Search
Filters
total: 139
filtered: 136
Search results for: BIOINDICATOR DIFFERENTIAL DISPLAY EXPRESSED SEQUENCE TAGS POLYCYCLIC AROMATIC HYDROCARBONS
-
cDNA fingerprint from the hepatopancreatic glands of pond snails (Lymnaea stagnalis) exposed to benzo[a]pyrene
PublicationIdentification of differentially expressed genes that could be potentially used as biomarkers of PAH exposure of common invertebrate animal (like freshwater snail) would be a valuable resource for investigators interested in toxicology and biomonitoring of aquatic environments. Therefore, the aim of this research was to investigate effects of waterborne benzo[a]pyrene (B[a]P) exposure on mRNA expression in the pond snail’s (Lymnaea...
-
A screening of select toxic and essential elements and persistent organic pollutants in the fur of Svalbard reindeer
PublicationReindeers play an important role in the polar ecosystem, being long-lived sole vegetarians feeding on local vegetation. They can be used as a valuable bioindicator, helping us to understand contaminants’ impact on the polar terrestrial ecosystem. Still, scarce data exist from research in which polar herbivores (especially those from the European parts of the Arctic) were a major study subject for trace elements and persistent organic...
-
The occurrence of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in the chosen area of Svalbard
PublicationIn the recent years, scientists have been paying more attention to the impact of compounds of anthropogenic origin on the environment. Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) are both groups of stable organic compounds, difficult to biodegrade, and potentially toxic. Because of their affinity to lipids, they can accumulate in fat tissue and exert influence on animal health. This paper present...
-
Arctic as a reservoir for polycyclic aromatic hydrocarbons and polychlorinated biphenyls- water samples from Foxfonna glacier
PublicationPolycyclic aromatic hydrocarbons and polychlorinated biphenyls are groups of stable compounds, hard to biodegrade, potentially toxic. Their presence in Arctic environment may have a big impact on natural balance, fauna and flora. Although Arctic areas should be unpolluted, some amounts of pollutants are transferred from lower latitudes with sea currents and air masses. This paper presents the amounts of selected persistent organic...
-
Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons – A review
PublicationAromatic hydrocarbons (AHs) are toxic environmental contaminants presented in most of the environmental matrices. Advanced oxidation processes (AOPs) for the removal of AHs in the account of complete mineralization from various environmental matrices have been reviewed in this paper. An in-depth discussion on various AOPs for mono (BTEX) and polyaromatic hydrocarbons (PAHs) and their derivatives is presented. Most of the AOPs were...
-
Polychlorinated Biphenyls (PCBs) and Polycyclic Aromatic Hydrocarbons (PAHs): Sediments and Water Analysis
PublicationUnfavorable side effects of different forms of anthropogenic activities can be found anywhere in the world. One of the basic characteristics of pollutants entering marine and ocean waters is their spread and movement in the global ocean. A portion of the substances entering the marine environment is rapidly degraded by chemical processes occurring in the air, sediments, and water, thereby losing their toxic properties. The biggest...
-
Method for the simultaneous determination of monoaromatic and polycyclic aromatic hydrocarbons in industrial effluents using dispersive liquid-liquid microextraction with GC-MS
PublicationWe present a new method for simultaneous determination of 22 monoaromatic and polycyclic aromatic hydrocarbons in postoxidative effluents from the production of petroleum bitumen using dispersive liquid-liquid microextraction coupled to gas chromatography and mass spectrometry. The eight extraction parameters including the type and volume of extraction and disperser solvent, pH, salting out effect, extraction and centrifugation...
-
Contamination of Runoff Water at Gdańsk Airport (Poland) by Polycyclic Aromatic Hydrocarbons (PAHs) and Polychlorinated Biphenyls (PCBs)
PublicationAirport runoff can contain high concentrations of various pollutants, in particular polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), the environmental levels of which have to be monitored. Airport runoff water samples, collected at the Gdańsk-Rębiechowo Airport from 2008 to 2009, were analysed for PAHs and PCBs by gas chromatography. The aromatic fractions were separated by liquid-liquid extraction...
-
Hydrophobic deep eutectic solvents as “green” extraction media for polycyclic aromatic hydrocarbons in aqueous samples
PublicationThe paper presents novel nonionic and hydrophobic deep eutectic solvents which were synthesized from natural compounds, i.e., thymol, ±camphor, decanoic and 10-undecylenic acids. Fundamental physicochemical properties of the synthesized deep eutectic solvents were determined, followed by their application as extractants in ultrasound-assisted dispersive liquid-liquid microextraction to isolate and enrich polycyclic aromatic hydrocarbons...
-
Sample preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacuum residue and bitumen
PublicationThis paper describes a novel method of samplepreparation for the determination of trace concentrations ofpolycyclic aromatic hydrocarbons (PAHs) in high-boilingpetroleum products. Limits of quantitation of the investigatedPAHs in materials of this type range from tens ofnanograms per kilogram to <20 μg/kg. The studies revealedthat in order to separate most of interferences from theanalytes without a significant loss of PAHs, it...
-
Polycyclic aromatic hydrocarbons in smoked fish - a critical review
PublicationDym wędzarniczy zawiera wśród setek składników co najmniej 100 wielopierścieniowych węglowodorów aromatycznych (WWA). Benzo{a}piren (BaP) jest uważany za wskaźnikowy, rakotwórczy WWA w wędzonych rybach. Współczesne procedury analityczne obejmujące ekstrakcję węglowodorów z matrycy, oczyszczenie, rozdzielenie metodą GC lub HPLC przy użyciu, odpowiednio, detektora MS albo FLD, umożliwiają oznaczenie indywidualnych WWA w wędzonych...
-
A hierarchical porous composite magnetic sorbent of reduced graphene oxide embedded in polyvinyl alcohol cryogel for solvent‐assisted‐solid phase extraction of polycyclic aromatic hydrocarbons
PublicationA hierarchical porouscomposite magnetic sorbent was fabricated and applied tothe dispersive solvent-assisted solid-phase extraction of five polycyclic aromatichydrocarbons. A sorbent was first prepared by incorporating graphene oxide,calcium carbonate, and magnetite nanoparticles into a polyvinyl alcohol cryo-gel. The graphene oxide was converted to reduced graphene oxide using ascorbicacid and a hierarchical porous structure was...
-
Polycyclic aromatic hydrocarbons as test probes to investigate the retention behavior of 1,3-alternate calix[4]arene silica-bonded stationary phases
PublicationA series of polycyclic aromatic hydrocarbons (PAHs) of different size and shape has been used to characterize the chromatographic behavior of five calix[4]arene stationary phases in 1,3-alternate conformation synthesized in our laboratory. The selection of linear, fourring nonlinear, and five-ring PAHs gave data on selectivity changes across range of the calix[4]arene columns. Retention of the 12 aromatic solutes has been evaluated...
-
Exploring avian exposure to parent polycyclic aromatic hydrocarbons (PAHs): Using the common eider Somateria mollissima in a global context
PublicationCompared to other organic contaminants, birds are rarely studied for their exposure to polycyclic aromatic hydrocarbons (PAHs), mainly due to their effective metabolization of parent PAHs. However, as some studies suggest, exposure to PAHs may result in adverse health effects including decreased survival, especially following oil spills. In the present study, we analyzed samples from a sea duck, the common eider Somateria mollissima...
-
Determination of polycyclic aromatic hydrocarbons (PAHs) and other organic pollutants in freshwaters on the western shore of Admiralty Bay (King George Island, Maritime Antarctica).
PublicationOrganic contamination in freshwater samples has never been investigated at the western shore of Admiralty Bay. Therefore, the presence of polycyclic aromatic hydrocarbons (PAHs) in five different sites distributed along a shore running from the Arctowski Station to the Baranowski Glacier was studied. Moreover, organic compounds such as n-alkanes, toluene and ethylbenzene were also noted. Increased ΣPAHs in late Austral summer 2016...
-
The presence of polycyclic aromatic hydrocarbons in disposable baby diapers: A facile determination method via salting-out assisted liquid-liquid extraction coupled with gas chromatography-mass spectrometry
PublicationIn this paper we demonstrate the development of the extraction procedure of polycyclic aromatic hy- drocarbons from baby diapers along with their quantification by gas chromatography-mass spectrometry. Apart from covering plastic foil, disposable baby diapers contain sorbents intended to absorb urine and feces. A hygroscopic, adsorptive, and tough-to-homogenize fibrous sorbent, represents an analytical chal- lenge to analytical...
-
Activated biochars reduce the exposure of polycyclic aromatic hydrocarbons in industrially contaminated soils
Publication -
The effects of exogenous application of melatonin on the degradation of polycyclic aromatic hydrocarbons in the rhizosphere of Festuca
Publication -
Determination of parent and methylated polycyclic aromatic hydrocarbons in water samples by dispersive liquid–liquid microextraction–two dimensional gas chromatography–time-of-flight mass spectrometry
PublicationPolycyclic aromatic hydrocarbons (PAHs) are contaminants frequently found in environmental waters. Owing to their toxic effects, it is important to develop analytical methodologies that allow their fast and reliable determination. Dispersive liquid–liquid microextraction (DLLME) allows a quick extraction of analytes with little organic solvent consumption. The best results regarding sample preparation are obtained when 40 mL of...
-
Determination of polycyclic aromatic hydrocarbons in bulk precipitation andrunoff waters in an urban region (Poland)
PublicationOznaczono 16 wielopierścieniowych węglowodorów aromatycznych w próbkach opadów atmosferycznych (10 stacji zbierania próbek) i wód spływnych (5 stacji) zbieranych na terenie Trójmiasta. Podjęto próbę ustalenia korelacji pomiędzy stężeniem analitów z grupy WWA i intensywnym ruchem pojazdów mechanicznych oraz sposobem ogrzewania mieszkań w okolicach punktu zbierania próbek.
-
Miniaturised analytical procedure of determining polycyclic aromatic hydrocarbons and polychlorinated biphenyls in bottom sediments
PublicationOpisano metodę oznaczania bardzo niskich stężeń polichlorowanych bifenyli w obecności wysokich zawartości wielopierścieniowych węglowodorów aromatycznych. Analizie techniką GC-MS poddawany jest ekstrakt z 1 g próbki osadu. Jako standardy wewnętrzne zastosowano Naftalen-d8, benzo[a]antracen-d12 i PCB 209. Średni odzysk standardów przedstawiał się następująco: 65, 55 i 60% odpowiednio. Do izolacji frakcji PCB stosowano niekomercyjne...
-
A multi‑criteria approach to investigate spatial distribution,sources, and the potential toxicological effect of polycyclic aromatic hydrocarbons (PAHs) in sediments of urban retention tanks
PublicationBottom sediments deposited in retention tanks (RTs) located on two urban streams (Oliwski and Strzyza) in the central part of Gdansk (Poland) were analysed for polycyclic aromatic hydrocarbons’ (PAHs) content. PAHs were extracted from samples with methylene chloride, then the extracts were subjected to clean-up applying the solid phase extraction (SPE) method. Quantitative and qualitative determination of 16 PAHs was performed...
-
Geochemical markers and polycyclic aromatic hydrocarbons in solvent extracts from diesel engine particulate matter
Publication -
Stability studies of selected polycyclic aromatic hydrocarbons in different organic solvents and identification of their transformation products
PublicationGłównym problemem w laboratoriach analitycznych jest konserwacja próbek i ekstraktów przeznaczonych do analizy. Rozpatrując procesy degradacji z analitycznego punktu widzenia i związanej z tym wiarygodności uzyskiwanych wyników pod uwagę należy wziąć wpływ procesów degradacji w badanym elemencie środowiska na poziom stężenia składników śladowych; wpływ tych samych procesów na poziom składników śladowych w już pobranych próbkach...
-
Enzymatic Activity and Content of Polycyclic Aromatic Hydrocarbons (PAHs) in Soils under Low-Stack Emission in Lublin
Publication -
Development of laboratory reference material: Soil 1. Baseline and highly elevated concentrations of metals and polycyclic aromatic hydrocarbons
PublicationMateriały odniesienia odgrywają istotną rolę we wszystkich elementach systemu zapewnienia jakości wyników pomiarów. Komisja Europejska od ponad 20 lat wspiera programy badawcze ukierunkowane na poprawę jakości pomiarów fizycznych, biologicznych i chemicznych przez używanie odpowiednich materiałów odniesienia. Temat ich stosowania i perspektyw w Europie i na świecie w tej dziedzinie jest przedmiotem licznych dyskusji. Aktualnie...
-
Optimization of a procedure for the simultaneous extraction of polycyclic aromatic hydrocarbons and metal ions by functionalized and non-functionalized carbon nanotubes as effective sorbents
Publication -
Remediation of Polycyclic Aromatic Hydrocarbons Contaminated Soil Using Combined Ozonation and Peroxy-Acid Treatment in the Site of Abadan Oil Refinery
Publication -
Emission sources and full spectrum of health impacts of black carbon associated polycyclic aromatic hydrocarbons (PAHs) in urban environment: A review
Publication -
Concentration and sources of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in surface soil near a municipal solid waste (MSW) landfill
PublicationDue to a continuous demand of land for infrastructural and residential development there is a public concern about the condition of surface soil near municipal solid waste landfills. A total of 12 surface (0–20 cm) soil samples from a territory near a landfill were collected and the concentration of 16 PAHs and 7 PCB congeners were investigated in these samples. Limits of detection were in the range of 0.038–1.2 μg/kg for PAHs...
-
DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS IN SOIL SAMPLES USING ULTRASONIC PROBE AND SALT-ASSISTED LIQUID-LIQUID EXTRACTION COUPLED WITH HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY
Publication -
Graphene oxide aerogels for adsorptive separation of aromatic hydrocarbons and cycloalkanes
PublicationEfficient separation of benzene and cyclohexane has critical importance for production of commodity chemicals, and is one of the most challenging separations in the industry. Physisorption by recyclable, porous solids has a significant potential in substituting energy-intensive azeotropic or extractive distillation methods. Reduced graphene oxide aerogels (rGOAs) are emerging materials holding great promise for connecting unique...
-
Photoelectrochemical and thermal characterization of aromatic hydrocarbons substituted with a dicyanovinyl unit
Publication -
Performance of the Direct Sequence Spread Spectrum Underwater Acoustic Communication System with Differential Detection in Strong Multipath Propagation Conditions
PublicationThe underwater acoustic communication (UAC) operating in very shallow-water should ensure reliable transmission in conditions of strong multipath propagation, significantly disturbing the received signal. One of the techniques to achieve this goal is the direct sequence spread spectrum (DSSS) technique, which consists in binary phase shift keying (BPSK) according to a pseudo-random spreading sequence. This paper describes the DSSS...
-
A review of the biogeochemical controls on the occurrence and distribution of polycyclic aromatic compounds (PACs) in coals
Publication -
Microbiological, biochemical and ecotoxicological evaluation of soils in the area of biochar production in relation to polycyclic aromatic hydrocarbon content
Publication -
Thermophysical properties and phase equilibria study of the binary systems {N-hexylquinolinium bis(trifluoromethylsulfonyl)imide+aromatic hydrocarbons, or an alcohol}
Publication -
Procedure for and results of simultaneous determination of aromatic hydrocarbons and fatty acids methyl esters in diesel fuels by high performance liquid chromatography
PublicationW pracy przedstawiono taki sposób modyfikacji metody EN-12916 /ASTM D-6591, który zapewnia jednoczesne oznaczenie poszczególnych grup węglowodorów aromatycznych, całkowitej zawartości węglowodorów poliaromatycznych oraz zawartości FAME w oleju napędowym. Stosuje się nadal detektor refraktometryczny i elucję n-heptanem, jednak przepływ zwrotny eluentu jest wykonywany po elucji policyklicznych węglowodorów aromatycznych. Dodatkowo...
-
Specjacja fizyczna analitów z grupy wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym = Physical speciation of polycyclic organic hydrocarbons in water environment
PublicationW oparciu o literaturę opisano zagadnienia związane ze specjacją fizyczną wielopierścieniowych węglowodorów aromatycznych w środowisku wodnym. Przedstawiono podstawowe zagadnienia związane z losami środowiskowymi tych związków oraz z ich fizyczną analityką specjacyjną.
-
Detection and removal of priority substances and emerging pollutants from stormwater: case study of the Kołobrzeska collector, Gdańsk, Poland
PublicationProgressive urban development affects environmental balance and disrupts the hydrologic cycle, in which rainfall plays a significant role. Since rainwater is considered a valuable resource of the environment, many technical solutions are implemented that enable effective rainwater management. On the other hand, stormwater runoff from urban areas contains numerous (also toxic) substances, and therefore should be properly treated....
-
Multi-Decision Analysis for selection of the best procedure for PAHs determination in smoked food.
PublicationMaking a proper decision in multifacitated situation is very challenging task. Especially, if there are many alternatives and criteria, even contradictory ones. The support tools may be application of MultiCriteria Decision Analysis methods. In this study the application of PROMETHEE...
-
Occurrence of specific pollutants in a mixture of sewage and rainwater from an urbanized area
PublicationUrban runoff appears to be a pathway for transferring new emerging pollutants from land-based sources to the aquatic environment. This paper aimed to identify and describe the groups of pollutants present in rainwater surface runoff as well as their mixture with wastewater in the combined sewer system from urbanized catchments and to determine the correlations between these pollutants. Four leading groups of new emerging pollutants...
-
Monetary values estimates of solvents emissions
PublicationThe impact values for environmental emissions of 52 solvents are estimated and expressed in monetary units. The impact values of solvents present in the air are calculated on the basis of 13 impact indicators and for solvents present in water on additional 2 impact indicators. These impact values are weighted with the results obtained with multi-compartment distribution model, allowing to calculate the fraction of solvent emitted...
-
Polychlorinated biphenyls (PCBs) in bottom sediments: Identification of sources
PublicationPolychlorinated biphenyls (PCBs) can enter the environment from various sources. They are synthetic chemicals and as such are present in the environment mainly as mixtures containing various amounts of PCB congeners. It is therefore difficult to pinpoint the source of PCB emissions into the environment and the pathways along which they migrate there. The situation is different where locating the emission sources of polycyclic aromatic...
-
Application of Diagnostic Ratios of PAHs to Characterize the Pollution Emission Sources
PublicationThe paper summarizes the potential of application of parent polycyclic aromatic hydrocarbons (PAHs) to identify their emission sources. Four parent PAHs diagnostic ratios are used for this purpose: anthracene/(anthracene + phenanthrene), fluoranthene/(fluoranthene + pyrene), benzo[a]pyrene/(benzo[a]pyrene + chryzene) and indeno[1,2,3-c,d]pyrene/(indeno[1,2,3-c,d]pyrene + benzo[g,h,i]perylene). The compounds of each ratio have the...
-
Persistent organic pollutants (POPs) as an indicator of surface water quality in the vicinity of the Polish Polar Station, Horsund
PublicationSurface waters were collected in the vicinity of the Polish Polar Station in Hornsund (Svalbard) to determine their concentration of various persistent organic pollutants (POPs), such as polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs). In addition, parameters such as pH, SEC and TOC were measured. In total, 15 samples of lake water from and 15 samples of stream water were analysed. The sampling took...
-
Contaminants in airport runoff water
PublicationDespite the many positives ensuing from the rapid expansion of the air transport sector, airport operations as a whole are a substantial source of environmental pollution.Increases in aviation developments have serious consequences on the surrounding air, soil and water bodies like lakes, rivers and ground water. The present work deals with the determination of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls...
-
Solid phase microextraction–comprehensive twodimensional gas chromatography–time-of-flight mass spectrometry: a new tool for determining PAHs in airport runoff water samples
Publicationfundamental aspect of airport operations is the pollution caused by airport runoff waters. Polycyclic aromatic hydrocarbons (PAHs) are one of the most important groups of xenobiotics which are commonly found in runoff water originating from airports. Only very limited data on the analysis of airport runoff water have been published until now. Therefore, a reliable and accurate analytical method based on headspace solid-phase microextraction...
-
Contamination of Arctic Lakes with Persistent Toxic PAH Substances in the NW Part of Wedel Jarlsberg Land (Bellsund, Svalbard)
PublicationThe expansion of glacier‐free areas in polar regions favours the appearance of lakes in the non‐glaciated parts of glacier basins. This paper presents the differentiation of organic compound concentrations in fifty‐four Arctic lakes collected in four locations (Logne Valley, in the vicinity of the Scott, Renard and Antonia glaciers). We cover meteorological measurements, chemical analysis of sixteen dioxin‐like compounds (Polycyclic...
-
Stopniowa chromatografia cienkowarstwowa w normalnych układach faz (NP-TLC), jako technika rozdzielania i oceny składu grupowego frakcji asfaltenowych z utleniania pozostałości próżniowej ropy naftowej
PublicationW pracy opisano wyniki badań nad opracowaniem metodyki oceny składu grupowego i czystości frakcji asfaltenowych techniką chromatografii cienkowarstwowej w normalnych układach faz (NP-TLC). Skupiono się na doborze takich parametrów/warunków rozdzielania, jak stężenie i masa próbki, a także skład i kolejność eluentów stosowanych podczas rozwijania chromatogramów TLC. Zastosowana trój-stopniowa metodyka polega na nałożeniu 5 µL frakcji...