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Wyniki wyszukiwania dla: POLYBROMINATED DIPHENYL ETHERS (PBDES)MATRIX SOLID-PHASE DISPERSION (MSPD)DUST SAMPLESGAS CHROMATOGRAPHY-ELECTRON IONIZATION-MASS SPECTROMETRY (GC-EIMS)SELECTION OF OPTIMAL CONDITIONS
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Rain Gardens GC_MS analysis dataset
Dane BadawczeThis dataset contains the results of samples analysis (no-target analysis: scan mode) using gas chromatography coupled with mass spectrometry GC–MS (GC-2030 NEXIS MS, Shimadzu, Japan or Thermo Scientific, Waltham, USA).
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Deep eutectic solvents in analytical sample preconcentration Part B: Solid-phase (micro)extraction
PublikacjaOne of the key challenges of modern analytical chemistry is the monitoring of trace amounts of contaminants using sensitive and selective instrumental techniques. Due to the variety and complexity of some samples, it is often necessary to properly prepare a sample and to perform a preconcentration of trace amounts of analytes. In line with the principles of Green Analytical Chemistry (GAC), it is important for an analytical procedure...
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On continuity conditions at the phase interface of two-phase elastic shells
PublikacjaW pracy rozwinięto ogólną nieliniową teorię powłok sprężystych podlegających przejściom fazowym typu martenzytowego. Przedstawione sformułowanie oparte jest na statycznie i kinematycznie ścisłym modelu powłokowym. Uwzględniono gęstośc energii odkształcenia, jak również siły i momenty zadane wzdłuż krzywoliniowego przejścia fazowego. W szczególności otrzymano statyczne warunki ciągłości wzdłuż koherentnego połączenia oraz połączenia...
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Selection Of Optimal Working Fluid For Use With Hybrid Microchannel-Microjet Heat Exchanger
PublikacjaThe paper presents the investigation to find best suited working fluid for a microjet- microchannel cooling module. In which microjets are impinging into the microchannels and forming a liquid film on the impingement surface. This technology takes benefits from two very attractive heat removal techniques. When laminar jets are impinging on the surface have a very high kinetic energy at the stagnation point, also in microchannels...
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Necessary conditions for optimal control of general N-D model
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Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry
PublikacjaOne of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples...
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Electric field effect on luminescence, and photoconduction in electron donor - electron acceptor organic solid films
PublikacjaZaobserwowano silne wygaszenie fotoluminescencji (80%) i duże fotoprądy (1mA/cm2) w układzie dendrymer aminowy m-MTDATA (donor elektronu) : pochodna fenantroliny BPT (akceptor elektronu) niedomieszkowanym oraz zawierającym domieszkę w postaci organicznego kompleksu platyny PtL2Cl. W interpretacji wyników uwzględniono elektrycznopolową dysocjację singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA : PtL2Cl...
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A dipole-driven path for electron and positron attachments to gas-phase uracil and pyrimidine molecules: a quantum scattering analysis
PublikacjaElectron and positron scattering processes in the gas-phase are analysed for uracil and pyrimidine molecules using a multichannel quantum approach at energies close to threshold. The special effects on the scattering dynamics induced by the large dipole moments in both molecules on the spatial features of the continuum leptonic wavefunctions are here linked to the possible bound states of the Rydberg-like molecular anions or ‘positroned’...
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Distillation cleanup preceded gc determination of short-chain monocarboxylic acids in aqueous and solid samples of wastewater origin = Oznaczanie krótkołańcuchowych kwasów monokarboksylowych w próbkach wodnych i stałych pochodzących z oczyszczalni ścieków z wykorzystaniem chromatografii gazowej poprzedzonej destylacją
PublikacjaShort-chain monocarboxylic acids (SCMAs) (C2-C5) formed in the process of aerobic biodegradation of larger organic molecules should often be monitored to optimize wastewater biological treatment and study the processes of converting organic waste matter into methane, etc. Gas chromatography (GC) seems a method of choice for such a task. Majority of samples require clean up before they can be injected into GC system. In this work...
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Novel analytical approach for real-time monitoring of volatile Maillard reaction products emitted from the sugar-amino acid model system using proton transfer reaction mass spectrometry
PublikacjaIn the presented research, volatile Maillard reaction products formation in the two sugar-amino acid model systems, namely glucoselysine and ribose-lysine model systems were investigated using proton transfer reaction mass spectrometry. Obtained data were supported by the reference method, i.e., UV/Vis spectrometry. A number of volatile organic compounds were selected based on the correlation of the effect of Maillard reaction...
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Seeking Optimal Nutrition for Healthy Body Mass Reduction Among Former Athletes
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Chapter 13 : The influence of dispersion phase on composite coating properties after cold working
PublikacjaW pracy określono wpływ fazy dyspersyjnej Al2O3 na wybrane potencjalne właściwości powłok kompozytowych o osnowie niklowej. Powłoki Ni-Al-Al2O3 zostały nałożone na próbki stalowe przy użyciu technologii poddźwiękowego płomieniowego natryskiwania cieplnego. Następnie poddane zostały obróbce plastycznej na zimno i na gorąco poprzez walcowanie, a także prasowania na zimno na prasie hydraulicznej. Obróbka plastyczna jest metodą alternatywną...
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Application of magnetic nanoparticles for magnetic solid-phase extraction in preparing biological, environmental and food samples
PublikacjaThe need to obtain meaningful results as the basis for determining the content of trace amounts of analytes has become the driving force behind the development of modern analytical techniques, including sample-preparation techniques, such as solid-phase extraction (SPE). Recently, great interest was aroused in the use of magnetic nanoparticles (MNPs) in SPE. These materials exhibit high selectivity, and, in small amounts, can provide...
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Rain Gardens LC_MS/MS analysis dataset
Dane BadawczeThis dataset contains the results of samples analysis (target analysis with certified reference materials) using ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS, Shimadzu, Japan).
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Polyfunctional chemically bonded stationary phase for reversed phase high-performance liquid chromatography
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A negative effect of carbon phase on specific capacity of electrode material consisted of nanosized bismuth vanadate embedded in carbonaceous matrix
PublikacjaLithium-ion batteries (LIBs) are widely used all over the world. The LIBs belong to a renewable energy source and energy storage devices. The increase in energy demand causes that new materials of higher energy and higher power densities are still under investigation. Herein, we compare electrochemical properties of bismuth vanadate (BiVO4) embedded and not embedded into carbonaceous matrix as an anode material along with structural...
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Modeling of Imaging Mass Spectrometry Data and Testing by Permutation for Biomarkers Discovery in Tissues
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Signal Partitioning Algorithm for Highly Efficient Gaussian Mixture Modeling in Mass Spectrometry
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Recent achievements in element analysis of bee honeys by atomic and mass spectrometry methods
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Profiling of polar ionogenic metabolites in Polish wines by capillary electrophoresis-mass spectrometry
PublikacjaThe composition of wine is determined by a complex interaction between environmental factors, genetic factors (i.e., grape varieties), and winemaking practices (including technology and storage). Metabolomics using NMR spec-troscopy, GC-MS, and/or LC-MS has shown to be a useful approach for assessing the origin, authenticity, and quality of various wines. Nonetheless, the use of additional analytical techniques with complementary...
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An automatic selection of optimal recurrent neural network architecture for processes dynamics modelling purposes
PublikacjaA problem related to the development of algorithms designed to find the structure of artificial neural network used for behavioural (black-box) modelling of selected dynamic processes has been addressed in this paper. The research has included four original proposals of algorithms dedicated to neural network architecture search. Algorithms have been based on well-known optimisation techniques such as evolutionary algorithms and...
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Optimal selection of the sawdust separation device for a narrow-kerf sawing machine PRW15-M
PublikacjaW pracy przedstawiono granulometryczną analizę rozkładu wiórów i pyłu drzewnego otrzymanego w procesie przecinania suchych pryzm sosnowych na pilarce ramowej wielopiłowej PRW15-M. Wielkości wiórów mieściły się w granicach od 84,7 μm do nawet 14 mm. Te ostatnie są elementami będącymi efektem rozszczepiania dolnej powierzchni pryzmy przez wychodzące z niej ostrza piły. Większośc wiórów z najmniejszych frakcji ma postać sześciennych...
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Determiantion of optimal conditions for the isolation of oil from the fishing industry offal
PublikacjaFish processing generates significant amounts of offal, which usually is converted into fodder meal or is stored into landfills. However, some part of this offal could serve as a source of valuable products, such as fish oil, collagen or gelatin. the aim of the study was to determine the conditions of oil isolation from salmon skins ensuring high yield and quality of the product.
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PBDEs in environmental samples: Sampling and analysis
PublikacjaThe paper reviews the subject literature concerning analytical procedures routinely sed for monitoring polybrominated diphenyl ethers (PBDE) in environmental samples. It describes and summarizes subsequent stages of analytical procedure including sample collection and preparation, extraction, clean-up and final determination. Different approaches with their advantages and limitations are presented. Special attention is drawn to...
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Sputtered silicon solid phase microextraction fibers with a polydimethylsiloxane stationary phase with negligible carry-over and phase bleed
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Assay of Cystathionine-γ-synthase (CaStr2p) activity determination.
Dane BadawczeThe study aimed to obtain conditions optimal for the activity of Candida albicans cystathionine-γ-synthase (CaStr2p) determination. The selection of appropriate reaction conditions included the identification of the reaction buffer and its pH, substrate, and enzyme concentrations. The activity of Str2p was measured by the detection of decrease of the...
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Activity assay of O-Acetyl-L-homoserine sulfhydrylase (CaMet15p).
Dane BadawczeThe study aimed to obtain conditions optimal for the activity of O-acetyl-L-homoserine sulfhydrylase (CaMet15p) and a method suitable for its measurement. The selection of appropriate reaction conditions included the identification of the reaction buffer and its pH, substrate and enzyme concentrations. The activity of CaMet15p was measured by the detection...
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Investigation of the Dynamism of Nanosized SOA Particle Formation in Indoor Air by a Scanning Mobility Particle Sizer and Proton-Transfer-Reaction Mass Spectrometry
PublikacjaTerpenes are VOCs of particular importance, since they are emitted from a wide range of indoor sources and are considered to be precursors of Secondary Organic Aerosol (SOA) formation. It has been proven that SOA particles, especially nanosized ones, pose a threat to human health. In this research, experiments with the application of an environmental chamber and real-time measurement techniques were carried out to investigate in...
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Solid phase extraction technique - trends, opportunities and applications
PublikacjaW pracy opisano wykorzystanie ekstrakcji do fazy stałej w chemii analitycznej. Ekstrakcja do fazy stałej może być przydatna nie tylko do izolacji i wzbogacania analitów z fazy wodnej, ale również do wymiany matrycy oraz oczyszczania ekstraktu. Stosowane sorbenty są analogiczne do stosowanych w chromatografii cieczowej. Omówione zostały: mechanizmy ekstrakcji, sposoby przeprowadzania ekstrakcji (kolumienki, krążki, pipety), rodzaje...
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Solid phase synthesis of two muramyl pentapeptide derivatives
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Interaction of imidazolium type ionic liquids with the solid phase
PublikacjaNiektóre ciecze jonowe, w szczególności te posiadające kation organiczny podstawiony długim łańcuchem alkilowym, wykazują strukturalne podobieństwo do surfaktantów. Samoczynne formowanie się agregatów cieczy jonowych może wpływać na procesy przenoszenia masy w wielu operacjach jednostkowych jak: ekstrakcja, nanofiltracja lub kataliza oraz transport i rozmieszczenie tych związków w środowisku naturalnym. W niniejszej publikacji...
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Application of gas chromatography-olfactometry (GC-O) in analysis and quality assessment of alcoholic beverages - a review
PublikacjaW ostatnich latach prowadzone są intensywne badania nad aktywnością sensoryczną poszczególnych składników zapachów napojów alkoholowych i nad zależnościami pomiędzy zapachem, a składem chemicznym lotnej frakcji tych produktów z wykorzystaniem techniki chromatografii gazowej z detekcją olfaktometryczną (GC-O). GC-O jest techniką wykorzystującą możliwość oceny sensorycznej eluatu z kolumny chromatograficznej, przy czym dla każdego...
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Relativistic theory of photoionization of one electron systems: an eigen channel R-matrix approach.
PublikacjaPrzedstawiono zastosowanie metody kanałów własnych R-macierzy do opisu procesu fotojonizacji relatywistycznych układów jednoelektronowych.
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Inelastic X-Ray Scattering Studies of Phonon Dispersion in PbTe and (Pb,Cd)Te Solid Solution
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Understanding the early-stage release of volatile organic compounds from rapeseed oil during deep-frying of tubers by targeted and omics-inspired approaches using PTR-MS and gas chromatography
PublikacjaDuring deep-frying, a plethora of volatile products is emitted with the fumes. These compounds could act as oil quality indicators and change the indoor air composition leading to health risks for occupants. The presented experiments focus on deep-frying of different tubers in rapeseed oil at different frying temperatures. Here, two scenarios for real-time monitoring of volatile organic compounds (VOCs) using proton transfer reaction...
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Gradient reversed-phase high-performance chromatography of ionogenic analytes
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Selection of optimal location and rated power of capacitor banks in distribution network using genetic algorithm
PublikacjaIn this paper, the problem of placement and rated power of capacitor banks in the Distribution Network (DN) is considered. We try to suggest the best places for installing capacitor banks and define their reactive power. The considered formulation requires the optimization of the cost of two different objectives. Therefore the use of properly multiobjective heuristic optimization methods is desirable. To solve this problem we use...
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Mass Spectrometry-Based Analysis of DNA Modifications: Potential Applications in Basic Research and Clinic
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Similarities and Differences in the Protein Composition of Cutaneous Melanoma Cells and Their Exosomes Identified by Mass Spectrometry
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The Current Use of Mass Spectrometry in Combination with Other Separation Techniques in Drug Discovery Arena
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Analytical techniques for trace organic compounds-III: Mass spectrometry in trace organic analysis
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APPLICATION OF BINARY-ENCOUNTER-BETHE METHOD TO ELECTRON-IMPACT IONIZATION CROSS SECTION CALCULATIONS FOR BIOLOGICALLY RELEVANT MOLECULES
PublikacjaElectron-impact cross sections for platinum chemotherapeutic compounds, purine and pyrimidine molecules calculated using binary-encounterBethe model are presented as examples of possible applications of that method.
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Tuning the extraction properties of ionogel-coated Solid-phase microextraction fibers based on the solvation properties of the ionic liquids
PublikacjaA silica-based network was used to immobilize ionic liquid-based ionogels and applied as a fiber coating forsolid-phase microextraction (SPME). The ionogels were prepared by a sol–gel process, using two ionic liquids,triethylsulfonium bis(trifluoromethylsulfonyl)imide ([Set3][TFSI]) and 1-butyl-1-methylpiperidinium bis(tri-fluoromethylsulfonyl)imide ([C4C1Pip][TFSI]), as well as their equimolar mixture. Methyltrimethoxysilane wasused...
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First deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives for DES application in separation techniques
PublikacjaThe paper presents the first application of deep eutectic solvents (DES) as stationary phases for gas chromatography. DES obtained by mixing tetrabutylammonium chloride (TBAC) as a hydrogen bond acceptor (HBA) with heptadecanoic acid being a hydrogen bond donor (HBD) in a mole ratio of HBA:HBD equal to 1:2 was characterized by its ability to separate volatile organic compounds (VOCs). The Rohrschneider – McReynolds constants determined...
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Selection of the UV irradiation conditions for accelerated edible oil oxidation procedure.
PublikacjaCelem badań było dobranie optymalnych warunków etapu naświetlania olejów roślinnych z zastosowaniem promieniowania ultrafioletowego. Dobrano powierzchnię naświetlania i grubość filmu oleju, a także odległość próbki oleju od źródła światła i moc promieniowania ultrafioletowego.Lotne produkty utleniania izolowano przy pomocy mikroekstrakcji do fazy stacjonarnej i rozdzielano z zastosowaniem chromatografii gazowej z detektorem płomieniowo-jonizacyjnym.
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Optimization of a Fabric Phase Sorptive Extraction protocol for the isolation of six bisphenols from juice pouches to be analysed by high performance liquid chromatography coupled with diode array detector
PublikacjaFabric Phase Sorptive Extraction (FPSE) combined with high pressure liquid chromatography using to diode array detection (HPLC-DAD) was applied for the simultaneous determination of bisphenols (BPA, BPB, BPC, BPE, BPF, BPS) in juice pouches. The FPSE procedure was optimized with regards to the critical parameters that affect the performance of the method including the selection of the FPSE membrane type and size, adsorption time,...
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Interference-Free Determination of Trace Copper in Freshly Ripened Honeys by Flame Atomic Absorption Spectrometry Following a Preconcentration by Solid-Phase Extraction and a Two-Step Elution Process
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Determination of Terpene Profile in Cape gooseberry (Physalis peruviana L.) with Use of HS-SPME/GCxGC-TOFMS Method
PublikacjaFresh fruits and products made of them, especially fruit juice, provide the basic energetic substances (simple and complex sugars) and are a source of health beneficial vitamins, macro and microelements, antioxidants and compounds which are classified together with essential oils (for example terpenes), which positively affect human s health. The terpenes profile of cape gooseberry was determined by headspace solid--phase microextraction...
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Application of normal-phase high-performance liquid chromatography followed by gas chromatography for analytics of diesel fuel additives
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Triplet energy exchange between fluorescent and phosphorescent organic molecules in a solid state matrix.
PublikacjaW pracy przedstawiono model wymiany energii trypletów na podstawie mechanizmu Dextera i zweryfikowano go w układzie dwuamina TPD : organiczny komleks Ir(ppy)3: matryca poliwęglanowa, mierząc czasy życia emisji Ir(ppy)3 przy różnych koncentracjach molekuł TPD.