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Wyniki wyszukiwania dla: solid state ionics
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Electrical properties and structure of lead-borate glass containing iron ions
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Mixed ionic polaron transport and rapid crystallization in (Bi, Pb)-Sr-Ca-Cu-O glass.
PublikacjaPrzedstawiono rezultaty pomiarów zmiennoprądowego przewodnictwa elektrycznego w szkłach (Bi,Pb)-Sr-Ca-Cu-O. Zaobserwowano dwa mechanizmy przewodnictwa.Zaproponowano hopping małych polaronów i dyfuzję jonów Cu(I) jako mechanizmy przewodnictwa.
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Transport of alkali metal cations in poly(3,4-ethylenethiophene) films.
PublikacjaElektrochemicznie otrzymana warstwa kompozytowa złożona z poli(3,4-etyleno-dioksytiofenu) i poli(styrenosulfonianu) podczas polaryzacji ulega odwracalnemu procesowi sorpcji-desorpcji kationów z elektrolitu zewnętrznego. Transportowi jonowemu towarzyszą cząsteczki wody (rozpuszczalnika). Ilość cząsteczek wody przypadająca na jednostkowy kation metali alkalicznych została wyznaczona za pomocą metody elektrochemicznej mikrowagi...
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Ionic conductivity of bismuth silicate and bismuth germanate glasses.
PublikacjaPrzedstawiono wyniki badań przewodnictwa d.c i a.c. szkieł BixGe1-xO2-0.5x (gdzie x=0.13, 0.23, 0.33, 0.47) i BixSi1-xO2-0.5x (gdzie x=0.47, 0.57, 0.67). Wyniki sugerują, że przewodnictwo elektryczne jest zdeterminowane ruchem jonów tlenu. Znaczący wzrost przewodnictwa elektrycznego przy x> 0.33 został wytłumaczony na podstawie faz perkolacyjnego modelu ruchu jonów w podsieci BiO5-6.
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Electronic conductivity in Na2O-FeO-P2O5 glasses. oz.
PublikacjaZbadano przewodnictwo stałe i zmiennoprądowe w szkłach: 50P2O5-(50-x)FeO-xNa2O i 50P2O5-(50-x)FeO-xCaO, gdzie x zmieniano od 7 do 20mol%. Wykazano,że zamiana CaO na Na2O w małym stopniu zmienia przewodnictwo elektryczne szkieł, co sugeruje, że przewodnictwo w szkłach zawierających Na2O ma charakter elektronowy. Do badania procesów migracji elektronów i jonów zastosowano metodę tarcia wewnętrznego. W widmie tarcia wewnętrznego...
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Cation diffusion coefficients in CuAgI via molecular dynamics simulations
PublikacjaPraca prezentuje wyniki analizy strukturalnej otrzymane poprzez symulacje dynamiczno-molekularne (zespół NpT, dwuciałowy potencjał Vashisty-Rahmana) superjonowego związku o składzie (1-x)Cu-xAg-I, x = 0.0, 0.25, 0.5, 0.75, 1.0). Wyznaczono wartość współczynnika dyfuzji kationów i energii aktywacji w funkcji składu szkła i temperatury. Otrzymane rezultaty porównano z danymi literaturowymi.
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On stability of iodine doped TiO2 electrodes in pH varied aqueous electrolytes
PublikacjaW pracy przedstaiono charakterystykę elektrochemiczną warstwy domieszkowanego jodem TiO2 na podłożu platynowym. Wyniki badań prowadzone w elektrolitach o różnym pH pozowoliły na określenie właściwości na granicy faz elektroda - elektrolit. Wyznaczono zależność potencjału pasma płaskiego od pH elektrolitu, a charakter otrzymanej funkcji potwirdził stabilność proszku I-TiO2 w kontakcie s roztworem.
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Synthesis and electrochemical characterization of poly(3,4-ethylenedioxythiophene) modified by iron hexacyanocobaltate
PublikacjaPraca dotyczy sposobu syntezy oraz elektrochemicznej charakterystyki materiału kompozytowego złożonego z poli(3,4-etylenodioksytiofenu) i heksacyjanokobaltanu(III) żelaza(II). Wybrany materiał badany był przy użyciu spektroskopii impedancyjnej, chronopotencjometrii oraz woltamperometrii cyklicznej w kontakcie z elektrolitem wodnym (KCl) oraz aprotycznym (LiPF6 w mieszaninie węglanu etylenu i węglanu propylenu). Materiał charakteryzuje...
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Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance
PublikacjaIn this work we present the outstanding energy storage of prepared inorganic-organic heterojunction where hydrogenated ordered titania nanotubes (H-TiO2NT) were modified by the hybrid made of poly(3,4-ethylenedioxythiophene) (pEDOT) and iron hexacyanoferrate centres (Fehcf, Prussian Blue). The material TiO2NT/pEDOT:Fechf was obtained electrochemically by means of: anodization, hydrogenation and finally, electropolymerization of...
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Electronic conductivity in the SiO2-PbO-Fe2O3 glass containing magnetic nanostructures
PublikacjaThe linear impedance spectra of iron–silicate–lead glass samples were measured in the frequency range from 1 MHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by means of XRD and atomic force microscopy. Local electrical and magnetic properties of the samples were tested with the aid of electrostatic force microscopy (EFM) and magnetic force microscopy (MFM). The obtained results show...
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Electrical properties and structure of lead-borate glass containing iron ions.
PublikacjaThe ac and dc conductivity in iron–lead-borate glass samples was investigated in the frequency range from 1 mHz to 1 MHz and in the temperature range from 153 K to 423 K. The structure was investigated by the means of atomic force microscopy (AFM) and the crystalline phases (if present) were identified by the means of X-ray diffractometry. Two types of ac electrical behaviour were observed. The first group of glass samples which...
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Tailoring of SiOC composition as a way to better performing anodes for Li-ion batteries
PublikacjaPolymer derived silicon oxycarbide (SiOC) ceramics are investigated as potential anodes for lithiumion batteries. Different SiOC ceramics are prepared by pyrolysis (1000 °C and 1400 °C under controlled argon atmosphere) of polysiloxanes ceramic precursors. Preceramic polymers are synthesized using the sol–gel method. Phenyltriethoxysilane (PhTES) and methyltriethoxysilane (MTES) have been used as starting precursors and mixed with...
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Photoelectrochemical properties of BIMEVOX (ME=Cu, Zn, Mn) electrodes in contact with aqueous electrolyte
PublikacjaLayered oxide Bi4O2O11 and mixed oxides of bismuth, vanadium and a third metal (ME = Cu, Zn, Mn) were synthesized and characterized using XRD, Raman and SEM. The energy band gap (Eg) of samples determined using UV–VIS reflectance spectra equals to 2.46, 2.34, 2.27 and 2.18 eV for Bi4V2O11, BICUVOX (Bi2V1 − xCuxO5.5 − 3x/2), BIZNVOX (Bi2V1 − xZnxO5.5 − 3x/2) and BIMNVOX (Bi2V1 − xMnxO5.5 − x/2) (x = 0.1), respectively. Open circuit...
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Electronic and ionic relaxations in strontium-borate glass and glass-ceramics containing bismuth and vanadium oxides
PublikacjaThe topography, microstructure and electrical properties of strontium-borate glass and SBO glass containing bismuth and vanadium oxides, were studied. The structure was measured using X-ray diffraction (XRD), Energy Dispersive X-ray Spectrometer (EDS) and Scanning electron microscope (SEM) methods. The A.C. complex conductivity was investigated as a function of temperature and frequency. The influence of the quantity of bismuth...
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Donor-substituted SrTi1+xO3−δ anodes for SOFC
PublikacjaPrzebadano wpływ niestechiometrii na właściwości tytanianu strontu domieszkowanego niobem. Zaproponowano chemię defektów dla tego typu związków.
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Electrochemical activity and characterization of hybrid material consisted of poly(3,4- ethylenedioxythiophene) and silver hexacyanocobaltate
PublikacjaPrac przedstawiono charakterystykę elektrochemiczną oraz powierzchniową materiału hybrydowego składającego się z polimeru przewodzącego, poli(3,4-etylenodioksytiofenu) oraz nieorganicznej sieci typu redoks, heksacyjanokobaltanu srebra. Materiał scharakteryzowano technikami jak AFM, SEM. Skład materiału oznaczono za pomocą mikroanalizy rentgenowskiej EDX. Analiza potwierdziła obecność sieci nieorganicznej w materiale. Proporcja...
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Nonlinear impedance in oxide glasses containing single and mixed alkali ions
PublikacjaThe aim of the present was to find more clues on the nonlinearities in impedance of oxide glasses. The first family of researched glasses has a composition of FeO-P2O5-Na2O. Oxide glasses containing iron and alkali are well known for a very low alkali ion mobility and may be considered purely polaron conducting. These glasses show no detectable nonlinearities in the impedance spectra. The second was a family of ionic conducting...
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Ion conduction in beryllium-alumino-silicate glasses doped with sodium or sodium and lithium ions
PublikacjaElectrical properties of beryllium-alumino-silicate glasses containing sodium ions or sodium and lithium ions were studied with impedance spectroscopy technique over a frequency range from 10 mHz to 1 MHz and at temperature range from 213 to 473 K. The frequency- and temperature-dependent conductivity spectra of individual single alkali glasses were superimposed by means of the Summerfield scaling. Mixed-alkali glasses do not overlap...
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Influence of pyrolysis atmosphere on the lithium storage properties of carbon-rich polymer derived SiOC ceramic anodes
PublikacjaPolymer derived carbon-rich SiOC ceramics are prepared from polysiloxane precursors through a pyrolysis process at 1000 °C using pure argon and argon/hydrogen mixture as pyrolysis atmosphere. The precursor is synthesized from a linear (Si–H)-containing polysiloxane cross-linked with divinylbenzene using hydrosilylation reaction in the presence of a platinum catalyst. Pyrolysis in Ar/H2 mixtures, compared to the treatment under...
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New ceramic materials derived from pyrolyzed poly(1,2-dimethylsilazane) and starch as a potential anode for Li-ion batteries
PublikacjaNewmaterialswere obtained by pyrolysis of starch (S) and poly(1,2-dimethylsilazane) (PSN) (weight ratio: PSN/S 30/70) at temperature a) 500 °C, b) 700 °C and c) 900 °C. Ceramic materials were characterized by infrared spectroscopy, TGA, Raman spectroscopy and SEM. New Si\O and shifted Si\C stretching vibration modes emerged confirming direct interaction between silicon originating fromsilazane and oxygen coming fromstarch. The...
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Properties of Nasicon-based CO2 sensors with Bi8Nb2O17 reference electrode
PublikacjaPotentiometric CO2 sensors based on Nasicon (Na+ conductor, Na3Zr2Si2PO12) electrolyte, Bi8Nb2O17/Pt reference electrode and different sensing electrodes have been prepared. Besides the sensing electrode material, sensors differ from each other in the reference electrode preparation technique. The main aim of this study is to investigate sensor construction and electrode fabrication process influence on sensor properties. The optimal...
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Nonlinear and linear impedance of bismuth vanadate ceramics and its relation to structural properties
PublikacjaThe nonlinear and linear electrical properties, topography, and microstructure of bismuth-vanadate ceramics, were studied. The structurewas observed with the use of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), atomic force microscopy (AFM) and confocal microscopy methods. The obtained results showed that ceramic is porous. Two phase transitionswere determinedwith the use of DSC measurements. The linear and nonlinear ac...
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Fabrication and properties of electrode material composed of ordered titania nanotubes and pEDOT:PSS
PublikacjaWe report on the two-stage preparation method of electrode material composed of titania nanotubes and poly(3,4-ethylenedioxythiopene):poly(2-styrenesulphonate) conductive polymer (pEDOT:PSS). Initially, titania nanotube arrays were produced by the anodization process of Ti substrate. Next, the polymer was potentiostatically deposited onto the thermally annealed nanotube arrays from the electrolyte containing monomer and counter...
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Nonlinear electrical properties of glass-ceramics nanocomposites containing ferroelectric nanocrystallites of Bi2VO5.5
PublikacjaNonlinear A.C. impedance measurements were conducted in the 50BiV-50SrBAlO nanocomposite as a function of frequency, temperature and A.C. voltage. This material is ferroelectric below temperature of 730 K, and above 730 K is a good ion-conductor. For this nanocomposite a low A.C. voltage of 1 V rms is enough to observe high nonlinearities. The origin of these nonlinear effects depends on the temperature and frequency. In the high...
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Synthesis and properties of porous Sr 0.96 Y 0.04 Ti 1−x Nb x O 3
PublikacjaA series of porous, single phase Sr0.96Y0.04Ti1-xNbxO3 samples was obtained using a wet synthesis method (modified citrate sol-gel) method. Temperature-programmed reduction (TPR) and temperature-programmed oxidation (TPO) measurements have shown high stability of the obtained material in variable (oxidizing/reducing) atmospheres. All samples exhibit high conductivity in hydrogen atmosphere with the highest value (around 1S/cm)...
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Electrical properties of A-site Ca-doped LaNb1-xAsxO4-δ ceramics
PublikacjaThe electrical properties of A-site Ca-doped LaNbO4 with the addition of As in the B-site, have been investigated. Total, grain- and specific grain boundary electric conductivities in different oxygen partial pressure, and water vapour partial pressure were determined. Additional conductivity measurements were performed in nitrogen, to suppress the possible p-type conductivity, focusing on protonic conductivity. The maximum measured...
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Flexible dye-sensitized solar cells based on Ti/TiO2 nanotubes photoanode and Pt-free and TCO-free counter electrode system
PublikacjaFlexible dye-sensitized solar cells (DSSCs) are getting more attention compared to standard glass covered DSSCs due to their unique commercial applications (e.g. tents or sail surfaces) and the possibility of rolling up into a small, portable device. In this work, titania nanotubes (TiO2 NT) modified with titania nanoparticles (TiO2 NP) were photoelectrochemically characterized as an anode for flexible dye-sensitized solar cells....
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Copper and cobalt co-doped ceria as an anode catalyst for DIR-SOFCs fueled by biogas
PublikacjaThe nanocrystalline compounds of Co and Cu co-doped ceria (with up to 20 mol.% of dopants) were fabricated by the reverse microemulsion synthesis method. They were deposited in a form of layers on the surface of SOFC anode in an aim to act as electrochemically active materials for biogas reforming process. Fourier Transformed Infrared Spectroscopy was used to analyze a composition of outlet gases simultaneously with the tests of...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublikacjaSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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ELECTROCHEMICAL AND SOLID STATE LETTERS
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The possibility of application of the potentiometric sensor with all-solid-state electrodes containing lipid-polymer membranes for classification of tested black leaf teas in terms of their quality
PublikacjaPotentiometric sensor with all-solid-state electrodes containing lipid-polymer membranes for a set of black leaf teas coming from four countries (China, India, Sri Lanka and Kenia) classification was applied. The tested tea samples were reassigned to quality classes marked with numbers I–V according to the information available. The sensor results of tea samples are presented in the form of radar charts. It was observed that, in...
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Opracowanie potencjometrycznej wieloczujnikowej platformy wykonanej całkowicie w technologii All-Solid-State do jednoczesnego oznaczania kilku jonów w roztworach wodnych
PublikacjaW pracy przedstawiono charakterystykę i konstrukcje różnych elektrod jonoselektywnych (EJS), a także opisano elektrodę odniesienia i jej funkcję. Przybliżono możliwości zastosowania EJS do monitorowania śladowych ilości ołowiu (II) w otoczeniu kopalni rud cynku i ołowiu, oraz jako biowskaźnik stanu pacjenta w czasie wstrząsu septycznego. Opisano wieloczujnikowe platformy potencjometryczne (WPP) w technologii All-Solid-State (ASS). W...
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Solid state electronics and nanoelectronics
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Comparison of Cu1.3Mn1.7O4 spinels doped with Ni or Fe and synthesized via wet chemistry and solid-state reaction methods, designed as potential coating materials for metallic interconnects
PublikacjaThe influence of the method applied to synthesize Cu-Mn-O spinel was evaluated. The methods selected for the investigation were EDTA gel processes and solid-state reaction synthesis. From the obtained powders, sinters were prepared and assessed in terms of their properties as potential coating materials. Additionally, the influence of Ni and Fe dopants was evaluated. The results show that the EDTA gel processes method seems to...
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A structural study of the hydrated and the dimethylsulfoxide, N, N´-dimet-hylpropyleneurea, acetonitryle, pyridine and N,N-dimethylthioformamide solvated nickel(II) ion in solution and solid state.
PublikacjaOznaczono strukturę w stanie stałym i ciekłym solwatowanego jonu niklu(II) w rozpuszczalnikach o różnych właściwościach donorowych: w wodzie, dimetylo-sulfotlenku, N,N`-dimetylopropylomoczniku, acetonitrylu, pirydynie i N,N-di-metylotioformamidzie. Stwierdzono, że nikiel(II) tworzy przede wszystkim sześciokoordynacyjne solwaty (woda, acetonitryl, DMTF). Jako solwat pięciokoordynacyjny istnieje tylko w dimetylopropylomoczniku....
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Cover Feature: Electronic Circular Dichroism Imaging (ECD i ) Casts a New Light on the Origin of Solid‐State Chiroptical Properties (Chem. Eur. J. 4/2022)
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IEEE JOURNAL OF SOLID-STATE CIRCUITS
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Effect of rPET Content and Preform Heating/Cooling Conditions in the Stretch Blow Molding Process on Microcavitation and Solid-State Post-Condensation of vPET-rPET Blend: Part I—Research Methodology and Results
PublikacjaPolyethylene terephthalate (PET) is widely used in bottle production due to its costeffectiveness and low environmental impact. The first part of this article describes the research and statistical analysis methodology of the influence of the virgin PET (vPET) and recycled PET (rPET) content in the vPET-rPET blend, as well as the preform heating/cooling conditions in the stretch blow molding (SBM) process on the microscopic bottle...
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Modeling of the alcohol dehydrogenase active site. Two different modes of alcohol binding in crystals of zinc and cadmium tri-tert-butoxysilanethiolates evidenced by X-ray diffraction and solid state vibrational spectroscopy
PublikacjaOpisano syntezę, struktury cząsteczkowe oraz widma FT-IR, 1H. 13C, 29Si, 113Cd NMR dziesięciu nowych, mieszanoligandowych kompleksów cynku i kadmu z ligandem tri-tert-butoksysilanotiolanowym i pochodnymi imidazolu. Za pomocą rentgenowskiej analizy strukturalnej i spektroskopii w podczerwieni udokumentowano dwa różne sposoby wiązania etanolu i metanolu w kryształach tych związków. Opisane kompleksy stanowią modele miejsca aktywnego...
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Modeling of the Alcohol Dehydrogenase Active Site: Two Different Modes of Alcohol Binding in Crystals of Zinc and Cadmium Tri‐tert‐butoxysilanethiolates Evidenced by X‐ray Diffraction and Solid‐State Vibrational Spectroscopy
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Solid State Electronics and Nanoelectronics 2021/22
Kursy Online -
Solid State Electronics and Nanoelectronics summer 2024
Kursy Online -
Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
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Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
PublikacjaScharakteryzowano strukturę heteroleptycznych kompleksów cynku(II), kobaltu(II) i kadmu(II) z 2-(2'-hydroksyetylopirydyną), tri-tert-butoksysilanotiolem i metanolem. Przy pomocy widm UV-Vis i NMR stwierdzono szybką wymianę N-liganda w roztworach tych kompleksów. Wyznaczono przesunięcia 15N NMR 2-(2'-hydroksyetylopirydyny) w kompleksach cynku(II) i kadmu(II). Na podstawie widm w podczerwieni i obliczeń DFT oszacowano względną moc...
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Crystallographic study of self-organization in the solid state including quasi-aromatic pseudo-ring stacking interactions in 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea and 1-benzoyl-3-(2-hydroxypropyl)thiourea
Publikacja1-Benzoylthioureas contain both carbonyl and thiocarbonyl functional groups and are of interest for their biological activity, metal coordination ability and involvement in hydrogen-bond formation. Two novel 1-benzoylthiourea derivatives, namely 1-benzoyl-3-(3,4-dimethoxyphenyl)thiourea, C₁₆H₁₆N₂O₃S, (I), and 1-benzoyl-3-(2-hydroxypropyl)thiourea, C₁₁H₁₄N₂O₂S, (II), have been synthesized and characterized. Compound (I) crystallizes...
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CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE
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The XRD diffraction patterns of as-prepared (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials synthesized via the solid state reaction method
Dane BadawczeThe (La0.3Sr0.6Ce0.1)0.9Me0.1Ti0.9O3-δ (Me= Co, Cu, Fe, Mn, Ni) materials were synthesized via the solid state reaction method and examined as a potential anode material. First, the mixed oxide reagents were pressed into pellets and calcined at 1200 °C for 12 hours to decompose most of the organic compounds. The resulting calcined pellet was ground...
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Physica Status Solidi (C) Current Topics in Solid State Physics
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The superconducting state in the B2H6 compound at 360GPa
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Perovskites in Solid Oxide Fuel Cells
PublikacjaPrzeglądowa publikacja dotycząca wykorzystania ceramicznych materiałów perowskitowych w tlenkowych ogniwach paliwowych.