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Search results for: endocrine disrupting compounds
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Microextraction Techniques Used in the Procedures for Determining Organomercury and Organotin Compounds in Environmental Samples
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Organomercury Compounds in Environmental Samples: Emission Sources, Toxicity, Environmental Fate, and Determination
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Role of Herbal Bioactive Compounds as a Potential Bioavailability Enhancer for Active Pharmaceutical Ingredients
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Cold-modulated leaf compounds in winter triticale DH lines tolerant to freezing and
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Comparison of the contents of bioactive compounds and the level of antioxidant activity in different kiwifruit cultivars
PublicationGłównym celem prowadzonych badań było stwierdzenie która z odmian owoców kiwi (''Hayward'', ''Daeheuhg'', ''Haenam'' oraz ''Bidan'') jest najbardziej odpowiednią z punktu widzenia konsumpcji przez człowieka. Z tego powodu w odpowiednio przygotowanych próbkach ekstraktów z owoców kiwi oznaczono:- profile związków bioaktywnych;- poziomy aktywności przeciwutleniającej. Wyniki pomiarów zawartości polifenoli (flawonoidy oraz kwasy fenolowe)...
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Interfacial behavior of polar, weakly polar, and nonpolar compounds bound to activated carbons
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Influence of composition of raw wastewater on removal of nitrogen compounds in multistage treatment wetlands
PublicationInfluence of composition of raw wastewater on the efficiency of organic matter and nitrogen removal in multistage treatment wetlands has been examined. Commonly used indicators, like COD/BOD5 and BOD5/TN ratio, determining wastewater susceptibility to biodegradation in conventional treatment technologies were assessed. It was confirmed that multistage treatment wetland may be used for treatment of wastewater with high loads of...
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PRELIMINARY RESULTS FROM APPLICATION PHOSLOCK® TO REMOVE PHOSPHORUS COMPOUNDS FROM WASTEWATER
PublicationThe aim of the study is to assess the removal effectiveness of phosphorus compoundsby using lanthanum-modified bentonite. This material was produced by the Australian company Phoslock® Water Solutions Pty Ltd. According to the company, Phoslock® has substantial capacity to bound phosphate anions. The investigation was carried out in steady conditions in laboratory model with beakers. The results of the study are related to the...
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Removal of organic compounds from water by solvent sublation. Criteria for solvent selection.
PublicationProces flotoekstrakcji zastosowano do usuwania z wody następujących związków organicznych: tetrachlorku węgla, chloroformu, 1,3,5-trimetylobenzenu (mezytylenu), fenolu i 2,4,5-trichlorofenolu. Jako odbierające fazy organiczne użyto: olej mineralny, 1-dekanol, 1-oktanol, octan amylu, dodekan i tetradekan. Mechanizmem decydującym o usuwaniu lotnych związków organicznych (VOC) było odparowanie do wnętrza pęcherzyków gazu, podczas...
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Organotin compounds in the liver tissue of marine mammals from the PolishCoast of the Baltic Sea.
PublicationOznaczono zawartość związków cynoorganicznych w próbkach wątrób pochodzących od ssaków morskich złowionych w polskiej strefie ekonomicznej Morza Bałtyckiego. W ramach przeprowadzonych badań opracowana została oryginalna metodyka analityczna. Całkowite stężenie związków z tej grupy wahało się w granicach od 43,9 do 7698 ng Sn/g próbki (w przeliczeniu na suchą masę). Badano zależność stężeń tych związków od wieku i płci osobników.
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The effect of chlorinated drinking water consumption on levels of volatile organohalogen compounds in urine.
PublicationW przedstawionej pracy podjęto próbę oznaczenia niezmienionych form lotnych rozpuszczalników chlorowcoorganicznych w próbkach materiału biologicznego jakim jest mocz dawców, używających w gospodarstwie domowym a także w pracy wody uzdatnianej między innymi w procesie chlorowania. Do wykonania oznaczeń zastosowano zmodyfikowaną technikę analizy fazy nadpowierzchniowej nad cienką warstwą cieczy z samoczynną generacją ciekłego sorbentu...
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Chemically modified glass fiber as a matrix-free reference material for volatile compounds
PublicationW pracy opisano sposób wytwarzania nowego typu bezmatrycowych materiałów odniesienia lotnych związków organicznych. Do otrzymywania lotnych analitów wykorzystano technikę termicznego rozkładu związków powierzchniowych. Jako nośnik zastosowano modyfikowane chemicznie włókna szklane. Związkiem oznaczanym był chlorek metylu.
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Adsorption from aqueous solutions of chlorinated organic compounds onto activated carbons
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Hydrazone Linker as a Useful Tool for Preparing Chimeric Peptide/Nonpeptide Bifunctional Compounds
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Biological Activity of Compounds Exhibiting Local Anesthetics's Properties Evaluated by QSAR Approach
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QSAR Analysis of Selected Antimicrobial Structures Belonging to Nitro-derivatives of Heterocyclic Compounds
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An activation-free route to porous magnetic carbon adsorbents for the removal of phenolic compounds
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Phenolic Compounds and Antioxidant Properties of Fermented Beetroot Juices Enriched with Different Additives
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Structural, spectral and magnetic properties of Ni(II), Co(II) and Cd(II) compounds with imidazole derivatives and silanethiolate ligands
PublicationA series of new metal heteroleptic complexes have been obtained in simple reactions of 1-(3-aminopropyl)-imidazole (api) and 1,4-bis(imidazol-1-yl)-butane (bbi) ligands with metal silanethiolates or acetylacetonates. The obtained complexes are the coordination polymers [Ni{SSi(tBuO)3}2(μ-api)]n1, [Co{SSi(tBuO)3}2(μ-api)]n2, [Cd{SSi(tBuO)3}2(μ-api)·2CH3OH]n3, [Cd{SSi(tBuO)3}2(μ-bbi)·CHCl3]n4 and the dimer [Co{SSi(tBuO)3}2(μ-bbi)·3CH3OH]25....
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Characterization of volatile compounds, structural, thermal and physico-mechanical properties of cross-linked polyethylene foams degraded thermo-mechanically at variable times
PublicationWaste cross-linked polyethylene foam (wXLPE) was thermo-mechanically degraded at variable time using internal batch mixer. The progress of wXLPE degradation has been investigated by using a simultaneous thermogravimetric/differential scanning calorimetry analyzer coupled with Fourier transform infrared spectroscopy, swelling measurements, tensile tests and scanning electron microscopy. Volatile organic compounds generated during...
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Efficient optimization approaches for microwave assisted extraction of high-quality antioxidant compounds from Salvia officinalis L.: UHPLC-HRMS differential analysis of phenolic profiles obtained by ultrasound and microwave extraction
PublicationThe study aims to optimize MAE of total phenolic compounds (TPC) and antioxidant capacity from Salvia officinalis L. leaves using a definitive screening design (DSD) and I-optimal design. UHPLC-HRMS analysis was used to identify and compare the composition of MAE and UAE optimal extracts. The results showed that DSD and I-optimal design were successfully applied for the optimization of MAE targeting phenolics and other antioxidants...
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Understanding the early-stage release of volatile organic compounds from rapeseed oil during deep-frying of tubers by targeted and omics-inspired approaches using PTR-MS and gas chromatography
PublicationDuring deep-frying, a plethora of volatile products is emitted with the fumes. These compounds could act as oil quality indicators and change the indoor air composition leading to health risks for occupants. The presented experiments focus on deep-frying of different tubers in rapeseed oil at different frying temperatures. Here, two scenarios for real-time monitoring of volatile organic compounds (VOCs) using proton transfer reaction...
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Quantitative assessment of the main antioxidant compounds, antioxidant activities and FTIR spectra from commonly consumed fruits, compared to standard kiwi fruit
PublicationBioactive compounds (polyphenols and ascorbic acid) and dietary fibers, and related antioxidant activities of commonly consumed apples, bananas, peaches, pears, blond and red grapefruits, pomelos, oranges, lemons, red plums, white grapes, mango, persimmon and strawberries grown in the same geographical and climatic conditions were compared with standard kiwi fruit. The presence of polyphenols was studied by Fourier transform infrared...
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Scheelite-Type Wide-Bandgap ABO4 Compounds (A = Ca, Sr, and Ba; B = Mo and W) as Potential Photocatalysts for Water Treatment
PublicationIn the present study, alkaline-earth metal scheelite-type compounds ABO4 (A = Ca, Sr, Ba, B = Mo, W) synthesized by a hydrothermal method were systematically studied. The as-obtained photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller surface area analysis (BET), UV–Vis diffuse reflectance spectroscopy (DR/UV-Vis), photoluminescence, and thermoluminescence (TL)...
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Fluorescence studies by quenching and protein unfolding on the interaction of bioactive compounds in water extracts of kiwi fruit cultivars with human serum albumin
PublicationThe main aim of this investigation was to characterize new kiwi fruit cultivars after cold storage treatment and to determine the similarities and differences between them, using spectroscopic methods. The chemometric comparison of kiwi fruit cultivars based on physicochemical indices during cold storage was carried out. All kiwi fruit cultivars showed a high level of correlation between the contents of phenolic compounds (polyphenols,...
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Interrelationship between total volatile organic compounds emissions, structure and properties of natural rubber/polycaprolactone bio-blends cross-linked with peroxides
PublicationNatural rubber/polycaprolactone (NR/PCL) bio-based blends with different organic peroxides were prepared using an internal batch mixer and subsequently cross-linked at 170°C. Two types of commonly used organic peroxides, dicumyl peroxide and di(tert-butylperoxyisopropyl)benzene peroxide, were applied as free-radical initiator. Cross-linking efficiency of NR/PCL blends were investigated using oscillating disc rheometer measurements,...
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Glutathione conjugation of the antitumor-active 1-nitroacridine derivatives compounds C-857 and C-1748 – the major role of glutathione S-transferase M1-1
Open Research DataObjectives: C-857 and C-1748 are antitumor-active agents, monomers of unsymmetrical bisacridine derivatives. The aim of this study was to analyze their glutathione (GSH) conjugation in vitro in the presence of glutathione S-transferase (GST) M1-1.
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Comparison of bioactive compounds, antioxidant and antiproliferative activities of Mon Thong durian during ripening
PublicationCelem przeprowadzonych badań było oszacowanie zmian zawartości związków odżywczych, związków bioaktywnych, kwasów tłuszczowych oraz przeciwutleniaczy w owocach duriana w trakcie różnych etapów procesu dojrzewania. W badaniach wykorzystano testy CURRAC, DPPH, ABTS i FRAP. Stwierdzono, że całkowita zawartość polifenoli, flawonoidów, kwasu askorbimowego, tanin oraz poziom aktywności przeciwutleniającej jest dla owoców niedojrzałych,...
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Investigations of New Phenothiazine-Based Compounds for Dye-Sensitized Solar Cells with Theoretical Insight
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Polysaccharide films modified by compounds of natural origin and silver having potential medical applications
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Inhibition Ability of Natural Compounds on Receptor-Binding Domain of SARS-CoV2: An In Silico Approach
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Application of Bayesian Multilevel Modeling in the Quantitative Structure–Retention Relationship Studies of Heterogeneous Compounds
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Application of cyanated asphaltenes in gas-phase adsorption processes for removal of volatile organic compounds
PublicationThe paper presents an innovative, chemically modified (methylcyanated) asphaltene-based adsorbent that can be an inter-esting low-cost alternative for traditional adsorbents. Adsorption properties of adsorbents were examined by inverse gas chromatography technique, adsorption isotherms, and breakthrough curves. A significant increase in retention volume for pyridine, 2-pentanone, nitropropane, toluene, and 1-butanol was observed....
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Ginsenoside and phenolic compounds in hydromethanolic extracts of American ginseng cell cultures and their antioxidant properties
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Analytical techniques for trace organic compounds-III: Mass spectrometry in trace organic analysis
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Electroactive heterojunctions of iron-based compounds in oxygen evolution reaction—Insight into synergy and mechanism
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Electrochemical sensor for measurement of volatile organic compounds employing square wave perturbation voltage
PublicationThe paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde in air. Sensitivity and limit of quantification of the sensor were determined for different internal electrolyte using the square wave voltammetry (SWV) as a detection technique. The working and counter electrodes were made of platinum. Ionic liquids 1-hexyl, 3-methylimidazolium chloride,1-hexyl, 3-methylimidazolium bis (trifluoromethanesulfonyl)...
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Investigation of Air Quality beside a Municipal Landfill: The Fate of Malodour Compounds as a Model VOC
PublicationThis paper presents the results of an investigation on ambient air odour quality in the vicinity of a municipal landfill. The investigations were carried out during the spring–winter and the spring seasons using two types of the electronic nose instrument. The field olfactometers were employed to determine the mean odour concentration, which was from 2.1 to 32.2 ou/m3 depending on the measurement site and season of the year. In...
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Bacterial presence in polar regions associated with environment modification by chemical compounds including contaminants
PublicationMicrobes are omnipresent and diverse members of all biological communities. In marine and freshwater ecosystems, microorganisms form the base of the food chain supporting higher trophic levels. Even though, microbes generally are thought to live in warm regions of Earth, many of them develop in cold climates. Polar regions remain relatively protected from widespread anthropogenic disturbances, which is a consequence of its remoteness...
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Problems of modelling toxic compounds emitted by a marine internal combustion engine in unsteady states
PublicationContemporary engine tests are performed based on the theory of experiment. The available versions of programmes used for analysing experimental data make frequent use of the multiple regression model, which enables examining effects and interactions between input model parameters and a single output variable. The use of multi-equation models provides more freedom in analysing the measured results, as those models enable simultaneous...
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A comparative study of phenolic compounds and antioxidant and antiproliferative activities in frequently consumed raw vegetables
PublicationCelem badań było oszacowanie właściwości przeciwutleniających wybranych warzyw spożywczych w stanie surowym: czosnek (Allium sativum L), biała, żółta i czerwona cebula (Allium cepa L), czerwony i zielony pieprz (Capsicum annuum L.) oraz biała kapusta (Brassica oleracea var. capitata f. alba) zbieranych w ciągu tego samego roku z różnych regionów geograficznych i stref klimatycznych. W badaniach odpowiednich ekstraktów metanolowych...
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The dynamic of processes responsible for transformation of nitrogen compounds in hybrid wetlands systems in a temperate climate.
PublicationAnalizowano ilościowe i jakościowe przemiany związków azotu po poszczególnych stopniach oczyszczania w hybrydowych systemach hydrofitowych w Wiklinie i Sarbsku.
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An attempt to identify volatile and semi-volatile organic compounds present in the Odra river waters.
PublicationCelem pracy była identyfikacja związków z grup lotnych i średniolotnych związkó organicznych. W badaniach wykorzystano technikę Pt-TD-GC-MS. Komputerowa analiza widm masowych wykazała obecność wielu związków organicznych pochodxenia naturalnego i antropogenicznego. W powłokach wód pobranych w okolicy Brzegu Dolnego oznaczono stężenia związków chloroorganicznych na poziomie pojedynczych prób. Nieco wyższe spektrum związków chloroorganicznych,...
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Determination of volatile organohalogen compounds in urban precipitation in Tricity area (Gdańsk, Gdynia, Sopot).
PublicationPróbki opadów atmosferycznych pobierano w 4 punktach na terenie Gdańska i Sopotu, od listopada 2000 do maja 2001. Oznaczano chloro- i bromopochodne metanu, etanu i etenu. Lotne związki chlorowcoorganiczne oznaczane były metodą bezpośredniego nastrzyku próbki wody do kolumny kapilarnej z wykorzystaniem detektora wychwytu elektronów na etapie detekcji (DAI-GC-ECD). Najczęściej oznaczanymi związkami na wszystkich stacjach pobierania...
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The importance of degradation in the fate of selected organic compounds in the environment. Part II. Photodegradation and biodegradation
PublicationDegradacja jest naturalnym, wszechobecnym procesem rozkładu substancji organicznych obecnych w środowisku. Produkty degradacji lub pośrednie produkty rozkładu związków organicznych często wykazują inną toksyczność w stosunku do mikroorganizmów, zwierząt i ludzi niż związki wyjściowe. Procesy fotodegradacji i biodegradacji zachodzą zwykle jednocześnie. Fotodegradacja uznawana jest za wstępny proces, po którym następuje rozkład...
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The importance of degradation in the fate of selected organic compounds in the environment. Part. I. General considerations.
PublicationZwiązki organiczne, w zależności od elementu środowiska w jakim występują (gleba, osady denne, wody powierzzchniowe i gruntowe) mogą ulegać powolnym przemianom pod wpływem rozmaitych procesów fizycznych, chemicznych biologicznych czy też fotochemicznych. W pracy przedstawiono drogę degradacji wybranych trwałych zanieczyszczeń organicznych w różnych warunkach. Omówiono problem pojawiania się produktów pośrednich w czasie degradacji...
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Development and evaluation of headspace gas chromatography method for the analysis of carbonyl compounds in spirits and vodkas
PublicationPrzedstawiono wyniki oznaczania związków karbonylowych (po przeprowadzeniu w pochodne przy użyciu odczynnika derywatyzującego - o-PFBHA) przy wykorzystaniu techniki analizy fazy nadpowierzchniowej w połączeniu z chromatografią gazową i detektorem wychwytu elektronów(ECD). Przedstawiono optymalizację metodyki oraz wyniki uzyskane podczas próbek rzeczywistych wybranych wyrobów spirytusowych.
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The effect of fixed adsorption bed height on adsorption of gaseous mixture of volatile organic compounds
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Impact of binary mixtures of Irgasan (triclosan) and Diclofenac on endocrine processes of the model organism Saccharomyces Cerevisiae (using XenoScreen YES/YAS test)
Open Research DataThe XenoScreen YES/YAS reagents and methodology is given in Kudłak et al. (2019) and in details in electronic supplementary material.
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Inhibiting activity of HIV-1: protease, reverse transcriptase and integrase all together by novel compounds using computational approaches (flexible and rigid docking)
PublicationAcquired immunodeficiency syndrome (AIDS), caused by human immunodeficiency virus type 1 (HIV-1) infection, is one of the most challenging diseases in recent decades. Nevertheless the shortcomings of chemical drugs such as toxicity, lack of curative effects, the search for more potent anti-HIV agents have been focused in our study. In current study, novel scaffold was designed having a benzyl and imidazole in it which are very...