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Search results for: ELECTROOXIDATION (EO) KINETICS
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Kinetics of photochromic reactions of substituted azobenzenes in solutions, and in liquid crystalline and polymer matrices
PublicationBadano kinetykę fotochromowych reakcji pochodnych azobenzenu: eterów koronowych z resztą benzenu i 4-metoksy-4´-halogenoazobenzenów zdolnych do tworzenia fazy ciekłokrystalicznej. Fotoaktywne związki rozpuszczano w alkanach, polimerach i w ciekłokrystalicznej matrycy. Izomeryzacja odpowiada kinetyce pierwszego rzędu w niektórych polimerach, jednakże stwierdzono zróżnicowanie stałych szybkości reakcji. Termiczna izomeryzacja cis-trans...
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Victor Eremeev prof. dr hab.
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Tb3+ ions in the presence of ZnS:Mn2+ nanocrystals incorporated into silica: Tb3+ and Mn2+ luminescence kinetics
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Decomposition of xenobiotics during visible light irradiation in the presence of immobilised photosensitisers: kinetics study
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Effects of the polyhistidine tag on kinetics and other properties of trehalose synthase from Deionococcus geothermalis
PublicationTwo recombinant trehalose synthases from Deinococcus geothermalis (DSMZ 11300) were compared. A significant influence of the artificial polyhistidine tag was observed in protein constitution. The recombinant trehalose synthase from D. geothermalis with His6 -tag has a higher K m value of 254 mM, in comparison with the wild-type trehalose synthase (K m 170 mM), and displayed a lower activity of maltose conversion when compared...
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Thermodynamics and kinetics of amphotericin B self-association in aqueous solution characterized in molecular detail
PublicationAmphotericin B (AmB) is a potent but toxic drug commonly used to treat systemic mycoses. Its efficiency as a therapeutic agent depends on its ability to discriminate between mammalian and fungal cell membranes. The association of AmB monomers in an aqueous environment plays an important role in drug selectivity, as oligomers formed prior to membrane insertion – presumably dimers – are believed to act differently on fungal (ergosterol-rich)...
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Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers
PublicationLinear biobased polyester polyols were prepared with the use of succinic acid and 1,3-pro- panediol (both with natural origin). Tetraisopropyl orthotitanate (TPT) was used as a catalyst. In order to determine the effect of various synthesis temperature conditions on the thermal degradation kinet- ics, nine sequences of temperature conditions were used during two-step polycondensation reaction. Thermogravimetric analysis was conducted...
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The application of Monod equation to denitrification kinetics description in the moving bed biofilm reactor (MBBR)
PublicationIn this paper, the kinetic constants Vmax and KCOD occurring in the Monod equation, which describe the denitrification process in the moving bed, are determined. For this purpose, a laboratory moving bed biofilm reactor (MBBR) was used. The filling of the reactor consisted of EvU Perl carriers. The experiment was carried out with an excess of nitrate, and denitrification rate was dependent on the concentration of external organic...
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Understanding the kinetics and atmospheric degradation mechanism of chlorotrifluoroethylene (CF2=CFCl) initiated by OH radicals
PublicationThe atmospheric degradation of chlorotrifluoroethylene (CTFE) by OH˙ was investigated using density functional theory (DFT). The potential energy surfaces were also defined in terms of single-point energies derived from the linked cluster CCSD(T) theory. With an energy barrier of −2.62 to −0.99 kcal mol−1 using the M06-2x method, the negative temperature dependence was determined. The OH˙ attack on Cα and Cβ atoms (labeled pathways...
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Kinetics of cyclohexane removal by Candida subhashii and Fusarium solani
Open Research DataDataset presents cyclohexane biodegradation in gas phase using two species of microorganisms: Candida Subhashii and Fusarium solani. Biodegradation was carried out in sealed chambers with a capacity of 1000 ml. In each of them there are two discs inhabited with microorganisms, made of polyurethane foam, 80 mm in diameter and 20 mm thick.
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Kinetics of the Adsorption of Copper and Lead Ions from Aqueous Solution on to WD-ekstra Activated Carbon
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The kinetics of substitution reaction of oxydiacetate and thiodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2’-bipyridine
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Bayesian separation algorithm of THz spectral sources applied to D-glucose monohydrate dehydration kinetics
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Crystallization Kinetics and Structural Properties of the 45S5 Bioactive Glass and Glass-Ceramic Fiber Doped with Eu3+
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Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide
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High-temperature kinetics study of 430L steel powder oxidized in air at 600–850 °C
PublicationThe 430L stainless steel powder with a mean particle size of 95 μm was studied to determine its high-temperature oxidation properties. Continuous thermogravimetric measurements were carried out for 100 h in air at temperatures in the range of 600–850 °C. Even though a considerable amount of Cr (up to ˜5 wt.% Cr) inside the grains was depleted – especially inside small grains – no breakaway oxidation was observed. This indicates...
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Esterification kinetics of glycerol with fatty acids in the presence of zinc carboxylates: Preparation of modified acylglycerol emulsifiers.
PublicationZbadano zależności kinetyczne estryfikacji glicerolu kwasami tłuszczowymi (C12:0 - C18:0), prowadzonych w obecności soli cynku tych kwasów tłuszczowych. Przeanalizowano wpływ temperatury, stężenia karboksylanu oraz budowy części hydrofobowej kwasu tłuszczowego i karboksylanu, na postęp reakcji estryfikacji. Wyznaczono wartości odpowiednich stałych szybkości reakcji, energii aktywacji oraz maksymalnej zawartości monoestru glicerolu,...
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The influence of chitosan hydrogel coating on different redox probes kinetics
Open Research DataThis dataset contains cyclic voltammetry studies of three redox probes: 1 mM K3[Fe(CN)6], [K4Fe(CN)6], C12H14FeO2, and [Ru(NH3)6]Cl2 dissolved in 0.1 M KCl or PBS as the primary electrolyte. The studies are made for glassy carbon electrode (GC) and glassy carbon electrode covered with thin chitosan hydrogel membrane (C2A2). Cyclic voltammograms were...
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Folding kinetics of WW domains with the united residue force field for bridging microscopic motions and experimental measurements
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Crystal Structure, Hydration, and Two-Fold/Single-Fold Diffusion Kinetics in Proton-Conducting Ba0.9La0.1Zr0.25Sn0.25In0.5O3−a Oxide
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Titanium(IV) Oxide Modified with Activated Carbon and Ultrasounds for Caffeine Photodegradation: Adsorption Isotherm and Kinetics Study
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Kinetics of the photosensitized degradation of benzyl 4-hydroxybenzoate in homogeneous aqueous solution under visible-light irradiation
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A Single Mutation in a Tunnel to the Active Site Changes the Mechanism and Kinetics of Product Release in Haloalkane Dehalogenase LinB*
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Sandwich-like mesoporous silica flakes for anticancer drug transport—Synthesis, characterization and kinetics release study
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Adsorption of cationic dyes onto Fe@graphite core–shell magnetic nanocomposite: Equilibrium, kinetics and thermodynamics
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Ammonium removal from aqueous solution by natural zeolite, Transcarpathian mordenite, kinetics, equilibrium and column tests.
PublicationOpisano wyniki badań procesu usuwania jonów amonowych z wodnych roztworów modelowych z wykorzystaniem mordenitu-naturalnego zeolitu (w postaci surowej i po odpowiedniej wstępnej obróbce) zarówno w warunkach statycznych jak i dynamicznych. Oszacowano pojemność jonowymienną w stosunku do jonów amonowych (1,64 meq/g) w przypadku, gdy stężenie początkowe analitu było na poziomie 1000 mg/l. Sprawdzono również wpływ na przebieg procesu...
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Oxidation kinetics and electrical properties of oxide scales formed under exposure to air and Ar–H2-H2O atmospheres on the Crofer 22 H ferritic steel for high-temperature applications such as interconnects in solid oxide cell stacks
PublicationA 100 h isothermal oxidation kinetics study for Crofer 22H was conducted in air and the Ar–H2-H2O gas mixture (p(H2)/p(H2O) = 94/6) in the range of 973–1123 K. The parabolic rate constant was independent of oxygen partial pressure in the range from 6.2 × 10−24 to 0.21 atm at 1023 and 1073 K, while at 973 and 1123 K it was higher in air than in Ar–H2-H2O. The scales consisted of Cr2O3 and manganese chromium spinel with an Mn:Cr...
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The Effect of Polymer Microstructure on Encapsulation Efficiency and Release Kinetics of Citropin 1.1 from the Poly(ε-caprolactone) Microparticles
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Kinetics of molecular decomposition under irradiation of gold nanoparticles with nanosecond laser pulses—A 5-Bromouracil case study
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Evaluation of Eucalyptus leaves as an adsorbent for decolorization of Methyl Violet (2B) dye in contaminated waters: Thermodynamic and Kinetics model
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Corrigendum to “Nonisothermal cure kinetics of epoxy/MnxFe3-xO4 nanocomposites” [Prog. Org. Coat. 140C (2020) 105505]
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Release kinetics and antimicrobial properties of the potassium sorbate-loaded edible films made from pullulan, gelatin and their blends
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TiO2 Modified with Organic Acids for the Decomposition of Chlorfenvinphos under the Influence of Visible Light: Activity, Performance, Adsorption, and Kinetics
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Kinetics of photoinducet birefringence in the guest-host system of poly(methyl methacrylate)doped with azobenzene-containing crown ethers
PublicationWykazano występowanie fotoindukowanej dwójłomności dla klasy fotoaktywnych eterów koronowych składających się z reszty azobenzenu i giętkiego fragmentu oligo(oksyetylenowego) o różnej długości. Kinetyka fotoindukowanej dwójłomności była badana dla serii tych eterów koronowych rozpuszczonych w matrycy z polimetakrylanu metylu. Oczekiwano, że kształt cząsteczek koron zapewni względną swobodę reorientacji podczas izomeracji, niezależnie...
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Kinetics of molecular decomposition under irradiation of gold nanoparticles with nanosecond laser pulses—A 5-Bromouracil case study
PublicationABSTRACT Laser illuminated gold nanoparticles (AuNPs) efficiently absorb light and heat up the surrounding medium, leading to versatile applications ranging from plasmonic catalysis to cancer photothermal therapy. Therefore, an in-depth understanding of the thermal, optical, and electron induced reaction pathways is required. Here, the electrophilic DNA nucleobase analog 5-Bromouracil (BrU) has been used as a model compound to...
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In vitro enzyme kinetics and NMR-based product elucidation for glutathione S-conjugation of the anticancer unsymmetrical bisacridine C-2028 in liver microsomes and cytosol: major role of glutathione S-transferase M1-1 isoenzyme
PublicationThis work is the next step in studying the interplay between C-2028 (anticancer-active unsymmetrical bisacridine developed in our group) and the glutathione S-transferase/glutathione (GST/GSH) system. Here, we analyzed the concentration- and pH-dependent GSH conjugation of C-2028 in rat liver microsomes and cytosol. We also applied three recombinant human GST isoenzymes, which altered expression was found in various tumors. The...
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The kinetics of phenol decomposition under UV irradiation with and without H2O2 on TiO2, Fe–TiO2 and Fe–C–TiO2 photocatalysts
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Heteroleptic cadmium(II) complex, potential precursor for semiconducting CdS layers. Thermal stability and non-isothermal decomposition kinetics
PublicationW ramach pracy zweryfikowano stabilność termiczną [Cd{SSi(OBut)3}(S2CNEt2)]2 - potencjalnego prekursora do otrzymywania warstw półprzewodnikowych CdS. Równocześnie przeprowadzono analizę kinetyki rozkładu za pomocą różnych metod izokonwersyjnych zaproponowanych przez Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose i Friedmanna w wyniku czego wyznaczono całkowity tryplet kinetyczny dla omawianego kompleksu.
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In-situ FTIR study of reaction mechanism and chemical kinetics of a Xundian lignite during non-isothermal low temperature pyrolysis
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Bifunctional sulfur-silicon podands as new nucleophilic ionophores in acyl transfer reactions. Influence of monovalent cations on the reaction kinetics
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The reaction of substituted N-phenacyl-pyridinium bromides in the pyridine ring with DABCO and DBU in water and DMSO. Kinetics and DFT studies
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublicationNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Adsorption Kinetics of Acid Dye Acid Red 88 onto Magnetic Multi‐Walled Carbon Nanotubes‐Fe3C Nanocomposite
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Chemical investigation on the mechanism and kinetics of the atmospheric degradation reaction of Trichlorofluoroethene by OH⋅ and Its subsequent fate in the presence of O2/NOx
PublicationThe M06-2X/6-311++G(d,p) level of theory was used to examine the degradation of Trichlorofluoroethene (TCFE) initiated by OH⋅ radicals. Additionally, the coupled-cluster single-double with triple perturbative [CCSD(T)] method was employed to refine the single-point energies using the complete basis set extrapolation approach. The results indicated that OH-addition is the dominant pathway. OH⋅ adds to both the C1 and C2 carbons,...
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Bio based PUR-PIR foams thermal degradation (TG) and isoconversional kinetics
Open Research DataIn the present work, we perform a thorough thermogravimetric (TG) analysis of the bio-based polyurethane – polyisocyanurate (PUR-PIR) foams in both nitrogen and oxygen atmosphere. A sustainable element of the foam was a biopolyol obtained via acid-catalyzed liquefaction of Zostera Marina and Enteromorpha Algae biomass. Based on isoconversional analysis...
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Revising Entrepreneurial Orientation Construct in Social Enterprise
PublicationEntrepreneurial behavior and entrepreneurial orientation (EO) have received significant scholarly attention in entrepreneurship and management research, but mainly in the commercial context. However, some attempts discussing such behavior and EO among non-profit organizations, but limited in the social enterprise context. The literature argues that EO is higher in such contexts (Zahra, Gedajlovic, Neubaum & Shulman, 2009; Lumpkin,...
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WITHDRAWN: The kinetics of phenol decomposition under UV irradiation with and without H2O2 on TiO2, Fe-TiO2 and Fe-C-TiO2 photocatalysts
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Kinetics of adsorption of hydrocarbon chloro-derivatives from seven-component aqueous solution onto a thin layer of DTO-activated carbon
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Degradation Efficiency and Kinetics Analysis of an Advanced Oxidation Process Utilizing Ozone, Hydrogen Peroxide and Persulfate to Degrade the Dye Rhodamine B
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Application of gas chromatography to the study of the kinetics of reactionsin solution. Ring opening reactions for á-lactams studied using internal standard
PublicationW pracy przedstawiono metodę badania kinetyki reakcji otwarcia pierścienia á-laktamu, wykorzystującą technikę chromatografii gazowej. Na podstawie badań kinetyki reakcji w różnych temperaturach wyznaczono wartości energii aktywacji dwóch badanych reakcji. Podstawowym celem pracy było pokazanie możliwości wykorzystania GC w badaniach kinetyki reakcji prowadzonych w mikroskali.