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One-step synthesis of N-doped metal/biochar composite using NH3-ambiance pyrolysis for efficient degradation and mineralization of Methylene Blue
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Probing the binding selected metal ions and biologically active substances to the antimicrobial peptide LL-37 using DSC, ITC measurements and calculations
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Unusual and Conventional Dative Bond Formation by s2 Lone Pair Donation from Alkaline Earth Metal Atoms to BH3, AlH3, and GaH3
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Enhancing the Fresh and Early Age Performances of Portland Cement Pastes via Sol-Gel Silica Coating of Metal Oxides (Bi2O3 and Gd2O3)
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Anthropogenic enrichment of the chemical composition of bottom sediments of water bodies in the neighborhood of a non-ferrous metal smelter (Silesian Upland, Southern Poland)
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Determination of nicotine in saliva, urine and wastewater samples using tantalum metal organic framework pipette tip micro-solid phase extraction
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In Situ Micro-Observation of Surface Roughness and Fracture Mechanism in Metal Microforming of Thin Copper Sheets with Newly Developed Compact Testing Apparatus
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Multi-step functionalization procedure for fabrication of vertically aligned mesoporous silica thin films with metal-containing molecules localized at the pores bottom
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Thermodynamic properties of inorganic salt in nonaqeous solvents. IV. Apparent molar volumes and compressibilities of divalent transition-metal bromides and chlorides in acetonitrile
PublikacjaWykonano pomiary gęstości roztworów chlorków i bromków w acetonitrylu w temperaturze 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K oraz pomiar szybkości rozchodzenia się dźwięku w badanych roztworach w temperaturze 298.15 K. Uzyskane wartości pozwoliły wyznaczyć pozorne objętości molowe oraz pozorne adiabatyczne ściśliwości, których wartości oraz zmiany ze stężeniem tłumaczone są obecnością złożonych układów komplesów w roztworze.
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Biomimetic Metal- and Ammonium-Thiolate Systems: The First Crystalline Imidazolium Thiolate and Cadmium Silanethiolate Complexes with Imidazole and Imidazole-Derived Co-ligands
PublikacjaPrzeprowadzono analizę strukturalną i opisano badania spektroskopowe biomimetycznych tiolanów kadmu oraz tiolanów imidazoliowych.
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Synthesis of thiol derivatives of azobenzocrown ethers. The preliminary studies on recognition of alkali metal ions by gold nanoparticles functionalized with azobenzocrown and lipoic acid
PublikacjaThe article presents the synthesis of novel 13- and 16-membered azobenzocrown derivatives with peripheral thiol moieties and preliminary studies assessing their possible application in plasmonic sensors based on gold nanoparticles. The effect of the length of the chain connecting the macrocycle with the thiol group and the effect of the presence of the additional functional compound,...
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The chemistry of river–lake systems in the context of permafrost occurrence (Mongolia, Valley of the Lakes). Part I. Analysis of ion and trace metal concentrations
PublikacjaThis study provides a description of water chemistry in river–lake systems located in central Mongolia, at the borderline of permafrost occurrence. The analysis involved water samples collected from two river–lake systems: Baydrag River–Böön Tsagaan Lake system, and Shargalyuut/Tuyn Rivers–Orog Lake system. In the water samples, ions and trace elements were detected and quantified. Additionally, the parameters of pH, electrical...
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Influence of orientational disorder on the optical absorption properties in hybrid metal‐halide perovskite CH3NH3PbI3. A combined DFT/TD‐DFT and experimental study.
PublikacjaAn experimental and theoretical investigation is reported to analyze the relation between the structural and absorption properties of CH3NH3PbI3 in the tetragonal phase. More than 3000 geometry optimizations were performed in order to reveal the structural disorder and to identify structures with the lowest energies. The electronic structure calculations provide an averaged band gap of 1.674 eV, which is in excellent agreement...
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Formaldehyde detection with chemical gas sensors based on WO3 nanowires decorated with metal nanoparticles under dark conditions and UV light irradiation
PublikacjaWe report results of formaldehyde gas (CH2O) detection under dark conditions and UV light irradiation with pristine tungsten trioxide nanowires (WO3 NWs) and metal nanoparticles decorated WO3 NWs gas sensing layers. The resistive layers were deposited by one step aerosol assisted chemical vapor deposition (AACVD) on commercial alumina substrates with 10-pair interdigitated platinum electrodes. The elaborated gas sensors, based...
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Insightful Analysis of Phenomena Arising at the Metal|Polymer Interphase of Au-Ti Based Non-Enzymatic Glucose Sensitive Electrodes Covered by Nafion
PublikacjaThis paper focuses on the examination of glucose oxidation processes at an electrode material composed of gold nanoparticles embedded in a titanium template. Three dierent conditions were investigated: the chloride content in the electrolyte, its ionic conductivity and the presence of a Nafion coating. The impact of the provided environment on the oxidation reaction was evaluated by cyclic voltammetry (CV) and electrochemical impedance...
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Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix
PublikacjaWe report on a photocatalytic setup that utilizes the organic photosensitizer (PS) diiodo-BODIPY and the non-precious-metal-based hydrogen evolution reaction (HER) catalyst (NH4)2[Mo3S13] together with a polyampholytic unimolecular matrix poly(dehydroalanine)-graft-poly(ethyleneglycol) (PDha-g-PEG) in aqueous media. The system shows exceptionally high performance with turnover numbers (TON > 7300) and turnover frequencies (TOF...
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Group-9 Transition-Metal Suboxides Adopting the Filled-Ti2Ni Structure: A Class of Superconductors Exhibiting Exceptionally High Upper Critical Fields
PublikacjaTi2Ni and the related η-carbide structure are known to exhibit various intriguing physical properties. The Ti2Ni structure with the cubic space group Fd3̅m is surprisingly complex, consisting of a unit cell with 96 metal atoms. The related η-carbide compounds correspond to a filled version of the Ti2Ni structure. Here, we report on the structure and superconductivity in the η-carbide-type suboxides Ti4M2O with M = Co, Rh, and Ir....
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The New Klebsiella pneumoniae ST152 Variants with Hypermucoviscous Phenotype Isolated from Renal Transplant Recipients with Asymptomatic Bacteriuria-Genetic Characteristics by WGS.
PublikacjaKlebsiella pneumoniae (Kp) is one of the most important etiological factors of urinary tract infections in renal transplant (RTx) recipients. We described the antimicrobial susceptibility phenotypes and genomic features of two hypermucoviscous (HM) Kp isolates recovered from RTx recipients with asymptomatic bacteriuria (ABU). Using whole genome sequencing (WGS) data, we showed that the strains belong to the ST152 lineage with the...
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Efficacy of daratumumab monotherapy in real-world heavily pretreated patients with relapsed or refractory multiple myeloma
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Privacy-Preserving, Scalable Blockchain-Based Solution for Monitoring Industrial Infrastructure in the Near Real-Time
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POEMS Syndrome: Real World Experience in Diagnosis and Systemic Therapy - 108 Patients Multicenter Analysis
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Multi-core processing system for real-time image processing in embedded computer vision applications
PublikacjaW artykule opisano architekturę wielordzeniowego programowalnego systemu do przetwarzania obrazów w czasie rzeczywistym. Dane obrazu są przetwarzane równocześnie przez wszystkie procesory. System umożliwia niskopoziomowe przetwarzanie obrazów,np. odejmowanie tła, wykrywanie obiektów ruchomych, transformacje geometryczne, indeksowanie wykrytych obiektów, ocena ich kształtu oraz podstawowa analiza trajektorii ruchu. Ang:This paper...
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Investigations of methods to measure longitudinal forces in continuous welded rail tracks using the tamping machine.
PublikacjaPraca przedstawia w sposób poglądowy próby znalezienia efektywnej metody określania sił podłużnych w szynach toru bezstykowego. Szczególną uwagę poświęcono metodzie wymuszonych przemieszczeń poprzecznych. Podstawowym stwierdzeniem z przeprowadzonych własnych badań była konieczność odejścia od podnoszenia odłączonego od podkładów odcinka szyny i skoncentrowanie się na przemieszczeniach poprzecznych; doprowadziło to koncepcji zastosowania...
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Synthesis, biological activity and conformational analysis of head-to-tail cyclic analogues of LL37 and histatin 5
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Chemistry Innovations and Ideas from the Classroom to the Real World: The Students’ Perspective on Becoming a Chemistry Entrepreneur
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SELECTED PROBLEMS PERTAINING TO MODERNISATION OF LAND AND BUILDING RECORDS – DETERMINATION OF BOUNDARIES OF REAL ESTATE PLOTS
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Maritime awareness and emergency management real time system using remotely accessible GIS technology
PublikacjaPrzedstawiono koncepcję oraz prototyp morskiego GIS do zdalnego monitorowania w czasie rzeczywistym zanieczyszczeń środowiska morskiego. System pozwala na gromadzenie i integrowanie różnych typów danych dotyczących zanieczyszczeń, pozyskiwanych na bieżąco za pomocą wielorakiego rodzaju sensorów, w tym akustycznych (echosondy jednowiązkowe i wielowiązkowe). Zadaniem systemu jest wizualizacja oraz mapowanie zanieczyszczeń, takich...
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Expression and cellular distribution of estrogen and progesterone receptors and the real-time proliferation of porcine cumulus cells
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Privacy-Preserving, Scalable Blockchain-Based Solution for Monitoring Industrial Infrastructure in the Near Real-Time
PublikacjaThis paper proposes an improved monitoring and measuring system dedicated to industrial infrastructure. Our model achieves security of data by incorporating cryptographical methods and near real-time access by the use of virtual tree structure over records. The currently available blockchain networks are not very well adapted to tasks related to the continuous monitoring of the parameters of industrial installations. In the database...
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Determination of rectification corrections for semi gantry crane rail axes in the local 3D coordinate system
PublikacjaElectronic tacheometers are currently the standard instruments used in geodetic work, including also geodetic engineering measurements. The main advantage connected with this equipment is among others high accuracy of the measurement and thus high accuracy of the final determinations represented for example by the points’ coordinates. One of many applications of the tacheometers is the measurement of crane rail axes. This measurement...
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Wavelet-based denoising method for real phonocardiography signal recorded by mobile devices in noisy environment
PublikacjaThe main obstacle in development of intelligent autodiagnosis medical systems based on the analysis of phonocardiography (PCG) signals is noise. The noise can be caused by digestive and respiration sounds, movements or even signals from the surrounding environment and it is characterized by wide frequency and intensity spectrum. This spectrum overlaps the heart tones spectrum, which makes the problem of PCG signal filtrating complex....
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FPGA-Based Real-Time Implementation of Detection Algorithm for Automatic Traffic Surveillance Sensor Network
PublikacjaArtykuł opisuje sprzętową implementację w układzie FPGA algorytmu wykrywającego pojazdy, przeznaczonego do zastosowania w autonomicznej sieci sensorowej. Zadaniem algorytmu jest detekcja poruszających się pojazdów w obrazie z kamery pracującej w czasie rzeczywistym. Algorytm ma na celu oszacowanie parametrów ruchu ulicznego, takich jak liczba pojazdów, ich kierunek ruchu i przybliżona prędkość, przy wykorzystaniu sprzętu sieci...
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Real and imaginary motion classification based on rough set analysis of EEG signals for multimedia applications
PublikacjaRough set-based approach to the classification of EEG signals of real and imaginary motion is presented. The pre-processing and signal parametrization procedures are described, the rough set theory is briefly introduced, and several classification scenarios and parameters selection methods are proposed. Classification results are provided and discussed with their potential utilization for multimedia applications controlled by the...
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SiC-Based Power Electronic Traction Transformer (PETT) for 3 kV DC Rail Traction
PublikacjaThe design of rolling stock plays a key role in the attractiveness of the rail transport. Train design must strictly meet the requirements of rail operators to ensure high quality and cost-eective services. Semiconductor power devices made from silicon carbide (SiC) have reached a level of technology enabling their widespread use in traction power converters. SiC transistors oering energy savings, quieter operation, improved reliability...
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Dependence of Housing Real Estate Prices on Inflation as One of the Most Important Factors: Poland’s Case
PublikacjaThe study aimed to examine the impact of inflation on the real estate market using Polish panel data for the last 13 years. It is based on a panel model, where price changes of one square meter of housing are determined as a function in changes of inflation, the central bank's base rate, dwellings built, as well as new mortgage loans. The quarterly dynamics of the average price of 1 square meter of housing in...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublikacjaEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Estimation of the angular position of a two-wheeled balancing robot using a real IMU with selected filters
PublikacjaA low-cost measurement system using filtering of measurements for two-wheeled balancing robot stabilisation purposes has been addressed in this paper. In particular, a measurement system based on gyroscope, accelerometer, and encoder has been considered. The measurements have been corrected for deterministic disturbances and then filtered with Kalman, α-β type, and complementary filters. A quantitative assessment of selected filters...
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System do diagnostyki dermatofitowych zakażeń powierzchniowych oparty na technice Real-Time PCR
PublikacjaDermatofity należą do blisko spokrewnionej grupy grzybów, które wykazują wysokie powinowactwo do skeratynizowanych tkanek. Cecha ta czyni je odpowiedzialnymi za powierzchniowe grzybice skóry, paznokci oraz włosów. Szacuje się, iż nawet do 20% ludzi na całym świecie dotkniętych jest infekcjami powodowanymi przez dermatofity. Ich leczenie wymaga długotrwałego zastosowania leków przeciwgrzybiczych. W celu dobrania odpowiedniego leczenia...
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Fast Real-Time RDFT- and GDFT-Based Direct Fault Diagnosis of Induction Motor Drive
PublikacjaThis paper presents the theoretical analysis and experimental verification of a direct fault harmonic identification approach in a converter-fed electric drive for automated diagnosis purposes. On the basis of the analytical model of the proposed real-time direct fault diagnosis, the fault-related harmonic component is calculated using recursive DFT (RDFT) and Goertzel DFT (GDFT), applied instead of the full spectrum calculations...
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublikacjaThe proliferation of consumer-grade three-dimensional (3D) printers using fused deposition, also known as fused filament fabrication, has given rise to concerns over the exposure of users to potentially harmful substances. Thermoplastic filaments made of different polymers are extruded through a heated printer nozzle and deposited layer by layer on a build platform to form the printed object. This process leads to the emission...
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Highly stable CsFAPbIBr perovskite solar cells with dominant bulk recombination at real operating temperatures
PublikacjaMixed-cation mixed-halide perovskite solar cells have been characterized in DC at different temperatures (from −20 °C up to 50 °C) and the time evolution of the device efficiency has been assessed using different degradation protocols (indoors and outdoors). The completely planar p–i–n structure is ITO/CuNiOx/PTAA/CsFAPbIBr/PCBM/PEI/Ag. Pristine current–voltage characteristics barely show hysteresis, at any temperature. Open circuit...
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Real-time isothermal DNA amplification monitoring in picoliter volumes using an optical fiber sensor
PublikacjaRolling circle amplification (RCA) of DNA can be considered as a great alternative to the gold standard polymerase chain reaction (PCR), especially during this pandemic period, where rapid, sensitive, and reliable test results for hundreds of thousands of samples are required daily. This work presents the first research to date on direct, real-time and label-free isothermal DNA amplification monitoring using a microcavity in-line...
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Real-time monitoring of volatiles and particles emitted from thermoplastic filaments during 3D printing
PublikacjaPresentation on the use of instrumental analytical techniques for the assessment of emission of volatiles and particulates during fdm 3d printing.
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Comparative DEM calculations of fracture process in concrete considering real angular and artificial spherical aggregates
PublikacjaArtykuł omawia wyniki obliczeń numerycznych pękania dla betonu stosując metodę elementów dyskretnych (DEM). Beton był opisany jako materiał 4-fazowy i był poddany zginaniu. Zbadano wpływ kształtu kruszywa na proces pekania i na zalezność obciązenia od ugięcia. Wyniki dwuwymiarowe i trzywymiarowe porównano bezpośrednio z doświadczeniami. Wyniki pokazały duzy wpływ kształtu kruszywa na wyniki numeryczne.
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LIGHT POLLUTION IN THE CONTEXT OF THREATS TO THE WILDLIFE CORRIDORS
PublikacjaAccess to remote sensing night-time imagery allows for modeling of light pollution Increasingly, data on the propagation of artificial light are a source of interesting information for different fields of science and affect the planning of economic development. The article presents the problem of light pollution in the context of threats to the wildlife corridors in Poland. Wildlife corridors are areas that allow safe migration...
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9 - Solid oxide fuel and electrolysis cells
PublikacjaIn this chapter, the fundamental reactions, the geometrical designs, the material requirements, and the status of SOFCs and SOECs are presented. In the following seven chapters, the most important components of an SOC are described and the chapter ends with a summary and outlook. The described components are: (i) oxygen-ion conductors (electrolyte), (ii) anode materials for SOFCs (cathode in SOEC mode), (iii) cathode materials...
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Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance
PublikacjaThe paper discusses the synthesis, photoelectrochemical and electrochemical behaviour of titania nanotube arrays modified by a pyrolyzed metal-organic framework (MOF). A poly(3,4–ethylenedioxyphene) (PEDOT) matrix with an embedded inorganic network of iron hexacyanoferrate (BP) covering TiO2 nanotubes (TNT) is used as a MOF for the further sintering procedure, resulting in a novel, thin film of carbonaceous wrap supported Fe catalytic...
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Renal denervation achieved by endovascular delivery of ultrasound in RADIANCE-HTN SOLO or by radiofrequency energy in SPYRAL HTN-OFF and SPYRAL-ON lowers blood pressure
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Morpho-chemical characterization and source apportionment of potentially toxic metal(oid)s from school dust of second largest populous city of Pakistan
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Branched Poly(l-lysine)-Derived Nitrogen-Containing Porous Carbon Flake as the Metal-Free Electrocatalyst toward Efficient Oxygen Reduction Reaction
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