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wszystkich: 511
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Wyniki wyszukiwania dla: OPTICAL SPECTROSCOPY, ELECTROLUMINESCENT DIODES, PHOTOVOLTAIC CELLS, ORGANIC ELECTRONICS
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Photovoltaic bulk heterojunctions with interpenetrating network based on semiconducting polymers
PublikacjaPhotovoltaic cells are supposed to be the most common generators of useful electricity in the nearest future as they utilize inexhaustible carriers of renewable energy called photons. Despite the fact that 95% of worldwide applied photovoltaic devices are based on inorganic semiconductors the area of organic photovoltaics grows successively due to possibility of considerable reduction of manufacturing costs. Since the Heeger's...
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Solvothermal synthesis and structural characterization of three polyoxotitanium-organic acid clusters
PublikacjaThree new titanium oxo-clusters Ti4O2(OiPr)10(OOCPhMe)2 (I), Ti6O4(OEt)8(OOCPhMe)8 (II) and Ti6O6(OEt)6(OOCCHPh2)6 (III) were obtained by easy one-step solvothermal reactions of titanium(IV) isopropoxide, alcohols and carboxylic acids. The three compounds were characterized by single-crystal and powder X-ray diffraction, TGA/DSC, optical and electron microscopy, and FTIR and NMR spectroscopy. X-ray powder diffraction and spectroscopy...
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An interactive system for remote modeling and design validation of hybrid photovoltaic systems
PublikacjaIn the paper a multi-functional demonstrator of the interactive system designed to modeling, monitoring and validation of hybrid photovoltaic systems assisted by fuel cells and thermoelectric generators is presented. The purpose of this paper is to report the system solution expressed in the form of a block diagram. Technical parameters of demonstrator components such as: silicon photovoltaic modules, fuel cells, thermoelectric...
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Chemical treatment of crystalline silicon solar cells as a main stage of pv modules recycling = Obróbka chemiczna krzemowych ogniw słonecznych jako najważniejszy etap w recyklingu modułów fotowoltaicznych
PublikacjaIn recent years, photovoltaic systems have gained worldwide recognition and popularity as a environmentally friendly way of solving energetic problems. However, a problem of utilizing worn out photovoltaic systems, amount of which will rapidly increase in the future, is yet to be solved. Establishing a technology of recycling and reusing obsolete photovoltaic panels is a necessity.Photovoltaic modules in crystalline silicon solar...
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The influence of the thickness, recombination and space charge on the loss of photocurrent in organic semiconductors: an analytical model
PublikacjaWe propose an analytical model of the photocurrent efficiency dependence on the light intensity in organic semiconductors. The influence of the thickness of sample, space charge effects and recombination of charge on the loss of photocurrent has been considered. We demonstrate that the presented model is the enhancement of an analytical model reported recently by Rappaport et al (2005 J. Appl. Phys. 98 033714). The method to identify...
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Tripping limitations of residual current devices in photovoltaic installations
PublikacjaIn electrical installations with photovoltaic sources of energy, earth fault current may comprise alternating current component and direct current component. The waveform shape of this earth fault current mainly depends on the point of the fault and the properties of a photovoltaic power electronics converter. The waveform shape of the current influences operation of protection devices, especially tripping threshold of residual...
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Influence of pH and low-molecular weight organic compounds in solution on selected spectroscopic and analytical parameters of flowing liquid anode atmospheric pressure glow discharge (FLA-APGD) for the optical emission spectrometric (OES) determination of Ag, Cd, and Pb
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Alternative Energy: Photovoltaic Modules and Systems
PublikacjaUse of solar energy does not contribute to global warming. The light-to-current conversion (photovoltaic conversion) takes place within solar cells, which in most cases are made of silicon. Solar module consists of many solar cells, which are electrically connected and placed between glass or Tedlar® and framed by an aluminium frame. A number of solar modules and other components form photovoltaic systems. In this entry, a brief...
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Hybrid P3HT: PCBM/GaN nanowire/Si cascade heterojunction for photovoltaic application
PublikacjaPoly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) are commonly used for the fabrication of organic photovoltaics (OPV). Efficiency limitations of OPVs could be circumvented by incorporation of inorganic nanostructures into organic blends. Again, integration of organic solar cells with well-developed silicon photovoltaic technology is ultimately desirable. In present work, GaN nanowires with diameters...
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Investigation of the Few‐Layer Black Phosphorus Degradation by the Photonic Measurements
PublikacjaFew-layer black phosphorus (FLBP) is a 2D material that gains worldwide interest for its possible applications, mainly in electronics and optoelec-tronics. However, as FLBP is prone to a degradation process under envi-ronmental conditions, there is a need for a monitoring method allowing investigation of its surface quality. Among many techniques, optoelectronic ones have unique advantages of fast response, non-contact, and non-invasive...
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Designing efficient A-D-A1-D-A type fullerene free acceptor molecules with enhanced power conversion efficiency for solar cell applications
PublikacjaThe achievement of highly efficient power conversion efficiency (PCE) is a big concern for non-fullerene organic solar cells (NF-OSCs) because PCE can depend on numerous variables. Here, new five novel acceptor molecules without fullerenes were developed and investigated using DFT (density functional theory) and TD-DFT (time dependent-density functional theory). Compared to the recently synthesized molecule (PZ-dIDTC6), the developed...
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Singlet Exciton Diffusion in Vacuum-Evaporated Films of Amine-Based Materials as Studied by Photocurrent and Photoluminescence Quenching Methods
PublikacjaThe singlet exciton diffusion lengths are determined by the photoconductivity as well as the luminescence surface quenching technique, in vacuum‐evaporated layers of (4,4′,4″‐tris(N‐(3‐methylphenyl)‐N‐phenylylamino) triphenylamine) (m‐MTDATA), 4,4′,4″‐tris[2‐naphthyl(phenyl)amino] triphenylamine (2TNATA), and N,N′‐diphenyl‐N,N′‐bis(3‐methylphenyl)‐[1,1′‐biphenyl]‐4,4′‐diamine (TPD) which are frequently used for fabrication of electroluminescent...
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Heat recovery from the hybrid photovoltaic tile – experimental studies with the solar light simulator
PublikacjaConsidering the current development of micro-cogeneration energy sources, supported by the national prosumer policy and the act on the renewable energy sources, there is a great demand for the effective solar technologies. In this area, the photovoltaic cells with a combined conversion of the solar radiation energy into the electrical and thermal energy (PV/T cells) seem to be attractive. They are already widely available and treated...
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Light-Powered Starter for Micro-Power Boost DC–DC Converter for CMOS Image Sensors
PublikacjaThe design of a starter for a low-voltage, micro-power boost DC–DC converter intended for powering CMOS image sensors is presented. A unique feature of the starter is extremely low current, below 1 nA, supplying its control circuit. Therefore, a high-voltage (1.3 V) configuration of series-connected photovoltaic diodes available in a standard CMOS process or a small external LED working in photovoltaic mode can be used as an auxiliary...
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Magnetic field effects in dye-sensitized solar cells controlled by different cell architecture
PublikacjaThe charge recombination and exciton dissociation are generally recognized as the basic electronic processes limiting the efficiency of photovoltaic devices. In this work, we propose a detailed mechanism of photocurrent generation in dye-sensitized solar cells (DSSCs) examined by magnetic field effect (MFE) technique. Here we demonstrate that the magnitude of the MFE on photocurrent in DSSCs can be controlled by the radius and...
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Synthesis of Titanium Dioxide via Surfactant-Assisted Microwave Method for Photocatalytic and Dye-Sensitized Solar Cells Applications
PublikacjaIn this study, titania nanoparticles were obtained using the microwave-assisted technique. Moreover, different surfactants (PEG (Mn = 400), Pluronic P123 and Triton X−100) were used during the synthesis in order to determine their impact on the crystallinity and morphology of the final products. Subsequently, techniques such as XRD, SEM and TEM (performed in high contrast and high-resolution mode), diffuse reflectance spectroscopy...
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Recovery of Valuable Materials and Methods for Their Management When Recycling Thin-Film CdTe Photovoltaic Modules
PublikacjaDue to the development of new photovoltaic technologies, there is a need to research new recycling methods for these new materials. The recovery of metals from photovoltaic (PV) modules would reduce the consumption of raw materials. Therefore, the development of recycling technologies for used and damaged modules of newer generations is important for environmental reasons. The aim of the research is to shed light on the nature...
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Praktyka wykonywania pomiarów instalacji fotowoltaicznych prowadząca do określenia rzeczywistego stanu technicznego
PublikacjaPraca przedstawia zasady wykonywania pomiarów instalacji fotowoltaicznych wg normy PN-EN 62446-1. Proponowany w normie zakres podstawowy pozwala tylko na ocenę bezpieczeństwa pracy instalacji. Dopiero zakres dodatkowy umożliwia uzyskanie informacji o referencyjnych mocach zainstalowanej elektrowni, jej sprawności, a nawet jednorodności poszczególnych ogniw fotowoltaicznych. Załączone przykłady pomiarów czystych i zabrudzonych paneli...
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GaN Nanowire Array for Charge Transfer in Hybrid GaN/P3HT:PC71BM Photovoltaic Heterostructure Fabricated on Silicon
PublikacjaAbstract: We demonstrate that a GaN nanowire array can be used for efficient charge transfer between the organic photovoltaic layer and silicon in a Si/GaN/P3HT:PC71BM inverted hybrid heterostructure. The band alignment of such a material combination is favorable to facilitate exciton dissociation, carrier separation and electron transport into Si. The ordered nature of the GaN array helps to mitigate the intrinsic performance...
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The use of recycled semiconductor material in crystalline silicon photovoltaic modules production - A life cycle assessment of environmental impacts
PublikacjaTo offset the negative impact of photovoltaic modules on the environment, it is necessary to introduce a longterm strategy that includes a complete lifecycle assessment of all system components from the production phase through installation and operation to disposal. Recycling of waste products and worn-out systems is an important element of this strategy. As the conclusions from the previous studies have shown, thermal treatment...
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Influence of Fragment Size on the Time and Temperature of Ethylene Vinyl Acetate Lamination Decomposition in the Photovoltaic Module Recycling Process
PublikacjaPhotovoltaics is a commercially available and reliable technology with significant potential for long-term growth in nearly all global regions. Several research institutes and companies are working on recycling concepts for thin film modules and modules with crystalline cells. The establishment of recycling and reuse technologies appropriate and applicable to all photovoltaics (PV) modules is a key issue to be addressed as part...
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Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups
PublikacjaRe(L1)–Re(L3), a series of rhenium(I) tricarbonyl chloride complexes with bpy-R2 derivatives L1–L3 (bpy = 2,2′-bipyridine, R represents the substitution at the 4- and 4′-positions), and their corresponding trishomoleptic Ru(L1)3–Ru(L3)3 as well as heteroleptic ruthenium(II) complexes Ru(tbbpy)2(L1) and Ru(tbbpy)2(L2) have been synthesized and characterized. Their applicability as immobilizable metal–organic chromophores in solar...
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In-situ monitoring of electropolymerization processes at boron-doped diamond electrodes by Mach-Zehnder interferometer
PublikacjaIn this work, the Mach-Zehnder interferometer was designed to monitor the electrochemical processes conducted at boron-doped diamond electrode surface. The diamond electrodes were synthesized via Microwave Plasma-Assisted Chemical Vapor Deposition on optical grade quartz glass. The achieved transmittance in working are of diamond electrodes reached 55 %. A cage system-based Mach-Zehnder interferometer was used which allowed the...
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Absorption spectroscopy setup for determination of whole human blood and blood–derived materials spectral characteristics
PublikacjaA dedicated absorption spectroscopy system was set up using tungsten-halogen broadband source, optical fibers, sample holder, and a commercial spectrometer with CCD array. Analysis of noise present in the setup was carried out. Data processing was applied to the absorption spectra to reduce spectral noise, and improve the quality of the spectra and to remove the baseline level. The absorption spectra were measured for whole blood...
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Application of thin diamond films in low-coherence fiber-optic Fabry Pérot displacement sensor
PublikacjaThe novel fiber-optic low coherence sensor with thin diamond films is demonstrated. The undoped and boron-doped diamond films were elaborated by the use of the microwave plasma enhanced chemical vapor deposition (μPE CVD) system. The optical signal from the Fabry–Pérot cavity made with the application of those thin films is sensitive to displacement. The sensor characterization was made in the range of 0–600 μm. The measurements...
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NOBLE METAL MODIFIED TiO2 FOR PHOTOCATALYTIC AIR PURIFICATION
PublikacjaTiO2 was surface modified with silver, gold, palladium and platinum ion clusters to improve its photocatalytic activity. The effect of metal content, the kind of dopant used during preparation procedure on the photoactivity were investigated. in toluene removal which was used as a model volatile organic compound. Toluene, at the concentration of about 100 ppm, was irradiated over noble metal modified TiO2 using light-emitting diodes...
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Photoconduction in the archetype organic hole transporting material TPD
PublikacjaW pracy przedstawiono charakterystykę fotoprzewodnictwa w zależności od przyłożonego pola elektrycznego, długości fali i natężenia światła wzbudzającego molekuły pochodnej diaminy (TPD)wykorzystywanej powszechnie jako organiczny przewodnik dziurowy w organicznych diodach elektroluminescencyjnych. Układy z pojedynczą warstwą TPD, kwarc/ITO/TPD/Al i kwarc/Al/TPD/Al, zostały wzbudzane od strony podłoża kwarcowego. Przy długościach...
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Injection of charge into the archetype organics hole transporting material TPD at the electrical contacts with ITO and Al
PublikacjaW pracy zaprezentowano dokładną analizę charakterystyk polowo-prądowych jednowarstwowych układów kwarc/ITO/TPD/Al oraz kwarc/Al1/TPD/Al2, zawierających próżniowo naparowane warstwy pochodnej diaminy (TPD) używane powszechnie jako materiał przewodzący dziury w organicznych diodach elektroluminescencyjnych. Prądy są zdominowane przez iniekcję dziur niezależnie od polaryzacji kontaktów elektrycznych. Oprócz oczywistej asymetrii w...
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Photoconduction in the archetype organic hole transporting material TPD
PublikacjaW pracy opisano mechanizm fotoprzewodnictwa w układzie ITO/warstwa TPD/Al oraz Al/warstwa TPD/Al, gdzie TPD oznacza dwaminę powszechne stosowaną jako transporter dziur w organicznych diodach EL.
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Injection of charge into the archetype organic hole transporting material TPD at the electrical contacts with ITO and Al
PublikacjaW pracy opisano mechanizm przewodnictwa ciemnego w układzie ITO/warstwa TPD/Al oraz Al/warstwa TPD/Al, gdzie TPD oznacza dwaminę powszechne stosowaną jako transporter dziur w organicznych diodach EL.
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Electromodulation and magnetomodulation of exciton dissociation in electron donor (starburst amine) : electron acceptor (bathocuproine) system
PublikacjaElectric field dependencies of electromodulated photoluminescence and photocurrents as well as the magnetic field effects on photocurrents, photovoltaic characteristics, electromodulated photoluminescence and photoluminescence have been investigated in vacuum evaporated films of m-MTDATA:BCP (4,4',4''-tris(N-(3-methylphenyl)-N-phenylamino)triphenylamine and bathocuproine) system. The electromodulation processes do remain in accordance...
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Sano-Tachiya-Noolandi-Hong, Onsager and Braun models vs Monte Carlo simulation of charge photogeneration in organic solids
PublikacjaThe Sano-Tachiya-Noolandi-Hong (STNH), Onsager, and Braun models as well as Monte Carlo (MC) simulations of charge recombination/separation have been applied for the first time to reproduce the results of the electromodulated photoluminescence measurements in vacuum-evaporated films of fluorescent materials commonly used in optoelectronic devices. The values of the electron-hole pair final recombination speed in the monomer emitters:...
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Simulation investigation of perovskite-based solar cells
PublikacjaThree models of thin-layer lead-halide perovskite solar cells with different electron-transport layers (TiO2,SnO2,ZnO) were investigatedby the simulation method. The perovskite layer thickness was optimized for all the systems. The analysis of the standard photovoltaic cell performanceparameters at various operating temperatures was performed. The best performance was achieved for the system with theSnO2conductive layer.
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Feasibility Study GaN Transistors Application in the Novel Split-Coils Inductive Power Transfer System with T-Type Inverter
PublikacjaA promising solution for inductive power transfer and wireless charging is presented on the basis of a single-phase three-level T-type Neutral Point Clamped GaN-based inverter with two coupled transmitting coils. The article focuses on the feasibility study of GaN transistor application in the wireless power transfer system based on the T-type inverter on the primary side. An analysis of power losses in the main components of the...
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POSSIBILITIES OF ELECTRICAL ENERGY GENERATION IN PHOTOVOLTAIC SYSTEMS INSTALLED IN CENTRAL EUROPE
PublikacjaNowadays, fossil fuels are the main sources of energy from which electricity is obtained. But these sources will not last forever, so in due course renewable energies will have to replace them in this role. One of these new sources is solar energy. To generate electricity from sunlight, solar (photovoltaic - PV) cells and modules are used. The increasing interest in PV cells and modules worldwide is due mainly to the fact that...
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Determination of refractive index dispersion using fiber-optic low-coherence Fabry–Perot interferometer: implementation and validation
PublikacjaWe present the implementation and validation of low-coherence Fabry–Perot interferometer for refractive index dispersion measurements of liquids. A measurement system has been created with the use of four superluminescent diodes with different optical parameters, a fiber-optic coupler and an optical spectrum analyzer. The Fabry–Perot interferometer cavity has been formed by the fiber-optic end and mirror surfaces mounted on a micromechanical...
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part I. On-line gas analyzers
PublikacjaThe paper reviews the subject literature concerning the analytical instruments routinely used for monitoring volatile organic compounds in atmospheric air. The analyzers are classified as stationary or mobile according to their ease of transport. Stationary DOAS (Differential Optical Absorption Spectroscopy) analyzer is characterized, as are MIMS (Membrane Introduction Mass Spectrometry), MESI (Membrane Extraction with Sorbent...
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Enhanced Eye-Tracking Data: a Dual Sensor System for Smart Glasses Applications
PublikacjaA technique for the acquisition of an increased number of pupil positions, using a combined sensor consisting of a low-rate camera and a high-rate optical sensor, is presented in this paper. The additional data are provided by the optical movement-detection sensor mounted in close proximity to the eyeball. This proposed solution enables a significant increase in the number of registered fixation points and saccades and can be used...
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Reliable renewable energy – application of electrochemical capacitors for electrical energy storage
PublikacjaThis paper presents electrical energy storage devices such as electrochemical capacitors, their principle of operation and electrode materials most commonly used in their manufacturing technology. Moreover, our research on development of new nanocomposite materials based on multi-walled carbon nanotubes and conducting polymer is shown. Additionally, the possibility and advantages of application of supercapacitors for accumulation...
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Synthesis of novel dinuclear ruthenium polypyridine dye for dye-sensitized solar cells application
PublikacjaA new dinuclear ruthenium(II) polypyridine complex has been successfully synthesized. The new compound has been characterized by spectroscopic and electrochemical methods. Its potential application as a sensitizing dye in dye-sensitized solar cells has been checked under AM 1.5 G irradiation conditions (100 mW cm−2) and its performance was compared to that of a commercially available mononuclear analogous dye. The overall light-to-electricity...
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Electric transport in organic system with planar DBP/F16ZnPc junction on the basis of direct current and small signal admittance spectra analysis
PublikacjaThe objective of this work was to determine electric transport in the organic device based on a planar junction of electron donor and electron acceptor materials, namely ITO/MoO3/DBP/F16ZnPc/BCP/Ag. The analysis reported herein was based on direct current-voltage measurements and small-signal admittance spectra in the dark and under illumination. Such analysis may provide information on potential barriers, parasitic resistances...
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Modification of current-voltage characteristics of planar organic systems by nm-thick interlayer
PublikacjaEffect of nm-thick interlayer of copper phthalocyanine (CuPc) or perylene dye (MePTCDI) on current-voltage characteristics of planar organic systems is discussed in the work. The MePTCDI layer strongly limits injection of holes from ITO into CuPc, while CuPc limits injection of electrons from ITO into MePTCDI. In the systems with CuPc/MePTCDI heterojunction an explicit photovoltaic effect occurs.
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Influence of the fragment size on the recycling process of thin-film modules based on CdTe
PublikacjaFor several years, the production of second generation cells (the so-called thin film), produced from amorphous silicon, cadmium telluride (CdTe) or copper indium (gallium) diselenide (CI(G)S), has been increasing. The total number of end-of-life panels by 2050 is expected to reach 9.57 million tonnes. They contain heavy metals that can be leached into the environment at the land field. The EU directive on waste electrical and...
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End-Of-Life Management of Photovoltaic Solar Modules
PublikacjaThe PV industry continues to push its credentials as a technology that addresses one of the fundamental challenges of our times – climate change. There are however two major concerns about this technology: first, the potential negative environmental impacts of energy used in the production stage and second, the possible shortage of the valuable materials in the future. The currently dominant semiconductor used in photovoltaic modules...
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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The Issue of Shading Photovoltaic Installation Caused by Dust Accumulation on the Glass Surface
PublikacjaThe issue of accumulation of dust and other pollutants on the surface of photovoltaic modules was thoroughly analysed over the years. One of the first surveys in this field of knowledge linked pollutant accumulation on the module surface with transmittance loss of its glass covering, which leads to lessened amount of solar radiation reaching solar cells. First stage of this accumulation process is linear transparency loss, and second...
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The Possibility of Phase Change Materials (PCM) Usage to Increase Efficiency of the Photovoltaic Modules
PublikacjaSolar energy is widely available, free and inexhaustible. Furthermore this source of energy is the most friendly to the environment. For direct conversion of solar energy into useful forms like of electricity and thermal energy, respectively photovoltaic cells and solar collectors are being used. Forecast indicate that the first one solution will soon have a significant part in meeting the global energy demand. Therefore it is...
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Biophotonic low-coherence sensors with boron-doped diamond thin layer
PublikacjaLow-coherence sensors using Fabry-Perot interferometers are finding new applications in biophotonic sensing, especially due to the rapid technological advances in the development of new materials. In this paper we discuss the possibility of using boron-doped nanodiamond layers to protect mirror in a Fabry-Perot interferometer. A low-coherence sensor using Fabry-Perot interferometer with a boron-doped nanodiamond (B-NCD) thin protective...
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Recovery of silver metallization from damaged silicon cells
PublikacjaMetallization is one of the key process steps to fabricate solar cells with high performance in a cost-effective way. Majority of photovoltaic solar cell manufacturing uses thick film screen print metallization with Ag containing paste to produce solar cells. The average lifetime of PV modules can be expected to be more than 25 years. The disposal of PV systems will become a problem in view of the continually increasing production...
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Low-frequency noise in Au-decorated graphene–Si Schottky barrier diode at selected ambient gases
PublikacjaWe report results of the current–voltage characteristics and low-frequency noise in Au nanoparticle (AuNP)-decorated graphene–Si Schottky barrier diodes. Measurements were conducted in ambient air with addition of either of two organic vapors, tetrahydrofuran [(CH2)4O; THF] and chloroform (CHCl3), as also during yellow light illumination (592nm), close to the measured particle plasmon polariton frequency of the Au nanoparticle...