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Search results for: MAGNETIC NANOPARTICLES (MNPS)
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Magnetically sensitive fiber probe with nitrogen-vacancy center nanodiamonds integrated in a suspended core
PublicationEfficient collection of photoluminescence arising from spin dynamics of nitrogen vacancy (NV) centers in diamond is important for practical applications involving precise magnetic field or temperature mapping. These goals may be realized by the integration of nanodiamond particles with optical fibers and volumetric doping of the particles alongside the fiber core. That approach combines the advantages of robust axial fixation of...
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Nano Tin/Tin Oxide Attached onto Graphene Oxide Skeleton as a Fluorine Free Anode Material for Lithium-Ion Batteries
PublicationHerein, we show a composite formation method of tin/tin oxide nanoparticles with graphene oxide and CMC based on laser ablation technique as an electrode material for energy storage devices. The material exhibited a three-dimensional conducting graphene oxide network decorated with tin or tin oxide nanoparticles. The structure, homogeneous distribution of nanoparticles, and direct contact between inorganic and organic parts were...
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The bahaviour of selected silver coated body implants in presence of various bacteria
PublicationThe article deals with implants covered with silver nanoparticles and its influence on bacteria adhesion.
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Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublicationOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....
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Preparation and characterization of monometallic (Au) and bimetallic (Ag/Au) modified-titania photocatalysts activated by visible light
PublicationThe Au-TiO2 and Ag/Au-TiO2 nanoparticles have been prepared using a water-in-oil microemulsion system of water/AOT/cyclohexane and water/Triton X-100/cyclohexane. The obtained photocatalysts were subsequently characterized by a BET method, DRS spectroscopy, X-ray photoelectron emission spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray powder diffraction analysis (XRD). For gold-doped titanium (IV) oxide...
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Implementation of localization and identification of ferromagnetic objects algorithm in labview enviroment
PublicationThe problem with detecting dangerous objects is still a matter of concern today. One of the methods of detecting dangerous objects is the magnetic method. While measuring a magnetic field in the surrounding of objects with ferromagnetic properties, it is possible to detect, localize and identify such object.
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Metal enhanced fluorescence of flavin mononucleotide using new plasmonic platform
PublicationNew plasmonic platform was successfully obtained to investigate the increase of fluorescence intensity of a fluorophore in the presence of silver nanoparticles. A flavin mononucleotide, was selected by us as a fluorophore for this study as a very important biological compound playing a key role in many biochemical process. Plasmonic platforms were characterized by means of luminescence spectroscopy. Flavin mononucleotide deposited...
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Ship’s de-perming process using coils lying on seabed
PublicationA ship built from ferromagnetic steel disturbs the uniformity of the Earth’s magnetic field. Changes of ship’s signature are due to the magneto-mechanical interaction of the hull with the Earth’s magnetic field. The ship’s magnetic field can be detected by a magnetic naval mine. For this reason, the vessel has to be demagnetized. There are several methods of ship’s de-perming. The results of experimental and computer simulations...
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Magnetism and charge density waves in RNiC2(R=Ce,Pr,Nd)
PublicationWe have compared the magnetic, transport, galvanomagnetic, and specific-heat properties of CeNiC2, PrNiC2, and NdNiC2 to study the interplay between charge density waves (CDW) and magnetism in these compounds. The negative magnetoresistance in NdNiC2 is discussed in terms of the partial destruction of charge density waves and an irreversible phase transition stabilized by the field-induced ferromagnetic transformation is reported....
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Unravelling the role of electron–hole pair spin in exciton dissociation in squaraine-based organic solar cells by magneto-photocurrent measurements
PublicationA high absorption coefficient and narrow absorption bands in squaraine (SQ) dyes have resulted in rapidly growing interest in them as a donor material in photovoltaic devices. The exciton dissociation process in organic systems proceeds via a multistep mechanism where the electron–hole pairs (charge transfer states) involved in the current generation process determine the recombination losses and subsequently limit the overall...
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Influence of silver-core gold-shell nanoparticle parameters on the variation of surface-enhanced Raman spectra
PublicationThe detection of molecules by surface-enhanced Raman spectroscopy (SERS) is dependent on the nanomaterial used to induce the enhancement effect. This depends on a variety of parameters of the substrate such as the metal used for their creation, their shape, size and size distribution, concentration, as well as the parameters of the solution, such as packing of the nanoparticles, the complexity of the sample, the solvent, etc. It...
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Burnout Investigation of Small Diameter Tubes Immersed in Nanofluids
PublicationThis paper deals with research into pool boiling critical heat flux (CHF) of water–Al2O3, water–TiO2 and water–Cu nanofluids on horizontal stainless steel tubes. The experiments were conducted under atmospheric pressure. Nanoparticles were tested at concentrations of 0.001%, 0.01%, 0.1% and 1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. Although dispersants were not used to...
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Ferromagnetic nanocrystallites in the SiO2 - PbO - Fe2O3 glass system
PublicationThe structure of 50% SiO2 - 35% PbO - 15% Fe2O3, 50% SiO2 - 30% PbO - 20% Fe2O3 and 50% SiO2 - 25% PbO - 25% Fe2O3 (in mol%) glass was investigated by the means of AFM microscopy and X-ray diffraction. Observation by the atomic force microscopy shows that each of prepared iron oxide glass doesn't have homogeneous structure and some nanocrystallites were detected. Next, test with neodymium magnet found out strong magnetic properties...
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Experimental investigation of thermal energy storage in shell-and-multi-tube unit with nano-enhanced phase change material
PublicationThis paper deals with thermal energy storage with use of nanoparticle enhanced phase change material in shell-and-multitube unit. The experiments are conducted under atmospheric pressure. Paraffin wax and two different fatty acids are used as base phase change material. Graphite and multi-walled carbon nanotubes serve as nanoparticles. Graphite nanoparticles are tested at the concentrations of 0.1%, 1% and 5% by weight, while multi-walled...
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Localization and identyfication of ferromagnetic objects
PublicationA compact ferromagnetic object placed in the earthly magnetic field causes disturbance of this field. This disturbance is associated with magnetization of the object. Ferromagnetic objects have induced and can also have permanent magnetization. In methods of locating and identifying ferromagnetic objects usually is using the model of the dipol moment. Determination of the position and values of the extremes of the magnetic field...
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Novel tetrahedral cobalt(II) silanethiolates: structures and magnetism
PublicationThree heteroleptic complexes of Co(II) tri-tert-butoxysilanethiolates have been synthesized with piperidine [Co{SSi(OtBu)3}2(ppd)2] 1, piperazine [Co{SSi(OtBu)3}2(NH3)]2(μ-ppz)·2CH3CN 2, and N-ethylimidazole [Co{SSi(OtBu)3}2(etim)2] 3. The complexes have been characterized by a single-crystal X-ray, revealing their tetrahedral geometry on Co(II) coordinated by two nitrogen and two sulfur atoms. Complexes 1 and 3 are mononuclear,...
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Volumetric incorporation of NV diamond emitters in nanostructured F2 glass magneto-optical fiber probes
PublicationIntegration of optically-active diamond particles with glass fibers is a powerful method of scaling diamond's magnetic sensing functionality. We propose a novel approach for the integration of diamond particles containing nitrogen-vacancy centers directly into the fiber core. The core is fabricated by stacking the preform from 790 soft glass canes, drawn from a single rod dip-coated with submicron diamond particles suspended in...
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Structural and physical characterization of NpPt2In7
PublicationA new neptunium intermetallic compound, NpPt2In7, has been synthesized in polycrystalline form and characterized by several macroscopic techniques. A Rietveld analysis of its powder x-ray diffraction pattern shows that NpPt2In7 crystallizes in a tetragonal lattice with I4/mmm symmetry and lattice parameters a = 4.58471(3) Å, c = 21.5065(3) Å. Magnetic susceptibility, electrical resistivity, Hall effect, and heat capacity measurements indicate...
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Influence of Gd deposition on the oxidation behavior and electrical properties of a layered system consisting of Crofer 22 APU and MnCo2O4 spinel
PublicationIn the study, the surface of the Crofer 22APU ferritic steel was modified with gadolinium oxide nanoparticles and a protective-conducting layer consisting of the MnCo2O4 spinel. This system was studied in the context of application in IT-SOFC interconnects. Four types of samples were studied: unmodified steel, steel coated with a manganese-cobalt spinel layer, steel modified with gadolinium oxide nanoparticles, and a system consisting...
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Revisiting Toroidal Dipolar Moment in Planar Metamaterial
PublicationThis article revisits the electric, magnetic, and toroidal dipolar moments in the metamaterial structure and presents the flatland design for generating a toroidal dipolar response for the electromagnetic plane wave at normal incidence. Based on the numerical analysis of the surface current, the electric field, the magnetic field, and the quantitative analysis of scattered power supported by the electromagnetic multipole theory,...
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INFLUENCE OF NANOPARTICLE CONCENTRATION ON THERMAL PROPERTIES OF THERMAL OIL-MWCNT NANOFLUID
PublicationThis paper deals with measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of thermal oil-MWCNT (TO-MWCNT) nanofluid. Nanoparticles were tested at the concentration of 0.001%, 0.005%, 0.01%, 0.05%, and 0,1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. Thermal oil (TO) was selected as a base liquid, because of possible application in ORC systems...
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LOKALIZACJA OBIEKTÓW BUDOWLANYCH W SĄSIEDZTWIE LINII 110 kV
PublicationW artykule omówiono wymagania przepisów w zakresie dopuszczalnych wartości pola elektrycznego i magnetycznego niskiej częstotliwości. Przedstawiono wyniki obliczeń rozkładu pola elektrycznego metodą ładunków stymulowanych i w programie FEMM dla przykładowej lokalizacji obiektu przemysłowego w sąsiedztwie linii 110 kV.
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Characterization methods of nickel nano-particles obtained by the ex-solution process on the surface of Pr, Ni-doped SrTiO3 perovskite ceramics
PublicationIn this paper, a novel electrode material based on Pr, Ni co-doped strontium titanate ( Sr0.7Pr0.3)xTi1−yNiyO3 with constant amount of 30% praseodymium dopant, different amount of nickel (y = 0.06 and y = 0.10) and additional nonstoichiometry in Sr-site (x = 1; x = 0.9 and x = 0.8) was investigated as fuel electrode for SOEC devices. A porous ceramics were prepared by solid-state reaction method. X-ray diffraction measurements...
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Influence of nanoparticle concentration on thermal properties of thermal oil-MWCNT nanofluid
PublicationResults of the measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of thermal oil-MWCNT (TO-MWCNT) nanofluid have been presented. Nanoparticles were tested at the concentration of 0.001%, 0.005%, 0.01%, 0.05%, and 0,1% by weight. Thermal oil (TO) was selected as a base liquid, because of possible application in ORC systems as an intermediate heating agent. Multi-walled carbon nanotubes were used...
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Analysis of leakage flux in deenergized transformer
PublicationThe article presents the numerical analysis of the magnetic field that occurs around the transformer after it has been switched off. The purpose of this analysis was to determine if it is possible to define the residual fluxes in the legs of transformer based on the measurements of this field. These studies have allowed us to determine the quantity and location of the sensors. The influence of the Earth's magnetic field has also...
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Nano-structured Pt embedded in acidic salts of heteropolymolybdate matrices: MS EXAFS study
PublicationA structural study of Pt nano-catalysts is presented in the paper. The innovation in the case of the considered catalytic materials resides in the use a meso-microporous inorganic matrix of heteropolyacid salt of composition X2.5H0.5YMo12O40 where X = Rb, Cs and Y = P, Si as a catalyst support. Metallic nanoparticles were created by platinum ions reduction in a hot H2/Argon stream and were mainly located into matrix pores. As the...
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Preparation and Characterization of Au/Pd Modified-TiO2 Photocatalysts for Phenol and Toluene Degradation under Visible Light—The Effect of Calcination Temperature
PublicationRutile loaded with Au/Pd nanoparticles was prepared using a water-in-oil microemulsion system of water/AOT/cyclohexane followed by calcination.Theeffect of calcination temperature (from350 to 700∘C) on the structure ofAu/Pd nanoparticles deposited at rutile matrix and the photocatalytic properties of Au/Pd-TiO2 was investigated in two model reactions (toluene degradation in gas phase and phenol degradation in aqueous phase). The...
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Simulation of the remanence influence on the transient states in a single-phase multiwinding transformer
PublicationThis paper presents the mathematical model of a single-phase multi-winding core type transformer taking into account magnetic hysteresis phenomenon based on the feedback Preisach model (FPM). The set of loop differential equations was developed for a K-th winding transformer model where the flux linkages of each winding includes flux Φ common to all windings as a function of magneto motive force Θ of all windings. The first purpose...
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Tuning of High Spin Ground State and Slow Magnetic Relaxation within Trimetallic Cyanide‐Bridged {Ni II x Co II 9− x [W V (CN) 8 ] 6 } and {Mn II x Co II 9− x [W V (CN) 8 ] 6 } Clusters
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Unusual divergence of magnetoacoustic beams
PublicationTwo-dimensional magnetosonic beams directed along a line forming a constant angle h with the equilibrium straight magnetic field are considered. Perturbations in a plasma are described by the system of ideal magnetohydrodynamic equations. The dynamics of perturbations in a beam are different in the cases of fast and slow modes, and it is determined by h and equilibrium parameters of a plasma. In particular, a beam divergence may...
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Effective Permeability of Multi Air Gap Ferrite Core 3-Phase Medium Frequency Transformer in Isolated DC-DC Converters
PublicationThe magnetizing inductance of the medium frequency transformer (MFT) impacts the performance of the isolated dc-dc power converters. The ferrite material is considered for high power transformers but it requires an assembly of type “I” cores resulting in a multi air gap structure of the magnetic core. The authors claim that the multiple air gaps are randomly distributed and that the average air gap length is unpredictable at the...
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Simulation of the Remanence Influence on the Transient States of the Single-Phase Transformer Including Feedback Preisach Model
PublicationThis paper presents the results of the experimental and simulation investigation concerning the influence of remanence in the core of a single-phase transformer at the no-load transient state. Experimental studies consisted of the discharge of the capacitor through the primary winding at several different values of the residual magnetic flux. The paper presents a model of the transformer test system, taking into account the magnetic...
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INFLUENCE OF SURFACE CURVATURE ON SESSILE DROPLET CONTACT ANGLE OF NANOFLUIDS
PublicationThis paper deals with change in contact angle of droplets of three nanofluids, i.e. water-Al2O3, water-TiO2 and water-Cu. Nanoparticles were tested at the concentration of 0.01%, 0.1%, and 1% by weight. Although dispersants were not used to stabilize the suspension, the solutions tested exhibited satisfactory stability. Ultrasonic vibration was used in order to stabilise the dispersion of the nanoparticles. Experimental measurements...
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Finite Element Method Applied in Electromagnetic NDTE: - A Review
PublicationThe paper contains an original comprehensive review of finite element analysis (FEA) applied by researchers to calibrate and improve existing and developing electromagnetic non-destructive testing and evaluation techniques, including but not limited to magnetic flux leakage (MFL), eddy current testing, electromagnetic-acoustic transducers (EMATs). Premium is put on the detection and modelling of magnetic field, as the vast majority...
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Electromagnetic Field Associated With Dermoscope Magnets May Affect the Safety of Cardiac Implanted Electronic Devices Patients
PublicationDermoscopy is currently used as an auxiliary tool in general dermatology. Since some commercially available dermoscopes have built-in magnets, electromagnetic interference (EMI) may occur when examining cardiac implantable electronic devices (CIED) patients. The aim of the study was to create maps of electromagnetic fields defining a safe distance in terms of EMI. The study was performed in laboratory conditions using measuring...
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Frontispiece: Tuning of High Spin Ground State and Slow Magnetic Relaxation within Trimetallic Cyanide‐Bridged {Ni II x Co II 9− x [W V (CN) 8 ] 6 } and {Mn II x Co II 9− x [W V (CN) 8 ] 6 } Clusters
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Nonlinear viscoelasticity in Three Dimensional filler reinforced rubber composites and nanocomposites
PublicationThis chapter describes the influence of three-dimensional nanofillers used in elastomers on the nonlinear viscoelastic properties. In particular, this part focuses and investigates the most important three-dimensional nanoparticles, which are used to produce rubber nanocomposites. The rheological and the dynamic mechanical properties of elastomeric polymers, reinforced with spherical nanoparticles, like POSS, titanium dioxide and...
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Spin and Orbital Effects on Asymmetric Exchange Interaction in Polar Magnets: M(IO3)2 (M = Cu and Mn)
PublicationMagnetic polar materials feature an astonishing range of physical properties, such as magnetoelectric coupling, chiral spin textures, and related new spin topology physics. This is primarily attributable to their lack of space inversion symmetry in conjunction with unpaired electrons, potentially facilitating an asymmetric Dzyaloshinskii–Moriya (DM) exchange interaction supported by spin–orbital and electron–lattice coupling. However,...
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Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)2
PublicationPolar magnetic materials exhibiting appreciable asymmetric exchange interactions can potentially host new topological states of matter such as vortex-like spin textures; however, realizations have been mostly limited to half-integer spins due to rare numbers of integer spin systems with broken spatial inversion lattice symmetries. Here, we studied the structure and magnetic properties of the S = 1 integer spin polar magnet β-Ni(IO3)2...
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A new technique with high reproducibility to estimate renal oxygenation using BOLD-MRI in chronic kidney disease
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Correlation between the Reactivity and Spectroscopic Properties of N-Substituted Secondary Thioamides. New Intramolecular N• •H+• •N Binding Approach and Proton Complexes Based on Thioamide Ligation
PublicationFrom a comparison of chem. shifts and wavenumbers of several secondary thioamides and amides having monocationic substituents attached to thiocarbamoyl or carbamoyl groups by a polymethylene chain, new intramol. unconventional N···H+···N H bonding effects were discovered. It is argued that the CH2-N rotation is hindered and two +H···NHMe nonequiv. protons occur in a proton spectrum of hydrochloride RCH2C(S)NH(CH2)3NHMe-HCl...
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Deducing 1D concentration profiles from EPR imaging: A new approach based on the concept of virtual components and optimization with the genetic algorithm
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Theoretical analysis of solvent effects on nitrogen NMR chemical shifts in oxazoles and oxadiazoles
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Spectral assignment and proton transfer studies ofN-(R-salicylidene)-1-amino-1-deoxy-d-sorbitols
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The Role of Specific Side Groups and pH in Magnetization Transfer in Polymers
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NMR relaxation enhancement in gels polymerized and cross-linked by ionizing radiation: A new approach to 3D dosimetry by MRI
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The Analysis of Hyperfine Shifts of Mono-Ligand High-Spin Cobalt(II) Pyrazolylborate Complexes
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Study of the Effect of Filling Thermoplastic Medical Polyurethane with PVA, PLA or Diatomite on the Relaxation Times Distributions of 1H NMR
PublicationIn this work, to characterize the mobility of diferent sections of the macromole‑ cules of polyurethane (PUR), polyvinyl alcohol (PVA), and polylactic acid (PLA), as well as the density of crosslinks of the polymer chains when using fllers, we used the distributions of spin–lattice and spin–spin relaxation times for the protons. It is shown that the rigidity of the thermoplastic polymers depends on the sizes of the granules of...
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Stereostructure of mycoheptin A2
PublicationThe absolute configurations of all the stereogenic centers of the antibiotic mycoheptin A2 were established upon previously elaborated general procedure, consisting of DQF-COSY, NOESY, ROESY, HSQC and HMBC experiments as major tools. The structure of mycoheptin A2 without stereochemistry of its aglycone has been reported before.
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Reaction of bis[bis(tri-tert-butoxysilanethiolato)cadmium(II)] with 3,5-dimethylpyridine - 113Cd NMR Solution study
PublicationAnaliza 113Cd NMR dla reakcji bis[bis(tri-tert-butoksysilanotiolanu)kadmu(II)] z 3,5-dimetylopirydyną została przeprowadzona w roztworze benzenu-d6 i toluenu-d8. Otrzymane wyniki wskazują, że w roztworze istnieje równowaga pomiędzy powstającymi mieszanymi kompleksami kadmu z ligandami siarkowymi i azotowymi.