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wszystkich: 340
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Wyniki wyszukiwania dla: POLYCHLORINATED BIPHENYLS (PCBS)
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Identification of synergistic and antagonistic actions of environmental pollutants: Bisphenols A, S and F in the presence of DEP, DBP, BADGE and BADGE·2HCl in three component mixtures
PublikacjaEcosystems are facing increased pressure due to the emission of many classes of emerging contaminants. However, very little is known about the interactions of these pollutants, such as bisphenols (BPs), plasticizers or pharmaceuticals. By employing bioluminescent bacteria (Microtox assay), we were able to define interactions between selected emerging pollutants (namely BPA, BPS, BPF, BADGE, BADGE·2HCl, DEP, DBP) in ternary mixtures, at...
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Determination of polybrominated diphenyl ethers in house dust using standard addition method and gas chromatography with electron capture and mass spectrometric detection
PublikacjaMonitoring of the environmental fate of polybrominated diphenyl ethers (PBDEs) involves determination of their concentration in air, airborne particles and settled dust. This requires the implementation of appropriate analytical tools like measuring instruments, reference materials and analytical procedures. In this study an analytical procedure was developed for determining PBDEs in samples with a complex matrix composition. The...
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Wielopierścieniowe węglowodory aromatyczne (WWA), Polichlorowane bifenyle (PCB), Lotne związki organiczne (VOC),Pestycydy.
PublikacjaW raporcie (2 wersje językowe) przedstawiono wyniki badań dorzecza rzeki Odry w ramach Międzynarodowego Programu Badań Odry (IOP) realizowanego w okresie 1997-2000 przez 12 jednostek badawczych z Polski i Niemiec. Badania były finansowane przez Federalne Ministerstwo Edukacji i Badań oraz Fundację Współpracy Polsko-Niemieckiej. Badaniom poddawano próbki wody, osadów dennych oraz zawiesiny pobierane w trakcie 8 kampanii...
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Scenariusze emisji metali ciężkich, dioksyn i PCB w Europie do 2020 roku
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Scenariusze emisji metali ciężkich, dioksyn i PCB w Europie do 2020 roku
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Relationships between concentrations of selected organohalogen contaminants and thyroid hormones and vitamins A, E and D in Faroese pilot whales
PublikacjaPilot whales (Globicephala melas) from the Faroe Islands, North-East Atlantic, have high body concentrations of organohalogenated compounds (OHCs), such as polychlorinated biphenyls (PCBs), organochlorinated pesticides (OCPs) and brominated flame retardants (BFRs). The aim of the present study was to examine if and to what extent blood plasma and liver concentrations of several groups of these OHCs are related to concentrations...
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Application potential of dummy molecularly imprinted polymers as solidphase extraction sorbents for determination of low-mass polybrominated diphenyl ethers in soil and sediment samples
PublikacjaDespite the introduction of restrictive regulations in the USA and the European Union, polybrominated diphenyl ethers (PBDEs) are still found in various types of environmental and biological samples at significant concentration levels. The presence of these persistent organic pollutants in the environment raises important issues because of their negative impact on immunological and neurological systems, and on the hormonal balances...
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Towards a global historical emission inventory for selected PCB congeners - a mass balance approach. 3. An update
PublikacjaPoprzednie prace autorów zawierały bardzo istotne informacje do oceny stężeń związków polychlorobifenylowych (PCB) w rejonach oddalonych od dużych źródeł emisji tych związków jak i w środowisku globalnym. Okazało się, że niezbędna jest modyfikacja emisji PCB po roku 2000. Przedstawiono nowe dane o produkcji PCB w Polsce oraz nowe dane nt. składu chemicznego różnych produktów technicznych opartych na PCB. Ulepszono też metody oceny...
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Badanie i analiza anten PCB w zastosowaniu ich w urządzeniach o ograniczonych rozmiarach
PublikacjaNiniejsze opracowanie zawiera wyniki przeprowadzonych badań dotyczących drukowanych anten o niewielkich rozmiarach. Celem tych badań było wytypowanie anten pracujących w pasmie 868MHz, które mogłyby znaleźć zastosowanie w urządzeniach do monitorowania położenia osób w środowiskach zamkniętych.
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublikacjaA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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Current trends in analytical strategies for the determination of polybrominated diphenyl ethers (PBDEs) in samples with different matrix compositions – Part 2: New approaches to PBDEs determination
PublikacjaHerein, we review the latest technical solutions for polybrominated diphenyl ethers (PBDEs) determination in samples with different matrix compositions, largely focusing on gas chromatography but also presenting some liquid chromatography–based solutions. Moreover, we discuss the use of diverse sample injection techniques while considering the advantages and disadvantages of each injection system in the context of PBDEs analysis....
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Polybrominated diphenyl ether (PBDE) concentrations in dust from various indoor environments in Gdańsk, Poland: Prediction of concentrations in indoor air and assessment of exposure of adults
PublikacjaMonitoring of polybrominated diphenyl ethers (PBDEs) in indoor environments involves the determination of their concentrations in air, airborne particles, and settled dust. Each of these is a source of human exposure to PBDEs. In this study, we attempted to model PBDEs concentrations in various typical indoor environments on the basis of real PBDEs measurements in dust collected from them. The analytical procedure for determining...
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Thermal properties of a cement composite containing phase change materials (PCMs) with post-pyrolytic char obtained from spent tyres as a carrier
PublikacjaThis work examines the possible use of post-pyrolysis char made from spent vehicle tyres as a carrier for phase change materials (PCM), which could be used as an additive to cement mortar. Because of the ability of PCM to accumulate heat, the cement composite obtained from it, apart from its structural and strength properties, will acquire an additional energy storage function, which can be very important for energy-saving construction. In...
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Optimization of a Fabric Phase Sorptive Extraction protocol for the isolation of six bisphenols from juice pouches to be analysed by high performance liquid chromatography coupled with diode array detector
PublikacjaFabric Phase Sorptive Extraction (FPSE) combined with high pressure liquid chromatography using to diode array detection (HPLC-DAD) was applied for the simultaneous determination of bisphenols (BPA, BPB, BPC, BPE, BPF, BPS) in juice pouches. The FPSE procedure was optimized with regards to the critical parameters that affect the performance of the method including the selection of the FPSE membrane type and size, adsorption time,...
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Genetic diversity of Legionella pcs and pmtA genes and the effect of utilization of choline by Legionella spp. on induction of proinflammatory cytokines
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Current trends in analytical strategies for determination of polybrominated diphenyl ethers (PBDEs) in samples with different matrix compositions – Part 1.: Screening of new developments in sample preparation
PublikacjaPolybrominated diphenyl ethers (PBDEs) are ubiquitous compounds in the environment. Restrictions on the use of PBDEs introduced at the beginning of the 21st century have not eliminated these highly persistent and bioaccumulative compounds from the environment. Despite many existing regulations to control and phase out, extensive research on PBDEs is still necessary to fully evaluate the hazard their create to the environment. In...
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The preparation and evaluation of core-shell magnetic dummy-template molecularly imprinted polymers for preliminary recognition of the low-mass polybrominated diphenyl ethers from aqueous solutions
PublikacjaThe design, preparation process, binding abilities, morphological characteristic and prospective field of application of dummy-template magnetic molecularly imprinted polymer (DMMIP) for preliminary recognition of the selected low-mass polybrominated diphenyl ethers (PBDE-47 and PBDE-99) from aquatic environment were investigated. The surface of iron oxide (Fe3O4) nanopowder (50-100 nm particles size) was modified with tetraethoxysilane...
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Sea spray as a secondary source of chlorinated persistent organic pollutants? - Conclusions from a comparison of seven fresh snowfall events in 2019 and 2021
PublikacjaSecondary sources of persistent organic pollutants (POPs) gain in importance worldwide as primary sources decline. In this work, we aim to determine whether sea spray may be a secondary source of chlorinated POPs to the terrestrial Arctic, since a similar mechanism was proposed there only for the more water-soluble POPs. To this end, we have determined polychlorinated biphenyls and organochlorine pesticides concentrations in fresh...
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Bisphenol A analogues and metabolic syndrome in women with polycystic ovary syndrome
PublikacjaBisphenols (BPs) have become a chemical group of special interest due to their ability to interfere with the endocrine system and their ubiquitous presence in the environment. As some of them possess mild estrogenic and anti-androgenic effects, they might be associated with the diagnosis of polycystic ovary syndrome (PCOS). Acting on multiple tissues, BPs exposure may lead to metabolic derangements characteristic for metabolic...
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Validation of high-resolution 3D patient QA for proton PBS and IMPT using laser CT of improved polymer gel dosimeters
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Ti/TiO2 nanotubes sensitized PbS quantum dots as photoelectrodes applied for decomposition of anticancer drugs under simulated solar energy
PublikacjaOne of the challenges in research into photoelectrocatalytic (PEC) degradation of pollutants is finding the appropriate photoanode material, which has a significant impact on the process efficiency. Among all others, photoelectrodes based on an ordered TiO2 nanotube arrays are a promising material due to well-developed surface area and efficient charge separation. To increase the PEC activity of this material, the SILAR method was...
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Oznaczanie analitów z grupy WWA i PCB w próbkach wody. Źródła błędów, identyfikacja i oszacowanie ich wielkości.
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(2,2'-Bipyridine)bis(tri-tert-butoxysilanethiolato-kS)lead(II) and (4,7-diphenyl-1,10-phenanthroline-k2N,N')bis(tri-tert-butoxysilanethiolato-kS)lead(II) benzene hemisolvate
PublikacjaWyznaczono i opisano struktury rentgenowskie tytułowych związków. Atom ołowiu w obu przypadkach wykazuje koordynację typu zniekształconej piramidy kwadratowej o rdzeniu PbON2S2 w której jeden z atomów siarki leży w pozycji osiowej. Struktury są stabilizowane przez oddziaływania międzycząsteczkowe typu pi-pi oraz C-H...pi.
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Singlet Exciton Diffusion in Vacuum-Evaporated Films of Amine-Based Materials as Studied by Photocurrent and Photoluminescence Quenching Methods
PublikacjaThe singlet exciton diffusion lengths are determined by the photoconductivity as well as the luminescence surface quenching technique, in vacuum‐evaporated layers of (4,4′,4″‐tris(N‐(3‐methylphenyl)‐N‐phenylylamino) triphenylamine) (m‐MTDATA), 4,4′,4″‐tris[2‐naphthyl(phenyl)amino] triphenylamine (2TNATA), and N,N′‐diphenyl‐N,N′‐bis(3‐methylphenyl)‐[1,1′‐biphenyl]‐4,4′‐diamine (TPD) which are frequently used for fabrication of electroluminescent...
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Chemical composition of water from roof in Gdańsk, Poland
PublikacjaThis study deals with the assessment of roof runoff waters from the region of Gdansk collected during the winter season (2007/2008). The chemical analysis includes 16 chemical variables: major ions, PAHs and PCBs measured at 3 sampling sites for 6-14 rain events. Although the data set is of limited volume the statistical data treatment using self-organizing maps (SOM) reveals the main factors controlling roof runoff water quality...
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Expanded graphite assistant construction of gradient-structured char layer in PBS/Mg(OH)2 composites for improving flame retardancy, thermal stability and mechanical properties
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Assessment of cytotoxic and endocrine potential of selected xenobiotics commonly present in food products
PublikacjaMore and more increased intensity of anthropopressure processes can be observed, among other things, in the release of great quantities of synthetic substances into the environment, including the Endocrine Disrupting Compounds (EDC). A vast number of chemical substances is considered to belong to the this group, including substances which occur naturally in the environment, such as mycotoxins and phytoestrogens, and substances...
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A review of phase change materials and heat enhancement methodologies
PublikacjaPhase change materials (PCMs) are an efficient alternative to store and release heat at a specific range of temperature. Here PCMs and heat enhancement methodologies for PCM storage are reviewed. A short overview of PCMs and their applications is presented in addition to the progress during the last 10 years. Heat enhancement techniques, that is, extended surfaces, multiple and composite PCMs, and encapsulation techniques, are...
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Determination of POPs in environmental matrices - proficiency tests for Polish laboratories
PublikacjaKatedra Chemii Analitycznej Wydziału Chemicznego PG we współpracy ze Stowarzyszeniem RefMat oraz firmą LGC Promochem Sp. z o.o. prowadzi od 2003 roku wieloletni projekt badań biegłości laboratoriów. Celem badań jest określenie biegłości laboratoriów w zakresie oznaczania związków organicznych (anality z grupy PCB, WWA, pestycydy) w próbkach środowiskowych. W ramach projektu przeprowadzono dotychczas trzy badania biegłości dotyczące...
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A novel (Ti/Ce)UiO-X MOFs@TiO2 heterojunction for enhanced photocatalytic performance: Boosting via Ce4+/Ce3+ and Ti4+/Ti3+ redox mediators
PublikacjaTitanium-substituted cerium-oxo-based UiO MOFs with terephthalate linkers modified by various groups (–Br, –NH2, –NO2) or their derivatives (N-heterocyclic or biphenyl groups) were combined with titanium dioxide in a multistep route to obtain a core-shell-like architecture. DFT simulations showed that Ce- and bimetallic Ti/Ce- MOFs exhibited different charge compensation. Extended characterization revealed the formation of heterojunctions between...
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Surface sediments pollution due to shipwreck s/s “Stuttgart”: a multidisciplinary approach
PublikacjaShipwrecks may pose a serious source of pollution for marine ecosystems. For this reason, it is of great importance to perform a marine ecosystem risk assessment due to plausible wreck presence. One of elements of such an assessment is determining the state of the environment in the vicinity of the wreck. In the work presented, the results of studies on surface sediments samples collected around the s/s Stuttgart ship sunk during...
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The potential role of bisphenol A in the pathogenesis of polycystic ovary syndrome
PublikacjaPolycystic ovary syndrome (PCOS) is the most common endocrinopathy in women of reproductive age, that lead to infertility, type 2 diabetes and coronary heart disease. Bisphenol A (BPA) is one of the most abundant chemicals produced worldwide and is used as a plasticizer in daily life. Nowadays it is also well know that it can interact with estrogen receptors, androgen receptors and peroxisome proliferatoractivated receptors g (PPARg)....
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Electrostatic interactions in finite systems treated with periodic boundary conditions: Application to linear-scaling density functional theory
PublikacjaWe present a comparison of methods for treating the electrostatic interactions of finite, isolated systems within periodic boundary conditions (PBCs), within density functional theory (DFT), with particular emphasis on linear-scaling (LS) DFT. Often, PBCs are not physically realistic but are an unavoidable consequence of the choice of basis set and the efficacy of using Fourier transforms to compute the Hartree potential. In such...
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Visualizing Carotid Bodies With Doppler Ultrasound Versus CT Angiography: Preliminary Study
PublikacjaOBJECTIVE. The purpose of this article is to evaluate the utility of ultrasound in identifying carotid bodies (CBs) in patients with drug-resistant arterial hypertension. SUBJECTS AND METHODS. We enrolled 13 patients with drug-resistant hypertension into a trial for surgical CB excision. CT angiography (CTA) and Doppler ultrasound (DUS) of the cervical arteries were performed before surgery. CBs were identified in a blind manner...
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Integrating Statistical and Machine‐Learning Approach for Meta‐Analysis of Bisphenol A‐Exposure Datasets Reveals Effects on Mouse Gene Expression within Pathways of Apoptosis and Cell Survival
PublikacjaBisphenols are important environmental pollutants that are extensively studied due to different detrimental effects, while the molecular mechanisms behind these effects are less well understood. Like other environmental pollutants, bisphenols are being tested in various experimental models, creating large expression datasets found in open access storage. The meta‐analysis of such datasets is, however, very complicated for various...
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Pressure-induced flow processing behind the superior mechanical properties and heat-resistance performance of poly(butylene succinate)
PublikacjaWe propose a pressure-induced flow (PIF) processing method for the simultaneous enhancement of strength, toughness, and heat resistance of biodegradable poly(butylene succinate) (PBS). The pressure and temperature were systematically adjusted to optimize the tensile strength of PBS. Under the optimized processing conditions, the structured PBS was characterized by relatively high strength of 89.5 MPa, toughness of 21.4 kJ·m−2 ,...
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Searching for the primary metabolic alterations of polycystic ovary syndrome by application of the untargeted metabolomics approach
PublikacjaDespite a large number of studies, the pathogenesis of polycystic ovary syndrome (PCOS) still remains unexplained. In light of ambiguous observations reported in metabolomics, there is a need to carry out studies focusing on confirming the discriminating power of the proposed metabolomics biomarkers. Our research aimed to perform a validation study of metabolites detected in our previous study from serum samples, on the new set...
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Procesy i efektywność usuwania zanieczyszczeń z odcieków ze składowisk odpadów komunalnych w oczyszczalniach hydrofitowych
PublikacjaOczyszczanie odcieków z SOK jest jednym z najbardziej istotnych problemów ekologicznych na świecie. Odprowadzenie odcieków do oczyszczalni ścieków komunalnych jest przeważnie niemożliwe, ze względu na ich zmienną ilość oraz skład, bardzo wysokie stężenia ChZT i azotu amonowego, a także obecność trwałych zanieczyszczeń organicznych (TZO) oraz metali ciężkich. Najlepszym rozwiązaniem jest oczyszczanie wód odciekowych na terenie składowiska....
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Phase Change Thermal Energy Storage – The Experience of the Materials Preparation for the Specific Applications.
PublikacjaThermal energy storage and temperature stabilization is very important in many engineering applications. There are three kinds of thermal energy storage: sensible heat storage, latent heat storage and reversible chemical reaction heat storage. Phase change materials (PCM) absorb, store and release large amounts of energy in the form of latent heat, at constant temperature, called the transition temperature. The amount of heat...
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The Research of the Contamination Levels present in Samples of Precipitation and Surface Waters Collected from the Catchment Area Fuglebekken (Hornsund, Svalbard Archipelago)
PublikacjaPersistent organic pollutants (POPs) are contaminants that may appear in polar regions. In present work surface water was collected from the main stream water in the Fuglebekken basin. The precipitationsamples was collected from the near area by Polish Polar Station in Hornsund. The present investigationreveals the results of the analysis of these samples for their total phenols, formaldehyde, TOC, PAHs and PCBs content. The...
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Optymalizacja parametrów procesu izolacji trwałych zanieczyszczeń organicznych z osadów dennych z uwzględnieniem formy ich występowania w środowisku wodnym
PublikacjaW pracy przedstawiono wyniki badań dotyczących optymalizacji metodyki oznaczania związków z grupy PCB w próbkach osadów dennych wykorzystując 3 rozpuszczalniki różniące się siłą elucji, polarnością, temperaturą wrzenia oraz toksycznością: dichlorometan, toluen, heksan oraz 3 techniki ekstrakcji związków z grupy PCB z próbek osadów, różniące się m.in czasem ekstrakcji oraz "czynnikiem" wspomagającym ekstrakcję. W wyniku przeprowadzonych...
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New empirical correlations for the viscosity of selected organic phase change materials
PublikacjaAlthough there are many methods and instruments for measuring viscosity, it is still difficult to determine a reliable value of the dynamic viscosity of complex chemicals such as paraffins and fatty acids. This is due to the complex and heterogeneous structure of these compounds in the case of commercial products. On the other hand, the measuring instrument should be selected very carefully, including its measuring principle and...
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Serum bisphenol A concentrations correlate with serum testosterone levels in women with polycystic ovary syndrome
PublikacjaThe aim of this study was to determine serum bisphenol A (BPA) concentrations using high performance liquid chromatography with tandem mass spectrometry (HPLC–MS/MS) in women with polycystic ovary syndrome (PCOS) (n=106, age range 18–40 yrs) and to evaluate its potential impact on their hormonal and metabolic profile. The control group consisted of age- and BMI-matched 80 eumenorrheic women with no clinical or biochemical hyperandrogenism....
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Beeswax And Palmitic Acid Utilization With Heat Pipes For Electronics Cooling
PublikacjaThis paper presents an experimental study of heat pipes supported by phase change materials (PCMs) coated at their adiabatic sections in application for electronics cooling. The PCMs investigated in this research were palmitic acid and beeswax, the latter being considered as a more cost-effective alternative. The study focused on three powers: 20W, 25W, and 30W. The experimental results revealed that the incorporation of palmitic...
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Influence of the addition of citric acid on the physico-chemical properties of poly(sorbitol sebacate-co- butylene sebacate)
PublikacjaThe article presents the results of the physicochemical properties of poly(sorbitol sebacate- co-butylene sebacate) (PSBS) obtained with 0.25; 0.5; 0.75; 1 mol of citric acid (KC). It was shown that PSBS obtained with 0.25 and 0.5 mol KC is characterized by the most optimal mechanical and thermal properties. As a result of the study, it was found that the use of sorbitol and citric acid allows obtaining ester materials with...
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Solar light driven degradation of textile dye contaminants for wastewater treatment – studies of novel polycationic selenide photocatalyst and process optimization by response surface methodology desirability factor
PublikacjaThe unplanned anthropogenic activities and raced industrial revolution detrimentally causes serious threat to terrestrial and aquatic life. A high discharge of wastewater from industries using dyes affects living organisms and the environment. This paper presents studies on polycationic selenides (PCS) synthesized by hydrothermal methods for photocatalytic degradation of dyes. The synthesized PCS were confirmed by various characterization...
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Identyfikacja nieparametryczna systemów farmakokinetycznych metodą funkcji korelacji.
PublikacjaW pracy omówiono metodę funkcji korelacji, przedstawiono jej ograniczenia numeryczne oraz pobudzenia zapewniające maksymalną dokładność estymat odpowiedzi impulsowej w tej metodzie: szum biały oraz pobudzenia PRBS.
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Monitoring of organic pollutants in coastal waters of the Gulf of Gdańsk, Southern Baltic.
PublikacjaPrzedstawiono zmiany zawartości zanieczyszczeń organicznych (np. VOC, PAH, PCB, chlorofenoli) w wodach Zatoki Gdańskiej na przestrzeni 5-ciu lat. Zawartość VOX i VOC zmieniała się od kilku ngdm-3 do kilkuset ngdm-3, podczas gdy zawartość chlorofenoli fenoksykwasów była na poziomie kilku ngdm-3. W większości próbek nie wykryto PCB.
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Opinia techniczna torów na bocznicy kolejowej ANWIL S.A. we Włocławku. Nawierzchnia kolejowa z szyn typu S42 na podkładach strunobetonowych typu PBS-1, INBK 3, INBK 4, INBK 7, INBK 9 i na podkładach drewnianych typu IIIB z przytwierdzeniem pośrednim typu K
PublikacjaOpinia techniczna torów na bocznicy kolejowej ANWIL S.A. we Włocławku dotycząca oceny nawierzchni kolejowej z szyn typu S42 na podkładach strunobetonowych typu PBS-1, INBK 3, INBK 4, INBK 7, INBK 9 i na podkładach drewnianych typu IIIB z przytwierdzeniem pośrednim typu K
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Opinia techniczna torów na bocznicy kolejowej ANWIL S.A. we Włocławku. Nawierzchnia kolejowa z szyn typu S49 na podkładach strunobetonowych typu PBS-1, INBK 3, INBK 4, INBK 7, INBK 9 i na podkładach drewnianych typu IIB z przytwierdzeniem pośrednim typu K
PublikacjaOpinia techniczna torów na bocznicy kolejowej ANWIL S.A. we Włocławku dotycząca nawierzchni kolejowa z szyn typu S49 na podkładach strunobetonowych typu PBS-1, INBK 3, INBK 4, INBK 7, INBK 9 i na podkładach drewnianych typu IIB z przytwierdzeniem pośrednim typu K