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Impedance spectroscopy of undoped cerium oxide.
PublikacjaW pracy przedstawiono badania impedancyjne niedomieszkowanego tlenku ceru. Wyniki wskazują na występowanie zjawiska dyfuzji,???? które nie są (.. jest.?)związane z odpowiedzią elektrodową. Rozważania teoretyczne dopuszczają obserwowanie impedancji Warburga, która reprezentuje zjawisko dyfuzji w przewodnikach mieszanych, jednakże niewiele informacji na ten temat można znaleźć w literaturze. W związku z tym szczegółowe badania zródła...
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Structural studies of titanium oxide multilayers
PublikacjaW pracy przedstawiono wyniki badań cienkich warstw TiO2 przy wykorzystaniu dyfrakcji rentgenowskiej i anihilacji pozytonów. Warstwy były wytwarzane różnymi metodami. Badania pozwalają na określenie optymalnych, z punktu widzenia późniejszych zastosowań, parametrów warstw.
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Electronic and ionic relaxations in oxide glasses
PublikacjaDokonano przeglądu procesów relaksacyjnych w szkłach wykazujących elektronowy i elektronowo-jonowy charakter przewodnictwa elektrycznego. Na podstawie badań impedancyjnych przedstawiono klasyfikację szkieł o mieszanym elektronowo-jonowym przewodnictwie. Wskazano na zalety metody tarcia wewnętrznego do badań procesów relaksacyjnych w szkłach tlenkowych.
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Iron–Sulfur Cluster Biogenesis Chaperones: Evidence for Emergence of Mutational Robustness of a Highly Specific Protein–Protein Interaction
PublikacjaBiogenesis of iron–sulfur clusters (FeS) is a highly conserved process involving Hsp70 and J-protein chaperones. However, Hsp70 specialization differs among species. In most eukaryotes, including Schizosaccharomyces pombe, FeS biogenesis involves interaction between the J-protein Jac1 and the multifunctional Hsp70 Ssc1. But, in Saccharomyces cerevisiae and closely related species, Jac1 interacts with the specialized Hsp70 Ssq1,...
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Sustainable energy system combined biogas-feedSolid Oxide Fuel Cell and Microalgae technology
PublikacjaIn the new frontier of energy and environmental safety, new efficient and clean safe energy conversion systems are required. In this sense, the present work is framed within the context of Circular Economy and proposes a multidisciplinary study for the development of more efficient, economically viable and non-polluting energy conversion systems, based on the synergetic combination of different technologies: fuel cells, biofuels,...
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Porosity and shape of airborne wear microparticles generated by sliding contact between a low-metallic friction material and a cast iron
PublikacjaThe wear of brakes in transport vehicles is one of the main anthropogenic sources of airborne particulate matter in urban environments. The present study deals with the characterisation of airborne wear microparticles from a low-metallic friction material / cast iron pair used in car brakes. Particles were generated by a pin-on-disc machine in a sealed chamber at sliding velocity of 1.3 m/s and contact pressure of 1.5 MPa. They...
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Hydroxyapatite films as biocompatibile coating for artifical bone
PublikacjaW artykule została szczegółowo opisana budowa kości oraz materiał biokompatybilny hydroksyapatyt (HAp). Autorzy wykazali jak wielkie podobieństwo do budowy kości przejawia sztuczny hydroksyapatyt. opisali syntezy powłoki z HAp.
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Conducting Polymer Microelectrodes Anchored to Hydrogel Films
PublikacjaArtykuł prezentuje wytwarzanie organicznych hydrożeli z mikroelektrodami poli(3,4-ethylenedioxythiophene, PEDOT), które wykazują obniżoną rezystywność 100 Ω/□. Proces przygotowania rozpoczyna się elektroosadzania przewodzącego PEDOT (ok. 20 S/cm) na mikroelektrodach Pt. Elektrolityczne wiąże się film PEDOT z hydrożelem. Tak wytworzona struktura jest odrywana elektrycznie pd podłoża.
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Electrical and optical characterization of ITO thin films
PublikacjaW pracy przestawiono wyniki badań tlenku cyny domieszkowanego indem (ITO) pod kątem zastosowania jako przezroczyste elektrody. opisano metody pomiarów wybranych właściwości elektrycznych i optycznych. cienką warstwę ito, naniesioną na szklane podłoże, wykonano metodą rozpylania magnetronowego.
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Optical and electrical properties of Pr0.8Sr0.2MnO3 thin films.
PublikacjaPrzedstawiono preparatykę, strukturę oraz optyczne i elektryczne właściwości cienkowarstwowego Pr0.8Sr0.2MnO3. Gęste filmy o grubości 50-70nm zostały naniesione na monokrystaliczne podłoże szafirowe metodą odwirowania prekursora polimerowego. Wyniki optycznych pomiarów zostały skorelowane z temperaturą syntezy filmów. Pokazano, że optyczne spektra zmieniają kształt wraz ze zmianą struktury filmu z amorficznej do krystalicznej....
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The photoconductivity of sol-gel derived TiO2 films.
PublikacjaPrzygotowano metodą zol-żel warstwy TiO2 na podłożu kwarcowym. Zbadano ich fotoprzewodnictwo w różnych warunkach. Stwierdzono, że fotoprąd w próżni jest o trzy rzędy większy niż w powietrzu. Jako wyjaśnienie zaproponowano absorpcję tlenu na powierzchni warstwy.
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Preparation and characterization of biopolymeric films with magnetic properties
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Superconductivity in amorphous thin films of tin–copper
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Singlet exciton interactions in solid films of Alq3.
PublikacjaW pracy tej na podstawie pomiarów zależności wydajności fluorescencji od natężenia światła wzbudzjącego, wyznaczono stałą oddziaływania ekscyton singletowy - ekscyton singletowy w warstwie organicznego kompleksu aluminium Alq3.
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Emissivity of LSCO and LSFO films for bolometer applications.
PublikacjaPrzedstawiono sposób pomiaru oraz wyniki pomiarów emisyjności warstw LSCO i LSFO przeznaczonych na bolometry.
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Raman investigation of hybrid polymer thin films
PublikacjaPrzestawiono problemy diagnostyki ramanowskiej transparentnych struktur cienkowarstwowych wykonanych metodą zol-żel z polimerów hybrydowych. Analizowano możliwości badania struktury molekularnej i grubości, a także określania jakości wykonania struktur falowodowych. Przedstawiono wyniki badań wykonanych mikroskopem ramanowskim dla polimerowych struktur cienkowarstwowych osadzonych na podłożach szklanych i krzemowych.
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Effect of transglutaminase on the solubility of chitosan-gelatin films
PublikacjaCelem pracy było zmniejszenie rozpuszczalności folii chitozanowo-żelatynowych w środowisku wodnym o różnym pH, poprzez usieciowanie składników przy użyciu transglutaminazy. Niemodyfikowane enzymatycznie folie rozpuszczały się w temperaturze pokojowej w 86 i 64% odpowiednio w buforze o pH 3 i 6. Ich rozpuszczalność została ograniczona do 19-23% po usieciowaniu polimerów enzymem w stężeniu 0.2mg/ml filmotwórczego roztworu. Enzymatycznie...
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Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties
PublikacjaAlthough significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublikacjaIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Deposition and Electrical and Structural Properties of La0.6Sr0.4CoO3 Thin Films for Application in High-Temperature Electrochemical Cells
PublikacjaLow-temperature deposition of electroceramic thin films allows the construction of new devices and their integration with existing large-scale fabrication methods. Developing a suitable low-cost deposition method is important to further advance the development of microdevices. In this work, we deposited a 1-lm-thick La0.6Sr0.4CoO3d (LSC) perovskite with high electrical conductivity on sapphire substrates at 400C and analyzed its...
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CGO as a barrier layer between LSCF electrodes and YSZ electrolyte fabricated by spray pyrolysis for solid oxide fuel cells
PublikacjaPerovskite La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) is often used as a cathode material for solid oxide fuel cells (SOFC) due to high mixed ionic and electronic conductivity and good catalytic activity. Unfortunately, sintering of the LSCF cathode together with the yttria stabilized zirconia (YSZ) electrolyte, leads to formation of the La2Zr2O7 and SrZrO3 phases in the interface. These phases increase the resistance of the cell. To avoid...
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Singlet Exciton Diffusion in Vacuum-Evaporated Films of Amine-Based Materials as Studied by Photocurrent and Photoluminescence Quenching Methods
PublikacjaThe singlet exciton diffusion lengths are determined by the photoconductivity as well as the luminescence surface quenching technique, in vacuum‐evaporated layers of (4,4′,4″‐tris(N‐(3‐methylphenyl)‐N‐phenylylamino) triphenylamine) (m‐MTDATA), 4,4′,4″‐tris[2‐naphthyl(phenyl)amino] triphenylamine (2TNATA), and N,N′‐diphenyl‐N,N′‐bis(3‐methylphenyl)‐[1,1′‐biphenyl]‐4,4′‐diamine (TPD) which are frequently used for fabrication of electroluminescent...
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LaNi1-xCoxO3-δ(x=0.4 to 0.7) cathodes for solid oxide fuel cells by infiltration
PublikacjaPerformance of LaNi 1-x Co x O 3−δ (LNC) (x=0.4 to 0.7) as a cathode in solid oxide fuel cell (SOFC) is evaluated. Symmetrical cathode/electrolyte/cathode cells for electrochemical testing are prepared by infiltration of yttria stabilized zirconia (YSZ) backbone with LNC solutions. It is showed that the cathode infiltrated with LaNi 0.5 Co 0.5 O 3−δ (LNC155) has the lowest polarization resistance and activation energy, 197 mΩ cm...
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Edgewise Compressive Behavior of Composite Structural Insulated Panels with Magnesium Oxide Board Facings
PublikacjaEdgewise compression response of a composite structural insulated panel (CSIP) with magnesium oxide board facings was investigated. The discussed CSIP is a novel multifunctional sandwich panel introduced to the housing industry as a part of the wall, floor, and roof assemblies. The study aims to propose a computational tool for reliable prediction of failure modes of CSIPs subjected to concentric and eccentric axial loads. An advanced...
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Powering the Future by Iron Sulfide Type Material (FexSy) Based Electrochemical Materials for Water Splitting and Energy Storage Applications: A Review
PublikacjaWater electrolysis is among the recent alternatives for generating clean fuels (hydrogen). It is an efficient way to produce pure hydrogen at a rapid pace with no unwanted by-products. Effective and cheap water-splitting electrocatalysts with enhanced activity, specificity, and stability are currently widely studied. In this regard, noble metal-free transition metal-based catalysts are of high interest. Iron sulfide (FeS) is one...
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Structure and thermoelectric properties of Bi–Te alloys obtained by novel method of oxide substrates reduction
PublikacjaA novel method of thermoelectric materials fabrication has been developed. Oxide reagents have been melted at high temperature in air, quenched, milled to powder and reduced in hydrogen to form Bi–Te alloys. Structural and thermoelectric properties of samples have been investigated depending on initial composition and temperature of reduction process. Sample 25Bi2O3–75TeO2 reduced at 340 °C for 10 h has been found to be a p-type...
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Effect of Functionalization of Reduced Graphene Oxide Coatings with Nitrogen and Sulfur Groups on Their Anti-Corrosion Properties
PublikacjaElectrophoretic production of anticorrosion carbonaceous coatings on copper could be successfully performed by anodic oxidation of negatively charged graphene platelets suspended in an aqueous solution. The various platelets were synthesized by Hummer’s method followed by a hydrothermal reduction in the presence of NH4SCN which was expected to substitute some parts of graphene structure with nitrogen and sulfur groups. X-ray photoelectron...
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Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions
PublikacjaAg-based plasmonic nanostructures were manufactured by thermal annealing of thin metallic films. Structure and morphology were studied using scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). SEM images show that the formation of nanostructures is influenced by the initial layer thickness as well as the...
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Recent advances on spinel-based protective coatings for solid oxide cell metallic interconnects produced by electrophoretic deposition
PublikacjaThe application of ceramic protective coatings to the metallic interconnects in solid oxide cells (SOCs) is a viable and effective method to limit interconnect degradation issues. This featured letter provides a critical overview of the main outcomes of current research on the use of the electrophoretic deposition (EPD) technique to produce protective coatings for SOC metallic interconnects, specifically focusing on different approaches...
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Trimethylamine N-oxide and the reverse cholesterol transport in cardiovascular disease: a cross-sectional study
PublikacjaThe early atherosclerotic lesions develop by the accumulation of arterial foam cells derived mainly from cholesterol-loaded macrophages. Therefore, cholesterol and cholesteryl ester transfer protein (CETP) have been considered as causative in atherosclerosis. Moreover, recent studies indicate the role of trimethylamine N-oxide (TMAO) in development of cardiovascular disease (CVD). The current study aimed to investigate the association...
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Nonlinear modeling of traction transformer with coiled iron core for dynamic simulation
PublikacjaW referacie przedstawiono wyprowadzenie zastępczego modelu obwodowego transformatora trakcyjnego o rdzeniu zwijanym do analiz zachowania sie transformatora w układzie napedowym jednostki trakcyjnej. Model zakłada nieliniowa charakterystyke magnesowania B-H i anizotropowe właściwosci magnetyczne i elektryczne zwijanego rdzenia. Wyprowadzenie modelu oparto na metodzie energetycznej Lagrange'a. Uzwojenia zostały zamodelowanie jako...
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Synthesis and electrochemical characterization of poly(3,4-ethylenedioxythiophene) modified by iron hexacyanocobaltate
PublikacjaPraca dotyczy sposobu syntezy oraz elektrochemicznej charakterystyki materiału kompozytowego złożonego z poli(3,4-etylenodioksytiofenu) i heksacyjanokobaltanu(III) żelaza(II). Wybrany materiał badany był przy użyciu spektroskopii impedancyjnej, chronopotencjometrii oraz woltamperometrii cyklicznej w kontakcie z elektrolitem wodnym (KCl) oraz aprotycznym (LiPF6 w mieszaninie węglanu etylenu i węglanu propylenu). Materiał charakteryzuje...
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Cadmium, arsenic, selenium and iron– Implications for tumor progression in breast cancer
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Electrical properties and structure of lead-borate glass containing iron ions
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Iron overload and HFE gene mutations in Polish patients with liver cirrhosis
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Imprinted polymer particles for iron uptake: Synthesis, characterization and analytical applications
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Electrochemical and catalytic assessment of peripheral bromoaryl-substituted manganese and iron porphyrazines
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Determination of the Content of Promoters in Magnetite and Wustite Phases in the Fused Iron Catalyst
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Modification of carbon-coated TiO2 by iron to increase adsorptivity and photoactivity for phenol
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Phonons of (100) and (110) iron surfaces from first-principles calculations
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Iron Core Inductor High Frequency Circuit Model for EMC Application
PublikacjaW referacie przedstawiono szerokopasmowy model obwodowy dławika z rdzeniem ferromagnetycznym przydatny do analizy propagacji zaburzeń elektromagnetycznych przewodzonych w układach przekształtnikowych. Opracowany model uwzględnia zmiany właściowści dławika w zakresie wysokich cżstotliwosci na skutek występowania naskórkowości, prądów wirowych oraz efektu zbliżenia w uzwojeniach.
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Diaryl Sulfide Derivatives as Potential Iron Corrosion Inhibitors: A Computational Study
PublikacjaThe present work aimed to assess six diaryl sulfide derivatives as potential corrosion inhibitors. These derivatives were compared with dapsone (4,4′-diaminodiphenyl sulfone), a common leprosy antibiotic that has been shown to resist the corrosion of mild steel in acidic media with a corrosion efficiency exceeding 90%. Since all the studied compounds possess a common molecular backbone (diphenyl sulfide), dapsone was taken as the...
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Iron filled single-wall carbon nanotubes – A novel ferromagnetic medium
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Electronic States of Tris(bipyridine) Ruthenium(II) Complexes in Neat Solid Films Investigated by Electroabsorption Spectroscopy
PublikacjaWe present the electric field-induced absorption (electroabsorption, EA) spectra of the solid neat films of tris(bipyridine) Ru(II) complexes, which were recently functionalized in our group as photosensitizers in dye-sensitized solar cells, and we compare them with the results obtained for an archetypal [Ru(bpy)3]2+ ion (RBY). We argue that it is difficult to establish a unique set of molecular parameter values by discrete parametrization...
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Actions of a nitric oxide donor on prostaglandin production and angiogenic activity in the equine endometrium
PublikacjaNitric oxide (NO) plays an important role in prostaglandin secretion and angiogenesis in the reproductive system. In the present study, the roles of the NO donor spermine NONOate and tumour necrosis factor-alpha (TNF; as a positive control) in prostaglandin production and angiogenic activity of equine endometria during the oestrous cycle were evaluated. In addition, the correlation between NO production...
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Preparation of Hydrogen Electrodes of Solid Oxide Cells by Infiltration: Effects of the Preparation Procedure on the Resulting Microstructure
PublikacjaIn this work, the infiltration technique was used to produce hydrogen electrodes for solid oxide cells. Different infiltration methodologies were tested in order to try to shorten the infiltration cycle time. The porous scaffolds used for infiltration were based on highly porous yttria-stabilized zirconia (YSZ) obtained by etching the reduced nickel from the Ni-YSZ cermet in HNO3 acid. The support had a complex structure which...
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Fabrication of Bi6Fe2Ti3O18 Ceramics by Mixed Oxide Method
PublikacjaIn the present study Bi6Fe2Ti3O18 (BFTO) ceramics has been fabricated by solid state reaction from the mixture of simple oxides viz. Bi2O3, TiO2 and Fe2O3. Stoichiometric mixture of the powders was thermally analyzed so parameters of the thermal treatment were determined. The EDS measurements have shown conservation of the chemical composition of the ceramic powder after calcination. Hot-pressing method was used for final densification...
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9 - Solid oxide fuel and electrolysis cells
PublikacjaIn this chapter, the fundamental reactions, the geometrical designs, the material requirements, and the status of SOFCs and SOECs are presented. In the following seven chapters, the most important components of an SOC are described and the chapter ends with a summary and outlook. The described components are: (i) oxygen-ion conductors (electrolyte), (ii) anode materials for SOFCs (cathode in SOEC mode), (iii) cathode materials...
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Improved performance of LaNi0.6Fe0.4O3 solid oxide fuel cell cathode by application of a thin interface cathode functional layer
PublikacjaIn this work, novel functional layers were prepared by a low temperature spray pyrolysis method on the oxygen side of the solid oxide cells. Thin layers of Ce0.8Gd0.2O2 and LaNi0.6Fe0.4O3 are prepared between the electrolyte and the porous oxygen electrode. Additionally the influence of the sprayed ceria barrier layer on the zirconia based electrolyte with the new layers is evaluated. Impedance spectroscopy results show improvement...