Wyniki wyszukiwania dla: SUBCRITICAL THERMODYNAMIC CYCLES
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Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance
PublikacjaThe paper discusses the synthesis, photoelectrochemical and electrochemical behaviour of titania nanotube arrays modified by a pyrolyzed metal-organic framework (MOF). A poly(3,4–ethylenedioxyphene) (PEDOT) matrix with an embedded inorganic network of iron hexacyanoferrate (BP) covering TiO2 nanotubes (TNT) is used as a MOF for the further sintering procedure, resulting in a novel, thin film of carbonaceous wrap supported Fe catalytic...
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Fatigue of titanium alloy Ti6Al4V with diamond structure obtained by Laser Power Bed Fusion method
PublikacjaThis paper presents the results of fatigue tests conducted on Ti6Al4V titanium alloy with diamond structure obtained by the Laser Power Bed Fusion method. Samples used in tests were printed with porosities: 81%, 73%, 50%, 34% and near-zero porosity. Samples were subjected to cyclic tests with a constant stress amplitude. The number of cycles until sample failure was registered. Obtained fatigue test results made it possible to...
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Development and Assessment of Regeneration Methods for Peptide-Based QCM Biosensors in VOCs Analysis Applications
PublikacjaCleaning a quartz crystal microbalance (QCM) plays a crucial role in the regeneration of its biosensors for reuse. Imprecise removal of a receptor layer from a transducer’s surface can lead to unsteady operation during measurements. This article compares three approaches to regeneration of the piezoelectric transducers using the electrochemical, oxygen plasma and Piranha solution methods. Optimization of the cleaning method allowed...
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Method of identification of the slide tribological system top layer condition by assessment of the t-02 four-ball tester friction node operation
Publikacjaa method is proposed of the assessment of t-02 four-ball tester friction node operation during extreme unit loads on the tribological system for identification of the top layer condition in that system lubricated with the tested lubricating oil. by identification of the friction node with a thermodynamic system, that operation is treated as an energy generating process of the created servo-layer structure. the friction node operation...
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Hysteresis curves and loops for harmonic and impulse perturbations in some non-equilibrium gases
PublikacjaEvolution of sound in a relaxing gas whose properties vary in the course of wave propagation, is studied. A relaxing medium may reveal normal acoustic properties or be acoustically active. In the first case, losses in acoustic energy lead to an increase in internal energy of a gas similarly as it happens in Newtonian fluids. In the second case, acoustic energy increases in the course of sound propagation, and the internal energy...
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WSPÓŁPRACA BLOKU GAZOWO-PAROWEGO Z OBIEGIEM ORC = Combinded power plant in cooperation with ORC
PublikacjaIn the paper presented is the idea of a combined gas and steam power plant cooperation with a low temperature organic Rankine cycle ORC unit. Considerations presented in the paper are accomplished for the Gorzów CHP. The intention of present analysis is heat recovery of low temperature energy and its further use in ORC cycle in order to produce electricity, without increase in fuel consumption. Waste energy is recovered from the...
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Diagnosing marine turbine engines through energy characteristics of their flow section
PublikacjaThe aim of the performed research was to develop of diagnostic method of the flow section of a marine turbine combustion engine based on the level of delamination of its energy characteristics. The here adopted diagnostic model provides for a formulation of the evaluation of the technical conditions based on the measurements of the parameters of the thermodynamic medium in the characteristic control cross-sections of the engine...
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THE COMPOSITION MODULATION EFFECT IN GaInPAs SOLID SOLUTIONS AS A MANIFESTATION OF ENERGY RESONANCE AFTER MATERIAL'S SPINODAL DECOMPOSITION
PublikacjaThe Cahn-Hilliard model concepts are extended to describe the spinodal decomposition of Ga$_x$In$_{1-x}$P$_y$As$_{1-y}$ solid solutions grown on the InP substrate. The energy of elastic deformation of the thin layer of a solid solution was calculated on the assumption of its coherent conjugation with the massive InP substrate. The excess energy of component mixing in the solid phase was modeled in accordance with the simple solution...
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Analytical method of determining dynamic properties of thermocouples used in measurements of quick – changing temperatures of exhaust gases in marine diesel engines
PublikacjaThe article presents selected issues of mathematical modeling of heat exchange between the thermocouple and the exhaust gas flowing them, in unsteady conditions. On the way of energy balancing consideration of thermodynamic processes developed differential equations describing the dynamic properties for three versions of the design sheathed thermocouples: with weld isolated from the sheath, with weld welded the sheath and with...
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A novel concept of enhanced direct-contact condensation of vapour- inert gas mixture in a spray ejector condenser
PublikacjaAn analytical model of direct steam condensation (DCC) in the novel idea of spray ejector condenser (SEC) in the presence of inert gas has been developed. It is based on continuity, momentum and energy equations for the steam-carbon dioxide mixture and direct contact condensation mechanisms due to heat transfer and concentration. Crucial in the process of DCC is atomisation of the motive fluid in the ejector. The effect of atomised...
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Exploring the cocrystallization potential of urea and benzamide
PublikacjaThe cocrystallization landscape of benzamide and urea interacting with aliphatic and aromatic carboxylic acids was studied both experimentally and theoretically. Ten new cocrystals of benzamide were synthesized using an oriented samples approach via a fast dropped evaporation technique. Information about types of known bi-component cocrystals augmented with knowledge of simple binary eutectic mixtures was used for the analysis...
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KTaO3-based nanocomposites for air treatment
PublikacjaThe advantage is that photocatalytic methods allow removing VOCs, NOx, SO2, deodorants, and microorganisms at the same system. The new third generation of photoactive materials activated by low powered and low cost irradiation sources (such as LEDs or black fluorescent UV lamps) can be used as photocatalysts in air purification systems. A series of single semiconductors and their nanocomposites combination were prepared using hydrothermal...
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Space-vector pulsewidth modulation for a seven-level cascaded H-bridge inverter with the control of DC-link voltages
PublikacjaThe control strategy of DC-link voltages for a seven-level Cascaded H-Bridge inverter is proposed in this paper. The DC-link voltage balancing is accomplished by appropriate selection of H-Bridges and control of their duty cycles in Space-Vector Modulation (SVM) algorithm. The proposed SVM method allows to maintain the same voltage level on all inverter capacitors. Regardless of the balancing function, the...
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Bistability in a One-Dimensional Model of a Two-Predators-One-Prey Population Dynamics System
PublikacjaIn this paper, we study a classical two-predators-one-prey model. The classical model described by a system of three ordinary differential equations can be reduced to a one-dimensional bimodalmap. We prove that this map has at most two stable periodic orbits. Besides, we describe the bifurcation structure of the map. Finally, we describe a mechanism that leads to bistable regimes. Taking this mechanism into account, one can easily...
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Experimental study of pressure rise at the evaporator of capillary pumped loop with acetone and water as working fluids
PublikacjaIn this work studied is the possibility of fluid pumping using capillary forces in the capillary pumped loop. Experimental and theoretical studies have been performed to understand the phenomena associated with heat transfer in porous structure of the evaporator. The capillary effect was studied during operation of two different capillary porous structures with two different working fluids, namely water and acetone. The results...
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Interaction of Acoustic and Thermal Modes in the Vibrationally Relaxing Gases. Acoustic Cooling
PublikacjaThe dynamic equation which governs an excess temperature associated with the thermal mode in vibrationally relaxing gas is derived. The nonlinear transfer of acoustic energy to the energy of the thermal mode in a relaxing gas causes slow variation of temperature with time. The nal dynamic equation is instantaneous. All types of sound, including aperiodic, may be considered as an acoustic source of corresponding heating or cooling....
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Analysis of the possibility of increasing thermal-electric energy conversion ratio in CHP units based on micro gas turbine
PublikacjaThe aim of this paper is to analyze the possibility of increasing thermal energy to electricity conversion efficiency in combined heat and power (CHP) units based on micro gas turbine during low heat demand periods. At the beginning sustainable development postulates under power engineering are explained. Next micro CHP as part of distributed generation idea is presented. The main part of the article is based on results of thermodynamic...
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CFD analysis of fluid flow through the labyrinth seal
PublikacjaSteam and gas turbines are some of the fundamental means of power generation. The energy efficiency of the turbines, however, is not satisfactory. Ever since the start-up of the first turbine in the world, engineers have been striving for their increased efficiency. Multiple solutions to the problem of steam loss in an operating turbine are available. The use of seals is one of them. Empirical methods or numerical calculations...
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Tensile strength test of PE foils modified with zinc oxide and zinc salts
Dane BadawczeThis dataset contains the results of PE foils mechanical tests, in which the material was evaluated for strength and extensibility at the moment of breaking and based on the same tests preceded by material fatigue in 50 stretching cycles. The principle of the method is to stretch the test sample placed in the clamps of the stretching apparatus at a...
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Szybkie uziemniki do ograniczania skutków zwarć łukowych w okrętowych rozdzielnicach SN
PublikacjaW artykule scharakteryzowano moc i napięcie łuku, jak również przedstawiono model termodynamiczny służący do obliczania ciśnienia i temperatury gazów w otoczeniu łuku zwarciowego. Przedstawiono przykładowy układ elektrowni okrętowej i zasilania najważniejszych odbiorników na statku do przewozu gazu ziemnego w stanie ciekłym. Na podstawie parametrów prądnic i silników odbiorników zasilanych z rozdzielnicy głównej obliczono prądy...
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Analiza przepływu gazu w kanałowych reduktorach ciśnienia podczas zwarć łukowych w rozdzielnicach SN
PublikacjaW artykule przedstawiono metodę obliczania ciśnienia i temperatury gazów podczas zwarcia łukowego wewnątrz przedziału wyłącznika rozdzielnicy średniego napięcia z wykorzystaniem modelu termodynamicznego procesów towarzyszących zwarciom łukowym wewnątrz rozdzielnic z izolacją powietrzną. Następnie, w oparciu o mechanikę płynów lepkich, przedstawiono metodę obliczania rozkładu prędkości i ciśnienia gazu w kanałowych reduktorach ciśnienia...
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Asynchronous Networked Estimation System for Continuous Time Stochastic Processes
PublikacjaIn this paper we examine an asynchronous networked estimation system for state estimation of continuous time stochastic processes. Such a system is comprised of several estimation nodes connected using a possibly incomplete communication graph. Each of the nodes uses a Kalman filter algorithm and data from a local sensor to compute local state estimates of the process under observation. It also performs data fusion of local estimates...
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Some variations of perfect graphs
PublikacjaWe consider (ψk−γk−1)-perfect graphs, i.e., graphs G for which ψk(H) =γk−1(H) for any induced subgraph H of G, where ψk and γk−1 are the k -path vertex cover number and the distance (k−1)-domination number, respectively. We study (ψk−γk−1)-perfect paths, cycles and complete graphs for k≥2. Moreover, we provide a complete characterisation of (ψ2−γ1)-perfect graphs describing the set of its forbidden induced subgraphs and providing...
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A note on polynomial algorithm for cost coloring of bipartite graphs with Δ ≤ 4
PublikacjaIn the note we consider vertex coloring of a graph in which each color has an associated cost which is incurred each time the color is assigned to a vertex. The cost of coloring is the sum of costs incurred at each vertex. We show that the minimum cost coloring problem for n-vertex bipartite graph of degree ∆≤4 can be solved in O(n^2) time. This extends Jansen’s result [K.Jansen,The optimum cost chromatic partition problem, in:...
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Diamond-Based Supercapacitors with Ultrahigh Cyclic Stability Through Dual-Phase MnO2-Graphitic Transformation Induced by High-Dose Mn-Ion Implantation
PublikacjaWhile occasionally being able to charge and dischargemore quickly than batteries, carbon-based electrochemical supercapacitors(SCs) are nevertheless limited by their simplicity of processing, adjustableporosity, and lack of electrocatalytic active sites for a range of redox reactions.Even SCs based on the most stable form of carbon (sp3carbon/diamond)have a poor energy density and inadequate capacitance retention during longcharge/discharge...
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A facile strategy for reclaiming discarded graphite and harnessing the rate capabilities of graphite anodes
PublikacjaGraphite negative electrodes are unbeaten hitherto in lithium-ion batteries (LiBs) due to their unique chemical and physical properties. Thus, the increasing scarcity of graphite resources makes smart recycling or repurposing of discarded graphite particularly imperative. However, the current recycling techniques still need to be improved upon with urgency. Herein a facile and efficient hydrometallurgical process is reported to...
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Dual functionality of amphiphilic 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids: surfactants with catalytic function
PublikacjaA series of amphiphilic 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids were synthesized. Acidic hydrogen sulfate ionic liquids with the alkyl chains C6–C14 are characterized by good surface properties. Their surface properties (adsorption and micellization parameters, degree of ionization of micelles, Krafft temperatures and thermodynamic parameters) were determined. Synthesized ionic liquids were applied as a co-catalyst...
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Superconductivity on a Bi Square Net in LiBi
PublikacjaWe present the crystallographic analysis, superconducting characterization and theoretical modeling of LiBi, that contains the lightest and the heaviest nonradioactive metal. The compound crystallizes in a tetragonal (CuAu-type) crystal structure with Bi square nets separated by Li planes (parameters a = 3.3636(1)Å and c = 4.2459(2) Å, c/a = 1.26). Superconducting state was studied in detail by magnetic susceptibility and heat...
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KTaO3-based nanocomposites for air treatment
PublikacjaA series of single semiconductors and their nanocomposites combination (such as KTaO3 + CdSe + SrTiO3; KTaO3 + CdS +WO3; KTaO3 + CdS + MoS2) were prepared using hydrothermal route. Photocatalytic activity of as-prepared nanocomposites was estimated by photocatalytic degradation of toluene in the gas phase using light-emitting diodes (LEDs, 375 nm) in four subsequent cycles. The nanocomposites were characterized by scanning electron...
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Interval incidence graph coloring
PublikacjaIn this paper we introduce a concept of interval incidence coloring of graphs and survey its general properties including lower and upper bounds on the number of colors. Our main focus is to determine the exact value of the interval incidence coloring number χii for selected classes of graphs, i.e. paths, cycles, stars, wheels, fans, necklaces, complete graphs and complete k-partite graphs. We also study the complexity of the...
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Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility
PublikacjaGround tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with transpolyoctenamer, which is an additive that is commercially dedicated...
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Global Surrogate Modeling by Neural Network-Based Model Uncertainty
PublikacjaThis work proposes a novel adaptive global surrogate modeling algorithm which uses two neural networks, one for prediction and the other for the model uncertainty. Specifically, the algorithm proceeds in cycles and adaptively enhances the neural network-based surrogate model by selecting the next sampling points guided by an auxiliary neural network approximation of the spatial error. The proposed algorithm is tested numerically...
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N-doped carbon materials as electrodes for highly stable supercapacitors
PublikacjaThis article reports a strategy to use nitrogen-doped carbon materials as electrodes for supercapacitors. Depending on the carbon precursor, the porous structure is changed with specific surface area reached up to 2270 m2 g−1. The capacitance of carbon materials used as electrodes is related strictly to pore size. The microstructure and nitrogen functionalities enable a high capacitance (327 F g−1) and cycle durability. The nanoporous...
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Low energy electron attachment to platinum(II) bromide (PtBr2)
PublikacjatDissociative electron attachment to PtBr2in the gas phase was studied in the low electron energy rangefrom zero up to 10 eV with an energy resolution of 150 meV. The experiments were carried out using ahemispherical electron monochromator coupled with a quadrupole mass spectrometer and pulse count-ing acquisition system. The only anion observed was Br−. This ion is formed at three resonance electronenergies: 0.4 eV, 1.2 eV and...
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Stripe order and magnetic anisotropy in the S=1 antiferromagnet BaMoP2O8
PublikacjaMagnetic behavior of yavapaiite-type BaMoP2O8 with the spatially anisotropic triangular arrangement of the S=1Mo4+ ions is explored using thermodynamic measurements, neutron diffraction, and density-functional band-structure calculations. A broad maximum in the magnetic susceptibility around 46 K is followed by the stripe antiferromagnetic order with the propagation vector k=(12,12,12) formed below TN≃21 K. This stripe phase is...
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Instantaneous Heating and Cooling Caused by Periodic or Aperiodic Sound of Any Characteristic Duration in a Gas with Vibrational Relaxation
PublikacjaThermodynamic relaxation of internal degrees of a molecule's freedom in a gas occurs with some characteristic time. This makes wave processes in a gas behave differently depending on the ratio of characteristic duration of perturbations and the relaxation time. In particular, generation of the secondary non-wave modes by intense sound in a nonlinear flow dependens on frequency. These kinds of interaction are considered in this...
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Excitation of Non-Wave Modes by Sound of Arbitrary Frequency in a Chemically Reacting Gas
PublikacjaThe nonlinear phenomena in the field of high intensity sound propagating in a gas with a chemical reaction, are considered. A chemical reaction of A → B type is followed by dispersion and attenuation of sound which may be atypical during irreversible thermodynamic processes under some conditions. The first and second order derivatives of heat produced in the chemical reaction evaluated at the equilibrium temperature, density and...
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Hydrodynamic reanalysis of ice conditions in the Baltic Sea using the PM3D model
Dane BadawczeThe dataset contains the results of numerical modeling of sea ice in the Baltic Sea since 1998. A long-term reanalysis was performed using the three-dimensional hydrodynamic model PM3D (Kowalewski and Kowalewska-Kalkowska, 2017), a new version of the M3D model (Kowalewski, 1997). A numerical dynamic-thermodynamic model of sea ice (Herman et al. 2011)...
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Long-term hindcast simulation of sea ice in the Baltic Sea
Dane BadawczeThe data set contains the results of numerical modeling of sea ice over a period of 50 years (1958-2007) in the Baltic Sea. A long-term hindcast simulation was performed using a three-dimensional hydrodynamic model PM3D (Kowalewski and Kowalewska-Kalkowska, 2017), a new version of the M3D model (Kowalewski, 1997). A numerical dynamic-thermodynamic model...
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Change of reaction quotients for SOFC fueled by biogas mixture at 750 C
Dane BadawczeThe dataset contains the Change of reaction quotients for SOFC fueled by biogas mixture at 750 C (60:40 CH4:CO2). The outlet concentration of the gases from SOFC were measured using novel FTIR-based unit.
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Analysing selection of low-temperature medium for cogeneration micro power plant
PublikacjaThe article analyses the ORC system working with dry and wet low-boiling media which are most frequently used in installations of this type. Two types of cycles were examined, which were the cycle with heat regeneration for dry media: fc72, hfe7100, R227ea, R245fa, R423a and R600a, and the cycle without heat regeneration for wet media: R11, R12, R134a, R718 and 507a. The calculations were performed for the assumed required thermal...
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Analysing selection of low-temperature medium for cogeneration micro power plant
PublikacjaThe article analyses the ORC system working with dry and wet low-boiling media which are most frequently used in installations of this type. Two types of cycles were examined, which were the cycle with heat regeneration for dry media: fc72, hfe7100, R227ea, R245fa, R423a and R600a, and the cycle without heat regeneration for wet media: R11, R12, R134a, R718 and 507a. The calculations were performed for the assumed required thermal...
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The Effect of Water and Frost on Fatigue Life of Asphalt Concrete
PublikacjaThis paper presents testing of fatigue life of asphalt concrete that has been subjected to action of water and frost. Simulation of water and frost action was based on the original AASHTO T283 method and its modification. The original method was modified in such a way that instead of a single freeze-thaw cycle, 50 and 150 cycles were applied. Fatigue life was measured in the indirect tensile fatigue test in the Nottingham asphalt...
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Global edge alliances in graphs
PublikacjaIn the paper we introduce and study a new problem of finding a minimum global edge alliance in a graph which is related to the global defensive alliance (Haynes et al., 2013; Hedetniemi, 2004) and the global defensive set (Lewoń et al., 2016). We proved the NP-completeness of the global edge alliance problem for subcubic graphs and we constructed polynomial time algorithms for trees. We found the exact values of the size of the...
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Research 1: Heterojunction of (P, S) co-doped g-C3N4 and 2D TiO2 for improved carbamazepine and acetaminophen photocatalytic degradation
Dane BadawczeThe first research article consisted on the synthesis of phosphorus and sulfur co-doped graphitic carbon nitride incorporated in 2D TiO2 structure for solar-driven degradation of emerging pollutants from the group of pharmaceuticals not susceptible to biodegradation. The hybrid photocatalysts with different loadings of (P, S)-doped g-C3N4 were characterized...
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Deep compaction control of sandy soils
PublikacjaVibroflotation, vibratory compaction, micro-blasting or heavy tamping are typical improvement methods for the cohesionless deposits of high thickness. The complex mechanism of deep soil compaction is related to void ratio decrease with grain rearrangements, lateral stress increase, prestressing effect of certain number of load cycles, water pressure dissipation, aging and other effects. Calibration chamber based interpretation...
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Measurements of the optical and thermal properties of the 2D black phosphorus coating
PublikacjaBlack phosphorus is a 2D material, which properties are still being discovered. In this paper, the sensitivity to the temperature of a few-layer black phosphorus coating deposited, on the surface of a microsphere-based fiber-optic sensor, by a dip-coating method is presented. The coating was investigated after 2, 3, and 5 deposition cycles and during temperature growth from 50 °C to 300 °C in an interferometric setup. The intensity...
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Wybrane zagadnienia optymalizacji organizacji ruchu kolejowego w celu minimalizacji kosztów energii elektrycznej
PublikacjaW artykule przedstawiono podział kosztów w transporcie kolejowym z uwzględnieniem kosztów wewnętrznych przedsiębiorstwa, do których zaliczają się między innymi koszty dostępu do infrastruktury, czy koszty energii. Stwierdzono, że przy odpowiedniej organizacji ruchu pociągów na sieci kolejowej, bez ponoszenia dodatkowych nakładów na infrastrukturę i specjalistyczne urządzenia, można znacznie ograniczyć zużycie energii, a co za tym...
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Hydrogen-enhanced degradation and oxide effects in zirconium alloys for nuclear applications
PublikacjaThe zirconium alloys used in nuclear industry include mainly ZreSn and ZreNb alloys ofdifferent chemical composition, microstructure and susceptibility to both hydrogendegradation and oxidation. The hypothetic nuclear accidents can create a real danger tothe Zr alloys and stability of parts made of these alloys, and especially such as loss ofcoolant accident (LOCA) and reactivity initiated accidents (RIA). The hydrogen degradationcan...
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Dynamics of Chains as a Tool to Study Thermomechanical Properties of Proteins.
PublikacjaPolymer dynamics can be formulated on different levels of detail. One approach eliminates microscopic degrees of freedom and a polymer molecule is represented by a simplified structure—a chain. In the simplest case monomers of ideal chain have fixed length, and their orientation is independent of the orientations and positions of neighbouring monomers. This is reason that two monomers can co-exist at the same place. Ideal chain...