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Chemical Vapor Transport Route toward Black Phosphorus Nanobelts and Nanoribbons
PublikacjaChemical vapor transport (CVT) method is widely used for bulk black phosphorus (BP) fabrication. In this work, we demonstrate that CVT provides a route for the fabrication of BP nanoribbons and nanobelts. This method consists of a two-step procedure, including initial BP column growth using the CVT technique, followed by ultrasonic treatment and centrifugation. The obtained nanostructures preserve BP column dimensions, forming...
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Mitigation of Fake Data Content Poisoning Attacks in NDN via Blockchain
PublikacjaAbstract—Information-centric networks struggle with content poisoning attacks (CPAs), especially their stronger form called Fake Data CPA, in which an intruder publisher uploads content signed with stolen credentials. Following an existing graphinfection based approach leveraging the constrained time when stolen credentials are useful, we design a blockchain-based mitigation scheme for Named Data Networking architectures. We postulate...
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Effect of Base-Connection Strength and Ductility on the Seismic Performance of Steel Moment-Resisting Frames
PublikacjaColumn-base connections in steel moment-resisting frames (SMFs) in seismic regions are commonly designed to develop the capacity of adjoining column with an intent to develop a plastic hinge in the column member, rather than in the connection (i.e., a strong-base design). Recent research has shown base connections to possess high ductility, indicating that this practice may be not only expensive but also unnecessary. This suggests...
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Catena-Poly[[(tetrahydrofuran-[kappa]O)lithium(I)]-bis([mu]-trimethylsilanolato-[kappa]2O:O)-gallium(III)-bis([mu]-trimethylsilanolato-[kappa]2O:O)-[(tetrahydrofuran-[kappa]O)lithium(I)]-[mu]-bromido]
PublikacjaThe title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane...
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Investigations on the removal of hydrophobic odorous volatile organic compounds by biotrickling filtration monitored with electronic nose
PublikacjaThe presented paper presents the results of research on the removal of selected hydrophobic volatile organic compounds (VOCs) from their mixture with air by means of a trickled-bed biofiltration. The efficiency of the removal of toluene and α-pinene, as model VOCs, in a three-section biotrickling filter is evaluated using GCFID and additionally monitored with an electronic nose. The results show that the removal of the model mixture...
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Application of fuzzy logic to determine the odour intensity of model gas mixtures using electronic nose
PublikacjaThe paper presents the possibility of application of fuzzy logic to determine the odour intensity of model, ternary gas mixtures (α-pinene, toluene and triethylamine) using electronic nose prototype. The results obtained using fuzzy logic algorithms were compared with the values obtained using multiple linear regression (MLR) model and sensory analysis. As the results of the studies, it was found the electronic nose prototype along...
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Air-sparged hydrocyclone (ASH) technology for separation and environmental clean-up
PublikacjaPrzedstawiono zastosowanie technologii wykorzystującej napowietrzany reaktor cyklonowy w oczyszczaniu środowiska. W pierwszych opracowaniach reaktora cyklonowego wykorzystano wkłady ze stali porowatej i polietylenu jako kontaktory fazy gazowej z ciekłą. Jako wynik badań nad rozwojem technologii wkłady porowate zostały zastąpione metalowymi siatkami, co wyeliminowało problem zatykania się elementów. Przeprowadzone badania laboratoryjne...
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Emissions of selected monoaromatic hydrocarbons as a factor affecting the removal of single-use polymer barbecue and kitchen utensils from everyday use
PublikacjaThe main focus of this study is the emission of monoaromatic hydrocarbons because these are the preliminary factors of potential solvent and monomer residues present in single-use plastic barbecue and kitchen utensils comprising polystyrene, polypropylene, natural cellulose, and biodegradable polymers intended for use with hot meal or beverages. Herein, the emissions of monoaromatic hydrocarbons (styrene, benzene, toluene, ethylbenzene,...
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Hybrid TiO2–Polyaniline Photocatalysts and their Application in Building Gypsum Plasters
PublikacjaHybrid materials of conjugated polymer and titanium(IV) oxide have attracted considerable attention concerning their potential benefits, including (i) ecient exploitation of visible light, (ii) a high adsorption capacity for organic contaminants, (iii) and eective charge carriers separation. The new class of the photocatalysts is promising for the removal of environmental pollutants in both aqueous and gaseous phases. For the first...
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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand
PublikacjaWe present two important trends in the reactivity ofthe titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}](MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph)with nucleophilic reagents RLi (R = Ph2P,tBuO, (Me3Si)2N, andtBu2N) depending on the reaction medium. Reaction in nonpolarsolvent (toluene) leads to three main products: via an autoredoxprocess and nucleophilic substitution at the Ti-atom to afford theTi(IV) complex [MeNacNacTi(R){η2-P-PtBu2}]...
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Badanie terenowe osiadania kolumny z kruszywa wykonanej w technologii wymiany dynamicznej
PublikacjaKolumny z kruszywa wykonane w technologii dynamicznej wymiany w gruntach organicznych. Badania osiadania pojedynczej kolumny w otoczeniu innych kolumn. Krzywa obciążenie-osiadanie przedstawiająca tempo stabilizacji osiadań pod wpływem stopniowego przykładania obciążenia.
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General route for the synthesis of terminal phosphanylphosphido complexes of Zr(IV) and Hf(IV): Structural investigations of the first zirconium complex with a phosphanylphosphido ligand
PublikacjaReactions of R2P-P(SiMe3)Li with [Cp2MCl2] (M = Zr, Hf) in hydrocarbons yield the related terminal phosphanylphosphidocomplexes [Cp2M(Cl){(Me3Si)P-PR2-jP1}] (R = iPr and tBu). The solid state structures of [Cp2M(Cl){P(SiMe3)-PiPr2-jP1}] (M = Zr, Hf) were established by single crystal X-ray diffraction studies. The phosphido-P atoms adopt almost planar geometries and the phosphanyl P atoms adopt pyramidal geometries. The reaction...
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Monitoring and efficiency assessment of biofilter air deodorization using electronic nose prototype
PublikacjaBiofiltration is one of the techniques used to reduce odorants in the air. It is based on the aerobic degradation of pollutants by microorganisms located in the filter bed. The research presents the possibility of using the electronic nose prototype for monitoring and efficiency assessment of air biofiltration. The study was conducted using model gas mixtures containing representatives of three groups of chemical compounds: n-hexane...
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KTaO3-based nanocomposites for air treatment
PublikacjaA series of single semiconductors and their nanocomposites combination (such as KTaO3 + CdSe + SrTiO3; KTaO3 + CdS +WO3; KTaO3 + CdS + MoS2) were prepared using hydrothermal route. Photocatalytic activity of as-prepared nanocomposites was estimated by photocatalytic degradation of toluene in the gas phase using light-emitting diodes (LEDs, 375 nm) in four subsequent cycles. The nanocomposites were characterized by scanning electron...
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Badania nad doborem najkorzystniejszego składu eluentu do rozdzielenia metabolitów wtórnych z grupy naftochinonów i flawonoidów z zastosowaniem chromatografii planarnej w normalnym i odwróconym układzie faz = A research on the composition of the eluent for separation of plant metabolities by reversed phase planar chromatography
PublikacjaIn the paper the results of separation of plant extracts by RP-TLC with different composition of the eluents are presented. Analysis of retention data allowed to select components of the eluent with favorable retention parameters, which can be used in the future for separation of this type of plant extracts by column liquid chromatography techniques.
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Bee Products and Essential Oils as Alternative Agents for Treatment of Infections Caused by S. aureus
PublikacjaBacteria of the genus Staphylococcus are important human and veterinary pathogens. A crucial characteristic for this group of bacteria is that they can easily acquire mechanisms of antibiotic resistance for a plethora of antibiotics currently in use for human and animal therapies. Therefore, there is a great need to find novel, non-antibiotic chemotherapeutics with marked antistaphylococcal activity. Promising but still underestimated...
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Wpływ konstrukcji mieszadła na prędkość cyrkulacji cieczy w wewnątrzobiegowym reaktorze kolumnowym z mieszaniem mechanicznym
PublikacjaBadano wpływ liczby i kształtu łopatek mieszadła śmigłowego na prędkość cyrkulacji cieczy w reaktorze airlift zbudowanym w dwóch współosiowych kolumn. Stwierdzono pomijalnie mały wpływ liczby łopatek w reaktorze ze strefą wznoszenia w przestrzeni pierścieniowej.
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Podchwycenie i wzmocnienie fundamentów kościoła św. Jana w Gdańsku metodą iniekcji strumieniowej
PublikacjaOpracowany i nadzorowany przez autora projekt zakładał podchwycenie fundamentów ścian nośnych i 6 filarów we wschodniej części kościoła poprzez układ kolumn sektorowych o kącie rozwarcia od 40 do 600, rozmieszczonych po obu stronach ścian.
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Effect of Laminar Pulsatile Fluid Flow on Separation of Volatile Organic Compounds from Aqueous Solution by a Hollow Fiber Membrane-Based Process
PublikacjaIn this study, a laminar pulsatile fluid flow was used for the separation of benzene, toluene, ethylbenzene, and xylene isomers (BTEX) from aqueous solutions. Polyether sulfone hollow fiber membrane has been applied to this process. The effects of BTEX concentration, and feed and extraction flow rates were examined. It was found that the application of the pulsatile fluid flow with...
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part I. On-line gas analyzers
PublikacjaThe paper reviews the subject literature concerning the analytical instruments routinely used for monitoring volatile organic compounds in atmospheric air. The analyzers are classified as stationary or mobile according to their ease of transport. Stationary DOAS (Differential Optical Absorption Spectroscopy) analyzer is characterized, as are MIMS (Membrane Introduction Mass Spectrometry), MESI (Membrane Extraction with Sorbent...
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Obtaining of coumarone-indene resins based on light fraction of coal tar 2. Coumarone-indene resins with epoxy groups
PublikacjaCoumarone-indene resins (CIR) with carboxy groups were synthesized via cooligomerization of unsaturated compounds presented in light fraction of coal tar and its fraction boiling out within 423–463 K with the addition of such industrial monomers as styrene, maleic anhydride, glycidyl methacrylate and methacrylic acid. 2,2`-Azobis(2-methylpropionitrile) in the form of 0.2 M solution in toluene was used as an initiator. The effect...
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On the Characteristic Graph of a Discrete Symmetric Channel
PublikacjaWe present some characterizations of characteristic graphs of row and/or column symmetric channels. We also give a polynomial-time algorithm that decides whether there exists a discrete symmetric channel whose characteristic graph is equal to a given input graph. In addition, we show several applications of our results.
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Chemical Derivatization Processes Applied to Amine Determination in Samples of Different Matrix Composition
PublikacjaAmines are important biological compounds, and so their analysis and monitoring in various matrices is worthy of investigation and development.Due to the polar nature of amines, chromatographic analysis of free amines is generally unsatisfactory owing to adsorption and decomposition of the solute on the column, resulting in peak tailing and losses. Therefore, many derivatization reactions are employed to reduce the polarity, improve...
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Experimental and numerical study on deformed steel columns subjected to impact load during earthquakes
PublikacjaThe soft-storey failure is one of the most typical types of damage observed in buildings during earthquakes. The failure of an upper soft storey of a structure results in large impact load acting on the lower floors and if the resistance of the structural members of the lower storeys is not sufficient it may further lead to progressive collapse of the whole building. The aim of the present paper is to investigate the dynamic behaviour...
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The effect of metal cluster deposition route on structure and photocatalytic activity of mono- and bimetallic nanoparticles supported on TiO2 by radiolytic method
PublikacjaTiO2 (P25) was modified with small and relatively monodisperse mono- and bimetallic clusters (Ag, Pd, Pt, Ag/Pd, Ag/Pt and Pd/Pt) induced by radiolysis to improve its photocatalytic activity. The as-prepared samples were characterized by X-ray fluorescence spectrometry (XRF), photoluminescence spectrometry (PL), diffuse reflectance spectroscopy (DRS), X-ray powder diffractometry (XRD), scanning transition electron microscopy (STEM)...
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Reactions of (Ph)tBuP-P(SiMe3)Li·3THF with [(PNP)TiCl2] and [MeNacNacTiCl2·THF]. Synthesis of first PNP titanium(IV) complex with phosphanylphosphinidene ligand [(PNP)Ti(Cl){η2-P-P(Ph)tBu}]
PublikacjaLithium derivative of diphosphane (Ph)tBuP-P(SiMe3)Li (1) was isolated for the first time and investigated in reactions with β-diketiminate (MeNacnac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2C6H3) and PNP-pincer (PNP = N[2-PiPr2-4-methylphenyl]2) Ti(III) complexes. The β-diketiminate titanium(III) complex containing phosphanylphosphido ligand [MeNacNacTi(Cl){η2-P(SiMe3)-P(Ph)tBu}] (2) was prepared in reaction of [MeNacNacTiCl2·THF]...
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Determination of tributyltin (TBT) in marine sediment using pressurised liquid extraction–gas chromatography–isotope dilution mass spectrometry (PLE–GC–IDMS) with a hexane–tropolone mixture
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Studies on Function of P-Glycoprotein in Photodynamic Therapy of Endometriosis
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“Dilute & Shoot” approach for rapid determination of trace amounts of nicotine in zero-level e-liquids by reversed phase liquid chromatography and hydrophilic interactions liquid chromatography coupled with tandem mass spectrometry-electrospray ionization
PublikacjaTwo analytical procedures are proposed where HILIC and RPLC techniques are coupled with tandem mass spectrometry detection for rapid determination of trace amounts of nicotine in zero-level liquids for electronic cigarettes. Samples are prepared on the basis of the approach “dilute & shoot” which makes this important step quick and not complicated. The chromatographic separation was carried out on a Zorbax XDB column (RPLC method)...
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Application of linear buckling sensitivity analysis to economic design of cylindrical steel silos composed of corrugated sheets and columns
PublikacjaThe paper deals with global stability of steel cylindrical silos composed of corrugated walls and vertical columns with loads imposed by a bulk solid following Eurocode 1. The optimum silo design with respect to the steel weight was based on a sensitivity analysis method. The changes of silo column profiles at each design step were performed by means of influence lines for the buckling load factor due to the unit column bending...
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Effect of initial imperfection on buckling of thin-walled I columns
PublikacjaEffects of initial geometrical imperfections on critical buckling loads of thin-walled I columns are investigated. Torsional and flexural buckling are taken into account. The column behaviour is described in accord to the theory of thin-walled beams with nondeformable cross-section. Some numerical examples and conclusions related to effects of imperfections on properties of the critical loads are presented.
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Influence of the Shear Cap Size and Stiffness on the Distribution of Shear Forces in Flat Slabs
PublikacjaThe scope of this paper is to investigate analytically and numerically the influence of shear cap size and stiffness on the distribution of shear forces in flat slabs in a slab–column-connections-reinforced concrete structure. The effect of support (shear cap) stiffness on the calculation of the length of the shear control perimeter according to the available methods is presented. Based on the analysis, the authors indicate in...
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Tiefreichende Bodenstabilisierung. Einsatz im Verkehrswegebau fuer Baugrundverbesserung und Gruendungen
PublikacjaPrzedstawiono ogólną klasyfikację metod wgłębnego mieszania gruntu na mokro oraz stosowane maszyny i głowice nieszające, uwzględniając systemy jedno i wielożerdziowe. Scharakteryzowano układy kolumn oraz obszary zastosowania tej technologii w inzynierii komunikacyjnej. Podano przykłady zastosowania przy budowie nasypu drogowego oraz posadowieniu podpór wiaduktu na słabym podłożu.
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Nowoczesne metody wzmacniania słabych gruntów dla bezpiecznego posadowienia dróg. Modern ground improvement methods for soft soils and safe road constructions.
PublikacjaW referacie przedstawiono ciekawsze i innowacyjne w skali polskiej i europejskiej rozwiązania geotechniczne, zastosowane w ciągu kilku ostatnich lat w Polsce. Przytoczone przykłady obejmują zastosowanie: geodrenów i przeciążenia, wibroflotacji i wibrowymiany, kolum żwirowych, mieszania wgłebnego gruntu na mokro oraz kolumn betonowych ze żwirową stopą.
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Determination of tributylotin (TBT) in marine sediment using pressurised liquid extraction-gas chromatography-isotope dilution mass spectrometry (PLE-GC-IDMS) with a hexane-tropolone mixture
PublikacjaOpracowano metodę oznaczania zawartości tributylocyny w próbkach osadu morskiego. Na etapie izolacji zastosowano technikę przyspieszonej ekstrakcji za pomocą roztworu tropolonu w heksanie.Na etapie oznaczeń końcowych wykorzystano technikę chromatografii gazowej, stosując metodę spektrometrii mas rozcieńczenia izotopowego. Wyznaczono parametry walidacyjne opracowanej metody: granicę wykrywalności, precyzję, poprawność i niepewność.
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Correlated electrons and transport in a quantum point contact and in a double-quantum-dot system
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Efficient Selenenylation of Malonates Using Bis(phosphorothioyl) Diselenide
PublikacjaBis(O,O-diisopropoxyphosphinothioyl) diselenide reacts readily and quickly with the sodium salt of malonates to give quantitatively stable sodium 2-(O,O-diisopropyl phosphorothioselenenyl)propanedioates. No traces of the corresponding C,C-diselenenylation products were detected. A standard aqueous workup procedure affords the products, albeit in poor yield (about 45%). It was proved that the reaction is reversible due to the presence...
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Application of microturbines in CHP systems with reciprocating engines
PublikacjaThe analysis was carried out for Combined Heat and Power generation systems with micro-turbines power plants working on heat rejected from the reciprocating engine. The calculations were performed for GE Jerbacher engines of J320 GS- C05, J320 GS- C25 and J416 GS- B05 types. We considered different working media (both wet and dry fluids): water, ammonia, ethanol, methanol, methylacetylene (propyne), dimethyloether, sulphur dioxide,...
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Catena-Poly[{[mu]-[eta]5:[eta]5-1-[2-(dimethylamino)ethyl-[kappa]N]cyclopentadienyl}-lithium(I)-([mu]-1,1,3,3-tetra-tert-butyltriphosphane-[kappa]3P2:P1,P3)lithium(I)]
PublikacjaThe title compound, [Li2(C9H14N)(C16H36P3)]n, is a by-product of the reaction of [Cp(C5H4CH2CH2NMe2)ZrCl2]n with tBu2P-P(SiMe3)Li in toluene. It is a coordination polymer composed of infinite chains running along [010]. One Li(I) atom is chelated by the cyclopentadienyl ring and and the N atom of the scorpionate ligand and a P atom, whereas the other Li(I) atom is coordinated by the backside of the cyclopentadienyl ring and two...
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Photocatalytic Decomposition of Air Pollutants using Electrodeposited Photocatalysts on Stainless Steel
PublikacjaThe aim of research was to develop an immobilization method for photocatalysts, which is an alternative to the sol-gel or dip coating methods and can be simply scaled up for technical applications. The investigated photocatalyst was TiO2, which was electrochemically deposited onto a cathode made of stainless steel. This deposited film was photocatalytically active. In order to enhance the photoactivity of the TiO2 film, commercially...
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Mobility and biodegradability of an imidazolium based ionic liquid in soil and soil amended with waste sewage sludge
PublikacjaSorption on solids and biodegradation are main phenomena that can mitigate the pollution of soil and water by ionic liquids (ILs). ILs sorbed on soil particles become immobilized (temporarily or permanently) which prevents them from spreading into deeper layers of soil or groundwater but which also makes them less bioavailable. In this study we attempt to examine if amendment of soil with waste sludge has a potential to mitigate...
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COMPUTER-AIDED CONSTRUCTION AT DESIGNING REINFORCED CONCRETE COLUMNS AS PER EC
PublikacjaThe article presents the author’s computer program for designing and dimensioning columns in reinforced concrete structures taking into account phenomena affecting their behaviour and information referring to design as per EC. The computer program was developed with the use of C++ programming language. The program guides the user through particular dimensioning stages: from introducing basic data such as dimensions, concrete...
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Separation of CO2 from biogas using absorption columns
PublikacjaBiogaz zawiera ok. 50-70% metanu, 30-40% di tlenku węgla oraz niewielkie ilości innych związków jak siarkowodór czy amoniaku. Dla uzyskania wysokokalorycznego gazu konieczne jest usunięcie ze strumienia di tlenku węgla. Praca opisuje potencjał użycia do tego celu kolumn absorpcyjnych oraz cieczy jonowych jako absorbenta
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Characteristics of calcium carbonate microparticles fabricated by the emulsion-emulsion technique in a large scale
PublikacjaReaktor zbudowany z dwóch współosiowych kolumn z mieszaniem w kolumnie wewnętrznej zastosowano do strącania cząstek węglanu wapnia metodą mieszania dwóch emulsji woda w oleju zawierających chlorek wapnia oraz węglan sodu jako reagenty. Zbadano wpływ częstości obrotów mieszadła, stężenia reagentów oraz czasu starzenia na wielkość cząstek stałych.
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Distortional buckling of thin-walled columns of closed quadratic cross-section
PublikacjaThe elastic stability of axially compressed column related to the cross-section distortion is investigated. Two kinds of closed quadratic cross-sections are taken into consideration with internal walls and without it. The governing differential equation is derived with aid of the principle of stationary total potential energy. The critical loads for the simply supported columns are found in an analytical form and compared with...
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The complexity of node blocking for dags
PublikacjaRozważamy następującą grę (pomiędzy dwoma graczami) kombinatoryczną o nazwie ''node blocking''. Dany jest graf skierowany. Każdy wierzchołek może być zajęty przez co najwyżej jeden token. Wyróżniamy dwa kolory tokenów, biały i czarny, każdy gracz może przemieszczać tylko własne tokeny. Gracze wykonują ruchy naprzemiennie. Ruch polega na wyborze dowolnego tokena własnego koloru i przesunięciu go na dowolnego niezajętego przez inny...
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A new simple approach to prepare rare-earth metals-modified TiO2 nanotube arrays photoactive under visible light: Surface properties and mechanism investigation
PublikacjaApplication of Ti90RE10 alloys (RE = Ho, Er, Nd, Y, Ce, Tm) as a working electrode, instead of Ti pure foil in anodic oxidation in a fluoride-based electrolyte, resulted in formation of well-ordered nanotubes made of TiO2 and RE2O3 mixture, which could be efficiently used for pollutant removal from water and air phase upon UV and visible irradiation and easily separable from the reaction mixture to recycle. The as-prepared NTs...
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Load-carrying capacity of axially loaded concrete-filled steel tubular columns made of thin tubes
PublikacjaAn experimental investigation was conducted on 30 CFST columns. An influence of the following factors on load-carrying capacity of the investigated columns was analyzed: the column slenderness (l1 = 42, l2 = 27 and l3 = 15), the tube thickness (the reinforcement ratio was equal to 4% or 6%), the way of applying the load to CFST columns (through the concrete core or through the entire cross-section), the bond strength between a...
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Preparatywna i procesowa chromatografia cieczowa.
PublikacjaOpisano znaczenie stosowania wysokosprawnej chromatografii cieczowej (P-HPLC) do rozdzielania i otrzymywania substancji. Podano rodzaje problemów rozdzielczych których rozwiązaniem jest odpowiednia kolumnowa chromatografia cieczowa. Przedstawiono zasady postępowania, zapewniające maksymalizację efektywności otrzymywania substancji z zastosowaniem P-HPLC. Opisano wymagania wobec kolumny chromatograficznej a szczególnie profilu przepływu...
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The First Dinuclear Nickel(II) Thiosulfate Obtained From Oxidation of Tri-tert-butoxysilanethiol. Contributions to the Chemistry of Silicon-Sulfur Compounds No. 78[1]
PublikacjaPrezentowany związek {[Ni2(μ-S2O3)2(C7H9N)4-H2O]C7H8} (1) jest pierwszym tiosiarczanem metalu otrzymanym w wyniku utlenienia silanotiolu. Mechanizm tej reakcji zakłada powstawanie (RO)3SiSSSi(OR)3 jako jako produktu pośredniego. Bimetaliczny związek niklu(II) posiada dwie reszty tiosiarczanowe pełniące rolę liganda zarówno -S,O chelatującego jak i S-mostkującego łączącego oba centra metaliczne. Związek krystalizuje jako dimer z...