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Wyniki wyszukiwania dla: SCALAR GREEN,S FUNCTION
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Green Analytical Chemistry: Summary of Existing Knowledge and Future Trends
PublikacjaAnalysis of recent publications in green analytical chemistry shows the current trends and future needs in this area. The main issues are related with search for cheaper, more efficient, more accurate, greener and miniaturized alternatives. Miniaturization is perhaps, the most notable current trend in analytical chemistry. Rapid developments and improvements in instrumentation have led to impressive range of benchtop technology...
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Optimization of liquid chromatographic separation of pharmaceuticals within green analytical chemistry framework
PublikacjaThe contribution is aimed at the development of methodology that allows to consider green analytical chemistry criteria during optimization of liquid chromatographic separation with design of experiment. The objectives of the optimization are maximization of peak areas of five non-steroid anti-inflammatory drugs, maximization of resolution between peaks, with simultaneous shortening of chromatographic separation time and minimization...
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Green analytical chemistry: Social dimension and teaching
PublikacjaGreen Analytical Chemistry (GAC) is the idea which every analytical chemist should be familiar of. Due to continuous improvement in the subject both from the aspects of theory and experimentation, the dynamic way analytical chemistry studies are evolving in the frame of chemistry degrees should not be surprising. Recently, many efforts have been made in order to include Green Chemistry principles to Education, also in the field...
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General scheme for construction of scalar separability criteria from positive maps
PublikacjaStandardowe nierówności entropijne są znanym narzędziem do detekcji splątania dwupodukładowych stanów kwantowych. W pracy podano metodę wyprowadzania nierówności przypominających standardowe nierówności entropijne z dowolnych odwzorowań dodatnich. Ponadto, przebadano nierówności w przypadku kilku znanych z literatury odwzorowań dodatnich.
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Beyond the standard entropic inequalities: stronger scalar separability criteria and their applications
PublikacjaNiedawno pokazano, że jeżeli dwupodukładowy stan kwantowy spełnia strukturalne kryterium separowalności oparte na pewnym liniowym odwzorowaniu dodatnim (tzw. odwzorowanie redukcyjne) to musi także spełniać skalarne kryterium separowalności oparte na nierównościach entropijnych. Ponieważ nierówności te są obiecującymi z eksperymentalnego punktu widzenia detektorami splątania w układach kwantowych, interesującym wydaje się pytanie...
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Recurrence scheme for FDTD-compatible discrete Green's function derived based on properties of Gauss hypergeometric function
PublikacjaIn this paper, the formulation of one-dimensional FDTD (Finite-difference time-domain)-compatible discrete Green's function (DGF) is derived based on the Gauss hypergeometric function (GHF). The properties of GHF make it possible to derive the recurrence scheme only in the time domain for the DGF generation. Furthermore, this recurrence scheme is valid for any stable time-step size and can be implemented using standard numerical...
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Analysis of radiation and scattering problems with the use of hybrid techniques based on the discrete Green's function formulation of the FDTD method
PublikacjaIn this contribution, simulation scenarios are presented which take advantage of the hybrid techniques based on the discrete Green's function formulation of the finite-difference time-domain (DGF-FDTD) method. DGF-FDTD solutions are compatible with the finite-difference grid and can be applied for perfect hybridization of the FDTD method. The following techniques are considered: (i) DGF-FDTD for antenna simulations, (ii) DGF-based...
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“Green” nature of the process of derivatization in analytical sample preparation
PublikacjaNowadays, the idea of Green Analytical Chemistry (GAC) is of high importance what impacts on the rapid growth in the sample preparation area with special emphasis on sample preparation simplification, miniaturization, and automation. Because the derivatization process is often an essential element of the analytical procedure, it should be important to focus on this issue from GAC perspective and conduct a series of experiments...
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Acceleration of the discrete Green's function computations
PublikacjaResults of the acceleration of the 3-D discrete Green's function (DGF) computations on the multicore processor are presented. The code was developed in the multiple precision arithmetic with use of the OpenMP parallel programming interface. As a result, the speedup factor of three orders of magnitude compared to the previous implementation was obtained thus applicability of the DGF in FDTD simulations was significantly improved.
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Local basis function method for identification of nonstationary systems
PublikacjaThis thesis is focused on the basis function method for the identification of nonstationary processes. The first chapter describes a group of models that can be identified using the basis function method. The next chapter describes the basic version of the basis function method, including its algebraic and statistical properties. The following section introduces the local basis function (LBF) method: its properties are described...
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Green Chemistry in Higher Education: State of the Art, Challenges, and Future Trends
PublikacjaNowadays, there is increasing interest in global sustainability, and thus, university students would like to know how human actions affect the health status of our planet. This is mainly due to their basic knowledge of problems such as global warming and greenhouse gases. Students would like to gain knowledge on how to safeguard the earth for future generations. This must involve changes in education programs at interested institutions...
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Metal-Organic Frameworks in Green Analytical Chemistry
PublikacjaTaking into consideration the rapid expansion of MOFs applications in the analytical chemistry area, it is important to evaluate the existing and future analytical MOF-based methods according to GAC principles. From this point of view, eco-friendly MOFs-based methods should include features such as: green design and synthesis of MOF, evaluation of toxicity issues of MOFs, and incorporation of MOFs in GAC methods. This Chapter will...
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Firing map of an almost periodic input function
PublikacjaIn mathematical biology and the theory of electric networks the firing map of an integrate-and-fire system is a notion of importance. In order to prove useful properties of this map authors of previous papers assumed that the stimulus function f of the system ẋ = f(t,x) is continuous and usually periodic in the time variable. In this work we show that the required properties of the firing map for the simplified model ẋ = f(t) still...
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Accuracy of the discrete Green's function computations
PublikacjaThis paper discusses the accuracy of the discrete Green's function (DGF) computations. Recently closed-form expression of the DGF and its efficient numerical implementation were presented which facilitate the DGF applications in FDTD simulations of radiation and scattering problems. By carefully comparing the DGF results to those of the FDTD simulation, one can make conclusions about the range of the applicability of the DGF for...
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A new tool for the evaluation of the analytical procedure: Green Analytical Procedure Index
PublikacjaA new means for assessing analytical protocols relating to green analytical chemistry attributes has been developed. The new tool, called GAPI (Green Analytical Procedure Index), evaluates the green character of an entire analytical methodology, from sample collection to final determination, and was created using such tools as the National Environmental Methods Index (NEMI) or Analytical Eco-Scale to provide not only general but...
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Stark-induced magnetic anapole moment in the ground state of the relativistic hydrogenlike atom: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaZnaleziono magnetyczny moment anapolowy indukowany w stanie podstawowym relatywistycznego atomu jednoelektronowego przez zewnętrzne stałe, słabe, jednorodne pole elektryczne. Podano wyrażenie analityczne dla polaryzowalności anapolowej takiego atomu. Obliczenia wykonano, stosując rozwinięcie sturmowskie uogólnionej funkcji Greena-Diraca-Coulomba.
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Gordon decomposition of the static dipole polarizability of the relativistic hydrogen-like atom: application of the Sturmian expansion of the first-order Dirac-Coulomb Green function.
PublikacjaWyprowadzono analityczne wyrażenie dla statycznej polaryzowalności dipolowej relatywistycznego atomu jednoelektronowego w stanie podstawowym. Dokonano rozkładu Gordona polaryzowalności. Pokazano, że polaryzowalność ma charakter czysto konwekcyjny.
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Chemometrics for Selection, Prediction, and Classification of Sustainable Solutions for Green Chemistry—A Review
PublikacjaIn this review, we present the applications of chemometric techniques for green and sustainable chemistry. The techniques, such as cluster analysis, principal component analysis, artificial neural networks, and multivariate ranking techniques, are applied for dealing with missing data, grouping or classification purposes, selection of green material, or processes. The areas of application are mainly finding sustainable solutions...
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Bioassays as one of the Green Chemistry tools for assessing environmental quality: A review
PublikacjaFor centuries, mankind has contributed to irreversible environmental changes, but due to the modern science of recent decades, scientists are able to assess the scale of this impact. The introduction of laws and standards to ensure environmental cleanliness requires comprehensive environmental monitoring, which should also meet the requirements of Green Chemistry. The broad spectrum of Green Chemistry principle applications should...
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Windowing of the Discrete Green's Function for Accurate FDTD Computations
PublikacjaThe paper presents systematic evaluation of the applicability of parametric and nonparametric window functions for truncation of the discrete Green's function (DGF). This function is directly derived from the FDTD update equations, thus the FDTD method and its integral discrete formulation can be perfectly coupled using DGF. Unfortunately, the DGF computations require processor time, hence DGF has to be truncated with appropriate...
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Port-based approach to distributed transfer function method
PublikacjaIn the paper there is presented an uniform, port-based approach to modeling of both lumped and distributed parameter systems. Port-based model of distributed system has been defined by application of distributed transfer function method (DTFM). The approach proposed combines versatility of port - based modeling and accuracy of distributed transfer function method. It enables to formulate appropriate input data for computer analysis...
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Spatial Heterogeneity Impacts of Bilateral Foreign Direct Investment on Green Energy Efficiency in China
PublikacjaAt present, green energy transformation and climate policy are increasingly connected. The need to improve national competitiveness and implement climate and energy strategies means that an energy-consuming country like China must rapidly enhance its green energy efficiency (GEE) and energy consumption structure. The following paper contributes to the existing literature by analyzing the effects of bilateral FDI on GEE from...
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The Concept of Using the Decision-Robustness Function in Integrated Navigation Systems
PublikacjaThe diversity and non-uniformity of the positioning systems available in maritime navigation systems often impede the watchkeeping officer in the selection of the appropriate positioning system, in particular, in restricted basins. Thus, it is necessary to introduce a mathematical apparatus to suggest, in an automated manner, which of the available systems should be used at the given moment of a sea trip. Proper selection of the...
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ROLE OF GREEN LOGISTICS IN THE CONSTRUCTION OF SUSTAINABLE SUPPLY CHAINS
PublikacjaThe global supply chain has been growing strongly in recent years. This development brings many benefits to the economy, society, and human resources in each country but also causes a large number of concerns related to the environment since traditional logistics activities in the supply chain have been releasing significant amount of emissions. For that reason, many solutions have been proposed to deal with these environmental...
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Trends in the new generation of green solvents in extraction processes
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Chemometrics approaches to green analytical chemistry procedure development
PublikacjaChemometric tools are widely used in analytical chemistry for the reduction of data dimensionality, grouping of variables and processing of analytical signals. They have also the potential to be applied in analytical procedure development with the aim of minimizing the procedure’s environmental impact. The design of experiment gives the possibility to obtain much better information on the system response than in case of “changing...
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Local basis function estimators for identification of nonstationary systems
PublikacjaThe problem of identification of a nonstationary stochastic system is considered and solved using local basis function approximation of system parameter trajectories. Unlike the classical basis function approach, which yields parameter estimates in the entire analysis interval, the proposed new identification procedure is operated in a sliding window mode and provides a sequence of point (rather than interval) estimates. It is...
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THE USE OF GREEN LOGISTICS ELEMENTS DURING THE CONSTRUCTION OF OFFSHORE VESSELS
PublikacjaThe article is aimed at the presentation referring to the use of green logistics elements during the construction of the offshore vessels in the following aspects: collection, removal and utilisation of any waste that is harmful for natural environment, elimination of the negative impact that such waste can have on natural environment and the search for the optimal solutions as regards these aspects.
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Tuning the work function of graphite nanoparticles via edge termination
PublikacjaGraphite nanoparticles are important in energy materials applications such as lithium-ion batteries (LIBs), supercapacitors and as catalyst supports. Tuning the work function of the nanoparticles allows local control of lithiation behaviour in LIBs, and the potential of zero charge of electrocatalysts and supercapacitors. Using large scale density functional theory (DFT) calculations, we find that the surface termination of multilayer...
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Electric and magnetic dipole shielding constans for the ground state of the relativistic hydrogen-like atom: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaStosując rozwinięcie sturmowskie funkcji Greena-Diraca-Coulomba, znaleziono wyrażenie analityczne dla stałych ekranowania elektrycznego i magnetycznego relatywistycznego atomu wodoropodobnego w stanie podstawowym.
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Electric-field-induced magnetic quadrupole moment in the ground state of the relativistic hydrogenlike atom: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaStosując rozwinięcie sturmowskie uogólnionej funkcji Greena-Diraca-Coulomba, znaleziono wyrażenie analityczne dla magnetycznego momentu kwadrupolowego, indukowanego przez zewnętrzne słabe, stałe, jednorodne pole elektryczne w stanie podstawowym relatywistycznego atomujednoelektronowego.
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Do clusters help companies to "go green"? Experience of Polish National Key Clusters
PublikacjaThis study aims to explore cluster activity in the field of green transformation, taking into account the green, low-carbon and circular economy. Our intention was to identify the main green practices used by cluster organizations, which we showed through the lens of the attributes of both the cluster and the cluster organization. Through our study, we sought to answer the question: what is the role of cluster organizations in...
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Deep slot effect in the squirrel-cage induction motors with scalar (V/F) control
PublikacjaQualitative characteristics of the electrical drive considerably depend on identification accuracy of math model parameters. In particular, it is depend on detection accuracy of stator active resistance r1 that is used in calculation of flux linkages, rotary speed in sensorless control systems. Paper provides analysis of influence of stator deep slot effect to stator active resistance value
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Green Chromatography: State-of-the-art, Opportunities and Future Perspectives
PublikacjaIt is well known that chromatographic procedures could have a significant impact on the environment if laboratory practice is not in line with the principles of green analytical chemistry (GAC). However, chromatographic techniques have the potential to be greener in all steps of the analysis. The approaches used to make chromatographic separations greener differ depending on the type of chromatographic method. This chapter considers...
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Roughness evaluation of turned composite surfaces by analysis of the shape of Autocorrelation Function
PublikacjaIn this paper, the application of an Autocorrelation Function for the characterisation of surface topography was validated. The roughness evaluation of turned composite surfaces was supported by sophisticated studies of the Autocorrelation Function properties, considering especially the shape of the function. Details were measured with the optical method. The selection of the surface roughness evaluation procedures was carried...
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Green aspects of techniques for the determination of pesticides in fruits and vegetables
PublikacjaApplied all over the world, pesticides are some of the most dangerous pollutants of the environment because of their stability, mobility, their ability to accumulate in the environment and their consequent long-term adverse effects on living organisms in general and human health in particular. Their presence in the environment is a particular danger. It is therefore crucial to monitor pesticide residues using all available analytical...
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Magnetic field-induced electric quadrupole moment in the ground state of the relativistic hydrogen-like atom: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaStosując rozwinięcie sturmowskie funkcji Greena-Diraca-Coulomba, znaleziono wyrażenie analityczne dla elektrycznego momentu kwadrupolowego, indukowanego przez zewnętrzne pole magnetyczne w relatywistycznym atomie wodoropodobnym w stanie podstawowym. Wykazano, że jest to efekt czysto relatywistyczny.
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Validation of dynamic electrochemical impedance spectrograms using autocorrelation function
PublikacjaValidation of impedance data is essential for checking the reliability of experimental data. Kramers – Kronig transformation is used to verify data obtained from classical Electrochemical Impedance Spectroscopy (EIS) measurements. Data obtained from Dynamic Electrochemical Impedance Spectroscopy (DEIS) could be validated in the same way, but in this case, there is no information about internal consistency between every single spectrum...
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The green waterfront of a city. Where are the limits of good planning? Gdansk case
PublikacjaThe aim of the article is to present the role of green public areas of waterfronts in shaping the image of cities, and the threats to such landscape which may be caused by wrong planning decisions. The case study of Gdansk sea-shore area in Poland is presented as an example to illustrate the values and potential of the waterfront landscape which can be easily destroyed by inadequate spatial development. Some theoretical studies...
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A Panel Analysis of the Impact of Green Transformation and Globalization on the Labor Share in the National Income
PublikacjaThis study aims to examine the impact of green transition and globalization processes on changes in the labour share. The study covers 76 national economies diversified in development, global production share and energy transition stage from 2000 to 2018. Based on the Total Economy Database data, panel models of the relationship between green transition, globalization and the labour share in the national income were estimated....
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Regularized Local Basis Function Approach to Identification of Nonstationary Processes
PublikacjaThe problem of identification of nonstationary stochastic processes (systems or signals) is considered and a new class of identification algorithms, combining the basis functions approach with local estimation technique, is described. Unlike the classical basis function estimation schemes, the proposed regularized local basis function estimators are not used to obtain interval approximations of the parameter trajectory, but provide...
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From grey to green
PublikacjaThe article presents conceptual project made by students during Urban European Summer School “City on water” in Bremen 2015. The area of study was Hemelingen, Aller-Harbour, Bremen, Germany. The aim was to make a design of regeneration of the area. Students were free in choosing methods and ideas for their project.
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Fast implementation of FDTD-compatible green's function on multicore processor
PublikacjaIn this letter, numerically efficient implementation of the finite-difference time domain (FDTD)-compatible Green's function on a multicore processor is presented. Recently, closed-form expression of this discrete Green's function (DGF) was derived, which simplifies its application in the FDTD simulations of radiation and scattering problems. Unfortunately, the new DGF expression involves binomial coefficients, whose computations...
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Green Approaches in Rubber Recycling Technologies: Present Status and Future Perspective
PublikacjaAs a consequence of massive production and consumption of rubbers, rubber blends, and rubber composites for myriad applications, elastomeric products have enormously accumulated and become an environmental threat. The disposal and burning of rubber wastes have been banned because of environmental and economic reasons. By contrast, a great deal of attention has been directed toward strategies enabling recycling and reuse of rubbers....
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Implementation of FDTD-Compatible Green's Function on Graphics Processing Unit
PublikacjaIn this letter, implementation of the finite-difference time domain (FDTD)-compatible Green's function on a graphics processing unit (GPU) is presented. Recently, closed-form expression for this discrete Green's function (DGF) was derived, which facilitates its applications in the FDTD simulations of radiation and scattering problems. Unfortunately, implementation of the new DGF formula in software requires a multiple precision...
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Green analytical chemistry introduction to chloropropanols determination at no economic and analytical performance costs?
PublikacjaIn this study we perform ranking of analytical procedures for 3-monochloropopane-1,2-diol determination in soy sauces with PROMETHEE method. Multicriteria decision analysis was performed for three different scenarios – metrological, economic and environmental, by application different weights to decision making criteria. All three scenarios indicate capillary electrophoresis – based procedure as the most preferable. Apart from...
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Public spaces connecting cities. Green and Blue Infrastructures potential.
PublikacjaA city fragmentation causes a lot of negative effects in urban environment such as: disconnecting the environmental, functional and compositional relations, a loss of urban compactness, chaotic development, visual chaos, a domination of technical landscape, reduction of security. This is why one of main challenges for urban planners is to connect the fragmented structures by creating friendly, attractive and safe public space....
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Experimental and Theoretical Screening for Green Solvents Improving Sulfamethizole Solubility
PublikacjaSolubility enhancement of poorly soluble active pharmaceutical ingredients is of crucial importance for drug development and processing. Extensive experimental screening is limited due to the vast number of potential solvent combinations. Hence, theoretical models can offer valuable hints for guiding experiments aimed at providing solubility data. In this paper, we explore the possibility of applying quantum-chemistry-derived...
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Management Strategy for Seaports Aspiring to Green Logistical Goals of IMO: Technology and Policy Solutions
PublikacjaRecently, because of serious global challenges including the consumption of energy and climate change, there has been an increase in interest in the environmental effect of port operations and expansion. More interestingly, a strategic tendency in seaport advancement has been to manage the seaport system using a model which balances environmental volatility and economic development demands. An energy efficient management system...
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Planning of the green road system as an element of spatial management in suburbs and small towns
PublikacjaThe premise for the development of sustainable forms of road infrastructure in small towns is the appropriate plan at an early stage or modifi cation in the case of existing spaces. A multi-directional approach is extremely important, which takes into account the specifi city of the regional (country) road system, availability, and capacity of traffi c network, but also social and environmental factors. Effi cient management...