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Search results for: green corrosion inhibitor
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Corrosion in Theory and Practice
e-Learning Coursesstopień: II, semestr: II
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Potential changes in an electric field and electrolytic corrosion.
PublicationSources have been described of corrosively hazardous electric fields and methods of determination of the corrosion hazard to metal structures caused by electrolytic corrosion. Results of potential and impedance investigations in the field of stray currents flowing out of a tram traction and in the presence of a defined electric field of low frequency have been presented. Uncertainties have been indicated relating to the generally...
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CORROSION REVIEWS
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Green Chemistry Metrics with Special Reference to Green Analytical Chemistry
PublicationThe concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor,...
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Trends in the new generation of green solvents in extraction processes
PublicationAnalytical chemistry, like other scientific fields, has undergone a number of changes to make it more consistent with the concept of sustainable development. Among the various steps of chemical analysis, without a doubt, sample preparation is the bottleneck in regard to following a green protocol, especially in terms of solvent consumption. Therefore, many attempts have been made to improve the environmental friendliness of this...
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Application of the corrosion tester in corrosion tests using the acoustic emission method.
PublicationThe article presents an innovative method of corrosion tests using the acoustic emission method and the corrosion tester. The problem of corrosion occurring in ballast tanks and tanks carrying petroleum products is discussed. The acoustic method is presented which, due to the use of a unique corrosion tester, is used to monitor the course of corrosion processes in steel. The principle of operation of the corrosion tester, its construction...
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Superconductivity at 2.2 K in the layered oxypnictide La3Ni4P4O2
PublicationW pracy przedstawiamy odkrycie nowego, warstwowego, związku nadprzewodzącego La3Ni4P4O2.
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High temperature corrosion and corrosion protection of porous Ni22Cr alloys
PublicationIn this work corrosion kinetics of the porous IN625 alloy is studied in the temperature range of 700 °C – 800 °C in air and humidified hydrogen for up to 1000 hours. Moreover, an effective and simple method of reducing corrosion rates of porous alloys by the infiltration of the rare earths elements is shown. Modification by the yttrium containing precursor reduces the corrosion rate by a factor of 50 in air at 700 °C so that the...
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Effect of native air-formed oxidation on the corrosion behavior of AA7075 aluminum alloys
PublicationThe microstructure of aluminum alloys plays a key role in their corrosion resistance. In particular, the presence of intermetallic precipitates differing in the potential from the alloy matrix induces local corrosion. The study presents the effect of native air-formed oxidation on the corrosion behavior of AA 7075 aluminum alloy. Various microscopic and spectroscopic techniques were used to examine the changes occurring in the...
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Instantaneous impedance monitoring of AA 7075 aluminum alloy corrosion in borate buffer with admixed chloride ions
PublicationThe study presents a research capabilities of Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a tool used for instantaneous on-line monitoring of corrosion processes on the example of AA 7075 aluminum alloy. A borate buffer with admixed chloride ions in a quantity ranging from 0.05 to 25 mM was used to represent different types of corrosion attack. The surface of samples specimens was evaluated before and after the tests...
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Green Lean in Services
PublicationThe study presents the basic aspects of the improvement of the company useing Green Lean concept. The authors refer to the basics of the concept, present its theoretical aspects together with a revew of possible actions to eliminate the green waste. All these considerations refer to the service activities of any kind in order to maintain holistic approach of the research.
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Influence of pitting corrosion on fatigue and corrosion fatigue of ship structures. Part I: pitting corrosion of ship structures.
PublicationThe paper is a literature survey focused on pitting corrosion and its influence on fatigue of ship and offshore steels. Mechanisms of short- and long-term pitting corrosion in marine environment have been described including pit nucleation and growth phases. Some models of pit growth versus time of exposure have been presented. Some factors which influence the pit growth have been discussed briefly.
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Green analytical chemistry as an integral part of sustainable education development
PublicationGreen chemistry is an important way of thinking in the field of chemistry and aims to conduct processes in accordance with the principles of sustainable development. It is the application of a wide range of principles that minimize the impact of both chemical processes and products on the environment. And what about analytical chemistry? Without a doubt, analytical chemistry plays an important role in the sustainable development...
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The 12 principles of green analytical chemistry and the SIGNIFICANCE mnemonic of green analytical practices
PublicationThe current rapid development of green analytical chemistry (GAC) requires clear, concise guidelines in the form of GAC principles that will be helpful in greening laboratory practices. The existing principles of green chemistry and green engineering need revision for their use in GAC because they do not fully meet the needs of analytical chemistry. In this article we propose a set of 12 principles consisting of known concepts...
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Wet H2S corrosion and degradation of pipeline in amine regeneration system
PublicationThe paper presents the results of NDT examinations, metallographic tests and risk assessment of degradation related to corrosion of amine regeneration unit in a desulphurisation system. Intensive corrosion resulting from acid gases environment upon water condensation causes perforation of the pipeline. Detailed analysis reveals cracking related to the mechanism of wet H2S. Hydrogen penetration, resulting from the wet H2S process,...
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Physics - Green Technologies - rok 2024/2025
e-Learning CoursesWykłady (Lectures) Kierunek: Green Technologies Wydział Chemiczny Stopień I, semestr 1
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Application of multivariate statistics in assessment of green analytical chemistry parameters of analytical methodologies
PublicationThe study offers a multivariate statistical analysis of a dataset, including the major metrological, “greenness” and methodological parameters of 43 analytical methodologies applied for aldrin determination (a frequently analyzed organic compound) in water samples. The variables (parameters) chosen were as follows: metrological (LOD, recovery, RSD), describing the “greenness” (amount of the solvent used, amount of waste generated)...
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Green and Sustainable Membranes: A review
PublicationMembranes are ubiquitous tools for modern water treatment technology that critically eliminate hazardous materials such as organic, inorganic, heavy metals, and biomedical pollutants. Nowadays, nano-membranes are of particular interest for myriad applications such as water treatment, desalination, ion exchange, ion concentration control, and several kinds of biomedical applications. However, this state-of-the-art technology suffers...
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Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions
PublicationCorrosion properties of aluminium alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic...
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Physical Chemistry for Green Technologies summer 2021/22
e-Learning CoursesPhysical Chemistry subject for Green Technologies, Semester IV
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Green, blue and energy in cities
PublicationThe article refers to the implementation of blue-green infrastructure in cities, with particular emphasis on the aspect of rainwater and energy management. The article presents the advantages of water and greenery in the city and gives examples of engineering solutions used, both the more popular (including green and biosolar roofs), as well as experimental solutions, which are an interesting and necessary alternative in the era...
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Aspects of intergranular corrosion of AISI 321 stainless steel in high-carbon-containing environments
PublicationPurpose – The purpose of this paper is to present a case study of unexpected sensitization to intergranular corrosion of highly resistant AISI 321 steel in petrochemical conditions, where it was subjected to the simultaneous influence of elevated temperature of 250°C and vapors from the asphalt production process. Design/methodology/approach – Corrosion coupons were exposed in an installation carrying asphalt vapors. To identify...
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History and Milestones of Green Analytical Chemistry
PublicationDue to the increased environmental consciousness, Green Analytical Chemistry (GAC) is an important concept steadily gaining popularity, as its implementation facilitates the decrease the detrimental effect analytical chemistry methodologies may have on the environment. In this chapter, a brief overview of the history of Green Analytical Chemistry (GAC) and its milestones was given. Emphasis has been put on the beginnings of green...
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The Application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) Technique in Corrosion and Corrosion Inhibition Studies
Publicationorrosion studies have attracted considerable interest in the areas of materials chemistry and industrial chemistry, as it affects the direct and indirect costs of industry, leading to huge economic setbacks due to the need for repair, maintenance, and even shutdowns due corrosion damage. This new volume is a comprehensive resource that presents new and up-to-date, theoretical, and experimental corrosion inhibition studies.
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The implementation of green transformation through clusters
PublicationThe paper addresses a poorly documented issue in the literature, namely the role of clusters in green transformation, including processes related to green, low-carbon, and circular economies. The purpose was to identify and understand the practices of clusters in this area. The adopted mixed research strategy consisted of both qualitative and quantitative research. Both research phases were conducted in a group of Polish Key National...
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Green Sample Collection
PublicationThe term of “green sample collection” is directly associated with both passive and dynamic analytical tools which allow for simultaneous management of the stage of collection and isolation and/or enrichment of a broad spectrum of chemical compounds from environmental samples. The use of passive sampling techniques at the stage of sample collection makes it possible to obtain in a simple yet inexpensive manner an analytical information...
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DETERMINATION OF THE EFFECT OF ENVIRONMENTAL FACTORS ON THE CORROSION OF WATER DISTRIBUTION SYSTEM BASED ON ANALYSIS OF ON-LINE CORROSION MONITORING RESULTS
PublicationCorrosion of water distribution system is a significant issue causing problems with quality, safety and continuity of distribution. The changes of corrosion rates of the water distribution systems in Cracow made of carbon steel were investigated by analysis of online corrosion monitoring system results. Corrosion rates were determined using the linear polarization method. The impact of rain, temperatures, conductivity, dissolved...
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Green adsorbents and solvents in food analysis
PublicationGreen analytical chemistry aims to minimize the negative impact of analytical procedures on the environment and human health. This can be achieved through the use of non-toxic and environmentally friendly reagents. Classical green solvents include water, ethanol, acetone, and supercritical fluids. Water has been used for the extraction of water-soluble compounds (sugars, amino acids). Ethanol and acetone have been used for the...
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Green analytical chemistry : theory and practice
PublicationThis tutorial review summarises the current state of green analytical chemistry with special emphasis on environmentally friendly sample preparation techniques. Green analytical chemistry is a part of the sustainable development concept; its history and origins are described. Miniaturisation of analytical devices and shortening the time elapsing between performing analysis and obtaining reliable analytical results are important...
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Green Therapy w projektowaniu ośrodków medycznych Green Therapy in complex design of health centres
PublicationKoncepcja przestrzenna ogrodu terapeutycznego podporządkowana jest generalnej idei otwierania się projektantów na poszukiwanie nowych możliwości poprawy samopoczucia odbiorcy - poprzez zapewnienie użytkownikom poczucia bezpieczeństwa, komfortu i odprężenia, harmonii. Dotyczy to nie tylko grupy osób chorych, które dręczone są przez niepokoje i napięcia wywołane przez niepełnosprawność czy chorobę, ale także pacjentów w różnym wieku...
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Green chromatography
PublicationAnalysis of organic compounds in samples characterized by different composition of the matrix is very important in many areas. A vast majority of organic compound determinations are performed using gas or liquid chromatographic methods. It is thus very important that these methods have negligible environmental impact. Chromatographic techniques have the potential to be greener at all steps of the analysis, from sample collection...
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Metrics for green analytical chemistry
PublicationGreen analytical chemistry, although not being a new concept, does not have a greenness metrics system. Green chemistry metrics are not suitable for analytical procedure assessment because they often refer to the mass of the product. Some efforts have been made to develop suitable metrics for analytical chemistry. Some are simple to use but do not cover all aspects of analytical methods’ environmental impact. Others are more comprehensive...
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Developments in Green Chromatography
PublicationGreen analytical chemistry is a widely recognized concept that has led to the development of new analytical methods with reduced environmental impact and minimized analyst occupational exposure. Achievements include the development of microextraction, ultrasound-assisted extraction (UAE), and microwave-assisted extraction (MAE) techniques. Research towards greener separation processes focuses on the elimination of toxic solvents...
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Activation of endogenous regenerative potential in mammals using epigenetic inhibitor zebularine
PublicationIn this work, a nucleoside inhibitor of DNA methyltransferases, zebularine, was investigated as a wound healing and regeneration promoting agent. It was found that a high dose of intraperitoneally delivered zebularine improved punch wound closure in the ear pinna in mice. Both cytidine, a zebularine analogue, and uridine, a zebularine metabolite, did not promote ear pinna hole closure. The effect of zebularine on ear pinna healing...
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Influence of pitting corrosion on fatigue and corrosion fatigue of ship and offshore structures. Part II: Load - pit crack interaction
PublicationIn the paper has been discussed influence of stresses on general corrosion rate and corrosion pit nucleation and growth rate, whose presence has been questioned by some authors but accepted by most of them. Influence of pit walls roughness on fatigue life of a plate suffering pit corrosion and presence of so called "non damaging" pits which never lead to initiation of fatigue crack, has been presented. Possibility of prediction...
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Corrosion monitoring by harmonic analysis in aqueous environments
PublicationThis paper presents tests concerning the rate of corrosion in non-alloy steel (type S235JR) in an aqueous environment, with an additive of sodium chloride by means of polarization resistance measurements and harmonic analysis. The tests have been carried out for steel samples exposed to the testing environment for six weeks, in order to obtain a constant rate of corrosion in the function of time. The measurements have aimed at...
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Philosophy (Green Technologies)
e-Learning CoursesKurs filozofii obejmujący zagadnienia z zakresu epistemologii, filozofii nauk, etyki oraz ekofilozofii.
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Green organic technologies
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Green Organic Technologies
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CONDITIONS OF THE GREEN TRANSFORMATION. THE CASE OF THE EUROPEAN UNION
PublicationThe main purpose of the paper is to identify the factors that determine the course of green transformation and to assess the current stage and possible directions of change in subsequent years in EU countries. The literature lacks comprehensive studies that show the impact of diverse types of factors on the course of green transformation. For this purpose, two perspectives of the research – economic and environmental – are usually...
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Anticandiadal properties of N-acylpeptides containing inhibitor of glucosamine-6-phosphate synthase
PublicationOtrzymano serię N-acylopeptydów zawierających inhibitor syntazy glukozamino-6-fosforanu i zbadano ich aktywność w stosunku do szczepów Candida albicans. Aktywność przeciwgrzybową skorelowano z właściwościami lipofilowymi otrzymanych peptydów. Peptydy zawierające resztę kwasu dekanowego wykazywały najwyższą aktywność przeciwgrzybową.
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Corrosion Monitoring in Petroleum Installations—Practical Analysis of the Methods
PublicationThis paper presents the most typical corrosion mechanisms occurring in the petroleum industry. The methods of corrosion monitoring are described for particular corrosion mechanisms. The field and scope of the application of given corrosion-monitoring methods are provided in detail. The main advantages and disadvantages of particular methods are highlighted. Measurement difficulties and obstacles are identified and widely discussed...
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Green analytical chemistry metrics: A review
PublicationGreen analytical chemistry encourages reducing the use of toxic chemicals/reagents, using energy-efficient equipment, and generating minimal waste. The recent trends in analytical method development focus on the miniaturization of the sample preparation devices, the development of solventless or solvent-minimized extraction techniques, and the utilization of less toxic solvents. The twelve principles of GAC serve as a basic guideline...
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Corrosion mechanisms in columns for atmospheric distillation of crude oil
PublicationThe paper presents the most common corrosion processes occurring in the columns for atmospheric distillation of crude oil. It describes the mechanisms leading to formation of the chemical compounds, which contribute to corrosion phenomena. The main technological factors influencing corrosion processes have been indicated. The paper also presents the interactions between particular corrosion mechanisms resulting in acceleration...
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Corrosion-inhibiting effect of Mimosa extract on brass-MM55 corrosion in 0.5 M H2SO4 acidic media
PublicationEkstrakt z mimosy był badany jako inhibitor korozji mosiądzu MM55 przy użyciu Elektrochemicznej Spektroskopii Impedancyjnej oraz techniki polaryzacyjnej. Badania te wykazały, że ekstrakt z mimosy wykazuje właściwości inhibitora anodowego. Własności inhibicyjne badanego ekstraktu rosły wraz ze wzrostem stężenia inhibitora w kwasie, związano to ze wzrostem adsorpcji cząsteczek inhibitora na powierzchni metalu.
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Corrosion behavior of hydrogen charged super duplex stainless steel welded joints
PublicationThe electrochemical behavior of the weld metal, heat-affected zone (HAZ), and base material of super duplex stainless steel (SDSS) welded joints, made with the application of flux-cored arc welding (FCAW) and submerged arc welding (SAW), were investigated with the use of metallographic examinations (optical microscopy and scanning electron microscopy), potentiodynamic polarization measurements and total hydrogen content determination...
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New technologies for green hydrogen activation, storage, and transportation
PublicationDeveloping new green hydrogen activation, storage, and transportation technologies is a highly complex and multidisciplinary endeavor. This challenge arises from integrating various scientific, engineering, and environmental considerations. Effective evaluation of green hydrogen technologies involves a holistic approach that considers not only the technical aspects but also economic, environmental, and social factors. These criteria...
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Elctrochemical oxidation and corrosion resistance of the Ti13Nb13Zr alloy
PublicationThis paper presents the results of oxidation and corrosion tests carried out on titanium alloy Ti13Nb13Zr. The oxide film was prepared by electrochemical environment 2M H3PO4 for 30 min and 1 h, at a constant voltage 40V. The tests of corrosion resistance were performed by potentiostatic method in Ringer's solution at different pH values: 7, 5 and 3. The change in an appearance of surface and the increase in corrosion resistance...
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Corrosion of AISI1018 and AISI304 steel exposed to sulfates
PublicationThis research analyses the behavior of corrosion, durability, and quality of reinforced concrete samples coated with two different materials when exposed to contaminated soil with sulfates. The initial assessment involved evaluating the water absorption rate of the coating materials before and after exposure to a solution containing 3%푁푎2푆푂4+3%푀푔푆푂4+3%퐾2푆푂4+3%퐶푎푆푂4to determine their durability. the corrosion...
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Green Polymer Nanocomposites for Skin Tissue Engineering
PublicationFabrication of an appropriate skin scaffold needs to meet several standards related to the mechanical and biological properties. Fully natural/green scaffolds with acceptable biodegradability, biocompatibility, and physiological properties quite often suffer from poor mechanical properties. Therefore, for appropriate skin tissue engineering and to mimic the real functions, we need to use synthetic polymers and/or additives as complements...