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A method of determination of electrical conduction mechanisms in complex amorphous materials
PublicationA novel approach to determine conduction mechanisms in complex amorphous materials was presented and tested on a real system. In the first step of the presented method, total electrical admittance of the material is analyzed in order to separate a couple of processes, each of which can be described by Jonscher's universal dielectric response. In the following step, a temperature dependence of dielectric response parameters of the...
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Structural and luminescence investigation of GeO2-PbO-Bi2O3-SrF2 glasses doped with Eu3+, Tb3+ and Tm3+ ions
PublicationThe GeO2-PbO-Bi2O3-SrF2 (GePbBiSr) glass systems doped with Eu3 +, Tb3 +, Tm3 + and triply-doped with Eu3 +/Tb3 +/Tm3 + ions were successfully synthesized. Their structural and luminescent properties have been investigated with various techniques. Obtained results indicate that these glass systems are suitable materials for the RE3 + ions hosts. RE3 + ions can be excited by single UV light wavelength (355/378/395 nm) and simultaneously...
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Polaron hopping conduction in manganese borosilicate glass
PublicationA study on a novel material - manganese borosilicate glass without alkali metals, was reported. It was found that the obtained samples containing high amount of manganese oxide (60MnO–xSiO2–(40 − x)B2O3, x = 5, 10, 15, 20 and 30 mol%) were amorphous and homogeneous. XPS measurements showed that most of manganese ions are at oxidation level of Mn2 + ions and the mean oxidation level slightly moves toward higher value, with increasing...
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Nonlinear Impedance as Possible Result of Ion-Polaron Interaction in Cu2O-Al2O3-SiO2 Glass
PublicationNonlinear a.c. impedance measurements were performed in Cu2O-Al2O3-SiO2 glass in wide frequency range. The obtained results shows that a large nonlinearity in the impedance signal is observed at moderate electric fields of an order 1V/mm. The contents of the third harmonics reaches about 10% and strongly depends on temperature and frequency. The investigated glass exhibits mixed electronic-ionic conductivity. Electronic conduction...
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Ac and dc conductivities in v2o5-p2o5 glasses containing alkaline ions
PublicationWe investigated the ac and dc conductivity in 50V2O5-(50 − x)P2O5-xA2O (A = Li, Na, K) glasses as a function of temperature. The measurements were carried out in the frequency range from 10−4 to 107 Hz. For all compositions, the dc conductivity decreased with the increasing alkali ion content. The decrease in conductivity was more pronounced for larger alkali ions. The ac conductivity exhibited a universal dynamic response: σac...
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Structure and superconductivity of VN-SiO2 films obtained by thermal nitridation of sol-gel derived coatings
PublicationPraca prezentuje wyniki badań strukturalnych oraz właściwości nadprzewodzących cienkich warstw xVN-(100-x)SiO2, gdzie x = 90, 80, 70, 60 mol%. Warstwy zostały wykonane metodą termicznego azotowania z użyciem amoniaku cienkich warstw tlenkowych otrzymanych metodą zol-żel. Badania struktury przeprowadzono metodami XRD oraz XPS, natomiast właściwości nadprzewodzące badano metodą MMMA. Właściwości nadprzewodzące warstw zależą zarówno...
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On electrical and photoconductive properties of mixed Nb2O5/TiO2 sol-gel thin films
PublicationPraca prezentuje wyniki przewodnictwa elektrycznego i fotoprzewodnictwa cienkich warstw TiO2 i Nb2O5/TiO2 otrzymanych metodą zol-żel. Pomiary przeprowadzono w funkcji temperatury i natężenia oświetlenia zarówno w próżni jak i w powietrzu. Struktura warstw została zbadana metodami XRD oraz AFM. W pracy zaobserwowano zaobserwowano spadek fotoprzewodnictwa wraz z zawartością Nb2O5
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NMR dispersion studies of poly(ethylene oxide)/sodium montmorillonitenanocomposites
PublicationPraca prezentuje wyniki badań dotyczące struktury nanokompozytów opartych na matrycy poli(tlenku etylenu) zawierającej montmorylonit sodowy. Układy zawierające PEO/MMT scharakteryzowano metodami NMR (Fast Field Cycling NMR), DSC oraz XRD.
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Photovoltaic effect in hybrid heterojunction formed from cadmium telluride and zinc perfluorophthalocyanine layers
PublicationPraca przedstawia wyniki badań zjawska fotowoltaicznego w planarnym układzie złożonym z następujących warstw: ITO, CdTe, perfluoroftalocyjanina cynku, BCP, Ag.
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On doubts about Mott-Schottky plot of organic planar heterojunction in photovoltaic cell
PublicationNa wykresie Motta-Schottky'ego przedstawione są wyniki pomiarów przeprowadzonych na komórkach fotowoltaicznych z planarnym heterozłączem organicznym. W pracy pokazano, że fotowoltaiczne układy z planarnym heterozłączem organicznym, podobnie jak planarne złącza półprzewodnikowe, mogą prowadzić do liniowych charakterystyk na wykresie Motta-Schottky'ego. Pokazano jednak, że parametry uzyskane z analizy otrzymanych prostych nie mogą...
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Nonlinear optical birefringence in Li2SO4-MgO-P2O5 amorphous system -influence of Cu ions
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Investigation of the effect of Au2O3 dopant on elastic properties of PbO-B2O3-SeO2: Er2O3 glass ceramics by ultrasonic techniques
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Electronic conduction in (Bi,Pb)–Sr–Ca–Cu–O glass-ceramics
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Influence of magnetic field on electronic conduction of (Bi,Pb)–Sr–Ca–Cu–O granular superconductors
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Influence of the rare-earth impurities on the Ga and Ge local structure in the Ca3Ga2Ge3O12 glass
PublicationW pracy przedstawione zostały wyniki analizy EXAFS realizowanejza pomocą metody GNXAS dla serii szkieł typu Ca3Ga2Ge3O12 domieszkowanych metalami ziem rzadkich (0.7 wt.% - Ce, Eu, Ho, Er; oraz 1.0 wt.% Nd). Badaniu poddano lokalne otoczenie wokół jonów Ge i Ga. Porównanie wyników z danymi strukturalnymi otrzymanymi dla szkła niedomieszkowanego wskazuje, że domieszka metali ziem rzadkich modyfikuje jedynie otoczenie jonów galu,...
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Electric properties of an Au-CuPc-Au sandwich system: Direct current and low signal admittance studies
PublicationPraca przedstawia wyniki pomiarów stałoprądowych i niskosygnałowej admitancji układu złoto/ftalocyjanina miedzi/złoto. Obserwowana asymetria charakterystyk stałoprądowych sugeruje, że prąd elektryczny płynący przez układ jest prądem ograniczonym elektrodowo i wydajność wstrzykiwania dziur jest uwarunkowana kolejnością nanoszenia warstw. W przypadku wstrzykiwania dziur przez bardziej regularną międzypowierzchnię (tj. gdy ftalocyjanina...
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The structure of liquid lead: EXAFS and MD studies
PublicationPraca poświecona jest analizie widm XAFS zmierzonych na krawędzi L3dla ciekłego ołowiu. W analizie strukturalnej EXAFS zastosowano podejście GNXAS. Przetestowano kilka modeli strukturalnych, zarówno numerycznych (MD-DLE, MD-TB), jak i tych otrzymanych doświadczalnie (ND, XRD) i ostatecznie zrekonstruowano pierwszy pik w parowej funkcji rozkładu, g(r). Zweryfikowano wcześniejsze doniesienia o obserwownym za pomocą metody XAFS gwałtownym...
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Analysis of mixing rules for the Stillinger-Weber potential: a case study of Ge-Si interactions in the liquid phase
PublicationCiekły stop Ge_{0.25}Si_{0.75} symulowano metodą dynamiki molekularnej, przy użyciu potencjału Stillingera-Webera. Badano wpływ parametryzacji członu potencjału odpowiedzialnego za oddziaływania trójciałowe w trójkach nieidentycznych atomów na strukturę symulowanego stopu. Wpływ ten okazał się być znaczący.Zmiany w parametrach rzędu kilku procent skutkowały istotnymi różnicami w parowych funkcjach rozkładu, kątowych funkcjach rozkładu...
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The structure and melting of lead nanocrystalline layer in reduced lead-germanate glass
PublicationNanokrystaliczna warstwa granul Pb na powierzchni szkieł ołowiowo-germanianowych została wytworzona poprzez wygrzewanie w wysokich temperaturach, w atmosferze wodoru. Właściwości tej warstwy silnie zależą od temperatury i czasu redukcji. Artykuł prezentuje rentgenowskie i mikroskopowe badania struktury warstwy oraz wpływ topnienia i krzepnięcia granul Pb na jej przewodnictwo.
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Thermally stimulated currents in amorphous solids due to complex heating regimes
PublicationPodano opis teoretyczny prądów termicznie stymulowanych w ciałach amorficznych. Dokonano rozszerzenia istniejących wzorów przybliżonych na przypadki opóźnionego i krokowego ogrzewania próbki. Otrzymane wyrażenia zweryfikowano za pomocą obliczeń numerycznych dla przypadku wykładniczego rozkładu pułapek.
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Bismuth germanate and bismuth silicate glasses in cryogenic detectors.
PublicationStwierdzono, że przewodnictwo elektryczne redukowanych szkieł silnie zależy od temperatury, czasu reakcji i koncentracji Bi. Zależność przewodnictwa elektrycznego od temperatury jest dobrze opisana przez funkcję ĺ~exp[-(T0/T)n,gdzie n=1/4. Współczynnik emisji wtórnej elektronów jest praktycznie niezależny od stopnia redukcji ale znacznie rośnie po domieszkowaniu szkieł alkalicznymi jonami. Badania dowiodły, że modyfikowane...
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Structural studies and melting of bismuth nanocrystals in reduced bismuthgermanate and bismuth silicate glasses.
PublicationOtrzymano nanostruktury krystalicznego bizmutu w matrycy XO2 (X=Si,Ge) oraz warstwę nanostruktur krystalicznego bizmutu na powierzchni redukowanych w atmosferze wodoru szkieł Bi0.33Ge0.67O1.84 i Bi0.57Si0.43O1.72. Kompozyt Bi-szkło badano metodą DSC, XRD oraz AFM. Zaobserwowano zmniejszenie temperatury topnienia nanokrystalicznego bizmutu znajdującego się w matrycy szkła z 544 K do 387 K oraz do 502 K w przypadku powierzchniowej...
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Mixed electronic-ionic conductivity in transition metal oxide glasses con-taining alkaline ions
PublicationOpisano właściwości elektryczne szkieł z tlenkami metali przejściowych zawierających jony metali alkalicznych. Szczególną uwagę zwrócono na typowe zmiany przewodnictwa występujące przy domieszkowaniu tego typu szkieł jonami metali alkalicznych. Porównano przewodnictwo elektryczne szkieł fosforanowo-żelazowych zawierających jony sodu z przewodnictwem szkieł bizmutowo-miedziowych.
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Influence of controlled crystallization and SrF2 content on the structure and properties of Eu3+ doped phosphate glasses
PublicationNew phosphate glasses and glass-ceramics P2O5–Bi2O3–K2O–Nb2O5-SrF2 doped with Eu were synthesized and studied in this work. The influence of the SrF2 content (0–15 mol%) and the parameters of the heat treatment on their structural and optical properties were investigated. For the above purpose, the structural characterization by FTIR spectroscopy and XRD measurements was carried out, which showed a significant effect of SrF2 on...
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XAFS investigations of nitrided NbN-SiO2 sol-gel derived films
PublicationPraca poświęcona jest wykorzystaniu analizy widm XAFS zmierzonych na krawędzi K atomów Nb do badania struktury cienkich warstw NbN-(100-x)SiO2 (x = 100, 80, 60 mol%) otrzymanych techniką zol-żel poprzez wysokotemperaturowe wygrzewanie warstw Nb2O5-SiO2 w atmosferze NH3. Otrzymana struktura filmu jest złożona z granul NbN ulokowanych w matrycy SiO2. Analiza XAFS pokazuje, że we wszystkich próbkach w lokalnym otoczeniu niobu znajduje...
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The effect of nitrogen on the structure and thermal properties of beryllium-containing Na-(Li)-Si-O-N glasses
PublicationTwo oxynitride glass series with the composition of 35Na2O-5BeO-(60-x)SiO2-xSi3N4 and 9Li2O- 27Na2O-5BeO-(59-x)SiO2-xSi3N4, were prepared. The glasses' topography and structure were studied by Scanning Electron Microscopy and Raman spectroscopy. The composition was analyzed by Inductively Coupled Plasma Optical Emission Spectrometer, SEM-EDS and nitrogen and oxygen elemental analyzer. Na-(Li)-Be-silicate glasses were found to contain...
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The influence of Be addition on the structure and thermal properties of alkali-silicate glasses
PublicationBe-Na-(Li)-Si oxide glasses containing up to 15 mol% of BeO were prepared. Their structure was characterized by X-ray powder diffraction and Raman as well as infrared spectroscopic techniques, while their chemical compositions were examined by Inductively Coupled Plasma Optical Emission Spectrometry. All materials were found to be amorphous and contain Al contaminations from minor dissolution of the alumina crucibles. The results...
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Effect of Nb and Al on in vitro dissolution behavior and structure of Na2O-MgO CaO-P2O5 glasses
PublicationIn vitro dissolution, structure, and thermal properties of the glass series Na2O-MgOsingle bondCaOsingle bondNb2O5 -Al2O3-P2O5 were studied. The dissolution behavior in phosphate-buffered saline (PBS) confirmed the potential bioactive properties of tested glasses. The dissolution process was found to depend on the Al, Nb, and Mg contents. Al, respectively, suppresses the Nb and accelerates the Mg release process from the glasses....
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Structural and luminescence properties of B2O3-Bi2O3-AlF3 glass doped with Eu3+, Tb3+ and Tm3+ ions
PublicationThe B2O3-Bi2O3-AlF3 glass system doped with Eu3+, Tb3+, Tm3+ and triply doped with Eu3+/Tm3+/Tb3+ ions in different molar ratios were successfully synthesized. Glass transition and crystallization temperatures were examined by Differential Scanning Calorimetry (DSC) measurements. X-ray Diffraction (XRD) confirmed the amorphous character of the samples. Fourier Transform Infrared Spectroscopy (FTIR) revealed that the glass matrix...
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COMPOSITE FOOTBRIDGE - SYNERGY EFFECT IN COOPERATION BETWEEN UNIVERSITIES AND INDUSTRY
PublicationPaper presents conditions of science and industry cooperation in Poland (restrictions, barriers, good practice). A key role in initiation of collaboration between units has financial support. What is also important, it is much easier to create innovative solutions on the base of combining the potential of individuals. That is why many countries all over the world look for innovative solutions using budget funds to support grants...
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Application of Diffusion Models in the Analysis of Financial Markets: Evidence on Exchange Traded Funds in Europe
PublicationExchange traded funds (ETFs) are financial innovations that may be considered as a part of the index financial instruments category, together with stock index derivatives. The aim of this paper is to explore the trajectories and formulates predictions regarding the spread of ETFs on the financial markets in six European countries. It demonstrates ETFs’ development trajectories with regard to stock index futures and options that...
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Assessment of the factors influencing on the formation of energy-oriented modes of electric power consumption by water-drainage installations of the mines
PublicationPurpose. Performing the analysis to determine energy-efficient modes and assess the characteristics of the main indicators of electric power consumption by mine water-drainage installations based on the developed research mathematical model. Methods. To achieve the purpose set, a methodology is used to develop the multiple multifactor correlation-regression modeling with respect to the modes of electric power consumption by electrical...
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Application of artificial intelligence into/for control of flexible manufacturing cell
PublicationThe application of artificial intelligence in technological processes control is usually limited. One problem is how to respond to changes in the environment of manufacturing system. A way to overcome the above shortcoming is to use fuzzy logic for representation of the inexact information. In this paper fundamentals of artificial intelligence and fuzzy logic are introduced from a theoretical point of view. Still more the fuzzy...
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Perforating systems in shale gas recovery
PublicationHydraulic fracturing is common method of shale gas recovery. Due to environmental, economical and technological problems many alternative technologies have been developed. One of the most promising group of technologies is based on perforating systems. This paper describes theoretical and practical aspects of best known technologies used to create perforations. New perforating/fracturing technologies which can replace hydraulic fracturing...
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NATURAL DEEP EUTECTIC SOLVENTS IN EXTRACTION PROCESS
PublicationDeveloping new, eco-friendly solvents which would meet technological and economic demands is perhaps the most popular aspects of Green Chemistry. Natural deep eutectic solvents (NADES) fully meet green chemistry principles. These solvents offer many advantages including biodegradability, low toxicity, sustainability, low costs and simple preparation. This paper provides an overview of knowledge regarding NADES with special emphasis...
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Spatial Modelling in Environmental Analysis and Civil Engineering
PublicationAs can be seen, Spatial Modelling in Environmental Analysis and Civil Engineering applies to a multitude of applications. In an attempt to bring the topic closer to potential readers, the special issue referred to security methods, optimization of calculations, conducting measurements and empirical tests. Each article has made an original contribution to the development of practical science that can be replicated by researchers...
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Implementing a CSR Strategy in a Small Enterprise - a Case Study
PublicationAs a result of employees’ meetings conducted according to Kaizen workshops formula and seeking new development directions for the company (including CSR actions) various product and service innovations have been implemented. Also a market niche has been discovered, and as a consequence the company gained another profitable aspect of the business activity. The atmosphere and contribution in performing tasks have improved among...
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Searching for innovation knowledge: insight into KIBS companies
PublicationThe paper analyses the activity of research for “innovation knowledge”—here defined as knowledge that can lead to the introduction of service innovations—by Knowledge-Intensive Business Services (KIBS) companies. It proposes a classification of the possible search approaches adopted by those companies based on two dimensions: the pro-activity of search efforts and the source primarily used. Such classification is then discussed...
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3D GIS technology. More accurate GIS-every-day-reality
PublicationGeographical space can be described with the Geographic Information System (GIS). It consists of software, hardware, data, algorithms, procedures for processing information and accessibility, as well as the people who use the system and the legal, technological and organisational procedures. GIS is commonly applied in such studies as “Environmental Protection Programmes”, and in numerous reports and documents regarding spatial...
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Android OS: A Review
PublicationDue to the technological development, mobile terminals have evolved into functionally sophisticated devices such as smartphones and tablets. The Android platform has become one of the most popular operating system with millions of new users each year. Despite many studies, none have provided a comprehensive description of this operating system. In this paper we present a review of the Android OS. We describe the platforms history...
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ECONOMICAL AND SAFE METHOD OF GRANULAR MATERIAL STORAGE IN SILOS IN OFFSHORE PORT TERMINALS
PublicationThe article discusses issues related with storage of granular materials in silos made of corrugated sheets and reinforced with vertical ribs. Advantages and disadvantages of these structures are named, and typical technological solutions used by largest silo producers are presented. Moreover, basic assumptions of Eurocode 3 are discussed in the context of determining the buckling load capacity of a ribbed jacket. Alternative methods...
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On the Disaster Resiliency within the Context of 5G Networks : The RECODIS Experience
PublicationNetwork communications and the Internet pervade our daily activities so deeply that we strongly depend on the availability and quality of the services they provide. For this reason, natural and technological disasters, by affecting network and service availability, have a potentially huge impact on our daily lives. Ensuring adequate levels of resiliency is hence a key issue that future network paradigms, such as 5G, need to address. This...
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Optimization of clamping stiffness during milling of high-dimensional structures with the use of techniques of experiment – aided virtual prototyping
PublicationThe subject of this paper is a method of searching for conditions of minimizing the vibration level of a tool-high dimensional flexible workpiece, at unchangeable technological parameters of the machining process. It depends on repeatable change of the values of the stiffness coefficients as soon as an optimal vibration state of the workpiece approaches. There are assessed the values of dominant ”peaks” in the frequency spectra...
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DESIGN LOGICAL LINGUISTIC MODELS TO CALCULATE NECESSITY IN TRUCKS DURING AGRICULTURAL CARGOES LOGISTICS USING FUZZY LOGIC
Publication: The study is aimed to develop the logic-linguistic models to design a number of rules for the correct calculation of the vehicles needed, taking into account the technical, technological, and weather and climate conditions of the harvesting and transport complex. The article has shown that the construction of the design of logic-linguistic models was not performed earlier to solve the problem of the agro-industrial production...
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An Overview of Sport and the Future Smart Cities
PublicationOne of the main challenges for future cities is to strengthen the role of people and their activities. Therefore, sport provides an opportunity to engage in physical activity, connecting citizens to the city. The question of how sport influences the development of cities and the concept of future smart cities arises. The aim of this study is to examine the relationship between sport and the concept of smart cities by identifying...
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Photogrammetric Development Of The Threshold Water At The Dam On The Vistula River In Wloclawek From Unmanned Aerial Vehicles (Uav)
PublicationBarrage in Wloclawek (Poland) was designed by Hydroprojekt and built in the years of 1962 - 1970 as the first stage of the planned Lower Vist ula Cascade. Cascade design assumed the construction of 8 dams in Wyszogr o d, Plock, Wloclawek, Nieszawa (Ciechocinek as an option), Solec Kujawski, Chelmno, Opalen and Tczew. Nieszawa dam was supposed to ensure the maintenance of an adequate free surface...
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The Employment of Ukrainians as an Opportunity to Fill the Labour Market in Poland – Selected Issues
PublicationThe labour market in Poland has undergone signifi cant transformations over the past two decades. The observed changes have been infl uenced by various factors related to, among other things, the possibility of free movement of the population resulting from membership of EU structures, demographic changes, technological changes, and the automation and robotisation of production processes. Demographic change is becoming a signifi...
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Niekonwencjonalne koła pojazdów
PublicationPrzedstawiono sposoby zapobiegania skutkom utraty ciśnienia w oponach pneumatycznych. Zaprezentowano koła niepneumatyczne, zastosowane w pojeździe księżycowym. Omówiono wyniki badań kół kompozytowych. Przedstawiono najnowsze rozwiązania konstrukcyjne koł niepneumatycznych przeznaczonych do pojazdów mechanicznych.
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Balance error generated by numerical diffusion in the solution of Muskingum equation
PublicationIn the paper the conservative properties of the lumped hydrological models with variable parameters are discussed. It is shown that in the case of the non-linear Muskingum equation the mass balance is not satisfied. The study indicates that the mass balance errors are caused by the improper form of equation and by the numerical diffusion which is generated in the solution. It has been shown that the classical way of derivation...
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The Diffusion of Information and Communication Technologies
PublicationThis book provides extensive evidence on information and communication technologies development patterns and dynamics of this process across developed economies over the period 1980 to the present day. It adopts newly developed methodology to identification of the ‘critical mass’ and isolation of technological takeoff intervals, which are intimately related to the process of technology diffusion. The statistically robust analysis...