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Abuse or contamination? Ratio determination of clenbuterol enantiomers to distinguish between doping use and meat contamination
PublikacjaClenbuterol has been detected in urine of several athletes during routine doping control in the past years. Athletes claimed that the clenbuterol was ingested by eating contaminated meat. Providing analytical prove for this claim is difficult. clenbuterol consists of two enantiomers, R(-) and S(+)-clenbuterol. Currently available human and veterinary preparations were found to consist of a racemic mixture of both enantiomers. When...
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Influence of microwave treatment conditions of GTR on physico-mechanical and structural properties of NBR/NR/GTR composites
PublikacjaThe increasing amount of tires used in the industry induces the researchers to find alternatives to the recycling of the end-of-life tires. Several alternatives in order to application of ground tire rubber GTR include their incorporation as a filler in composites. The main issue in this approach is the lack of compatibility between GTR and polymer matrix. In order to solve this problem the devulcanization by microwaves has been...
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Evaluation of structural change during fast transformation process of cross-linked NR into liquid NR by light pyrolysis
PublikacjaThe presence of cross-linked networks in rubber creates a tremendous problem for recycling and reusing of waste rubber. Fast transformation of cross-linked natural rubber (NR) into liquid natural rubber was carried out by light pyrolysis in temperature range from 240 to 300 °C in variable time (in range: 1–30 min). The transformation efficiency was evaluated by measuring the sol fraction and the cross-link density of the gel fraction....
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Interfacial adhesion evaluation in (low-density polyethylene)/elastomer blends
PublikacjaLow-density polyethylene (LDPE) with different elastomers at a ratio of 50/50 wt% blends was prepared by using a co-rotating twin-screw extruder. Three kinds of elastomers were used: ground tire rubber (GTR), partially crosslinked butyl rubber (KalarVR ), and styrenebutadiene- rubber block copolymer (SBS; KratonVR ). For better characterization of interaction between polyethylene and elastomer, influence of the type of elastomer on...
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An approach to evaluation of arguments in trust cases
PublikacjaTrustworthiness of IT systems can be justified using the concept of a trust case. A trust case is an argument structure which encompasses justification and evidence supporting claimed properties of a system. It represents explicitly an expert's way of assessing that a certain object has certain properties. Trust cases can be developed collaboratively on the basis of evidence and justification of varying quality. They can be complex...
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Progress in used tyres management in the european union: a review
PublikacjaThe dynamic increase in the manufacture of rubber products, particularly those used in the automobile industry, is responsible for a vast amount of wastes, mostly in the form of used tyres, of which more than 17 million tonnes are produced globally each year. The widely differing chemical compositions and the cross-linked structures of rubber in tyres are the prime reason why they are highly resistant to biodegradation, photochemical...
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Risks related to car fire on innovative Poroelastic Road Surfaces-PERS
PublikacjaTo reduce tyre/road noise, the concept of poroelastic road surfaces (PERS) was invented. PERS is a road surface material that is porous, and at the same time, it is flexible because of the substantial amount of rubber granulate content (from 20% to 85%). The rubber and stone particles are bound by polyurethane resin instead of bitumen. It was feared that in case of fire, because of the high content of rubber and polyurethane, there...
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Evaluation and rationale of the performance of several elastomeric composites incorporating devulcanized EPDM
Publikacjathylene Propylene Diene rubber (EPDM), is present in many applications. However, its crosslinked structure makes difficult its recycling. The use of devulcanized EPDM, (dEPDM) as a component of elastomeric composites, is a real possibility to reuse EPDM scraps. In this study, three matrices (natural rubber (NR), styrene butadiene rubber (SBR) and EPDM rubber) have been tested including devulcanized EPDM as a recycled component....
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Novel investigation of pyrolysis mechanisms and kinetics for functional groups in biomass matrix
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In-situ oxidative degradation of sulfamethoxazole by calcium peroxide/persulfate dual oxidant system in water and soil
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Enrichment and distribution of trace elements in Padhrar, Thar and Kotli coals from Pakistan: Comparison to coals from China with an emphasis on the elements distribution
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A comprehensive review of biogeochemical distribution and fractionation of lead isotopes for source tracing in distinct interactive environmental compartments
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Impact of Large-scale urban interventions on contemporary city centers. Gdansk case study. Wpływ przedsiewzięć urbanistycznych dużej skali na centra miast. Studium przypadku Gdańska
PublikacjaLarge scale urban interventions have become a common development practice in cotemporary cities, allowing achieving rapid changes in their urban structure. They can be analyzed taking into account various perspectives. Some of them include planning and development models, transformation of brownfields and other types of distressed urban areas, as well as consequences and results of their implementation in existing urban structures....
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Buck-Boost Inverters with Symmetrical Passive Four-terminal Networks
PublikacjaAlternating Voltage Inverters (Converters) supplied by low-voltage sources DC (ex. fuel cell, photovoltaic cell) are most frequently realized on the basis of the three fundamental topologies: a) PWM voltage inverter with boost-converter" system, b) PWM voltage inverter with transformed converter DC/DC in the ,,boost-converter" system, c) PWM current converter. However none of these solutions is claimed to be the best and dominant...
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Innovation in the strategies of Polish provinces - a comparative study of selected cases
PublikacjaMany strategic management theorists and practitioners believe that the implementation of innovation is one of the key factors determining the company success and show the relationship between long-term innovation strategy and business development strategy. It has also been claimed that similar strategies should be developed for each unit of public administrationMinistry of Economy has set National Development Strategy 2007-2015...
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Functional Safety and Cybersecurity Analysis and Management in Smart Manufacturing Systems
PublikacjaThis chapter addresses some of the issues of the integrated functional safety and cybersecurity analysis and management with regard to selected references and the functional safety standards: IEC 61508, IEC 61511, ISO 13849-1 and IEC 62061, and a cybersecurity standard IEC 62443 that concerns the industrial automation and control systems. The objective is to mitigate the vulnerability of industrial systems that include the information...
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Prediction of the fatigue lifetime of PUR structural elements using a combined experimental-numerical approach
PublikacjaThis paper presents a method for estimating the fatigue life of polyurethane elastomeric components. A rubber replacement - polyurethane of hardness 80ShA commonly used in vibration damping systems, for example, in motor vehicle suspensions, was used for the study. A metal-rubber bushing component was selected for analysis, and numerical analysis was carried out along with a fatigue model proposal based on a modification of the...
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Impact and stretching standardized tests as useful tools for assessment of viscoelastic behavior for highly rubberized asphalt binder
PublikacjaAsphalt binder is generally identified as a brittle material at low service temperature or under high-speed load, and the brittleness becomes serious after weathering aging. Improving the toughness of asphalt binder through adding high-content of crumb tire rubber is an efficient method to solve this problem. Devulcanized rubber modified asphalt binder (DRMA) with different contents (15–40%) of devulcanized rubber (DR) were prepared...
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Poroelastic Road Surfaces - State of The Art
PublikacjaPoroelastic Road Surfaces (PERS) constitute a specific group of pavements containing a great amount of crumbled rubber. In most cases rubber aggregate constitutes about 20% of the mixture (by weight) and a polyurethane resin is used as a binder. As a result, PERS is characterized by a much higher elasticity than asphalt and a high porosity typical for drainage pavements. Due to this, tire/road noise is greatly reduced and on top...
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The origins of the brick architecture in Pomerania
PublikacjaTraditionally, brick is one of the most popular building materials on the southern coast of the Baltic Sea. Although the origins of brick architecture have been the subject of numerous research studies, their results were focused on the Kingdom of Denmark, merchant-towns and the State of the Teutonic Order. Most scholars claimed that Pomeranian architecture had not been as developed as that in the neighbouring countries. Moreover,...
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Chromium-Catalyzed CO2–Epoxide Copolymerization
PublikacjaIminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.
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Thermoplastic Elastomers Filled With GTR
PublikacjaIn recent years, searching for new and cost-effective methods of recycling waste tires has been a subject of research in many laboratories worldwide. This is due to regulations in the law and environmental factors, which have both stimulated industry to re-use high quality rubber found in ground tire rubber (GTR). One of the most promising solutions in this area seems to be thermoplastic elastomers (TPEs) filled with GTR, which...
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Modyfikacja kompozytów elastomerowych NR za pomocą ligniny i glicerolizatu
PublikacjaPrzedmiotem opisanych w niniejszym artykule badań są wulkanizaty kauczuku naturalnego. Celem pracy było zbadanie wpływu ligniny oraz glicerolizatu na wybrane właściwości kompozytów zawierających kauczuk naturalny. Strukturę chemiczną przygotowanych materiałów potwierdzono, wykorzystując analizę spektroskopową w podczerwieni (FTIR). Zbadano również właściwości mechaniczne przy statycznym rozciąganiu, twardość, ścieralność oraz odbojność...
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Pyrolysis Process of Whole Waste Tires as a Biomass Energy Recycling
PublikacjaThe article is devoted to the description of material recycling of whole waste tires, including a new method of pyrolysis process, resulting in the final products: technically oil fractions (rubber plasticizer of rubber compounds) or diesel fuels (light, medium and heavy), activated carbon, gas fuel and steel scrap. Operational and performance tests of the first version of the pilot plant, consisting of three contributions cooperating...
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Maturity Mismatch in the Polish Banking System and its Impact on the Economy
PublikacjaIn the article maturity mismatch in the Polish banking system is estimated based on the publicly available data. Then the impact on the economy is discussed. Based on Polish central bank’s data it may be estimated that between 1996 and 2012 the maturity gap increased significantly – average residual maturity of assets exceeds 6 years in 2012 (less than 2 years in 1996), while that of liabilities remains below 1 year. The gap...
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Synchrotron radiation photoemission spectroscopy of the oxygen modified CrCl3 surface
PublikacjaWe investigate the experimentally challenging CrCl3 surface by photon energy dependent photoemission (PE). The core and valence electrons after cleavage of a single crystal, either in a ultrahigh vacuum (UHV) or in air, are studied by keeping the samples at 150 1C, aiming at confirming the atomic composition with respect to the expected bulk atomic structure. A common spectroscopic denominator revealed by data is the presence of...
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GTR/Thermoplastics Blends: How Do Interfacial Interactions Govern Processing and Physico-Mechanical Properties?
PublikacjaIn this work, GTR/thermoplastics blends (in ratio 50/50 and 75/25 wt.%) were prepared by melt-compounding in an internal mixer. During research, trans-polyoctenamer rubber (TOR), ethylene-vinyl acetate copolymer (EVA), ethylene-octene copolymer (EOC), and linear low-density polyethylene (LLDPE), were used in their thermoplastic phase. Microstructure and processing-performance property interrelationships of the studied materials...
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A systematic review on global pollution status of particulate matter-associated potential toxic elements and health perspectives in urban environment
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Synergistic effects of biochar and processed fly ash on bioavailability, transformation and accumulation of heavy metals by maize (Zea mays L.) in coal-mining contaminated soil
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Recent advances in carbon-based renewable adsorbent for selective carbon dioxide capture and separation-A review
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Environmental transformation and nano-toxicity of engineered nano-particles (ENPs) in aquatic and terrestrial organisms
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Effects of biochar on uptake, acquisition and translocation of silver nanoparticles in rice (Oryza sativa L.) in relation to growth, photosynthetic traits and nutrients displacement
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Enrichment of Bi-Be-Mo-Cd-Pb-Nb-Ga, REEs and Y in the Permian coals of the Huainan Coalfield, Anhui, China
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Investigating the biochar effects on C‐mineralization and sequestration of carbon in soil compared with conventional amendments using the stable isotope (δ13C) approach
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Biochar-mediated transformation of titanium dioxide nanoparticles concerning TiO2NPs-biochar interactions, plant traits and tissue accumulation to cell translocation
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Reply to “Enrichment of Bi-Be-Mo-Cd-Pb-Nb-Ga, REEs and Y in the Permian coals of the Huainan Coalfield, Anhui, China: Discussion”
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Combustion characteristics and retention-emission of selenium during co-firing of torrefied biomass and its blends with high ash coal
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The chapter analyses the K-Means algorithm in its parallel setting. We provide detailed description of the algorithm as well as the way we paralellize the computations. We identified complexity of the particular steps of the algorithm that allows us to build the algorithm model in MERPSYS system. The simulations with the MERPSYS have been performed for different size of the data as well as for different number of the processors used for the computations. The results we got using the model have been compared to the results obtained from real computational environment.
PublikacjaThe chapter analyses the K-Means algorithm in its parallel setting. We provide detailed description of the algorithm as well as the way we paralellize the computations. We identified complexity of the particular steps of the algorithm that allows us to build the algorithm model in MERPSYS system. The simulations with the MERPSYS have been performed for different size of the data as well as for different number of the processors used...
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Dissociative electron attachment to the radiosensitizing chemotherapeutic agent hydroxyurea
PublikacjaDissociative electron attachment to hydroxyurea was studied in the gas phase for electron energies ranging from zero to 9 eV in order to probe its radiosensitizing capabilities. The experiments were carried out using a hemispherical electron monochromator coupled with a quadrupole mass spectrometer. Diversified fragmentation of hydroxyurea was observed upon low energy electron attachment and here we highlight the major dissociation...
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Numerical study on seismic response of a base-isolated building modelled with shell elements
PublikacjaSeismic isolation is counted among the most popular and effective means of protecting structures against earthquake forces. Base isolators, like Lead-Rubber Bearings (LRB), High-Damping Rubber Bearings (HDB) or Friction Pendulum Systems (FPS) are extensively used in practice in many earthquake-prone regions of the world. The present paper reports the results obtained from the numerical study on seismic response of a base-isolated...
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Domination subdivision and domination multisubdivision numbers of graphs
PublikacjaThe domination subdivision number sd(G) of a graph G is the minimum number of edges that must be subdivided (where an edge can be subdivided at most once) in order to increase the domination number of G. It has been shown [10] that sd(T)<=3 for any tree T. We prove that the decision problem of the domination subdivision number is NP-complete even for bipartite graphs. For this reason we define the domination multisubdivision number...
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Marine traffic risk modelling – an innovative approach and a case study
PublikacjaThis paper presents a model to analyse the risk of two common marine accidents: collision and grounding. Attention is focused on oil tankers since they pose the highest environmental risks. A case study in selected areas of the Gulf of Finland in ice-free conditions is presented. The model utilizes a formula for risk calculation that considers both the probability of an unwanted event and its consequences. The model can be decomposed...
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Polymeric Bearings – A New Base Isolation System to Reduce Structural Damage during Earthquakes
PublikacjaBase isolators, like lead rubber bearings, high damping rubber bearings or friction pendulum systems are extensively used in practice in many seismically active regions to protect structures against earthquake forces. The present paper reports the results obtained from the experimental study aimed to determine the effectiveness of the Polymeric Bearings in suppressing structural vibrations during dynamic excitations and therefore...
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Influence of magnetic interaction on lattice dynamics of FeBO 3
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Synergistic effects of low-/medium-vacuum carbonization on physico-chemical properties and stability characteristics of biochars
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In situ synthesis of micro-plastics embedded sewage-sludge co-pyrolyzed biochar: Implications for the remediation of Cr and Pb availability and enzymatic activities from the contaminated soil
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Compositional characteristics of black-carbon and nanoparticles in air-conditioner dust from an inhabitable industrial metropolis
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Biomonitoring and health risks assessment of trace elements in various age- and gender-groups exposed to road dust in habitable urban-industrial areas of Hefei, China
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Hydrothermal dewatering of low-rank coals: Influence on the properties and combustion characteristics of the solid products
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A comprehensive review on environmental transformation of selenium: recent advances and research perspectives
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