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Metal–Organic Frameworks (MOFs) for Cancer Therapy
PublikacjaMOFs exhibit inherent extraordinary features for diverse applications ranging from catalysis, storage, and optics to chemosensory and biomedical science and technology. Several procedures including solvothermal, hydrothermal, mechanochemical, electrochemical, and ultrasound techniques have been used to synthesize MOFs with tailored features. A continued attempt has also been directed towards functionalizing MOFs via “post-synthetic...
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Non-Linear Analysis of Structures Utilizing Load-Discretization of Stiffness Matrix Method with Coordinate Update
PublikacjaThis paper proposes a stiffness method based structural analysis algorithm for geometrically non-linear structures. In this study, the applied load on the joints has been discretized to a sequence of a few loadings applied. Each loading step produces incremental external nodal displacements, which are added to the corresponding coordinates to get a new geometrical shape of the structure. This process is iteratively repeated until...
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Grid-Forming Operation of Energy-Router Based on Model Predictive Control with Improved Dynamic Performance
PublikacjaThe focus of this study is on the grid-forming operation of the Energy Router (ER) based on Model Predictive Control (MPC). ER is regarded as a key component of microgrids. It is a converter that interfaces the microgrid (s) with the utility grid. The ER has a multiport structure and bidirectional energy flow control. The ER concept can be implemented in Nearly Zero-Energy Buildings (NZEB) to provide flexible energy control. A...
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Wear Resistance Enhancement of Al6061 Alloy Surface Layer by Laser Dispersed Carbide Powders
PublikacjaIn this paper, results of the experimental study on improving wear resistance in sliding friction of Al-based alloy are presented. The technique used involves the formation of a metal matrix composite (MMC) in the alloy surface layer by laser dispersion of carbide powders such as WC, TiC and SiC. For WC and TiC MMC surface coatings fabricated under conditions typical for most of the technologically relevant solid-state lasers (wavelength...
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Experimental and DFT insights into an eco-friendly photocatalytic system toward environmental remediation and hydrogen generation based on AgInS2 quantum dots embedded on Bi2WO6
PublikacjaBismuth tungstate (Bi2WO6) can work as a photocatalyst but suffers from rapid recombination of photogenerated charge carriers. Herein, density functional theory (DFT) simulations revealed that the formation of a thermodynamically stable AgInS2(112)/Bi2WO6(010) heterojunction could promote charge separation and enhance the photoactivity of Bi2WO6. To confirm these theoretical predictions, a new type of photocatalysts in the form...
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Recycling of Waste Rubber by the Manufacturing of Foamed Polyurethane-Based Composites—Current State and Perspectives
PublikacjaWorn car tires are disruptive waste, and the issue of their management is crucial for the natural environment. In many countries, the primary method of end-of-life tires utilization is energy recovery. However, more effective and beneficial for the environment is material recycling. Using them for the production of polymer-rubber composites seems to be an auspicious direction of research. Incorporation of ground tire rubber into...
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Analysis
PublikacjaNew food products and diverse formulations containing the regulated steviol glycoside(s) as well as Stevia extracts or Stevia leaves have been brought on the global market. The upcoming multitude of such food products, but also their falsification and adulteration, does have impact on food analysis. Robust high-throughput methods that cope with different food matrices are required for food control to ensure food safety. The analysis...
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Determination of phenol biodegradation pathways in three psychrotolerant yeasts, Candida subhashii A011, Candida oregonensis B021 and Schizoblastosporion starkeyi-henricii L012, isolated from Rucianka peatland
PublikacjaIn this study, three psychrotolerant phenol-degrading yeast strains Candida subhashii (strain A011), Candida oregonenis (strain B021) and Schizoblastosporion starkeyi-henricii (strain L012) isolated from Rucianka peatland were examined to determine which alternative metabolic pathway for phenol biodegradation is used by these microorganisms. All yeast strains were cultivated in minimal salt medium supplemented with phenol at 500,...
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Extracellular proteolytic activity of Deinococcus geothermalis
PublikacjaProduction of extracellular protease by extremophilic bacteria Deinococcus geothermalis cultivated in liquid media containing 0.1% (w/v) of peptone K, 0.1% yeast extract and 0.2% marine salt reached a maximum in 14 h of the cell growth at 45°C and pH 8.0. The enzyme was purified by a two-step procedure using fractionation by a graded ammonium sulphate precipitation technique and gel filtration on Sephadex G-100 column. Protease...
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Electromodulation of monomer and excimer phosphorescence in vacuum-evaporated films of platinum (II) complexes of 1,3-di(2-pyridyl)benzenes
PublikacjaElectric field-modulated photoluminescence (EML) measurements are presented for vacuum-evaporated films of cyclometallated Pt (II) complexes of 1,3-di(2-pyridyl) benzenes used as triplet emitters in organic light-emitting diodes (OLEDs). The excimer phosphorescence is quenched by the external electric field of 2.5 MV/cm up to 25% but the same effect on monomer phosphorescence is one order of magnitude smaller. The higher quenching...
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Analytical procedures for the determination of fuel combustion products, anti-corrosive compounds, and de-icing compounds in airport runoff water samples
PublikacjaThe purpose of this study is to propose and evaluate new procedures for determination of fuel combustion products, anti-corrosive and de-icing compounds in runoff water samples collected from the airports located in different regions and characterized by different levels of the activity expressed by the number of flights and the number of passengers (per year). The most difficult step in the analytical procedure used for the determination...
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Development of a compact microstrip resonant cell aimed at efficient microwave component size reduction
PublikacjaA comprehensive comparison of a wide collection of compact microstrip resonant cells (CMRCs) found in the extensive body of literature has been presented. The evaluation of different CMRC designs has led to the selection of the most promising CMRC geometry for the efficient miniaturisation of modern microwave components. In order to showcase the vital effectiveness of the approach, the initially selected CMRC has been notably...
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Analytical procedures for the determination of surfactants in environmental samples
PublikacjaBecause of their specific physical and chemical properties (amphiphilicity, solubility in polar and nonpolar liquids, ability to form micelles, adsorption at phase boundaries, low toxicity) surfactants (surface-active compounds) are widely applied in industry and in the household. As their applications are on a very large scale, it has become necessary to acquire a more detailed understanding of their environmental fate.In the...
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Functionalization of Parylene During Its Chemical Vapor Deposition
PublikacjaTwo possible mechanisms for the reaction of four halogenated (metha)acrylate-based molecules with Parylene [poly (paraxylylene)] during its chemical vapor deposition were proposed. The chemical reactivity of acrylate double bond with the paraxylylene biradical was calculated for all four (metha)acrylate-based molecules. These calculations allowed the evaluation of the energetically favorable mechanism and indeed a direct correlation...
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Methods of data extraction from sub-bottom profiler's signal
PublikacjaData obtain during sounding Gdansk Bay with SES-2000 Standard parametric sub-bottom profiler has two types of information: envelope and pure signal. First is used to plot echograms in real time and contain envelope of echo. The second one is stored during sounding and can be processed after recording data. Comparison of results will be shown and discussed. First step in investigation was proper configuration of small measurement...
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Nitrogen mass balance and mathematical model of a Structured- Bed Reactor (SBRRIA)
PublikacjaAn up-flow structured-bed reactor subjected to recirculation and intermittent aeration (SBRRIA) was operated under varying influent conditions. The influent COD/N ratio was adjusted by maintaining a stable organic loading rate (average of 1.07 kgCOD m-3 d-1) and changing the nitrogen loading rate from 0.1 to 0.4 kg N m-3. Therefore, three different COD/N ratios were tested: 9.7±1 (Scenario 1); 7.6±1 (Scenario 2) and 2.9±1 (Scenario...
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Applying ground penetrating radar to tracking of ancient architectural transformations: the case of the monastery St. Peter on the Island of Rab (Croatia)
PublikacjaThe ground-penetrating radar (GPR) method has been used for many years in archaeological research. However, thismethod is still not widely used in studies of past architecture. The biggest problem with the implementation of the GPRmethod at such sites is usually connected with extensive debris layers, plant cover and standing relics of walls and otherfeatures that restrict the available measurement area. Despite of these, properly...
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Operation of multistage constructed wetlands systems in temporary climate
PublikacjaThe investigation were carried out at two different hybrid constructed wetlands, which treated municipal sewage after mechanical treatment from small villages in Pomeranian Region. In all facilities first step of biological treatment were horizontal flow beds. The main difference concern configuration of the facilities and sewage distributions systems into vertical flow beds. The measurement period was divided into vegetation...
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Exposure scenario and risk assessment of infants and newborns to bisphenols and their derivatives from diapers
PublikacjaNewborns and infants are more sensitive to harmful compounds such as bisphenols and their derivatives because of their not fully developed detoxification mechanism. Exposure to these substances can lead to developmental problems and health consequences in adulthood. Since disposable baby diapers are used from the first days of life and remain in contact with the baby skin, it seems important to monitor the levels of endocrine disrupting chemicals...
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Pre-analytical aspects in metabolomics of human biofluids – sample collection, handling, transport, and storage
PublikacjaMetabolomics is the field of omics research that offers valuable insights into the complex composition of biological samples. It has found wide application in clinical diagnostics, disease investigation, therapy prediction, monitoring of treatment efficiency, drug discovery, or in-depth analysis of sample composition. A suitable study design constitutes the fundamental requirements to ensure robust and reliable results from the...
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Degradable poly(ester-ether) urethanes of improved surface calcium deposition developed as novel biomaterials
PublikacjaBones, which are considered as hard tissues, work as scaffold for human body. They provide physical support for muscles and protect intestinal organs. Percentage of hard tissues in human body depends on age, weight, and gender. Human skeleton consists of 206 connected bones. Therefore, it is natural that the hard-tissue damage such as fractures, osteoporosis, and congenital lack of bone may appear. The innovative way of bone healing...
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Technology Concept of TLP Platform Towing and Installation in Waters with Depth of 60 m
PublikacjaThe article is part of the design and research work conducted at the Gdansk University of Technology, Faculty of Ocean Engineering and Ship Technology, in cooperation with a number of other research centres, which concerns offshore wind farms planned to be built in the Polish zone of the Baltic sea in the next years. One of most difficult tasks in this project is building suitable foundations for each power unit consisting of a...
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Investigation of stability and limit load of a truss overhead opened bridge
PublikacjaThe paper presents selected methods of determining stability and limit load of a truss top chord in opened bridges. These methods include linear buckling and non-linear static analysis based on the finite element method and algorithms based on design code procedures. The described methods were tested on an example of a steel footbridge situated in Straszyn. The results of stability analysis are compared. The results of geometrical...
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Pure cross-anisotropy for geotechnical elastic potentials
PublikacjaThe pure cross-anisotropy is understood as a special scaling of strain (or stress). The scaled tensor is used as an argument in the elastic stiffness (or compliance). Such anisotropy can be overlaid on the top of any elastic stiffness, in particular on one obtained from an elastic potential with its own stress-induced anisotropy. This superposition does not violate the Second Law. The method can be also applied to other functions...
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Structural and electrochemical heterogeneities of boron-doped diamond surfaces
PublikacjaThis brief review is focussed on the recent progress in studies of the heterogeneous electrochemical behaviour of various boron-doped materials extending from zero-dimensional particles through polycrystalline or nanostructured three-dimensional surfaces. A boron-doped diamond reveals large heterogeneities induced by numerous factors, inter alia multi-faceted crystallinity, inhomogeneous boron concentration, sp2/sp3-carbon ratio,...
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Recovering Evaluation of Narrow-Kerf Teeth of Mini Sash Gang Saws
PublikacjaSash gang saws with narrow-kerf saw blades are used in the production of glued laminate flooring elements in plants where dry technology is applied. This means that boards or friezes are sawn into top layer lamellae in dry conditions (moisture content of about 10–12%) from expensive wood species, often exotic. The object of this research was stellite-tipped teeth of narrow kerf saw blades sharpened under industrial conditions....
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Novel Cold Crucible Ultrasonic Atomization Powder Production Method for 3D Printing
Publikacja: A new powder production method has been developed to speed up the search for novel alloys for additive manufacturing. The technique involves an ultrasonically agitated cold crucible installed at the top of a 20 kHz ultrasonic sonotrode. The material is melted with an electric arc and undergoes pulverization with standing wave vibrations. Several different alloys in various forms, including noble and metallic glass alloys, were...
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Towards Healthcare Cloud Computing
PublikacjaIn this paper we present construction of a software platform for supporting medical research teams, in the area of impedance cardiography, called IPMed. Using the platform, research tasks will be performed by the teams through computer-supported cooperative work. The platform enables secure medical data storing, access to the data for research group members, cooperative analysis of medical data and provide analysis supporting tools...
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Microfluidic SIW-Based Tunable Self-Diplexing Antenna for Sub-6 GHz Band Applications
PublikacjaThis work introduces a novel frequency tunable self-diplexing antenna (SDA) design based on substrate integrated waveguide (SIW) technology. A modified A-shaped slot is employed on the cavity’s top plane, which is excited by two independent 50 Ω microstrip feed lines to operate at each resonant frequency. The frequency flexibility of the proposed antenna allows for fine-tuning at each resonance frequency. The frequency flexibility...
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Shielded HMSIW-Based Self-Triplexing Antenna With High Isolation for WiFi/WLAN/ISM Band
PublikacjaThis article presents a novel design of a miniaturized self-triplexing antenna (STA) based on the shielded half-mode substrate integrated waveguide (S-HMSIW) for WiFi/WLAN/ISM-band applications. The S-HMSIW is constructed by assembling one row of vias and an open slot at the open-ended side of the conventional HMSIW. This configuration increases the quality factor and minimizes unwanted radiation loss, which allows for achieving...
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MODELOWANIE TURBINY WIATROWEJ Z DWOMA PRZECIWBIEŻNIE OBRACAJĄCYMI SIĘ WIRNIKAMI
PublikacjaW artykule przedstawiono sposoby modelowania dwuwirnikowej turbiny wiatrowej z wykorzystaniem technik Obliczeniowej Mechaniki Płynów. Omówiono uproszczone metody modelowania Actuator Disc i Actuator Line Method oraz aspekty związane z dokładnym odwzorowaniem turbiny na siatce obliczeniowej. Zaprezentowano przykładowe wyniki obliczeń turbiny dwuwirnikowej złożonej z wirników NREL o mocy nominalnej 5 MW każdy. Do wykonania badań...
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Globalne trendy w certyfikacji systemu zarządzania środowiskowego
PublikacjaMinimalizacja wpływu działalności organizacji na środowisko naturalne jest jednym z najważniejszych założeń strategicznych przedsiębiorstw. Działania te wynikają z wdrażania strategii CSR, która w odniesieniu do polityki środowiskowej w organizacjach realizowana jest poprzez system EMAS bądź wymagania normy ISO 14001. Wdrożenie Systemu Zarządzania Środowiskowego, a następnie poddanie systemu certyfikacji przez niezależną jednostkę...
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ASSESSMENT OF GOLD AND/OR CRUDE OIL AS INVESTMENTS FOR PORTFOLIO DIVERSIFICATION. A WARSAW STOCK EXCHANGE CASE STUDY
PublikacjaThe purpose of the study is to assess whether the inclusion of investments in gold and/or crude oil improves an investment portfolio consisting of shares of enterprises included in the WIG20 index (traditional invest-ments). All possible combinations of investment portfolios with minimal risk and maximum efficiency were tested. The portfolios were determined based on Markowitz’s portfolio theory. All results were compared...
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Threats to Armenia’s Security in the National Strategy and Practice with Special Emphasis on External Security,
PublikacjaThe national security strategy adopted in 2007 provided a detailed definition of security and identified its threats. The key threat to the Armenian state was considered to be the Nagorno-Karabakh conflict. The document indicated the Collective Security Treaty Organisation main guarantor of security, with Russia being Armenia’s main partner in bilateral relations. The second position in the strategy was assigned to cooperation...
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Process layout planning and optimised product range selection in manufacture of wooden construction sets
PublikacjaThis paper introduces a systematic deterministic framework for planning and the analysis of facility layouts aimed at manufacturing a variety of parts, as components of specific end products. The essence of the proposed approach lies in the decomposition of a traditional job-shop into layout modules of generic material flow patterns, that inherently yields improved efficiency of the entire system. It entails the use of a relevant...
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Objectivization of phonological evaluation of speech elements by means of audio parametrization
PublikacjaThis study addresses two issues related to both machine- and subjective-based speech evaluation by investigating five phonological phenomena related to allophone production. Its aim is to use objective parametrization and phonological classification of the recorded allophones. These allophones were selected as specifically difficult for Polish speakers of English: aspiration, final obstruent devoicing, dark lateral /l/, velar nasal...
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Growth and Isolation of Large Area Boron‐Doped Nanocrystalline Diamond Sheets: A Route toward Diamond‐on‐Graphene Heterojunction
PublikacjaMany material device applications would benefit from thin diamond coatings, but current growth techniques, such as chemical vapor deposition (CVD) or atomic layer deposition require high substrate and gas‐phase temperatures that would destroy the device being coated. The development of freestanding, thin boron‐doped diamond nanosheets grown on tantalum foil substrates via microwave plasma‐assisted CVD is reported. These diamond...
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Hydrogen Production from Energy Poplar Preceded by MEA Pre-Treatment and Enzymatic Hydrolysis
PublikacjaThe need to pre-treat lignocellulosic biomass prior to dark fermentation results primarily from the composition of lignocellulose because lignin hinders the processing of hard wood towards useful products. Hence, in this work a two-step approach for the pre-treatment of energy poplar, including alkaline pre-treatment and enzymatic saccharification followed by fermentation has been studied. Monoethanolamine (MEA) was used as the...
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Thermoplastic polyurethanes with glycolysate intermediates from polyurethane waste recycling
PublikacjaThe polyol is a major component in polyurethane formulations and therefore introducing to the formulation recycled polyol (obtained during decomposition process) allows decreasing the usage of pure petrochemical components. In this work, thermoplastic polyurethanes were prepared using various mixtures of a petrochemical macrodiol poly(ethylene-butylene adipate)diol (PEBA) and a recycled glycolysate intermediate, called glycolysate...
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Nanoporous TiO2 electrode grown by laser ablation of titanium in air at atmospheric pressure and room temperature
PublikacjaRecently, fabrication of the nanoporous TiO2 photoelectrode on metal foils by means of sputtering of the Ti film on preheatedmetal substrate followed by the TiO2 deposition (doctor blade technique) and sintering represents the frequently applied technique. This is despite the relatively complicated procedure and number of parameters to be controlled in order to fabricate films of required properties. In this work an approach is...
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Sano-Tachiya-Noolandi-Hong, Onsager and Braun models vs Monte Carlo simulation of charge photogeneration in organic solids
PublikacjaThe Sano-Tachiya-Noolandi-Hong (STNH), Onsager, and Braun models as well as Monte Carlo (MC) simulations of charge recombination/separation have been applied for the first time to reproduce the results of the electromodulated photoluminescence measurements in vacuum-evaporated films of fluorescent materials commonly used in optoelectronic devices. The values of the electron-hole pair final recombination speed in the monomer emitters:...
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Effective method for determining environmental loads on supporting structures for offshore wind turbines
PublikacjaThis paper presents a description of an effective method for determining loads due to waves and current acting on the supporting structures of the offshore wind turbines. This method is dedicated to the structures consisting of the cylindrical or conical elements as well as (truncates) pyramids of polygon with a large number of sides (8 or more). The presented computational method is based on the Morison equation, which was originally...
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Proposition of the methodology for Data Acquisition, Analysis and Visualization in support of Industry 4.0
PublikacjaIndustry 4.0 offers a comprehensive, interlinked, and holistic approach to manufacturing. It connects physical with digital and allows for better collaboration and access across departments, partners, vendors, product, and people. Consequently, it involves complex designing of highly specialized state of the art technologies. Thus, companies face formidable challenges in the adoption of these new technologies....
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Electrochemical determination of nitroaromatic explosives at boron-doped diamond/graphene nanowall electrodes: 2,4,6-trinitrotoluene and 2,4,6-trinitroanisole in liquid effluents
PublikacjaThe study is devoted to the electrochemical detection of trace explosives on boron-doped diamond/graphene nanowall electrodes (B:DGNW). The electrodes were fabricated in a one-step growth process using chemical vapour deposition without any additional modifications. The electrochemical investigations were focused on the determination of the important nitroaromatic explosive compounds, 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitroanisole...
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Liquefaction of alder wood as the source of renewable and sustainable polyols for preparation of polyurethane resins
PublikacjaLiquefaction of wood-based biomass gives different polyol properties depending on the reagents used. In this article, alder wood sawdust was liquefied with glycerol and poly(ethylene glycol) solvents. Liquefaction reactions were carried out at temperatures of 120, 150 and 170 °C. The obtained bio-polyols were analyzed in order to establish the process efficiency, hydroxyl number, acid value, viscosity and structural characteristics...
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Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis
PublikacjaIn this study, the glycerolysis of polyurethane (PU) foam and the applicability of obtained glycerolysate (GLY) for cast PUs were investigated. It was found that crude glycerine with purity grade of 84% might be successfully used for the glycerolysis. The optimal conditions were determined as follows: reaction time of 60 min at 220 °C using dibutyltin dilaurate catalyst (0.5%). Moreover, the purification of GLY by means of liquid-liquid...
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Modular Approach for Modelling Warming Up Process in Water Installations with Flow-Regulating Elements
PublikacjaThe paper presents a new method for modelling the warming up process of a water system with elements regulating the flow in a stochastic manner. The paper presents the basic equations describing the work of typical elements which the water installation is composed of. In the proposed method, a new computational algorithm was used in the form of an iterative procedure enabling the use of boundary conditions that can be stochastically...
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Green TPUs from Prepolymer Mixtures Designed by Controlling the Chemical Structure of Flexible Segments
PublikacjaThis study concerns green thermoplastic polyurethanes (TPU) obtained by controlling the chemical structure of flexible segments. Two types of bio-based polyether polyols—poly(trimethylene glycol)s—with average molecular weights ca. 1000 and 2700 Da were used (PO3G1000 and PO3G2700, respectively). TPUs were prepared via a two-step method. Hard segments consisted of 4,4?- diphenylmethane diisocyanates and the bio-based 1,4-butanodiol...
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Borrelia burgdorferi BmpA-BBK32 and BmpA-BBA64: New Recombinant Chimeric Proteins with Potential Diagnostic Value
PublikacjaCurrently, the diagnosis of Lyme disease is based mostly on two-tiered serologic testing. In the new generation of immunoenzymatic assays, antigens comprise whole-cell lysates of members of the Borrelia burgdorferi sensu lato (s.l.) species complex, with the addition of selected recombinant proteins. Due to the high diversity of members of the B. burgdorferi s.l. genospecies and the low degree of conservation among the amino acid...
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Influence of addition of carbon nanotubes on rheological properties of selected liquid lubricants - a computer simulation study
PublikacjaThis work is motivated by the improvement of anti-friction properties of lubricants by addition of CNTs proved experimentally in literature. In particular, a methodology is developed to compute the shear viscosity of liquid lubricants (Propylene Glycol) based on Molecular Dynamics simulation. Non-Equilibrium molecular dynamics (NEMD) approach is used with a reactive force field ReaxFF implemented in LAMMPS. The simulations are...