Wyniki wyszukiwania dla: microbiologically influenced corrosion
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Corrosion of titanium biomaterials, mechanisms, effects and modelisation
PublikacjaBadania in vivo oraz in vitro wskazują na bardzo małą szybkość korozji biostopów tytanu.Najczęstsza przycyną jest korozja ogólna i lokalna oraz korozja frettingowa. Trzy możliwe mechanizmy to: rozpuszczanie warstwy tlenku tytanu, dyfuzja pierwiastków przez warstwę tlenkową oraz reakcje elektrochemiczna w środowisku korozyjnym odsłoniętego metalu. Procesy korozyjne prowadzą do obluzowania implantów i poważnych schorzeń. Standardowe...
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Imaging of the effects of pitting corrosion with the use of AFM
Dane BadawczePitting corrosion is a local attack on a metal surface, limited to a point or small area, which appears as a hole. Pitting corrosion is one of the most harmful forms of corrosion due to the fact that it is associated with small, difficult to detect damage, that can even lead to perforation of the structure. A single pit may range in size from micrometers...
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Corrosion degradation of spacers – examination of changes in bone cement coating.
PublikacjaSpacer is a special implant used at the time of infection after endoprosthetic surgery. It consists of a metal core and bone cement coating with an antibiotic. In the human body spacers are exposed to degradation processes. This paper looks at the effect of corrosion on spacers. Electrochemical corrosion tests were performer on titanium pins with bone cement coating in two solutions: Ringer’s solution and artificial...
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Applying of Doped Graphene Oxide Coatings for Corrosion Prevention
PublikacjaINTRODUCTION Graphene is a carbonaceous material characterized by extraordinary properties (high electron mobility, high surface area, high mechanical strength of 1100 GPa, very dense network hindering the passage of even the smallest helium atoms) [1]. Therefore, it found many applications, also as an anti-corrosive layer [2]. Electrophoretic Deposition (EPD) is one of the methods to deposit coatings. However, due to slight solubility...
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SEM micrographs of Ti tooth implant corrosion
Dane BadawczeThe dataset contains micrographs made with a scanning electron microscope (SEM) Hitachi S-3400N of the tooth implant removed after inflammation. The inflammation was induced by the increased corrosion rate of the titanium screw. The reason for the corrosion to occur was the appearance of the concentration cell of different aeration for various areas...
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Jacek Ryl dr hab. inż.
OsobyStopień doktora nauk technicznych uzyskał w roku 2010. W tym samym roku podjął pracę w Katedrze Elektrochemii, Korozji i Inżynierii Materiałowej na Wydziale Chemicznym. W 2018 roku uzyskał stopień doktora habilitowanego nauk technicznych w dyscyplinie technologia chemiczna. Od 2021 roku zatrudniony w Instytucie Nanotechnologii i Inżynierii Materiałowej Wydziału Fizyki Technicznej i Matematyki Stosowanej PG. W pracy naukowej skupia...
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RAMAN-SCATTERING IN HEXAGONAL ICE INFLUENCED BY SYMMETRY OF CRYSTAL-LATTICE
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Nondestructive global corrosion measurement using guided wavefield data
PublikacjaMetallic structures often face degradation, and corrosion ranks among the most prevalent forms of deterioration. Accurate quantification of corrosion is crucial, especially for structures exposed to harsh environmental conditions, such as marine vessels and offshore installations. Because the traditional measurement methods based on scanning by ultrasonic gauge are time-consuming and provide only rough information on the thickness...
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Corrosion and Materials
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Corrosion and Protection
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Corrosion Communications
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MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
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Sodium nitrite as a corrosion inhibitor of copper in simulated cooling water
PublikacjaThe corrosion inhibition behavior of sodium nitrite (NaNO2) towards pure copper (99.95%) in simulated cooling water (SCW) was investigated by means of electrochemical impedance spectroscopy (EIS) and dynamic electrochemical impedance spectroscopy (DEIS). NaNO2 interferes with metal dissolution and reduce the corrosion rate through the formation or maintenance of inhibitive film on the metal surface. Surface morphologies illustrated...
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Assessment of copper surface coverage with corrosion inhibitor using AFM-based local electrical measurements
PublikacjaThe paper presents a new method of assessment of metal surface coverage with corrosion inhibitor and thus of inhibitor protective performance. It is based on the atomic force microscopy measurement performed in a contact mode. Apart from topography images the proposed approach allows acquisition of local DC maps and local electrical impedance spectra via application of DC bias voltage or AC perturbation signal between the conductive...
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Electrical mapping of AISI 304 stainless steel subjected to intergranular corrosion performed by means of AFM-LIS in the contact mode
PublikacjaThe paper presents results of the AFM-based approach to local impedance spectroscopy (LIS) measurements performed in a 20 20 lm grid within an austenite grain–grain boundary region for sensitized AISI 304 stainless steel (SS). Maps of electrical parameters obtained on the basis of localized impedance spectra were demonstrated, presenting their changes and correlation with the sample topography. Performed research revealed significant...
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CORROSION TESTING OF SAMPLES ACCORDING TO ASTM G36
PublikacjaAt the end of the study, samples were found to have structures characteristic for intercrystalline corrosion. This indicates that the samples provided (fragments of the whole) were sensitized before starting the study in boiling MgCl2.On cross sections, fine cracks are observed on all samples tested.
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Corrosion process monitoring by AFM higher harmonic imaging
PublikacjaThe atomic force microscope (AFM) was invented in 1986 as an alternative to the scanning tunnelling microscope, which cannot be used in studies of non-conductive materials. Today the AFM is a powerful, versatile and fundamental tool for visualizing and studying the morphology of material surfaces. Moreover, additional information for some materials can be recovered by analysing the AFM's higher cantilever modes when the cantilever...
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Experimental and numerical identification of corrosion degradation of ageing structural components
PublikacjaThe study presents experimental and numerical identification of corrosion degradation of thin-walled structural components employing guided wave propagation. The steel structural components are subjected to through-thickness varying corrosion degradation levels. The developed approach using the non-destructive guided wave-propagation quantifies the equivalent average corrosion degradation level by exploring a limited number of...
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Determination of pitting corrosion stage of stainless steel by galvanodynamic impedance spectroscopy
PublikacjaThis paper investigates the methodology for differentiation of multistep process of pitting corrosion of AISI 304 stainless steel in the environment of iron (III) chloride. Measurements were performed using Galvanodynamic Electrochemical Impedance Spectroscopy (GDEIS). Application of this methodology allowed monitoring of natural corrosion process without external current (IDC = 0A) nor potential perturbation of the system. Applied...
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Novel fast non-linear electrochemical impedance method for corrosion investigations
PublikacjaThe paper presents a novel approach to corrosion rate monitoring using non-linear electrochemical impedance spectroscopy. The authors propose a new variant of non-linear impedance measurement using amplitude-modulated multi-frequency ac perturbation signal. It allows shortening of measurement duration so it is possible to monitor corrosion rate of the systems experiencing rapid changes. In this way a limitation resulting from lack...
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PROBLEMS WITH CORROSION PROTECTION STEEL STACKS IN FGD SYSTEMS
PublikacjaThis paper presents problems associated with corrosion of steel stacks and changes in philosophy of corrosion protection when implemented into flue gas desulphurization systems. In-situ tests were taken by means of electrochemical impedance spectroscopy at a stack which discharges flue gas before wet lime/limestone desulphurization. A very rapid soaking of spherical infill vinylester coating with electrolyte has been observed....
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Sulfate‐reducing bacteria‐assisted hydrogen‐induced stress cracking of 2205 duplex stainless steels
PublikacjaThe paper presents the results of a laboratory investigation of the microbiologically assisted hydrogen‐induced stress cracking (HISC) of 2,205 duplex stainless steel (DSS). The testing of susceptibility toward HISC was performed with two different methods. Precharged in sulfate‐reducing bacteria (SRB), inoculated medium samples were subjected to slow strain‐rate testing in artificial seawater. In situ constant load tests were...
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Formation of High Corrosion Resistant Nanotubular Layers on TitaniumAlloy Ti13Nb13Zr
PublikacjaThis paper presents results of oxidation tests and corrosion investigations of titanium alloy Ti13Nb13Zr performed at different conditions. The oxide layers have been formed by electrochemical method in 2M H3PO4 + 0.3% HF solution for 30 min. and 1 h at 20 V constantvoltage. The corrosion tests have been made by potentiodynamic method in Ringer`s solution at pH ranged between 3 and 7. It has been shown that the nano-oxide films,...
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Formation of High Corrosion Resistant Nanotubular Layers on TitaniumAlloy Ti13Nb13Zr
PublikacjaThis paper presents results of oxidation tests and corrosion investigations of titanium alloy Ti13Nb13Zr performed at different conditions. The oxide layers have been formed by electrochemical method in 2M H3PO4 + 0.3% HF solution for 30 min. and 1 h at 20 V constantvoltage. The corrosion tests have been made by potentiodynamic method in Ringer`s solution at pH ranged between 3 and 7. It has been shown that the nano-oxide films,...
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High temperature corrosion evaluation and lifetime prediction of porous Fe22Cr stainless steel in air in temperature range 700–900 °C
PublikacjaThis work describes a high temperature corrosion kinetics study of ~30% porous Fe22Cr alloys. The surface area of the alloy (~0.02 m2 g-1) has been determined by tomographic microscopy. The weight gain of the alloys was studied by isothermal thermogravimetry in the air for 100 hours at 700 - 900 °C. Breakaway oxidation was observed after oxidation at 850 °C (~100 hours) and 900 °C (~30 hours). The lifetime prediction shows the...
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WASTE INCINERATORS: CORROSION PROBLEMS AND CONSTRUCTION MATERIALS - A REVIEW
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Case Study of Stray Current Corrosion of Tall Ship Mast
PublikacjaNowadays, in the present technical civilization there are numerous complex technical systems that may generate various hazards. Large transport units like ships can be considered as the most dangerous systems. Therefore, it is important to eliminate all possible hazards, especially for ship crewmembers. Destruction of ship structural components caused by vast corrosion is one of these hazards. Usually, its activity leads to a decrease...
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High temperature corrosion of evaporator tubes with thermal sprayed coatings
PublikacjaDegradation examinations of outer surface of low-emission steam boiler evaporator tubes are presented in the paper. Metallographic evaluation of scale morphology, its micro sites chemical composition analysis and distribution of elements on cross sections have been performed. Water-wall tubes were exposed in steam boiler for up to two years period. Common tubes made of 16Mo3 steel suffered sulphide and molten salts corrosions....
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Determination of Local Corrosion Current from Individual Harmonic Components
PublikacjaHarmonic analysis has been used in corrosion measurements for several decades. During this period the method has been refined and developed. Nevertheless, the technique has not been applied to properties determination in local scale yet. This paper is focused on local corrosion current measurements based on harmonic analysis. For this purpose, a non-linear nature of electrode processes is used and measured in local scale applying...
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Experimental ultimate strength assessment of stiffened plates subjected to marine immersed corrosion
PublikacjaThis study experimentally analyses the impact of marine immersed corrosion degradation on the compressive strength of the stiffened plates where the lower degradation levels were considered. The corrosion degradation test was accelerated by controlling the natural corrosion environmental factors, avoiding applying an electric current. Different groups of corrosion degradation levels and initial plate thicknesses were investigated....
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An improved methodology for accelerated marine immersed corrosion testing of ship structural components
PublikacjaCorrosion degradation is a prominent ageing mechanism in engineering structures (e.g. ships and offshore structures), leading to safety concerns and significant economic expenses. This study presents an improved methodology for indoor accelerated corrosion testing of structural components. The method involves controlling natural factors (oxygen saturation, temperature, salinity, and flow rate) to accelerate the corrosion in a controlled...
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Indoor accelerated controlled corrosion degradation test of small- and large-scale specimens
PublikacjaThe work presented here is a part of a long-term project analysing the structural behaviour of ageing marine structures. An accelerated corrosion degradation set-up was developed to reproduce corroded marine structural specimens of different degrees of degradation, controlling various natural factors, i.e., temperature, oxygen content, salinity, and flow velocity. The nine stiffened plates of 1.2 m length and 30 small scale specimens...
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Corrosion of evaporator tubes in low emission steam boilers
PublikacjaPurpose of this paper is to reveal the mechanisms of corrosion processes of outer surfaces of low-emission steam boiler evaporator tubes. Examinations were performed to find the reasons of different corrosion susceptibility of tubes situated at combustion chamber on various levels. Examinations were conducted on several segments of 57 x 5.0 mm evaporator tubes made of 16M (16Mo3) steel grade. Segments were taken from level of...
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ARCHITECTURE IN BRANDING AND OVERBRANDING PROCESS. HOW GLOBALIZATION INFLUENCED ARCHITECTURE QUALITY.
PublikacjaGlobalization is unification. In the field of architecture and in the social structure alike, the globalization leads to a blending of economies and cultures that produces uniformly branded public space as a response to universal assumptions of integration and correlation. While branding consists in creating a recognizable and outstanding image a strong contradiction exists between both of these approaches. As a result, regional...
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Guided ultrasonic wave technique for corrosion monitoring and thickness variability analysis
PublikacjaCorrosion degradation poses a significant challenge to the structural integrity of industrial components, especially in critical sectors such as oil and gas, marine, and energy. This paper presents a novel approach to assessing corrosion damage using guided ultrasonic waves (GUWs), focusing on the statistical characterization of thickness variability in corroded plates. A combined algorithm is developed to estimate key statistical...
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Juliusz Orlikowski prof. dr hab. inż.
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Accelerated large scale test set-up design in natural corrosion marine environment
PublikacjaThe standards for conducting small-scale specimen tests are well developed, but there is a lack of direct guidelines for conducting corrosion tests for large-scale specimens. The objective here is to develop a methodology which may be used in designing an accelerated corrosion test of large-scale structural components subjected to a natural corrosion marine environment. Different factors influencing corrosion degradation of steel...
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Determination of causes of accelerated local corrosion of austenitic steels in water supply systems
PublikacjaThis paper concerns an inspection of a water supply system, made of AISI 304 steel, which showed signs of local corrosion at the weld. Such corrosion caused material perforation after very short periods of operation. It was revealed that steel was sensitised during the welding process. It was also proven that chromium micro-segregation occurred in the alloy leading to galvanic cell formation which initialised the process of pitting...
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An investigation of microstructural basis for corrosion behavior of Al-CNT composites fabricated by SPS
PublikacjaIn this research effect of the addition of multi-wall carbon nanotubes (MWCNTs) as additive powder on microstructure and corrosion behavior of fabricated Al-CNT composites was studied. The aluminum powder and CNTs were mixed with high energy planetary ball-mill. It is observed that by increasing milling time, the uniformity of CNTs on aluminum matrix and consequently corrosion resistance of Al-CNT composite is increased. On the...
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The application of impedance measurements for the determination of the probability of the course of corrosion processes
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Corrosion rate measurements by non-linear electrochemical impedance spectroscopy
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Effect of microstructure on mechanical properties and corrosion resistance of 2205 duplex stainless steel
PublikacjaThis paper presents results of the research on impact of microstructure of austenitic-ferritic steel of duplex type on its mechanical properties and susceptibility to stress corrosion cracking. As showed, improper processing technologies more and more often used in shipbuilding industry for plates and other half-finished products made of duplex steel may cause significant lowering their properties, which frequently makes their...
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The Impact of Crushed Rock Spoil on Pitting Corrosion of Selected Stainless Steel
PublikacjaThe paper presents the results of the pitting resistance investigations of selected stainless steels in the chloride environment and the simultaneous impact of erosive factors using the cyclic polarization technique. Additionally, using electrochemical techniques, ie: electrochemical impedance spectroscopy (EIS) and measurement of corrosion potential, the behavior of the passive layer of selected stainless steels in the environment...
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Complex Corrosion Monitoring System for Crude Distillation Unit in Form of Neutral Network
PublikacjaComplex and successful corrosion monitoring of refinery processes can significantly reduce material losses and failure risk. The developed corrosion monitoring system is based on online ultrasonic sensors, ER (electrical resistance) probes, gravimetric method and multipoint analytical analysis of chemical composition of the fluids. Additional online LPR (linear polarization resistance) sensors controlling corrosiveness of sour...
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The Influence of Global Corrosion Degradation on Localized Damage Detection Using Guided Waves
PublikacjaThis paper presents the results of a numerical analysis of the influence of corrosion degradation of metal plates on the wave propagation phenomenon. There are several different corrosion types, but general and pitting corrosion are the most common. General corrosion is more or less uniformly distributed over the entire exposed surface of the metal while pitting corrosion takes the form of localized cracks. Because the general...
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Effects of the preheating laser treatment on microstructure and corrosion resistance of Ti6Al4V bioalloy
PublikacjaThe laser remelting of the Ti6Al4V alloy was made on specimens pre-heated at elevated temperatures. The laser treatment effected in change of microstructures of surface layers and an appearance of blisters and numerous cracks. The corrosion tests demonstrated the decrease in corrosion resistance for each preheating temperature. The observed effects were attributed to negative influence of excessive compressive stresses with no...
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Influence of yttria surface modification on high temperature corrosion of porous Ni22Cr alloy
PublikacjaProtective coatings for porous alloys for high temperature use are relatively new materials. Their main drawback is high temperature corrosion. In this work protective coatings based the on Y-precursor infiltrated into the sintered Ni22Cr alloys are studied at 700°C. Effects of the amount of the protective phase on the resulting corrosion properties are evaluated in air and humidified hydrogen. Weight gain of the samples, their...
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Corrosion behavior of concrete produced with diatomite and zeolite exposed to chlorides
PublikacjaChloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete structures. The electrochemical impedance of reinforcing steel in diatomite- and zeolite-containing concrete exposed to sodium chloride was assessed. Chemical, physical and mineralogical properties of three concrete samples (20% diatomite, 20% zeolite, and a reference containing neither)...
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Inhibitive effect of sodium molybdate on corrosion of AZ31 magnesium alloy in chloride solutions
PublikacjaIn this work, corrosion inhibition of the AZ31 magnesium alloy was investigated in NaCl solutions containing different amounts of sodium molybdate inhibitor. Electrochemical, hydrogen evolution, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. The results showed that Na2MoO4 inhibitor provides reliable inhibition at high concentrations (150 mM). Surface examination...
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Instantaneous impedance monitoring of synergistic effect between cavitation erosion and corrosion processes
PublikacjaThe most common method of determination of cavitation erosion resistance as well as the magnitude of erosion-corrosion synergistic interaction is based on the weight loss measurements. Nondestructive characterization of installations elements is in most cases impossible to perform. Also, such a measurement does not include local types of failure or alteration of operating conditions. There is an urge to elaborate a method for monitoring...