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Search results for: POLYURETHANE FOAMS, DAMPING VIBRATION CAPABILITY, NATURAL RESOURCE, SUSTAINABLE PRODUCTION, ENVIRONMENTAL ATTITUDES
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Fabrication and Characterization of Green Polyurethane Foams with Enhanced Vibration Damping Capability
PublicationOver the past decades, there has been an intensive development of the technologies and innovations aimed at increasing the quality of life. This development largely concerns the comfort of use of everyday products that, among others, are products of the automotive, construction, or furniture industries. Considering the increase in the comfort of using products such as cars, houses, and flats, one of the comfort features of their...
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Biobased Ultralow-Density Polyurethane Foams with Enhanced Recyclability
PublicationPolyurethane (PUR) foams are widely used in many engineering applications, but their efficient recycling has remained a major challenge for many years. This study presents a novel strategy of incorporating hydrolyzable ester units into the PUR structure to enhance PUR foam recyclability. The present ecodesign concept of PUR materials enables fully the replacement of petrochemical polyols with biobased alternatives and production...
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rigid polyurethane foams modified with selected nanofillers
PublicationThe nanofillers: natural montmoryllonite (MMT) - Bentonite, natural MMT modified with a quaternary ammonium salt - Cloisite30B, has been used in rigid polyurethane foams (PUFs). The influence of fillers amounts on processing parameters, physical-mechanical properties (density, water absorption, brittleness and compression strength) and thermal properties (thermal stability, fire behaviours) of such foams has been analysed. The...
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Investigating lubricants behaviour in microgravity for vibration damping purposes
PublicationVibration is one of the harshest environments an object is exposed to during and after launch into space on a launch vehicle. Such vibrations should be damped to avoid destruction of the spacecraft or its elements. Currently, active and material damping is used. A possibility of using lubrication as the damping factor is suggested by some research. MoS2 is a typical solid lubricant used in space applications. Its properties vary...
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Elastic polyurethane foams containing graphene nanoplatelets
PublicationElastic polyurethane foams were produced from two-component polyurethane systems (SPECFLEX NE 113 izocyjanian/NR 816 poliol system—SPC and Elastic MBMarket company system POLYOL ET MB 500/ISO ET MB 800—ET) by using a one-step method. The foams were a graphene nanoplatelets (GNP) in the amount ranging from 1 to 2 wt.%. The effect of the nanofiller on polyurethane matrix was determined by analyzing the chemical structure, static...
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Preparation and characterization of rigid polyurethane-polyglycerolnanocomposite foams
PublicationThis work reports on the preparation of polyurethane-polyisocyanurate (PUR-PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Clays as Inhibitors of Polyurethane Foams’ Flammability
PublicationPolyurethanes are a very important group of polymers with an extensive range of applications in different branches of industry. In the form of foams, they are mainly used in bedding, furniture, building, construction, and automotive sectors. Due to human safety reasons, these applications require an appropriate level of flame retardance, often required by various law regulations. Nevertheless, without the proper modifications,...
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A recent developments in polyurethane foams containing a low-cost and pro-ecological modifiers
PublicationDiversity of the polyurethane (PU) foams applications cause that investigation of the relationships between their structure and properties is currently very popular topic among the many research institutions and companies. At the turn of the last years many scientific papers about PU foams and their composites were published. The one of the main research trends in this field is related to the reduction of production costs of...
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Preparation and characterization of rigid polyurethane -polyglycerol nanocomposite foams
PublicationThis work reports on the preparation of polyurethane–polyisocyanurate (PUR–PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Rigid polyurethane foams from a polyglycerol-based polyol
PublicationRigid polyurethane foams (rPUs) were synthesized by replacing 35 and 70 wt.% of petrochemical polyol with polyglycerol. Two types of polyglycerol with different molecular weights and hydroxyl numbers were used to obtain new ‘‘green’’ polyurethane–polyglycerol foams. The foams were prepared by a single step method for the ratio of NCO/OH groups equal to 2. rPUs synthesized with polyglycerol showed regular cellular structure, with...
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THERMOMECHANICAL PERFORMANCE OF FLEXIBLE POLYURETHANE FOAMS AS A FUNCTION OF THE ISOCYANATE INDEX
PublicationPolyurethane foams are very versatile materials applied in different branches of industry. Their popularity is attributed, among others, to the flexibility in engineering their mechanical performance by the adjustment of their formulations. One of the most crucial factors is the isocyanate index, determining the ratio between the free hydroxyl and isocyanate groups present in the polyurethane system. By the change of this ratio,...
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Rigid polyurethane foams modified with selected flame retardants
PublicationThe flame retardants: expandable graphite, triethylphosphatehas been used in rigid polyurethane foams (PUFs). The influence of fillers amounts on processing parameters, physical-mechanical properties (compression strength, density, water absorption, brittleness)and thermal properties (thermal stability) of such foams has been analyzed.The gel, cram and rise time for PUFs modified with flame retardant has been observed during synthesis...
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Rigid polyurethane foams modified with selected layered silicate nanofillers
PublicationThe aim of this study was to investigate the effect of three different nanofillers on the properties of rigid polyurethane foams, which were prepared by a one-step, laboratory-scale method from a two-component system at the ratio of NCO groups to OH groups equaled to 2. The reaction mixture consisted of the proper amounts of the commercial oligoether polyol, catalysts, water, nanoclays, and polymeric diphenylmethane diisocyanate....
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Polyurethane/ground tire rubber composite foams based on polyglycerol: processing, mechanical and thermal properties
PublicationDuring the synthesis of rigid polyurethane foams, petrochemical polyol was substituted with polyglycerol, the product of thermo-catalytic polycondensation of waste glycerol, resulting from biodiesel production. Two types of ground tire rubbers, untreated and thermo-mechanically reclaimed, were used to obtain ‘‘green’’ polyurethane-polyglycerol composite foams. Samples were prepared by a single-step method for the ratio of NCO/OH...
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Effect of ground tire rubber on structural, mechanical and thermal properties of flexible polyurethane foams
PublicationFlexible polyurethane foams were modified with two kinds of ground tire rubber, untreated and thermo-mechanically reclaimed. A reclamation process was performed in auto-thermal conditions, which reduced the cost of the process and decreased the environmental impact of devulcanization (e.g., emission of gases). The reclamation process was carried out in a continuous manner using a co-rotating twin screw extruder. The foams were...
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Effect of bio-polyol molecular weight on the structure and properties of polyurethane-polyisocyanurate (PUR-PIR) foams
PublicationThe increasing interest in polyurethane materials has raised the question of the environmental impact of these materials. For this reason, the scientists aim to find an extremely difficult balance between new material technologies and sustainable development. This work attempts to validate the possibility of replacing petrochemical polyols with previously synthesized bio-polyols and their impact on the structure and properties...
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Ground tire rubber functionalization as a promising approach for the production of sustainable adsorbents of environmental pollutants
PublicationWaste tires management and further utilization are currently one of the biggest concerns regarding the environment and human health protection. At present, shredding, grinding, or pulverization of waste tires are the most popular options for industrial recycling. Although many solutions for ground tire rubber (GTR) applications were checked and verified so far, their further implementation at an industrial scale is still very limited....
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Synthesis and Physicochemical Characteristics of Chitosan-Based Polyurethane Flexible Foams
PublicationThe use of shrimp waste to obtain chitosan (Ch) is an essential issue, considering a circular economy, waste management, and its application to environmentally friendly materials. In this study, northern prawn shells were utilized to obtain Ch, which could then be used for synthesizing chitosan-based polyurethane (PUR+Ch) foams with different Ch concentration. The chemical structure, morphology, hardness, thermal properties, viscoelastic...
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Management of ground tire rubber waste by incorporation into polyurethane-based composite foams
PublicationRapid economic growth implicated the developing multiple industry sectors, including the automotive branch, increasing waste generation since recycling and utilization methods have not been established simultaneously. A very severe threat is the generation of enormous amounts of post-consumer tires considered burdensome waste, e.g., due to the substantial emissions of volatile organic compounds (VOCs). Therefore, it is essential...
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Chemical modifications of natural oils and examples of their usage for polyurethane synthesis
PublicationNatural oils have been used in the production of plastics for a long time. However, the number of studies dedicated to polyurethane research has shown an increase only recently. Usually, petrochemical components are used in polyurethane synthesis. Nowadays, there have been attemptsmade to replace polyols in polyurethanes with the modified oils and other natural raw materials. It is a promising and important scenario because the...
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Resource productivity and environmental degradation in EU-27 countries: context of material footprint
PublicationThis study explores the relationship between the resource productivity and environmental degradation in European Union-27 countries. This study tests this relationship in context of high, moderate, and low material footprint sub-samples; these samples are formed utilizing the expectation–maximization machine learning algorithm. Using the panel data set of EU-27 countries from 2000 to 2020, linear and non-linear autoregressive distributed...
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Rigid polyurethane foams with different flame retardants and their physical and mechanical properties
PublicationRigid polyurethane foams (PUFs) containing 3, 6 or 9 % of one of of two selected fire retardants (FR): oligomeric ethyl ethylene phosphate (Fyrol PNX) and expandable graphite (EG) were prepared, inspected and compared to foam without that fillers as the control. The thermal stability of PUFs was described by horizontal test according to norm: UL 94 HB. Compressive strength and physical properties (density, fragility and water absorption)...
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Comprehensive Investigation of Stoichiometry–Structure–Performance Relationships in Flexible Polyurethane Foams
PublicationPolyurethane (PU) foams are versatile materials with a broad application range. Their performance is driven by the stoichiometry of polymerization reaction, which has been investigated in several works. However, the analysis was often limited only to selected properties and compared samples differing in apparent density, significantly influencing their performance. In the bigger picture, there is still a lack of comprehensive studies...
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Environmental Taxes and Their Role in the Economics of Sustainable Development
PublicationThe purpose of this article is to answer the question of the role of environmental taxes in the economics of sustainable development. The first part of the article discusses the idea of sustainable economic development and the economics of sustainable development. Then, environmental taxes are defined, their essence explained and their role in the economics of sustainable development discussed in theoretical terms, which finally...
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Study of the effect of thermally reduced graphene oxide on the physical and mechanical properties of flexible polyurethane foams
PublicationFlexible polyurethane foams were obtained from a two-component system via the one-step method. The foams were modified with thermally reduced graphene oxide added in the amount equal to 0.25, 0.5 and 0.75 wt%. The morphology, static and dynamic properties, and thermal stability of modified foams were determined. The application of carbon filler resulted in the visible increase in the cell size, apparent density and rigidity of...
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Auxetic foams
PublicationThis paper presents a method of producing auxetic polyurethane foams (PUFs) and their unique properties. The experience was based on a synthesis of traditional flexible polyurethane foam and thermal conversion to auxetic foam. The foam specimens were transformed from conventional Poisson's ratio to auxetic (negative Poisson's ratio) [1]. Basic research was performed to determine the mechanical properties and cell structure. Auxetic...
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The influence of crude glycerol and castor oil-based polyol on the structure and performance of rigid polyurethane-polyisocyanurate foams
PublicationIn this work, biopolyol obtained from two types of industrial crops’ processing products: crude glycerol and castor oil was used for preparation or rigid polyurethane-polyisocyanurate foams. Bio-based polyol was obtained via crude glycerol polymerization and further condensation of resulting polyglycerol with castor oil. Rigid polyurethane-polyisocyanurate foams were prepared at partial substitution (0–70 wt.%) of petrochemical...
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Microstructure–Property Relationship of Polyurethane Foams Modified with Baltic Sea Biomass: Microcomputed Tomography vs. Scanning Electron Microscopy
PublicationIn this paper, novel rigid polyurethane foams modified with Baltic Sea biomass were compared with traditional petro-based polyurethane foam as reference sample. A special attention was focused on complex studies of microstructure, which was visualized and measured in 3D with high-resolution microcomputed tomography (microCT) and, as commonly applied for this purpose, scanning electron microscopy (SEM). The impact of pore volume,...
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Rigid polyurethane foams modified with ground tire rubber - mechanical, morphological and thermal studies
PublicationRigid polyurethane foams, prepared by a single step method, were modified with the two types of ground tire rubber particles, i.e. untreated and thermo-mechanically reclaimed by using a co-rotating twin screw extruder. The foaming process as well as the structure and the physical, mechanical and thermal properties of the resulting foams were investigated. The presence of ground tire rubber decreased the velocity of polymerization....
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The study on application of biopolyols obtained by cellulose biomass liquefaction performed with crude glycerol for the synthesis of rigid polyurethane foams
PublicationIn this work rigid polyurethane foams (PUR) were obtained by replacement of 0–70 wt% of petrochemical polyol with bio-polyol obtained via cellulose liquefaction in presence of crude glycerol. The foams with different content of a bio-polyol were prepared by single step method for NCO/OH ratio equals 1.5. The prepared materials were analyzed in terms of their morphology, chemical structure, thermal stability and basic physical and...
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Towards sustainable catalyst-free biomass-based polyurethane-wood composites (PU-WC): From valorization and liquefaction to future generation of biocomposites
PublicationA substantial aspect of materials engineering lies in the responsible process of designing polymer-based materials. Due to environmental pollution, excessive consumption of natural resources, and increasing environmental awareness of society, there is a massive need for polyurethane (PU) materials with reduced environmental impact. To date, research on catalyst-free polyurethane-wood composites (PU-WC) has demonstrated a huge potential...
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The Impact of Ground Tire Rubber Oxidation with H2O2 and KMnO4 on the Structure and Performance of Flexible Polyurethane/Ground Tire Rubber Composite Foams
PublicationThe use of waste tires is a very critical issue, considering their environmental and economic implications. One of the simplest and the least harmful methods is conversion of tires into ground tire rubber (GTR), which can be introduced into different polymer matrices as a filler. However, these applications often require proper modifications to provide compatibility with the polymer matrix. In this study, we examined the impact...
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Polyurethane Glycerolysate as a Modifier of the Properties of Natural Rubber Mixtures and Vulcanizates
PublicationChemical recycling of polyurethanes can be realized in several different ways, but the most important methods are glycolysis and glycerolysis. Both methods permit recovery of polyols (when the process is realized with the mass excess of depolymerizing agent) or substitutes of polyols, which contain urethane moieties in the main chains and terminate mainly in hydroxyl groups (when the process is realized with the mass excess of...
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The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites
PublicationIn this work the use of polyurethane chemical recycling product (i.e. glycolysis of polyurethane waste realized with the mass excess of polymer) as a plasticizer for natural rubber-based composites was proposed. The effect of plasticizer type (napthenic oil and polyurethane foam glycolysate) and amount (2, 4, 6 or 8 parts per 100 parts of natural rubber) on the processing properties of rubber mixtures and chemical structure, swelling,...
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Comprehensive Enhancement of Prepolymer-Based Flexible Polyurethane Foams’ Performance by Introduction of Cost-Effective Waste-Based Ground Tire Rubber Particles
PublicationMaterial innovations in polyurethane (PU) foams should ideally combine performance enhancement, environmental impact limitation, and cost reduction. These goals can be achieved by applying recycled or waste-based materials without broader industrial applications, implicating their low price. Herein, from 5 to 20 parts by weight of ground tire rubber (GTR) particles originated from the recycling of postconsumer car tires were incorporated...
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Synthesis and thermal studies of flexible polyurethane nanocomposite foams obtained using nanoclay modified with flame retardant compound
PublicationThis work presents thermal studies of nanocomposites based on the flexible polyurethane (PU) matrix and filled using montmorillonite organically modified with organophosphorus flame retardant compound. Flexible PU nanocomposite foams were prepared in the reaction carried out between reactive alcoholic hydroxyl and isocyanate groups with the ratio of NCO to OH groups equal to 1.05. The amount of an organoclay ranging from 3 to 9...
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Hilton Environmental Reporting as a tool of Corporate Social Responsibility.
PublicationArtykuł ten przedstawia historię, kryteria oraz procedury wprowadzone w komputerowym systemie środowiskowym Hilton Environmental Reporting.
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EIA in teaching sustainable development and environmental protection in engineering education
PublicationA multifaceted approach in teaching the environmental impact assessment (EIA) as a way to stress the role of environmental education in technical sciences is the focus of this article. The EIA is an example of an effective tool that supports spatial planning in implementing sustainable development. The aim is to present the idea and benefits of a facilitative and collaborative approach in teaching the EIA, stressing the role of...
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Structural, thermal and physico-mechanical properties of polyurethane/brewers’ spent grain composite foams modified with ground tire rubber
PublicationIn this work, brewers’ spent grain (BSG) and ground tire rubber (GTR) waste fillers were applied as low-cost reinforcement phase in rigid polyurethane foam (PUR). PUR/BSG/GTR composites were prepared by a single step method, using polyglycerol as partial substitute of commercially available petrochemical polyols. Foaming parameters, chemical structure, dynamic mechanical properties, thermal stability, physico-mechanical properties...
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Integration of natural and artificial intelligence in production systems
PublicationIntegration processes play an increasingly important role in modern economy, and seriously co-decide about the effectiveness of the company. Integration phase occurs in the system life cycle by preceding the final stages of its implementation and activation. In turn, used in software engineering (SE) iteration-evolutionary models, such as spiral model make that the integration activities can occur in varying degrees in all phases...
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Active Damping of Impulse-Excited Flexible Plate Vibration
PublicationArtykuł prezentuje metodę aktywnego tłumienia drgań podatnej płytki wzbudzanych impulsowo. Układ sterowania składa się z aktywych wzbudników piezoelektrycznych przymocowanych do przedmiotu. Efektywnośc metody została potwierdzona badaniami eksperymentalnymi.
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Highly sensitive large strain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite foams: From design to performance evaluation
PublicationAerogel-based polymer composite foams are promising for large strain piezoresistive sensors, but their aerogel skeleton is partially destroyed during the foaming process, limiting their sensitivity. Herein, the thermoplastic polyurethane was synthesized on the aerogel skeleton to obtain cellulose/multiwalled carbon nanotubes (MWCNTs)/thermoplastic polyurethane (TPU) nanocomposite materials foamed with the aid of supercritical carbon...
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Responsible resource management in hotels - attitudes, indicators, tools and strategies ; doctoral thesis.
PublicationHotele stanowią jeden z głównych i wciąż rozwijających się sektorów turystyki. Budynki hotelowe sa dość energochłonne, a instalacje i zamontowane systemy często nieefektywne co prowadzi do wyraźnych skutków ubocznych dla środowiska naturalnego. Niniejsza praca zawiera informacje na temat istniejących inicjatyw prośrodowiskowych w światowym sektorze hotelarskim. Analiza wyników ankiety przeprowadzonej wśród 610 przedstawicieli europejskiego...
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Polyurethanes modified with natural polymers for medical application. Part II. Polyurethane/gelatin, polyurethane/starch, polyurethane/cellulose
PublicationThis paper is a literature overview of biomedical PUR modifications with natural polymers such as starch, cellulose and gelatin. Properties like biodegradability and biocompatibility of modified PUR cause that these materials may be used as wound dressings, tissue scaffolds, tissue implants and also vascular grafts.
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Preparation and characterization of rigid polyurethane–polyglycerol nanocomposite foams
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Morphology of bio-based polyurethane composites filled by mer-cerized or silanized natural fibres
PublicationBio-composites are materials which possess unique properties and undergo biodegra-dation under specific conditions. Bio-composites belong to the group of materials produced with the use of renewable raw materials. They contain reinforcement, mainly in the form of natural fiber, which has high stiffness and resistance; filler powders are less frequently used. Significant features of natural fibers are elongation, density, thermal...
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Resource saving by optimization and machining environments for sustainable manufacturing: A review and future prospects
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Renewable Resources for Polyurethanes and Polyurethane Composites: A Review
PublicationEach year, more than two million tons of polyurethane is produced in the EU by reacting isocyanates with polyols made from fossil fuel. In addition, there are appreciable quantities of petroleum based functional additives applied in the industry nowadays for both polyols and polyurethane materials. It is therefore of key importance to develop sustainable economically viable polyols with enhanced functionalities, and thereby reducing...
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Experimental Verification of Natural Vibration Models of Steel-concrete Composite Beams
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Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production
PublicationThe rapidly increase in the world's population has resulted in a corresponding increase in the energy demand. This demand is largely being met by fossil fuels for power generation, industrial fuel and transportation. However, due to the limited availability of fossil fuels and their negative effects on the environment. The use of fossil fuels results in by-products such as carbon, nitrogen and sulfur oxides which have negative...