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Search results for: DLLME-GC-MS
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Analytical Strategies and Applications in Lipidomics
PublicationLipidomics is a field of study aiming at a comprehensive analysis of a set of lipids in biological systems. This includes both quantitative and qualitative characterization of lipid profiles, comparative studies of lipidomes, and analysis of lipid-protein interactions. Lipids are structurally diversified that make their analysis a challenging task. The constant advances in analytical technologies, especially in the field of high-performance...
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Copper(II) complexes of 7-amino-2-methylchromone and 7-aminoflavone: Magneto-structural, spectroscopic and DFT characterization
PublicationFour new complexes of copper(II) consisting of two different chromone derivatives with carbonyl and amine donor atoms: 7-aminoflavone (L1) and 7-amino-2-methylchromone (L2), were synthesized and characterized by X-ray diffraction, UV–Vis, FT-IR, EPR spectroscopy, MS and elemental analysis. In all four compounds, the chromone derivatives were found to act as monodentate O- or N-ligands. The structural characteristics of 1a and...
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Rapid and Green Separation of Mono- and Diesters of Monochloropropanediols by Ultrahigh Performance Supercritical Fluid Chromatography–Mass Spectrometry Using Neat Carbon Dioxide as a Mobile Phase
PublicationThis study demonstrates the effect of column selectivity and density of supercritical carbon dioxide (SC-CO2) on the separation of monochloropropanediol (MCPD) esters, known as food toxicants, using SC-CO2 without addition of cosolvent in ultrahigh performance supercritical fluid chromatography–mass spectrometry (UHPSFC-MS). This study shows that over 20 2-monochloropropanediol (2-MCPD) and 3-monochloropropanediol (3-MCPD) mono-...
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Przyrząd wirtualny do szacowania niepewności pomiaru mocy chwilowej.
PublicationW artykule przedstawiono zagadnienie dotyczące wykorzystania przyrządu wirtualnego do szacowania niepewności pomiaru mocy chwilowej. Analiza dotyczy układu do diagnostyki łożysk tocznych, składającego się z przetworników: napięcia oraz prąd-napięcie, który wykorzystano do badań diagnostycznych łożysk silników indukcyjnych metodą, opartą na pomiarze i analizie sygnałów napięcia i prądu pobieranych przez maszynę. Zaprezentowano opracowany...
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Preliminary Citation and Topic Analysis of International Conference on Agile Software Development Papers (2002-2018)
PublicationThis study utilizes citation analysis and automated topic analysis of papers published in International Conference on Agile Software Development (XP) from 2002 to 2018. We collected data from Scopus database, finding 789 XP papers. We performed topic and trend analysis with R/RStudio utilizing the text mining approach, and used MS Excel for the quantitative analysis of the data. The results show that the first five years of XP...
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Design, synthesis and biological evaluation of novel N-phosphorylated and O-phosphorylated tacrine derivatives as potential drugs against Alzheimer’s disease
PublicationIn this work, we designed, synthesised and biologically investigated a novel series of 14N- and O-phosphorylated tacrine derivatives as potential anti-Alzheimer’s disease agents. In the reaction of 9-chlorotacrine and corresponding diamines/aminoalkylalcohol we obtained diamino and aminoalkylhydroxy tacrine derivatives. Next, the compounds were acid to give final products 6–13 and 16–21 that were characterised by 1H, 13 C, 31P...
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Preparation of Allyl Alcohol Oligomers Using Dipicolinate Oxovanadium(IV) Coordination Compound
PublicationCurrently, new precatalysts for olefin oligomerization are being sought in the group of vanadium(IV) complexes. Thus, the aim of our research was to examine the catalytic activity of the oxovanadium(IV) dipicolinate complex [VO(dipic)(H2O)2] 2 H2O (dipic = pyridine-2,6-dicarboxylate anion) in 2-propen-1-ol oligomerization as well as to characterize oligomerization products using matrix-assisted laser desorption/ionization–time-of-flight...
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Nanodiamond phantoms mimicking human liver: perspective to calibration of T1 relaxation time in magnetic resonance imaging
PublicationPhantoms of biological tissues are materials that mimic the properties of real tissues. This study shows the development of phantoms with nanodiamond particles for calibration of T1 relaxation time in magnetic resonance imaging. Magnetic resonance imaging (MRI) is a commonly used and non-invasive method of detecting pathological changes inside the human body. Nevertheless, before a new MRI device is approved for use, it is necessary...
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Measurements of the coefficients of current distribution between two generators operating in parallel in a ship power station
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data, expressing the coefficients...
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Measurements of apparent power distribution in a ship power station with two generators working in parallel
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data, expressing an apparent...
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C-1311 (Symadex), a potential anti-cancer drug, intercalates into DNA between A and G moieties. NMR-derived and MD-refined stereostructure of the d(GAGGCCTC) 2 :C-1311 complex
PublicationImidazoacridinone C-1311 (Symadex®) is an antitumor agent which has been recommended for Phase II clinical trials a few years ago. Previously, it was shown experimentally that during the initial stage of its action C-1311 forms stable intercalation complexes with DNA duplexes. Herein, a NMR-derived stereostructure of d(GAGGCCTC)2:C-1311 complex was reported. The ligand was found locating itself between A and G moieties, forming...
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Determination of volatile organohalogen compounds in urban precipitation in Tricity area (Gdańsk, Gdynia, Sopot).
PublicationPróbki opadów atmosferycznych pobierano w 4 punktach na terenie Gdańska i Sopotu, od listopada 2000 do maja 2001. Oznaczano chloro- i bromopochodne metanu, etanu i etenu. Lotne związki chlorowcoorganiczne oznaczane były metodą bezpośredniego nastrzyku próbki wody do kolumny kapilarnej z wykorzystaniem detektora wychwytu elektronów na etapie detekcji (DAI-GC-ECD). Najczęściej oznaczanymi związkami na wszystkich stacjach pobierania...
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Occurence volatile halogenoorganic compounds in precipitation in an urban area in Tricity (Gdańsk-Gdynia-Sopot). Występowanie lotnych związków fluorowcoorganicznych w opadach atmosferycznych na terenie miejskim.
PublicationSzczególne znaczenie wśród zanieczyszczeń występujących w wielkomiejskim powietrzu atmosferycznym, mają lotne związki chlorowcoorganiczne, ze względu na powszechność stosowania i trwałość (od 77 dni - CH2Cl2 do 67 lat - CCl4). Większość związków chlorowcoorganicznych stanowi zagrożenie dla życia ludzkiego przez swoje kancerogenne, mutagenne i teratogenne działanie. Związki chlorowcoorganiczne obecne w środowisku są w większości...
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Determination of polybrominated diphenyl ethers (PBDEs) in dust samples collected in air conditioning filters of different usage – method development
PublicationThis study presents the results of studies aimed at the development of an analytical procedure for separation, identification, and determination of PBDEs compounds in dust samples collected from automotive cabin air filters and samples collected from filters installed as part of the air purification system in academic facilities. Ultrasound-assisted dispersive solid phase extraction (UA-dSPE) was found to perform better in terms...
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The computational methods in the development of a novel multianalyte calibration technique for potentiometric integrated sensors systems
PublicationIn recent years, integration and miniaturization of ion-selective electrodes (ISEs) have brought many benefits resulting in the possibility of simultaneous determination of the ions concentration in small volume samples. One of the key problems related to the preparation of potentiometric integrated sensors systems (PISSs) is a calibration procedure due to the necessity to calibrate each particular sensor separately. The main aim...
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PBL oczami studentów i wykładowców
EventsWięcej o innych spotkaniach i szkoleniach, które będą odbywać się w każdy piątek od godz. 13.15 na platformie MS Teams, można przeczytać na stronie https://cne.pg.edu.pl/szkolimy/dydaktyczne-piatki.
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Development of new silica-based sorption phase with immobilized ionic liquids for the determination organic pollutants from environmental samples using solid phase microextraction and gas chromatography (SPME-GC).
ProjectsProject realized in Department of Physical Chemistry according to UMO-2014/15/N/ST4/02732 agreement from 2015-08-05
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Spektrometria mas jako narzędzie umożliwiające poznanie metabolomu-główne strategie i wyzwania
PublicationBadania z zakresu metabolomiki ukierunkowane są na wykrywanie i oznaczanie endogennych związków małocząsteczkowych o masie <1000 Da (np. aminokwasy, cukry, lipidy) w próbkach biologicznych takich jak płyny biologiczne (głównie krew i mocz) oraz kondensaty wydychanego powietrza. Ze względu na szerokie spektrum występowania i niskie poziomy stężeń metabolitów w próbkach, analizy metabolomiczne wymagają stosowania technik o wysokiej...
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Bioactive compounds and the antioxidant capacity in new kiwi fruit cultivars
PublicationThe aim of this investigation was to find the best among seven different kiwi fruit cultivars (‘Hayward’, ‘Daheung’, ‘Haenam’, ‘Bidan’, ‘Hort16A’, ‘Hwamei’ and ‘SKK12’) for human consumption and to classify them as groups. Therefore, the contents of bioactive compounds and the level of antioxidant capacities of these cultivars were determined in four different extracts and compared. It was found that the contents of the bioactive...
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How proteins bind to DNA: target discrimination and dynamic sequence search by the telomeric protein TRF1
PublicationTarget search as performed by DNA-binding proteins is a complex process, in which multiple factors contribute to both thermodynamic discrimination of the target sequence from overwhelmingly abundant off-target sites and kinetic acceleration of dynamic sequence interrogation. TRF1, the protein that binds to telomeric tandem repeats, faces an intriguing variant of the search problem where target sites are clustered within short fragments...
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Efficient optimization approaches for microwave assisted extraction of high-quality antioxidant compounds from Salvia officinalis L.: UHPLC-HRMS differential analysis of phenolic profiles obtained by ultrasound and microwave extraction
PublicationThe study aims to optimize MAE of total phenolic compounds (TPC) and antioxidant capacity from Salvia officinalis L. leaves using a definitive screening design (DSD) and I-optimal design. UHPLC-HRMS analysis was used to identify and compare the composition of MAE and UAE optimal extracts. The results showed that DSD and I-optimal design were successfully applied for the optimization of MAE targeting phenolics and other antioxidants...
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Assessment of the impact of bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes)
PublicationThe assessment of the impact of the bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes) Tecoflex® and Tecothane® is presented. The polyurethane samples were incubated with pure cultures of the microorganisms at 30 °C for five months. The changes in the chemical structure of the polymers were evaluated using loss of weight and contact angle...
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Mass Spectrometry-Based Direct Analytical Techniques
PublicationDirect analysis of samples is considered as one of the most environmentally sustainable solutions in analytical chemistry. In the ideal case, such solutions do not require sample preparation and analytes separation steps, therefore do not consumpt harmful substances (or consumpt only minimum amounts of them) and do not generate hazardous waste. Technical solutions for direct analysis also offer miniaturized and field-portable analyzers...
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Spotkanie informacyjne ws. naboru do programu Szkoły Startup
EventsZapraszamy na spotkanie informacyjne w związku z naborem do Szkoły Startup, które są dobrą okazją, aby dowiedzieć się więcej na temat programu oraz skonsultować się z kierownikiem projektu.
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Spotkanie informacyjne ws. naboru do programu Szkoły Startup
EventsZapraszamy na spotkanie informacyjne w związku z naborem do Szkoły Startup, które są dobrą okazją, aby dowiedzieć się więcej na temat programu oraz skonsultować się z kierownikiem projektu.
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Lipid fingerprinting of Staphylococcus aureus strains by High Performance Liquid Chromatography coupled with Mass Spectrometry (LC-Q-TOF-MS) and advanced chemometric tools.
ProjectsProject realized in Department of Analytical Chemistry according to UMO-2014/13/N/ST4/03899 agreement from 2015-02-18
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Silica-Based Ionogels: Nanoconfined Ionic Liquid-Rich Fibers for Headspace Solid-Phase Microextraction Coupled with Gas Chromatography–Barrier Discharge Ionization Detection
PublicationIn this work, hybrid silica-based materials with immobilized ionic liquids (ILs) were prepared by sol–gel technology and evaluated as solid-phase microextraction (SPME) fiber coatings. High loadings of the IL 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide ([C4MIM][TFSI]) were confined within the hybrid network. Coatings composition and morphology were evaluated using scanning electron microscopy and energy dispersive...
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Size-exclusion chromatography for the determination of the boiling point distribution of high-boiling petroleum fractions
PublicationThe paper describes a new procedure for the determination of boiling point distribution of high-boiling petroleum fractions using size exclusion chromatography with refractive index detector. Thus far, the determination of boiling range distribution by chromatography has been accomplished using simulated distillation with gas chromatography with the flame ionization detection. This study revealed that in spite of substantial differences...
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Physicochemical and Volatile Compounds Analysis of Fruit Wines Fermented with Saccharomyces cerevisiae: FTIR and Microscopy Study with Focus on Anti-Inflammatory Potential
PublicationThe growing trend in fruit wine production reflects consumers’ interest in novel, diverse drinking experiences and the increasing demand for healthier beverage options. Fruit wines made from kiwi, pomegranates, and persimmons fermented using S. bayanus Lalvin strain EC1118 demonstrate the versatility of winemaking techniques. Kiwifruit, persimmon, and pomegranate wines were analyzed using HPLC and GC-TOFMS analyses to determine...
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The comparison of cytotoxic and genotoxic activities of glucosinolates, isothiocyanates, and indoles
PublicationChemopreventive properties of Brassica vegetables are attributed mainly to their characteristic compounds—glucosinolates (GLs) and their main hydrolysis products—isothiocyanates (ITCs) and indoles. In this study, we compared antiproliferative activity (MTT test in HT29 cells) and genotoxic effects (comet assay in HT29 cells and restriction analysis in a cell-free system) of three GLs (sinigrin (SIN), glucotropaeolin (GTL), and...
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Szkolenie online dla promotorów w Szkole Doktorskiej
EventsDn. 22.02.2023 r. o godz. 16.00 odbędzie się szkolenie dla promotorów (obecnych i potencjalnych) w Szkole Doktorskiej prowadzonej wspólnie z IMP PAN i IBW PAN.
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Jak systemowo wspierać nauczycieli akademickich? – rozmowa
EventsWięcej o innych spotkaniach i szkoleniach, które będą odbywać się w każdy piątek od godz. 13.15 na platformie MS Teams, można przeczytać na stronie https://cne.pg.edu.pl/szkolimy/dydaktyczne-piatki.
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Measurements of active power coefficients in a ship power station with two generators working in parallel
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data, expressing active...
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Measurements of the coefficients of active power distribution between two generators operating in parallel in a ship power station
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data, expressing coefficients...
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Measurements of active power distribution in a ship power station with two generators working in parallel
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data expressing an active...
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Measurements of reactive power distribution in a ship power station with two generators working in parallel
Open Research DataThe presented dataset is part of research focusing on the assessment of metrological properties of the instrument, Estimator/Analyzer (E/A v.2), developed and made at the Faculty of Electrical Engineering, Department of Marine Electrical Power Engineering of Gdynia Maritime University. The attached dataset contains processed data, expressing a reactive...
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Związki endokrynne w środowisku. Problemy i wyzwania cz. II Wykrywanie i oznaczanie związków endokrynnych i/lub endokrynności próbek
PublicationOdkrycie istnienia w środowisku mikrozanieczyszczeń, do których należą między innymi związki z grupy EDC, spowodowało konieczność opracowania i wdrożenia nowych metod do praktyki analitycznej. Jedną z nich są nabierające coraz większego znaczenia techniki immunoanalizy. Mimo, iż nie są one rozwiązaniem nowym, ponieważ od dawna z powodzeniem stosuje się je w analizie klinicznej, mają wiele zalet pozwalających na wykorzystanie...
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Lipidomics of Staphylococcus aureus – a new insight into the antibiotic resistant phenotype
PublicationStaphylococcus aureus is an aggressive pathogen responsible for a variety of diseases, in cluding life-threatening sepsis. Many strains of these bacteria are resistant to multiple classes of antibiotics, which is a substantial clinical problem in the treatment of S. aureus infections. We developed a comprehensive untargeted lipidomic workflow, including sample preparation, liquid chromatography-quadrupole-time-of-flight mass spectrometry...
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An Assessment of RASSCF and TDDFT Energies and Gradients on an Organic Donor−Acceptor Dye Assisted by Resonance Raman Spectroscopy
PublicationThe excitation energies and gradients in the ground and the first excited state of a novel donor−(π- bridge)−acceptor 4-methoxy-1,3-thiazole-based chromophore were investigated by means of MS-RASPT2/RASSCF and TDDFT in solution. Within both methods, the excitation energies strongly depend on the employed equilibrium structures, whose differences can be rationalized in terms of bond length alternation indexes. It is shown that functionals with...
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Chemical composition of shells from red (Strongylocentrotus franciscanum) and green (Strongylocentrotus droeba-chiensis) sea urchin
PublicationThe shells from red and green sea urchins accounted for 47.9 and 40.7% of their body weights, respectively. The red and green sea urchin shells contained 91.08 and 90.77% minerals and 4.06 and 4.99% proteins, respectively. The shells did not contain any chitin. Sea urchin shells had a relatively large amount of naphthoquinone pigments, 121 mg per 100 g in red and 163 mg per 100 g in green species. The small quantities of glucosamine...
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The influence of roasting and additional processing on the content of bioactive components in special purpose coffees
PublicationCoffee being the beverage consumed worldwide is also a very competitive commodity. Consequently, producers seek ways of attracting consumers by proposing e.g. novel ingredient combinations usually without evaluating their health quality. In this study, variations in health-promoting determinants for five special purpose coffee brews were characterized. The major bioactive components - chlorogenic acids (CAs) - detected by HPLC-DAD-MS...
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Biological Activity of Tea-Chokeberry and Chokeberry Fermented Beverages
PublicationFermented beverages, such as kombucha are gaining more and more popularity due to their beneficial effects on human health. These products are obtained by the fermentation of tea infusion using so called tea fungus. This microbial consortium can also be used to prepare fermented fruit beverages. Therefore, the aim of this study was to determine the changes in the antioxidant profile of tea-chokeberry and chokeberry beverages...
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Lower rim substituted tert-butylcalix[4]arenes.Part 8: Calix[4]arenes with dialkoxyphosphoryl functions. Synthesis and complexing properties
PublicationW pracy przedstawiono syntezę i charakterystykę otrzymanych związków (1, 2), pochodnych alkoksyfosforylowych p-tert-butylokaliks[4]arenu: 5,11,17,23-tetra-tert-butylo-25,26,27,28-tetrakis(3-diizopropoksyfosforylopropoksy)kaliks[4]arenu (1) oraz 5,11,17,23-tetra-tert-butylo-25,26,27,28-tetrakis(3-methoksyetoksyfosforylopropoksy)kaliks[4]arenu (2). Zbadano właściwości jonoforowe związków 1 i 2 w membranie elektrod jonoselektywnych,...
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Evaluation of Health Hazard Due to Emission of Volatile Organic Compounds from Various Processing Units of Wastewater Treatment Plant
PublicationThe paper describes an attempt at health risk assessment and odour concentration determination in the most important units of a wastewater treatment plant. The cancer risk (CR) and hazard index (HI) parameters in selected measurement locations were calculated based on the results of chromatographic analyses (GCxGC-TOF-MS) and the United States Environmental Protection Agency (US EPA) guidelines. No exceedance of the CR and HI acceptable...
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Theoretical and Actual Feed Per Tooth During Wood Sawing on an Optimizing Cross-Cut Saw
PublicationThe work presents the geometries of circular saw teeth, whose task is to divide the cross-cut of the cutting layer. For efficient machining on a cross-cut saw with high feed speed values (about 1 ms−1) maximal theoretical feeds per tooth are determined. These values were compared with the actual values determined during transverse cutting of pine wood on a special test stands in industrial conditions. In the experiment the rotational...
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TECHNOLOGIE WYTWARZANIA ENERGII ELEKTRYCZNEJ [Niestacjonarne][2020/21]
e-Learning CoursesZajęcia z przedmiotu będą realizowane na platformie MS Teams. Dołączenie do zespołu (grupy) pod tym linkiemLogowanie za pomocą konta @o365.pg.edu.pl Prośby o dołączenie zostaną zaakceptowane przed pierwszymi zajęciami.
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The estimation of total volatile organic compounds emissions generated from peroxide cured natural rubber/polycaprolactone blends
PublicationNatural rubber (NR)/polycaprolactone (PCL) blends at the ratio of 90/10% wt. (NR/PCL90/10) and 70/30% wt. (NR/PCL70/30), with a constant amount of dicumyl peroxide, were prepared by compounding in an internal mixer. Obtained NR/PCL bio-based blends were cured at three different temperatures (150 °C, 160 °C and 170 °C). The total content of volatile organic compounds (TVOC) as a function of the NR/PCL blends ratio, and their curing...
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Opracowanie metodyki oznaczania pestycydów chloroorganicznych oraz polichlorowanych bifenyli w próbkach żywności pochodzenia morskiego
PublicationW pracy przedstawiono wyniki badań dotyczących możliwości wykorzystania różnych technik ekstrakcji związków chloroorganicznych z próbek żywności. Zaprezentowano podstawy badanych technik, oceniono ich przydatność do izolacji wybranych analitów z grupy pestycydów i polichlorowanych bifenyli z próbek żywności i wytypowano najkorzystniejszą technikę. Przedstawiony został wpływ różnych parametrów ekstrakcji na odzyski analitów. Wyłoniono...
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Synteza i właściwości fizyko-chemiczne polimerowych mikrosfer zawierających ugrupowania pirolidonowe
PublicationIntensywny rozwój nauki i techniki, a w konsekwencji także przemysłu stwarza ogromne zapotrzebowanie na nowe materiały. Stosowane tradycyjnie od stuleci kamień, drewno, bawełna czy stal zostają zastąpione przez ich polimerowe odpowiedniki. Wśród ogromnej rzeszy materiałów polimerowych szczególną pozycję zajmują polimerowe mikrosfery [1]. Są one wykorzystywane jako specyficzne sorbenty, nośniki leków, katalizatory, wypełnienia kolumn...
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Mocz ludzki jako źródło informacji na temat narażenia człowieka na różnorodne czynniki chemiczne
PublicationMocz - jest to wydzielina wytwarzana przez nerki w ilości ok. 1500 ml na dobę; płyn zawierający oprócz wody (95%) szkodliwe i zbędne produkty przemiany materii. Mocz jest materiałem biologicznym niezwykle bogatym w niezbędne informacje na temat funkcjonowania organizmu człowieka i efektów narażenia na szkodliwe substancje pochodzące z otaczającego środowiska. Ze względu na swoje właściwości, prosty sposób pobierania próbki, który...