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Search results for: t-rozpietosc
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Theoretical study of the photoelectron spectrum of ethyl formate: Ab initio and density functional theory investigation
PublicationThe first ionization energy and associated photoelectron spectrum of ethyl formate are investigated with quantum chemistry calculations. The geometries, harmonic vibrational frequencies and first ionization energy are computed at the Hartree-Fock (HF) and at the second order Moller-Plesset perturbation theory (MP2). Moreover, accurate ionization energies are obtained with the Coupled-Cluster theory including singles and doubles...
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Superconductivity in a new intermetallic structure type based on endohedral Ta@Ir7Ge4 clusters
PublicationWe report the observation of superconductivity at a temperature near 3.5 K for the previously unreported compound TaIr2Ge2. In addition to being a superconductor, this material displays a new crystal structure type that contains endohedral clusters, as determined by single-crystal x-ray diffraction structure refinement; the structure is more complex than those of the commonly observed tetragonal 122 intermetallic phases. Despite...
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Analysis of drinking water
PublicationOpisano źródła organicznych i nieorganicznych zanieczyszczeń wody do picia w tym: lotnych związków chlorowcoorganicznych, pestycydów, wielopierścieniowych węglowodorów aromatycznych, polichlorowanych bifenyli, fenoli, kwasów chlorooctowych, aldehydów, ketonów itp. a także metody ich oznaczania. Przedstawiono schemat technik izolacji i oznaczania końcowego oraz schemat metod wykorzystujących analizę fazy nadpowierzchniowej. Opisano...
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Fracture in composite/aluminium joints of variable adhesive properties
PublicationA strain gauge technique recently developed with the wedge test, for estimating crack length and, thus, the fracture energy of structural adhesive bonding, has been employed on a system in which one adherend had two types of surface treatment. Simple polishing and polishing with subsequent sandblasting were the treatments used, with a distinct straight line, perpendicular to the sample edges, separating the two. Despite the clear-cut...
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The realization of ASON/GMPLS control plane
PublicationASON (Automatic Switched Optical Network) is a concept of optical network recommended in G.8080/Y.1304 by ITU-T. Control Plane of this network could be based on GMPLS (Generalized Multi-Protocol Label Switching) protocols like RSVP-TE, OSPF-TE, LMP. This solution is named ASON/GMPLS. In this chapter we present the control plane problems and proposes ASON/GMPLS network realization that are tested on testbed consists of three and...
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Quality measure of VoIP services in carrier grade systems
PublicationThis paper describes passive measurement method of VoIP services quality in carrier grade systems, engaging slight system resources. Measurement is based on analyzing quality information in sender and receiver reports in RTCP packets sent by the end points of RTP session. Data is analyzed and stored by Session Boarder Controllers SBC. Objective evaluation of VoIP calls is based on quality information of IP connection and voice...
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The quality of sewage sludge stabilized for a long time in reed basins
PublicationThe aim of the work was to determine changes of long-term sewage sludge quality stabilized in reed basins from 7-15 years. The following parameters were evaluated: dry matter and organic matter concentration, nitrogen, phosphorus, and selected heavy metal (Cd, Ni, Pb, Cr, Cu, Zn) fractions. The material for the investigations was collected from 4 reed basin systems (utilisated sewage sludge) located in conventional WWTPs in Denmark...
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Analysis of drinking water
PublicationOpisano źródła organicznych i nieorganicznych zanieczyszczeń wody do picia w tym: lotnych związków chlorowcoorganicznych, pestycydów, wielopierścieniowych węglowodorów aromatycznych, polichlorowanych bifenyli, fenoli, kwasów chlorooctowych, aldehydów, ketonów itp. a także metody ich oznaczania. Przedstawiono schemat technik izolacji i oznaczania końcowego oraz schemat metod wykorzystujących analizę fazy nadpowierzchniowej. Opisano...
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Water: Drinking
PublicationOpisano źródła organicznych i nieorganicznych zanieczyszczeń wody do picia w tym: lotnych związków chlorowcoorganicznych, pestycydów, wielopierścieniowych węglowodorów aromatycznych, polichlorowanych bifenyli, fenoli, kwasów chlorooctowych, aldehydów, ketonów itp. a także metody ich oznaczania. Przedstawiono schemat technik izolacji i oznaczania końcowego oraz schemat metod wykorzystujących analizę fazy nadpowierzchniowej. Opisano...
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Synthesis and structure of Bi 5 FeTi 3 O 15 ceramics
PublicationAim of the present research was to fabricate and study crystal structure and phase composition of Bi5FeTi3O15 (BTFO) ceramics exhibiting Aurivillius - type structure. By means of simultaneous thermal analysis and X-ray diffraction analysis the process of synthesis of BTFO ceramics has been studied. Mixed oxide method followed by pressureless sintering was used for ceramics preparation. Three endothermic thermal effects have been...
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Study of nanomechanical properties of (1-y)BST-yMgO thin films
PublicationIn the present study thin films of MgO – modified Ba0.6Sr0.4TiO3 (BST60/40) solid solution were prepared by the sol-gel-type chemical solution deposition method on stainless steel substrates. A multilayer spin-coating approach was utilized for the Ba0.6Sr0.4TiO3-MgO thin film deposition with subsequent thermal annealing at T=650-750C. Dried BST60/40-MgO gel powders were studied with thermogravimetric and differential thermal analysis...
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Magnetoelectric effect in (BiFeO3)x–(BaTiO3)1-x solid solutions
PublicationThe aim of the present work was to study magnetoelectric effect (ME) in (BiFeO3)x–(BaTiO3)1x solid solutions in terms of technological conditions applied in the samples fabrication process. The rapidly growing interest in these materials is caused by their multiferroic behaviour, i.e. coexistence of both electric and magnetic ordering. It creates possibility for many innovative applications, e.g. in steering the magnetic memory...
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Polytypism and superconductivity in the NbS2 system
PublicationWe report on the phase formation and the superconducting properties in the NbS2 system. Specifically, we have performed a series of standardized solid-state syntheses in this system, which allow us to establish a comprehensive synthesis map for the formation of the two polytypes 2H-NbS2 and 3R-NbS2, respectively. We show that the identification of two polytypes by means of X-ray diffraction is not always unambiguous. Our physical...
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Superconductivity in the intermetallic compound Zr5Al4
PublicationPolycrystalline Zr5Al4 was synthesized using the arc-melting method. Powder X-ray diffraction confirms the previously reported crystal structure of the Ti5Ga4-type P63/mcm with lattice parameters: a = 8.4312(6) A , and c = 5.7752(8) A . Electrical resistivity and low-temperature magnetic susceptibility measurements indicate that Zr5Al4 exhibits superconducting behavior below 2 K. The normalized heat capacity jump at Tc= 1.82 K...
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Solvation of ionic liquids based on N -methyl- N -alkylmorpholinium cations in N,N -dimethylformamide and N,N -dimethylacetamide – Volumetric and compressibility studies
PublicationDensity and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl- morpholinium cations: N-ethyl- -methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-Nmethylmorpholinium bis(trifluoromethanesulfonyl)imide, N-octyl-N-methyl -morpholinium bis(trifluor omethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in N, N-dimethylformamide and N,N-dimethylacetamide were...
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Enhancement of the Magnetoresistance in the Mobility‐Engineered Compensated Metal Pt 5 P 2
PublicationThe magnetoresistance (MR) in nonmagnetic materials continues to be a fertile research area in materials science. The search for giant, positive MR has been limited to a rather small window of materials such as high-mobility semimetals in single-crystalline form. Here, the observation of a very large positive MR in metallic Pt5P2 in polycrystalline form is reported. The observations reveal that improvement of the crystallinity...
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Tuning the ferromagnetic phase in the CDW compound SmNiC2 via chemical alloying
PublicationWe report a study on tuning the charge density wave (CDW) ferromagnet SmNiC2 to a weakly coupled superconductor by substituting La for Sm. X-ray diffraction measurements show that the doped compounds obey Vegard’s law, where La (Lu) alloying expands (shrinks) the lattice due to its larger (smaller) atomic size than Sm. In the series Sm1−xLaxNiC2, CDW transition (TCDW =148K) for SmNiC2 is gradually suppressed, while the ferromagnetic...
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Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review
PublicationAdvanced oxidation processes (AOPs) hold great promise in the removal of organic contaminants. Reactive oxygen species (ROS) produced in AOPs react with target pollutants to initially form several intermediate compounds that finally undergo complete mineralization. Such observations are reported, especially for laboratory-scale experiments performed in pure water. On the other hand, while considering real contaminated wastewater...
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A comparative study of pentanol (C5 alcohol) and kerosene blends in terms of gas turbine engine performance and exhaust gas emission
PublicationThe growing demand for sustainable and clean energy sources provides the incentive for the development of alternative fuels. Simultaneously, the development of gas turbine technologies with flexible fuel supply systems enables the use of alternative non-fossil fuels that can play key roles in contributing to global efforts in meeting emissions targets. This paper presents the current state of knowledge on the production and potential...
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Carbonic anhydrase inhibitors. Synthesis, and molecular structure of novel series N-substituted N'-(2-arylmethylthio-4-chloro-5- methylbenzenesulfonyl)guanidines and their inhibition of human cytosolic isozymes I and II and the transmembrane tumor-associated isozymes IX and XII
PublicationA series of novel N-substituted N'-(2-arylmethylthio-4-chloro-5-methylbenzenesulfonyl)guanidines 9 e41 have been synthesized and investigated as inhibitors of four isoforms of zinc enzyme carbonic anhydrase (CA.EC 4.2.1.1), that is the cytosolic CA I and II, and cancer-associated isozymes CA IX and XII. Against the human CA I investigated compounds showed KI in the range of 87e6506 nM, toward hCA II ranging from 7.8 to 4500 nM,...
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Measurements of fundamental properties of homogeneous tissue phantoms
PublicationWe present the optical measurement techniques used in human skin phantom studies. Their accuracy and the sources of errors in microscopic parameters’ estimation of the produced phantoms are described. We have produced optical phantoms for the purpose of simulating human skin tissue at the wavelength of 930 nm. Optical coherence tomography was used to measure the thickness and surface roughness and to detect the internal inhomogeneities....
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Electronically Excited States in Solution via a Smooth Dielectric Model Combined with Equation-of-Motion Coupled Cluster Theory
PublicationWe present a method for computing excitation energies for molecules in solvent, based on the combination of a minimal parameter implicit solvent model and the equation-of-motion coupled-cluster singles and doubles method (EOM-CCSD). In this method, the solvent medium is represented by a smoothly varying dielectric function, constructed directly from the quantum mechanical electronic density using only two tunable parameters. The...
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Duration of disability, functional independence, coping styles and the quality of life in patients with spinal cord injury – Pilot study
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Studies on the Preparation and Characterisation of Carbon Nanostructures
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Rural domestic wastewater treatment in Norway and Poland: experiences, cooperation and concepts on the improvement of constructed wetland technology
PublicationThis article describes Norwegian and Polish experiences concerning domestic wastewatertreatment obtained during nearly 20 years of operation for constructed wetland (CW) systemsin rural areas and scattered settlements. The Norwegian CW systems revealed a highperformance with respect to the removal of organic matter, biogenic elements and faecalindicator bacteria. The performance of the Polish CW systems was unstable, and varied...
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Coexistence of HFE and rare UGT1A1 genes mutations in patients with iron overload related liver injury
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High-Throughput Matrix-Assisted Laser Desorption Ionization-Time of Flight Mass Spectrometry as an Alternative Approach to Monitoring Drug Resistance of Hepatitis B Virus
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Atmospheric heavy metal deposition accumulated in rural forest soils of southern Scandinavia
PublicationPrzeprowadzono obliczenia zakumulowanej ( w okresie 50 lat) atmosferycznej depozycji metali ciężkich na glebach leśnych na obszarach wiejskich. Podstawę do obliczeń stanowiły:- pomiary zawartości metali ciężkich w opadach atmosferycznych (przeprowadzone przez okres 33 lat) na terenie Danii,- europejska baza danych o emisji zanieczyszczeń.Oznaczano zawartość metali ciężkich (Pb, Cd, Cu, Zn, V, Ni, As) w próbkach opadów atmosferycznych...
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New domino reaction. One pot synthesis of 4,7-dihydroxythioaurone derivatives from benzaldehydes and 4-acetyl-2-oxo-benz[1,3]oxathiole
PublicationDogodna metoda syntezy pochodnych 4,7-dihydroksytioauronów poprzez rekcję typu ''one pot'' aldehydu benzoesowego z 4-acetylo-2-oxo-benz[1,3]oxatiolem i octanem piperydyny w środowisku DMSO. Strukturę związku udowodniono metodami NMR. Układ tioauronowy powstaje w wyniku trzech kolejnych reakcji: otwarcia pierścienia oksatiolonowego, utleniania powstałego ugrupowania merkaptanowego i kondensacji z aldehydem benzoesowym.
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Optical Theorem Helps Understand Thresholds of Lasing in Microcavities With Active Regions
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Comparative study of donor-induced quantum dots in Si nano-channels by single-electron transport characterization and Kelvin probe force microscopy
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Intrinsic and defect-related luminescence of YAlO3 and LuAlO3 single crystals and films
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Thermotropic Biaxial Nematic Phase in Liquid Crystalline Organo-Siloxane Tetrapodes
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Mortality in people with mental disorders in Poland: A nationwide, register-based cohort study
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Production of gold nanoparticles using atmospheric pressure glow microdischarge generated in contact with a flowing liquid cathode – a design of experiments study
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Size-controlled synthesis of gold nanoparticles by a novel atmospheric pressure glow discharge system with a metallic pin electrode and a flowing liquid electrode
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New devices to capture the temperature effect under dynamic compression and impact perforation of polymers, application to PMMA
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Chemical diffusion and surface exchange in selected Ln–Ba–Sr–Co–Fe perovskite-type oxides
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Testing heart rate asymmetry in long, nonstationary 24 hour RR-interval time series
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Measurements of glucose content in scattering media with time-of-flight technique: comparison with Monte Carlo simulations.
PublicationZbadano możliwości pomiaru koncentracji glukozy w materiale silnie rozpraszającym światło z wykorzystaniem techniki czasu przelotu. Badania przeprowadzono wykorzystując ''Intralipid'' będącym fantomem tkanki. Stężenie glukozy wynosiło 100, 200, 300, 500, 1000, 2000,4000 lub 8000 mg/dl. Wyniki pomiarów porównano z wynikami uzyskanymi na drodze modelowania matematycznego.
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Concentrations and loads of DOC, phenols and aldehydes in a proglacial arctic river in relation to hydro-meteorological conditions. A case study from the southern margin of the Bellsund Fjord – SW Spitsbergen
PublicationClimate warming accelerates the melting and thawing of cryosphere components. Therefore, it favours the release of contaminants stored in High-Arctic glaciers for many years. The rate of land-based glacier retreat is of particular importance for the hydrological regime of glacial rivers, but also for the chemical composition of their waters. In this study, we examined 84 surface water samples collected during a period of 42 days...
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Samotestowanie toru analogowego ze wzmacniaczem w pełni różnicowym w elektronicznych systemach wbudowanych sterowanych mikrokontrole-rami
PublicationPrzedstawiono nową metodę samotestowania toru analogowego opartego na wzmacniaczu w pełni różnicowym w elektronicznych systemach wbu-dowanych sterowanych mikrokontrolerami. Bazuje ona na nowej metodzie diagnostycznej opartej na przekształceniu transformującym próbki odpo-wiedzi czasowej badanej części analogowej na pobudzenie "ujemnym" impulsem prostokątnym na wejściu Vocm na krzywe identyfikacyjne w przestrzeni pomiarowej. Metoda...
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Differential antitumor effects of vitamin D analogues on colorectal carcinoma in culture
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Transcriptomic landscape of blood platelets in healthy donors
PublicationBlood platelet RNA-sequencing is increasingly used among the scientific community. Aberrant platelet transcriptome is common in cancer or cardiovascular disease, but reference data on platelet RNA content in healthy individuals are scarce and merit complex investigation. We sought to explore the dynamics of platelet transcriptome. Datasets from 204 healthy donors were used for the analysis of splice variants, particularly with...
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Transcriptomic landscape of blood platelets in healthy donors
PublicationBACKGROUND Blood platelet RNA-sequencing is increasingly used among the scientific community. Aberrant platelet transcriptome is common in cancer or cardiovascular disease, but reference data on platelet RNA content in healthy individuals are scarce and merit complex investigation. METHODS We sought to explore the dynamics of platelet transcriptome. Datasets from 204 healthy donors were used for the analysis of splice variants,...
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Wykorzystanie składowych ortogonalnych w wirtualnych cyfrowych przetwornikach mocy.
PublicationW referacie omówiony jest cyfrowy przetwornik mocy, który został zrealizowany jako przyrząd wirtualny w środowisku LabVIEW. W przetworniku tym mnożone sygnały cyfrowe są przedstawione w postaci składowych ortogonalnych prądu i napięcia. Składowe ortogonalne tworzą dwa sygnały o jednakowej amplitudzie i częstotliwości, przesunięte względem siebie o kąt pi/2. Przesunięcie to uzyskuje się na kilka sposobów, np. przez opóźnienie dostępnego...
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Statistical data of hull main parameters useful for preliminary design of SWATH ships
PublicationW artykule przedstawiono rezultaty badań dotyczących statystycznych relacji głównych parametrów projektowych kadłuba statków typu SWATH, wykonanych w oparciu o zebrane w literaturze przedmiotu dane o ponad osiemdziesięciu statkach. Zależności statystyczne przedstawiono w postaci histogramów: długości statku L, histogramów wartości stosunków długości do szerokości L/B, długości do wysokości bocznej L/H, długości pływaków do ich...
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Statistic and probabilistic measures of diagnosis likelohood on the state of self-ignition combustion engines
PublicationW artykule zaproponowano, aby wiarygodność diagnozy o stanie technicznym silników o zapłonie samoczynnym była rozpatrywana jako losowa cecha tej diagnozy. Wykazano możliwość oceny wiarygodności diagnozy za pomocą liczb rzeczywistych z przedziału [0, 1]. Uzasadniono potrzebę rozróżniania wiarygodności diagnozy i trafności diagnozy. Wyprowadzono wzór na prawdopodobieństwo sformułowania prawidłowej diagnozy jako miary wiarygodności...
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Recovery of silver metallization from damaged silicon cells
PublicationMetallization is one of the key process steps to fabricate solar cells with high performance in a cost-effective way. Majority of photovoltaic solar cell manufacturing uses thick film screen print metallization with Ag containing paste to produce solar cells. The average lifetime of PV modules can be expected to be more than 25 years. The disposal of PV systems will become a problem in view of the continually increasing production...
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Modelling of the Polish Electricity Generation Subsystem in MARKAL Program with Emphasis on the EU Emissions Trading Scheme
PublicationThis paper addresses issues related to greenhouse gas emissions in the European Union and measures to reduce them, in particular the European Emissions Trading Scheme (EU ETS). A model of the Polish electricity generation subsystem, taking into account EU ETS mechanisms, has been developed using the MARKAL optimization package. Data collected on the basis of available projects, regulations and statistics were entered into the model....