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Wyniki wyszukiwania dla: COBALT OXYHYDROXIDE
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Badania spektroskopowe wybranych silanotiolanów kobaltu(II)
PublikacjaPodjęto próby otrzymania i scharakteryzowania tri-tert-butoksysilanotiolanowych kompleksów kobaltu(II), mogących spełnić rolę biomimetyków dla centrów katalitycznych wybranych metaloprotein. Przedstawiono wyniki analizy strukturalnej otrzymanych kompleksów uzyskanych z wykorzystaniem metod spektroskopii UV-vis i FT-IR zarówno dla roztworów jak i w ciele stałym. Skonfrontowano je z danymi uzyskanymi metodą analizy rentgenostrukturalnej...
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Coal International
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Coal Conversion
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Design of OFDM-based radio communication systems for coast-to-sea and coast-to-air propagation environments
PublikacjaIn the paper the study of radio communication system design process for systems based on OFDM transmission is considered. The signal propagation model for 1.4 GHz frequency band is discussed, and the study of signal propagation characteristics, important from the point of view of OFDM system design, is presented. The methodology of OFDM interface design is proposed and some characteristics of the OFDM-based radio communication...
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Selectivity of Mixed Iron-Cobalt Spinels Deposited on a N,S-Doped Mesoporous Carbon Support in the Oxygen Reduction Reaction in Alkaline Media
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Effect of cobalt addition on the corrosion behaviorof near equiatomic NiTi shape memory alloy in normal saline solution: electrochemical and XPS studies
PublikacjaThe electrochemical and corrosion (uniform and localized) behavior of a binary Ni52Ti48 shape memory alloy (SMA) and two ternary Ni52Ti48-xCox (x = 1.5 and 4.0 wt.%) SMAs were studied. Measurements were conducted in 0.9% NaCl solution at 37 oC employing various electrochemical methods. These include: linear polarization resistance (LPR), linear sweep voltammetry (LSV), chronoamperometry and dynamic electrochemical impedance spectroscopy...
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Structural Variety of Cobalt(II), Nickel(II), Zinc(II), and Cadmium(II) Complexes with 4,4′-Azopyridine: Synthesis, Structure and Luminescence Properties
PublikacjaSelf-assembled bi- and polymetallic complexes of CoII, NiII, ZnII, and CdII were obtained by the reaction of 4,4′-azopyridine (azpy) with metal tri-tert-butoxysilanethiolates (Co, 1; Cd, 2), acetylacetonates (Ni, 3; Zn, 4), and acetates (Cd, 5). All compounds were characterized by single-crystal X-ray structure analysis, elemental analysis, FTIR spectroscopy, and thermogravimetry. Complexes 1, 2 and 4, 5 exhibit diverse structural...
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Iminodiacetate complex of cobalt(II) – Structure, physicochemical characteristics, biological properties and catalytic activity for 2-chloro-2-propen-1-ol oligomerization
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Tuning Cu-Content La1−xSrxNi1−yCuyO3−δ with Strontium Doping as Cobalt-Free Cathode Materials for High-Performance Anode-Supported IT-SOFCs
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3D mesoporous α-Co(OH)2 nanosheets electrodeposited on nickel foam: A new generation of macroscopic cobalt-based hybrid for peroxymonosulfate activation
PublikacjaCobalt-based catalysts with high stability and facile recovery for heterogeneous peroxymonosulfate (PMS) activation are still rather sparse and therefore highly desirable. Herein, 3D mesoporous α-Co(OH)2 nanosheets was created on robust nickel foam (NF) via facile electrodeposition approach at 6 mA/cm2 for only 400 s. Almost complete removal of phenol can be achieved within 7 min with a degradation rate of 0.39 min−1, 2 times higher...
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Investigation of cationic distribution, Y–K angles, and optical and dielectric properties of as-synthesized cerium-doped cobalt nano-ferrites prepared by co-precipitation method
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Fast determination of bisphenol A in spiked juice and drinking water samples by pipette tip solid phase extraction using cobalt metal organic framework as sorbent
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SIMPLY AND LOW COAST ELECTROMYOGRAPHY SIGNAL AMPLIFIER
PublikacjaRecently, there has been a noticeable increase in interest in solu tions utilizing electrical signals accompanying muscle activity. Electromyography (EMG) is a technique for recording, analysis and evaluating the electrical activity produced by striated muscle. Its great popularity is due, among other, to the ability to measure with non-invasive electrodes (calle d as sEMG surface electromyography)....
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Correction to: Investigation of cationic distribution, Y–K angles, and optical and dielectric properties of as-synthesized cerium-doped cobalt nano-ferrites prepared by co-precipitation method
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Manganese–Cobalt Based Spinel Coatings Processed by Electrophoretic Deposition Method: The Influence of Sintering on Degradation Issues of Solid Oxide Cell Oxygen Electrodes at 750 °C
PublikacjaThis paper seeks to examine how the Mn–Co spinel interconnect coating microstructure can influence Cr contamination in an oxygen electrode of intermediate temperature solid oxide cells, at an operating temperature of 750 °C. A Mn–Co spinel coating is processed on Crofer 22 APU substrates by electrophoretic deposition, and subsequently sintered, following both the one-step and two-step sintering, in order to obtain significantly...
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Amine–alkyl derivatives of hydantoin: New tool to combat resistant bacteria
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Enrichment and distribution of trace elements in Padhrar, Thar and Kotli coals from Pakistan: Comparison to coals from China with an emphasis on the elements distribution
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The X-ray crystallographic structures, spectral and magnetic properties of nickel(II), copper(II) and cobalt(II) complexes with tetra(3-iso-propylpyrazol-1-yl)borate
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Clean Coal Technology
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Coal Science and Technology
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Anisakids of seals found on the southern coast of Baltic Sea
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Maritime heritage of small port towns of the Polish coast
PublikacjaThe article describes problems of the gradual disappearance of real maritime heritage in small Polish port cities. The maritime heritage of small port cities was shaped by coastal processes and urban historical conditions what has led to creation of specific types of landscapes. Special architectural objects of the post-port heritage of small ports of the Polish coast are hydrotechnical constructions (i.e. breakwaters, quays),...
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Koncert Jazzowy – New Coast
WydarzeniaKoncert jazzowy zespołu „New Coast”, który po blisko 30 latach wróci na scenę klubu Kwadratowa. Koncert będzie zamknięciem jubileuszu 60-lecia klubu.
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Programmes to Combat the Economic Impact of the COVID-19 Pandemic in Kazakhstan and Ukraine and Unemployment
PublikacjaThe following article presents economic programmes to combat the negative effects of the COVID-19 pandemic. The analysed programmes were undertaken by the governments of Ukraine and Kazakhstan. They contributed to reducing unemployment in both countries. The findings of Ukrainian researchers focused mainly on estimating losses in the SME sector, especially in the hotel, tourism and transport sectors. Scientific literature in Kazakhstan...
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Intercorrelation between CPTU-DMT tests for sands on the Baltic coast
PublikacjaNa podstawie badań terenowych opracowano szereg zależności między parametrami uzyskanymi z badania CPTU i DMT w czystych piaskach kwarcowych na Wybrzeżu Bałtyku. Uwzględniono wpływ historii geologicznej złoża oraz prekonsolidacji. Przedstawiono zależności dla piasków normalnie konsolidowanych i prekonsolidowanych. Prekonsolidacja i historia geologiczna bardziej wpływają na wyniki badania DMT niż CPTU. Zaproponowano oszacowanie...
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Probabilistic prognosis of cliffslide along Baltic Sea coast in Poland.
PublikacjaAnaliza stateczności wybrzeży klifowych metodą probabilistyczną. Określnie stref zagrożonych utratą stateczności.
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The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublikacjaThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
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Wpływ czasu i temperatury utleniania na napawane warstwy ze stopu kobaltu
PublikacjaBadano wpływ czasu utleniania na strukturę i skład chemiczny warstw ze stopu kobaltu wytworzonych metodą napawania laserowego. Do napawania użyto proszku o wysokiej zawartości chromu i średniej zawartości wolframu. Utlenianie przeprowadzono w temperaturze 1100 degC w czasach od 15 minut do 50 godzin. Porównano uzyskane wyniki ze skutkami utleniania w temperaturze 750 degC w czasie 200 godzin. Stwierdzono postępującą degenerację...
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HYDRAULIC CONDUCTIVITY OF COAL MINE TAILINGS
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MEDIUM-TERM WAVE AND CURRENT MODELLING FOR A MESOTIDAL WADDEN SEA COAST
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Assessment of river water quality in the South Baltic coast by multivariate techniques
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Chemical analysis of low carbon content coals and their applications as dye adsorbent
PublikacjaCoal is primarily a fuel material but lately it has been utilized as an adsorbent for removing toxic metal ions. However, its usage for removing organic pollutants is not well studied. We report here a systematic study on the use of coal samples of varying carbon contents as adsorbents for removing Basic Blue 41 as a model cationic dye. The coal samples were collected from coal mines and were thoroughly characterized. The concentrations...
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Mixed-ligand complexes of zinc(II), cobalt(II) and cadmium(II) with sulfur, nitrogen and oxygen ligands. Analysis of the solid state structure and solution behavior. Implications for metal ion substitution in alcohol dehydrogenase
PublikacjaScharakteryzowano strukturę heteroleptycznych kompleksów cynku(II), kobaltu(II) i kadmu(II) z 2-(2'-hydroksyetylopirydyną), tri-tert-butoksysilanotiolem i metanolem. Przy pomocy widm UV-Vis i NMR stwierdzono szybką wymianę N-liganda w roztworach tych kompleksów. Wyznaczono przesunięcia 15N NMR 2-(2'-hydroksyetylopirydyny) w kompleksach cynku(II) i kadmu(II). Na podstawie widm w podczerwieni i obliczeń DFT oszacowano względną moc...
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Wpływ utleniania w wysokich temperaturach na struktury napawanych warstw na bazie kobaltu
PublikacjaPrzedmiotem badań są napawane plazmowo warstwy wykonane ze stopu kobaltu zawierające ok. 29% chromu, ok. 5% wolframu i ok. 2% niklu, nałożone powierzchnie przylgni grzybków zaworów wylotowych silnika dieslowskiego. Powierzchnia podlega zarówno oddziaływaniom temperatury i środowiska, jak i oddziaływaniom mechanicznym. Podczas badań warstwy poddano oddziaływaniu środowiska utleniającego i wysokich temperatur: 750°C- górna w normalnej...
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Badanie własności napawanych warstw na bazie kobaltu na przylgnie zaworów silników diesla.
PublikacjaBadano mikrostrukturę i własności mechaniczne (twardość) nowych stopów na bazie kobaltu przeznaczonych do pracy w warunkach wysokiej temperatury, obciązeń mechanicznych i agresywnego środowiska. Celem wytwarzania warstw napawanych jest przedłużenie żywotności zaworów wylotowych okrętowych silnikow diesla
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Present state of sewage and wastewater treatment plants in the polish coast of Baltic Sea
PublikacjaIn the paper the state of art of wastewater management in four zones of Polish Baltic Sea coast: the Vistula Lagoon, the Bay of Gdansk and Bay of Puck, the open sea zone and the Szczecin Lagoon, is discussed. Hydrological characteristics of these four zones as well as characteristics and operation effectiveness of wastewater treatment plants (WWTPs) located there, are presented.
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A review of the biogeochemical controls on the occurrence and distribution of polycyclic aromatic compounds (PACs) in coals
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Sea surface temperature distribution during upwelling along the Polish Baltic coast
PublikacjaAmong over 150 maps of sea surface temperature in the Polish Baltic coastal region derived from satellite data during the warm period of the year (April-October) in 2000-2002, 41 cases were noted where its distribution showed characteristic features indicating the occurrence of coastal upwelling. The fundamental parameters of range, probability of occurrence and temperature modification caused by water from deeper sea layers...
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Influence of water salinity on corrosion risk - the case of the southern Baltic Sea coast.
PublikacjaWater corrosivity in Gdansk Bay, Poland, the southern part of the Baltic Sea, was investigated. The analysed region is heavily industrialized, and the coastline is very diverse. Twenty-seven test points along the coastline were selected. Water parameters such as salinity, total dissolved solids content, resistivity, conductivity, oxygenation, pH and corrosion rate were determined. The results of the investigation are presented....
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Influence of geotechnical conditions on damage states of Gdansk Bay Coast cliff formations
PublikacjaA geotechnical aspect of destruction processes of seashores was identified based on the case of erosion of Gdansk Bay Coast cliff formations. Causative factors of landslide were described in the context of natural phenomena, land development and its anthropogenic transformations. Possible directions of theoretical analysis of changes in groundwater relations were indicated.
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Climate change impact on groundwater resources in sandbar aquifers in southern Baltic coast
PublikacjaShallow coastal aquifers are vulnerable hydrosystems controlled by many factors, related to climate, seawater‑freshwater interactions and human activity. Given on‑going climate change, sea level rise and increasing human impact, it is especially true for groundwater resources situated in sandbars. We developed numerical models of unsaturated zone water flow for two sandbars in northern Poland: the Vistula Spit and the Hel Spit...
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Present state of sewage and wastewater treatment plants in the polish coast of Baltic sea.
PublikacjaW pracy przedstawiono stan gospodarki ściekowej w czterech strefach polskiego wybrzeża Bałtyku: Zalewu Wiślanego, Zatoki Gdańskiej z Zatoką Pucką, strefy otwartego morza oraz Zalewu Szczecińskiego. Wymienione strefy scharakteryzowano pod względem hydrologicznym oraz przedstawiono charakterystykę i efektywność pracy oczyszczalni ścieków zlokalizowanych na terenie każdej z nich. Ponadto, oszacowano inne, istotnie ważne źródła zanieczyszczeń...
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Editorial: Advances in geochemistry and macromolecular structure of coal
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Prediction of coking dynamics for wet coal charge
PublikacjaA one-dimensional transient mathematical model describing thermal and flow phenomena during coal coking in an oven chamber was studied in the paper. It also accounts for heat conduction in the ceramic oven wall when assuming a constant temperature at the heating channel side. The model was solved numerically using partly implicit methods for gas flow and heat transfer problems. The histories of temperature, gas evolution and internal...
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Search for new tools to combat Gram-negative resistant bacteria among amine derivatives of 5-arylidenehydantoin
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The Effectiveness of Basic Resuscitation Activities Carried out by Combat Paramedics of the Police, as Exemplified by Polish Counterterrorist Units
PublikacjaThe tasks carried out by Police officers are often accompanied by dangerous situations that threaten the life and health of the people involved, the police themselves, and bystanders. It concerns especially counter-terrorism police units whose activities are aimed at terrorists and particularly dangerous criminals, and their course is violent and aggressive. In conjunction with the inability to bring civilian rescue services into...
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Charakterystyka warstw ze stopu kobaltu napawanych laserowo i plazmowo po ekspozycji w spalinach
PublikacjaBadano warstwy wytworzone z proszku na bazie kobaltu, napawane laserowo i plazmowo. Proszki zaweirałY 5,3% wolframu.Jakość otrzymanych warstw była dobra. Badania ich degradacji prowadzono w środowidku spalin przez dwa miesiące.
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Morfologia napawanych warstw na bazie kobaltu po utlenianiu i korozji w gazach spalinowych
PublikacjaPrzedmiotem badań były warstwy wytworzone z proszku na bazie kobaltu, napawane laserowo i plazmowo na przylgnie zaworów wylotowych silników Diesla. Dla wszystkich warstw stwierdzono dobrą jakość, brak pęknięć i jednorodność struktury na powierzchni. Badania degradacji wykonano w specjalnie wykonanej komorze w gazach spalinowych silnika okrętowego. Badania napoin przeprowadzono po 2 miesiącach ekspozycji w podwyższonej temperaturze...
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Cobalt(II) tri-tert-butoxysialanethiolates.Synthesis, properties, crystal and molecular structures of [Co{SSi(OtBu)3}2(L)] and[Co{SSi(OtBu)3}2(L)2] type complexes with monodentate nitrogen ligands.
PublikacjaThe title heteroleptic neutral cobalt(II) tri-tert-butoxysilanethiolate complexes with monodentate nitrogen bases (L) as additional ligands have been prepared by the reactions of [Co{μ-SSi(OtBu)3}{SSi(OtBu)3}(NH3)]2 (1) with respective bases. For pyridine both types have been prepared...
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Hydrothermal dewatering of low-rank coals: Influence on the properties and combustion characteristics of the solid products
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