volume assessment. However, its disadvantage is some inaccuracy, which is said to be higher in huge, especially substernally extended goitres. Aims The aim of the study was to compare the US and CT thyroid volumetric measurements: multi-observers (CT MO) and one-observer (CT OO) to CT planimetry results (CT Pl) in patients with large goitres. Materials & Methods The...
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Systematic Study of Hydration Patterns of Phosphoric(V) Acid and Its Mono-, Di-, and Tripotassium Salts in Aqueous Solution
PublicationSpektroskopia oscylacyjna FTIR w zakresie drgania OD cząsteczki HDO została zastosowana do zbadania różnych form fosforanów w kolejności malejącego stopnia protonacji: H3PO4, KH2PO4, K2HPO4, K3PO4. HDO rozcieńczona izotopowo w H2O została otrzymana przez dodanie odpowiednich ilości wody ciężkiej (D2O) do roztworów w wodzie zwykłej. Do wyizolowania widm HDO zaburzonej przez substancję rozpuszczoną zastosowano metodę widm różnicowych....
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Chemoselektywność w reakcjach wybranych związków fosforu z pochodnymi hydroksyloaminy
PublicationZaprezentowane reakcje wielofunkcyjnych pochodnych hydroksyloaminy składają w większości przypadków z ciągów równoległych i następczych procesów, które prowadzą do powstawania mieszanin produktów. Uzyskane i przeanalizowane rezultaty badań pogłębiają wiedzę na temat ważnej biologicznie i mającej znaczenie praktyczne reakcji przeniesienia fosforylu z udziałem pochodnych hydroksyloaminy. I tak, zbadano wpływ budowy reagentów i mechanizmy...
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SkinDepth - synthetic 3D skin lesion database
Open Research DataSkinDepth is the first synthetic 3D skin lesion database. The release of SkinDepth dataset intends to contribute to the development of algorithms for:
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Self-Organization of Graft Copolymers and Retortable iPP-Based Nanoporous Films Thereof
PublicationPolyolefins might become inexpensive alternatives to the existing membranes based on polyethersulfone. Here we disclose the production of retortable, well-defined PP-based nanoporous membranes derived from amphiphilic graft copolymer precursors. The graft copolymers, containing a polypropylene backbone and polyester grafts, were obtained by grafting lactones, specifically δ-valerolactone and ε-caprolactone, from well-defined randomly...
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The impact of knowledge risk management on sustainability
PublicationPurpose The purpose of this study is to examine the effect of knowledge risk management (KRM) on organizational sustainability and the role of innovativeness and agility in this relationship. Methodology The study presents the results of a quantitative survey performed among 179 professionals from knowledge-intensive organizations dealing with knowledge risks and their management in organizations. Data included in this study are...
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Informal Settlements and International Migrants: The city of Rome (Italy) as Case Study
PublicationToday, urbanization is happening at an unprecedentedly rapid rate, owing heavily to the influx of migrants. Empirical evidence shows the development of informal settlements in cities as a result of migration, including Rome. Furthermore, information on informal settlements is either insufficient or inadequate, which makes it challenging for architects, urban planners, and policymakers to form viable solutions to deal with the situations...
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Capacity Transforming challenges into opportunities
PublicationThe Urban Initiative Laboratory (UIL) aims to upgrade the smart city concept in Gdańsk by introducing the Food-Water-Energy (FWE) nexus to the city. It was agreed in the CRUNCH international consortium that projects on different scales would be implemented in the individual countries to test the Integrated Decision Supportive system platform, which would, in principle, concern urban scale. The regular urban scale was to be researched...
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Multi-objective optimization of water quality, pumps operation, and storage sizing of water distribution systems
PublicationA multi-objective methodology utilizing the Strength Pareto Evolutionary Algorithm (SPEA2) linked to EPANET for trading-off pumping costs, water quality, and tanks sizing of water distribution systems is developed and demonstrated. The model integrates variable speed pumps for modeling the pumps operation, two water quality objectives (one based on chlorine disinfectant concentrations and one on water age), and tanks sizing cost...
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Combining X-ray tomogrpahy imaging and DEM simulations to investigate granular material flow during silo discharging
PublicationEven after few decades of research, the study of particle motion taking place during silo discharging hasn’t been fully addressed, both experimentally and numerically, because of nontrivial behaviors that occur during associated flow patterns. For instance, discrete element method (DEM) has shown good qualitative prediction potential of velocity profile, but, on the other hand, frequently failed to match quantitatively experimental...
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Load introduction to composite columns revisited—Significance of force allocation and shear connection stiffness
PublicationThe AISC 360-16 Specification recommends that the design shear force between parts of a composite column in the load introduction area shall be calculated based on the force allocation at ultimate limit state. Applicability of this straightforward method to the load levels that usually arise in slender composite columns is questionable, as this capacity-based force allocation is only true when the axial force is equal to the plastic...
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Analytical ‘Steady-State’-Based Derivation and Clarification of the Courant-Friedrichs-Lewy Condition for Pipe Flow
PublicationThis article addresses the problem of choosing the optimal discretization grid for emulating fluid flow through a pipeline. The aggregated basic flow model is linearized near the operating point obtained from the steady state analytic solution of the differential equations under consideration. Based on this model, the relationship between the Courant number (μ) and the stability margin is examined. The numerically set coefficient...
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Modeling protein structures with the coarse-grained UNRES force field in the CASP14 experiment
PublicationThe UNited RESidue (UNRES) force field was tested in the 14th Community Wide Experiment on the Critical Assessment of Techniques for Protein Structure Prediction (CASP14), in which larger oligomeric and multimeric targets were present compared to previous editions. Three prediction modes were tested (i) ab initio (the UNRES group), (ii) contact-assisted (the UNRES- contact group), and (iii) template-assisted (the UNRES-template...
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Fundamentals of classical and analytical mechanics
PublicationThe book is a monographic description of the present attempt to Newtonian and Lagrangian mechanics. But also, it could be found as a supplementary educational material useful for the graduate courses in mechanics taken by students majoring in mechanical engineering, physics or physical science. In the book you can find a brief introduction to concepts and principles of algebra of vectors; Kinematics of particles, mainly focused...
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Low-frequency noise in Au-decorated graphene–Si Schottky barrier diode at selected ambient gases
PublicationWe report results of the current–voltage characteristics and low-frequency noise in Au nanoparticle (AuNP)-decorated graphene–Si Schottky barrier diodes. Measurements were conducted in ambient air with addition of either of two organic vapors, tetrahydrofuran [(CH2)4O; THF] and chloroform (CHCl3), as also during yellow light illumination (592nm), close to the measured particle plasmon polariton frequency of the Au nanoparticle...
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Metody i mikrosystemy pomiarowe impedancji do diagnostyki grubowarstwowychpowłok antykorozyjnych.**2003, 104 s. 90 rys. 18 tab. bibliogr. 106 poz. Rozprawa doktorska (04.03.2003 r.), Wydz. ETI. Promotor: prof. dr inż. R. Zielonko.
PublicationPraca jest rozprawą doktorską, której celem było opracowanie nowych metodpomiarowych i procedur diagnostycznych powłok antykorozyjnych, zwłaszczagrubowarstwowych, drogą identyfikacji parametrów impedancyjnych ich modeli(układów zastępczych), nadających się do realizacji praktycznej w mikrosys-temach pomiarowych przeznaczonych do pracy w terenie oraz realizacja przyk-ładowego mikrosystemu pomiarowo-diagnostycznego powłok...
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Wpływ wybranych parametrów środowiska na przebieg degradacji rur okładzinowych ze stali P110
PublicationMateriały używane na orurowanie odwiertów w poszukiwaniu i wydobyciu ropy i gazu poddawane są niekorzystnym warunkom eksploatacji takich jak: podwyższona temperatura, wysokie ciśnienie, turbulentny przepływ korozyjnych cieczy z zawieszonymi cząstkami stałymi. Jednym z gatunków stali używanych do produkcji rur okładzinowych jest stal P110 (za normą API 5CT) będąca stalą średnio-węglową, niskostopową o wysokiej wytrzymałości. Celem...
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Fourier transform infrared spectroscopic and theoretical study of water interactions with glycine and its N-methylated derivatives
PublicationZbadano hydratację glicyny i jej metylowych pochodnych: N-metyloglicyny (NMG), N,N-dimetyloglicyny (DMG) i N,N,N-trimetyloglicyny (TMG) przy wykorzystaniu spektroskopii FTIR, z zastosowaniem cząsteczki HDO jako sondy molekularnej. Ilościowa wersja metody widm różnicowych pozwoliła na wyizolowanie widma wody zaburzonej przez substancję rozpuszczoną. Wyniki widmowe zostały skonfrontowane z obliczeniami teoretycznymi w ramach teorii...
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Synteza, struktura chemiczna i właściwości termoplastycznych bio-poli(etero-uretanów) syntezowanych z surowców pochodzenia roślinnego.
PublicationPrzeprowadzone studia literaturowe, zaprezentowane w części teoretycznej dysertacji, umożliwiły wskazanie głównego kierunku badawczego w ramach studiów doktoranckich. Zaplanowane badania miały na celu opracowanie syntezy oraz zbadanie struktury chemicznej i właściwości nowych termoplastycznych bio-poli(etero-uretanów) (TPUs) otrzymywanych z zastosowaniem monomerów pochodzenia roślinnego. Zrealizowane badania zostały podzielone...
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The effect of sunscreen 4‐methylbenzylidene camphor in different and reproductive models, its bioaccumulation and molecular effects on ligand‐receptor interaction, and protein expression
Publication4-Methylbenzylidene camphor (4-MBC) is a photo-absorbing UV filter prevalently used in cosmetics, which can be absorbed into circulation and cause systemic effects. 4-MBC is continued to be released in the environment despite the growing knowledge about its bioaccumulation and endocrine disrupting effects. Previous reviews have mentioned UV-filter together but this review considers 4-MBC alone, due to its prevalence and concerning...
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Zastosowanie czasowo-częstotliwościowej analizy sygnałów dla poprawy właściwości metrologicznych systemów optycznej tomografii koherentnej
PublicationOptyczna tomografia koherentna (OCT) jest metodą obrazowania wewnętrznej struktury obiektów rozpraszających promieniowanie optyczne. Metoda ta wykorzystuje interferometrię niskokoherentą do pomiaru czasu przelotu promieniowania wstecznie rozproszonego od elementów struktury obrazowanego obiektu z rozdzielczością w zakresie od jednego do kilkunastu mikrometrów. Rozprawa dotyczy dwóch rozszerzeń metody OCT. Pierwsze z nich – polaryzacyjna...
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A New Critical Risk on the Block: Cyber Risks as an Example of Technical Knowledge Risks in Organizations
PublicationThe breakout of the COVID-19 pandemic has intensified the appearance of many additional technical knowledge risks in organizations. Cyber risks in particular are becoming a great challenge for organizations. At the same time, academic research on cyber risks, their costs, consequences and ability of overcoming them is still scarce and fragmented. In order to fill this gap, the paper is aimed to identify different types of cyber...
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Effect of MgSO4 nutrition on Theobroma cacao L. susceptibility to Phytophthora megakarya infection
PublicationA new strategy to reduce the severity of black pod disease (BPD) in T. cacao plants using MgSO4 nutrition was investigated. The dynamics of the tolerance to BPD of 18 susceptible T. cacao plantlets coming from the cross (♀SNK64 × ♂UPA14) was monitored during weekly (8 weeks) supply of MgSO4 into the soil. Prior to MgSO4 application, disease scores of the 18 plantlets (in six sets of three plantlets per set) were varying between...
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Synteza i właściwości nowych pochodnych 1,4,7,10-tetraazacyklododekanu
PublicationCelem pracy była synteza i zbadanie właściwości pochodych 1,4,7,10-tetraazacyklododekanu (cyklenu). Otrzymano trzy grupy związków: alkilowe pochodne cyklenu, acylowe pochodne cyklenu i pochodne posiadające w swojej budowie ugrupowanie azowe. Acylowe pochodne zostały zsyntezowane w reakcji z wykorzystaniem p-nitrofenylowych estrów aktywnych, co nie było do tej pory stosowane w chemii cyklenu. Jest to jednoetapowa reakcja w wyniku...
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Coupling between Blood Pressure and Subarachnoid Space Width Oscillations during Slow Breathing
PublicationThe precise mechanisms connecting the cardiovascular system and the cerebrospinal fluid (CSF) are not well understood in detail. This paper investigates the couplings between the cardiac and respiratory components, as extracted from blood pressure (BP) signals and oscillations of the subarachnoid space width (SAS), collected during slow ventilation and ventilation against inspiration resistance. The experiment was performed on...
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„Rozpocznij karierę z firmą Deloitte” – spotkanie online
Events12 maja br. Biuro Karier PG zaprasza studentów i absolwentów PG na spotkanie online z przedstawicielami firmy Deloitte.
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Applications of Tensor Analysis in Continuum Mechanics
PublicationA tensor field is a tensor-valued function of position in space. The use of tensor fields allows us to present physical laws in a clear, compact form. A byproduct is a set of simple and clear rules for the representation of vector differential operators such as gradient, divergence, and Laplacian in curvilinear coordinate systems. The tensorial nature of a quantity permits us to formulate transformation rules for its components...
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Organic Vapor Sensing Mechanisms by Large-Area Graphene Back-Gated Field-Effect Transistors under UV Irradiation
PublicationThe gas sensing properties of graphene back-gated field-effect transistor (GFET) sensors toward acetonitrile, tetrahydrofuran, and chloroform vapors were investigated with the focus on unfolding possible gas detection mechanisms. The FET configuration of the sensor device enabled gate voltage tuning for enhanced measurements of changes in DC electrical characteristics. Electrical measurements were combined with a fluctuation-enhanced...
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Olmesartan for the Delay or Prevention of Microalbuminuria in Type 2 Diabetes
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A continual model of a damaged medium used for analyzing fatigue life of polycrystalline structural alloys under thermal–mechanical loading
PublicationThe main physical laws of thermal–plastic deformation and fatigue damage accumulation processes in polycrystalline structural alloys under various regimes of cyclic thermal–mechanical loading are considered. Within the framework of mechanics of damaged media, a mathematical model is developed that describes thermal–plastic deformation and fatigue damage accumulation processes under low-cycle loading. The model consists of three...
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Knowledge management approaches among KIBS companies and their determinants – case study analysis
PublicationThis paper aims to present knowledge management (KM) approaches manifested by knowledge intensive business service (KIBS) companies together with their potential determinants (company size, type of services offered, and organizational structure). In particular, two types of approaches have been selected and examined, i.e. emergent KM approach and deliberate KM approach. Indeed, although KM approaches have been abundantly investigated...
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Numerical Issues and Approximated Models for the Diagnosis of Transmission Pipelines
PublicationThe chapter concerns numerical issues encountered when the pipeline flow process is modeled as a discrete-time state-space model. In particular, issues related to computational complexity and computability are discussed, i.e., simulation feasibility which is connected to the notions of singularity and stability of the model. These properties are critical if a diagnostic system is based on a discrete mathematical model of the flow...
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Is Digitalization Improving Governance Quality? Correlating Analog and Digital Benchmarks
PublicationThe digitalization of public governance and the resulting concept of electronic governance is a characteristic feature of contemporary information society. Both can be defined as the process and outcome of digital transformation: transformation of the “analog” version of governance into “digital” governance. Measuring both versions of governance against typical performance measures of efficiency, effectiveness, equity, openness...