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Wyniki wyszukiwania dla: COLLOID
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Colloidal aspects of protein digestion
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Recent progress in the engineering of multifunctional colloidal nanoparticles for enhanced photodynamic therapy and bioimaging
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Enhancing colloidal stability of nanodiamond via surface modification with dendritic molecules for optical sensing in physiological environments
PublikacjaPre-treatment of diamond surface in low-temperature plasma for oxygenation and in acids for carboxylation was hypothesized to promote the branching density of the hyperbranched glycidol polymer. This was expected to increase the homogeneity of the branching level and suppress interactions with proteins. As a result, composite nanodiamonds with reduced hydrodynamic diameters that are maintained in physiological environments were...
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COLLOIDS IN SEPTIC TANK EFFLUENT AND THEIR INFLUENCE ON FILTER PERMEABILITY
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Investigation of the magnetic hyperthermia effect in an aqueous dispersion of colloidosomal nanoparticle clusters
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Synthesis and characterization of colloidal gallium selenide nanowires
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Preparation of colloidal silver in W/O microemulsion
PublikacjaStabilne koloidy srebra otrzymano poprzez redukcję azotanu srebra w mikroemulsji dodekan-woda-AOT. Otrzymane zawiesiny nanocząstek srebra w dodekanie wykazywały stabilność w czasie, tj. nie zmieniały właściwości przez kilka miesięcy. Stwierdzono, że stabilność otrzymanych roztworów koloidalnych nie zależy od stężenia srebra w zakresie od 60 do 1000 mg/dm3, natomiast silnie zależy od stężenia surfaktanta. Niska toksyczność dodekanu,...
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The role of bile salts in digestion
PublikacjaBile salts (BS) are bio-surfactants present in the gastrointestinal tract (GIT) that play a crucial role in the digestion and absorption of nutrients. The importance of BS for controlled release and transport of lipid soluble nutrients and drugs has recently stimulated scientific interest in these physiological compounds. BS are so-called facial amphiphiles showing a molecular structure that is very distinct from classical surfactants....
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Rhamnolipid CMC Prediction
PublikacjaRelationships between the purity, pH, hydrophobicity (log Kow) of the carbon substrate, and the critical micelle concentration (CMC) of rhamnolipid type biosurfactants (RL) were investigated using a quantitative structure–property relationship (QSPR) approach and are presented here for the first time. Measured and literature CMC values of 97 RLs, representing biosurfactants at different stages of purification, were considered....
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Protection and viability of fruit seeds oils by nanostructured lipid carrier (NLC) nanosuspensions
PublikacjaIn this paper, we focused on the development of nanostructured lipid carriers (NLCs) for dermal application. The NLC matrix was designed as a protective reservoir of biological active compounds that naturally occur in domestic fruit seed oils. Over the years, emulsions, as a popular physicochemical form of personal care products, were refined in order to obtain the best possible penetration into the skin of any bioactive compound...
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Room temperature synthesis of water-dispersible Ln 3+ :CeF 3 (Ln = Nd, Tb) nanoparticles with different morphology as bimodal probes for fluorescence and CT imaging
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Contribution to the mechanism of liquid membrane oscillators involving cationic surfactant.
PublikacjaIt is shown that liquid membrane oscillators with cationic surfactants havemore complex oscillation patterns than observed previously. The actual details of the oscillations depend strongly on the nature of the membrane material, dislosing even the presence of parallel molecular events. It appearsthat sampling topology also has a great influence on the observed oscillato-ry behaviour. Variation of oscillation patterns with...
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Study of the selection mechanism of heavy metal (Pb 2+, Cu 2+, Ni 2+ and Cd2+) adsorption on clinoptilite
PublikacjaBadano proces adsorpcji jonów metali ciężkich (w warunkach statycznych) z wodnych roztworów jednoskładnikowych i wieloskładnikowych na klinoptylolicie zarówno surowym jak i po wstępnej obróbce. Proces sorpcji ma charakter procesu jonowymiennego i składa sie z trzech etapów:- adsorpcji na powierzchni mikokryształów,- inwersji,- adsorpcji wewnątrz mikrokryształów.Proces sorpcji może być dobrze opisany zarówno za pomocą modelu Frendlicha...
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Polymer-free cubosomes for simultaneous bioimaging and photodynamic action of photosensitizers in melanoma skin cancer cells
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Photocatalytic hydrogen evolution from glycerol-water mixture under visible light over zinc indium sulfide (ZnIn2S4) nanosheets grown on bismuth oxychloride (BiOCl) microplates
PublikacjaZnIn2S4 (ZIS) is one of the widely studied photocatalyst for photocatalytic hydrogen evolution applications due to its prominent visible light response and strong reduction ability. However, its photocatalytic glycerol reforming performance for hydrogen evolution has never been reported. Herein, the visible light driven BiOCl@ZnIn2S4 (BiOCl@ZIS) composite was synthesized by growth of ZIS nanosheets on a template-like hydrothermally...
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Morphology control through the synthesis of metal-organic frameworks
PublikacjaDesignable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual...
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Nickel-based catalysts for electrolytic decomposition of ammonia towards hydrogen production
PublikacjaNickel is an attractive metal for electrochemical applications because it is abundant, cheap, chemically resilient, and catalytically active towards many reactions. Nickel-based materials (metallic nickel, its alloys, oxides, hydroxides, and composites) have been also considered as promising electrocatalysts for ammonia oxidation. The electrolysis of ammonia aqueous solution results in evolution of gaseous hydrogen and nitrogen....
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Extraction pathways and purification strategies towards carminic acid as natural-based food colorant: A comprehensive review
PublikacjaAs a current trend of fabricating healthier products, food manufacturing companies seek for natural-based food colorant aiming to replace the synthetic ones, which apart from meeting sensorial and organoleptic aspects, they can also act as health promoters offering additional added value. Carminic acid is a natural based food colorant typically found in several insect taxa. However, there are current approaches which pursue the...
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Mangiferin: A comprehensive review on its extraction, purification and uses in food systems
PublikacjaWith the target of fabricating healthier products, food manufacturing companies look for natural-based nutraceuticals that can potentially improve the physicochemical properties of food systems while being nutritive to the consumer and providing additional health benefits (biological activities). In this regard, Mangiferin joins all these requirements as a potential nutraceutical, which is typically contained in Mangifera indica...
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Magnetic nanocomposites for biomedical applications
PublikacjaTissue engineering and regenerative medicine have solved numerous problems related to the repair and regeneration of damaged organs and tissues arising from aging, illnesses, and injuries. Nanotechnology has further aided tissue regeneration science and has provided outstanding opportunities to help disease diagnosis as well as treat damaged tissues. Based on the most recent findings, magnetic nanostructures (MNSs), in particular,...
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Nitrogen-doped porous carbon embedded with cobalt nanoparticles for excellent oxygen reduction reaction
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A facile approach to prepare porous cup-stacked carbon nanotube with high performance in adsorption of methylene blue
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Influence of dipalmitoylphosphatidylcholine (or dioleoylphosphatidylcholine) and phospholipase A2 enzyme on the properties of emulsions
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Model studies on then-alkane emulsions stability
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What affects the biocompatibility of polymers?
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Kinetics of adsorption of hydrocarbon chloro-derivatives from seven-component aqueous solution onto a thin layer of DTO-activated carbon
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Adsorption from aqueous solutions of chlorinated organic compounds onto activated carbons
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Fixed-bed adsorption of chlorinated hydrocarbons from multicomponent aqueous solution onto activated carbon: Equilibrium column model
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Desorption of chloroorganic compounds from a bed of activated carbon
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On the Anomalous Behavior of Alcohol Adsorption on Polymer-Coated Siliceous Materials
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Effects of surface nonuniformity and molecular association on mechanism of butanol adsorption from solution
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Bonding of doxorubicin to nanosilica and human serum albumin in various media
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Interfacial behavior of polar, weakly polar, and nonpolar compounds bound to activated carbons
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Equilibrium and kinetic studies on acid dye Acid Red 88 adsorption by magnetic ZnFe2O4 spinel ferrite nanoparticles
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Intumescent flame retardants inspired template-assistant synthesis of N/P dual-doped three-dimensional porous carbons for high-performance supercapacitors
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Facile synthesis N-doped hollow carbon spheres from spherical solid silica
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Waste-based nanoarchitectonics with face masks as valuable starting material for high-performance supercapacitors
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Adsorption of anionic azo-dyes from aqueous solutions onto graphene oxide: Equilibrium, kinetic and thermodynamic studies
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Removal of anionic dyes using magnetic Fe@graphite core-shell nanocomposite as an adsorbent from aqueous solutions
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Estimation–identification problem for diffusive transport in porous materials based on single reservoir test: Results for silica hydrogel
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Mechanism of nitromethane liquid membrane oscillator containing sodium oleate
PublikacjaBadano osylacyjne zachowanie oscylatora z anionowym surfaktantem na poziomie molekularnym. Zastosowano przybliżenie oparte na zasadach kinektyki chemicznej. Membranę ciekłą stanowił nitrometan z 2,2' bipirydyną. Faza wodna domowa zawierała oleinian sodu i butanol, a faza wodna akceptora chlorek sodu. Ustalono, że oscylacje zachodzą na granicy fazy akceptorowej i membrany ciekłej. Zaproponowano 3-etapowy mechanizm oscylacji i potwierdzono...
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Thermodynamics of micellization of imidazolium ionic liquids in aqueous solutions
PublikacjaPodobieństwo pomiędzy strukturami niektórych cieczy jonowych, a surfaktamtami jonowymi wskazuje na możliwość wykazywania, przez te związki, tendencji do agregacji i adsorpcji na powierzchniach międzyfazowych. Mierząc w różnych temperaturach przewodnictwo elektryczne w funkcji stężenia oznaczono temperaturę Kraffta i zależność temperaturową krytycznego stężenia micelizacji (CMC) dla czterech, różniących się długościami łańcucha,...
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Influence of the Hofmeister anions on self-organization of 1-decyl-3-methylimidazolium chloride in aqueous solutions
PublikacjaW pracy określono wpływ anionów z szeregu Hofmeistera na agregację micelarną wodnych roztworów chlorku 1-decylo-3-metyloimidazoliowego. Pod uwagę wzięto dwa czynniki - rodzaj anionu oraz siłę jonową. Wykazano, że dodatek zastosowanych soli skutkuje obniżaniem krytycznego stężenia micelizacji związku z siłą zgodną z trendem opisanym szeregiem Hofmeistera. Dodatek elektrolitu powoduje obniżenie wartości entalpii micelizacji i przejście...
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Modeling the Influence of Salts on the Critical Micelle Concentration of Ionic Surfactants
PublikacjaWe show for the first time that a phenomenological, augmented volume-based thermodynamics (aVBT) model is capable to predict the critical micelle concentrations of ionic surfactants, including ionic liquids, with added salts. The model also adjusts for the type of salt added by including its molecular volume, which might form a connection to the Hofmeister effect. The other physico-chemically relevant quantities included in the...
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Ionic liquids for nano- and microstructures preparation. Part 1: Properties and multifunctional role
PublikacjaIonic liquids (ILs) are a broad group of organic salts of varying structure and properties, used in energy conversion and storage, chemical analysis, separation processes, as well as in the preparation of particles in nano- and microscale. In material engineering, ionic liquids are applied to synthesize mainly metal nanoparticles and 3D semiconductor microparticles. They could generally serve as a structuring agent or as a reaction...
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Ionic liquids for nano- and microstructures preparation. Part 2: Application in synthesis
PublikacjaIonic liquids (ILs) are widely applied to prepare metal nanoparticles and 3D semiconductor microparticles. Generally, they serve as a structuring agent or reaction medium (solvent), however it was also demonstrated that ILs can also play a role of a co-solvent, metal precursor, reducing as well as surface modifying agent. The crucial role and possible types of interactions between ILs and growing particles have been presented in...
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Adsorption behavior and corrosion inhibitive characteristics of newly synthesized cyano-benzylidene xanthenes on copper/sodium hydroxide interface: Electrochemical, X-ray photoelectron spectroscopy and theoretical studies
PublikacjaElegant process for synthesis of 3-(7H-dibenzo[c,h]xanthen-7-yl)benzaldehyde (3), as new starting material to create a set of novel xanthene analogues, 2-(3-(7H-dibenzo[c,h]xanthen-7-yl)benzylidene)malononitrile (4), 3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylic acid (5), and Ethyl-3-(3-(7H-dibenzo[c,h]xanthen-7-yl)phenyl)-2-cyanoacrylate (6), was achieved starting with available materials under mild conditions. Various...
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Hierarchical MnO2 nanoflowers blooming on 3D nickel foam: A novel micro-macro catalyst for peroxymonosulfate activation
PublikacjaIn this work, birnessite-type δ-MnO2 nanoflowers were uniformly deposited on 3D nickel foam (NF) by one-step hydrothermal route for high-efficient activation of peroxymonosulfate (PMS) towards degradation of acid orange 7 (AO7). High specific surface area, large pore volume and 3D hierarchical structure promotes the mass and electron transfer for great catalytic activity. Low reaction energy barrier (Ea=27.5 kJ/mol) and outstanding...
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How thermal stability of ionic liquids leads to more efficient TiO2-based nanophotocatalysts: Theoretical and experimental studies
PublikacjaIonic liquids (ILs) containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, imidazolium, ammonium, morpholinium) were first used for the preparation of 23 IL-TiO2 types of composites by ionic liquid assisted solvothermal synthesis. These 23 optimal ILs structures (i.e. compounds exhibiting an optimal combination of specific properties, functionality, and safety) for synthesis and experimental validation...
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Bile salts in digestion and transport of lipids
PublikacjaBecause of their unusual chemical structure, bile salts (BS) play a fundamental role in intestinal lipid digestion and transport. BS have a planar arrangement of hydrophobic and hydrophilic moieties, which enables the BS molecules to form peculiar self-assembled structures in aqueous solutions. This molecular arrangement also has an influence on specific interactions of BS with lipid molecules and other compounds of ingested food...