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Search results for: BIOORTHOGONAL REACTIONS
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Comparative analysis of numerical models of arch-shaped steel sheet sections
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Non-Wave Variations in Temperature Caused by Sound in a Chemically Reacting Gas
PublicationA weakly nonlinear generation of non-acoustic modes in the field of sound in a gas is considered. An exotericchemical reaction of A->B type, which takes place in a gas, may be reversible or not. Two types of sound areconsidered, low-frequency and high-frequency as compared with the characteristic time of a chemical reaction.For both these cases, the governing equations of non-acoustic modes are derived and conclusions of the efficiencyof...
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Cross sections for electron scattering from selected components of DNA and RNA
PublicationWykorzystując metodę atomów niezależnych obliczono różniczkowe i całkowite przekroje czynne na sprężyste rozproszenie elektronów na wybranych drobinach, będących analogami składników DNA i RNA. Przekroje te obliczono w zakresie energii zderzenia od 50eV do 200 eV dla następujących drobin: C4H8O, C4H8O2, C5H10O2 oraz H3PO4. Przy użyciu metody BEB (binary-ecounter Bethe method) dla powyższych związków obliczono również przekroje...
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CROSS SECTIONS CALCULATIONS FOR ELECTRON SCATTERING FROM RHODANINE AND CYANOACETIC ACID
PublicationCross sections for electron-impact ionization and for elastic electron scattering for rhodanine (C3H3NOS2) and cyanoacetic acid (C3H3NO2) have been calculated in wide impinging electron energy range.
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Comparison of nitrogen and VFA removal pathways in autotrophic and organotrophic anammox reactors
PublicationOrganotrophic anammox is a promising process for treating both nitrogen and organic containing wastewater than that of the traditional autotrophic anammox for sole nitrogen removal. However pathways of nitrogen removal particularly at metagenomic level in both processes are still unknown. Here we report, metabolic pathways of nitrogen removal in two lab-scale sequencing batch reactors (SBR), one autotrophic and another organotrophic...
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Ttotal dissociative electron attachment cross sections of selected amin acids
PublicationZaprezentowano całkowite przekroje czynne na dysocjacyjny wychwyt elektronów przez aminokwasy: glicynę, alaninę, prolinę, tryptofan oraz fenyloalaninę. Wartości przekrojów czynnych wyznaczono z pomiarów wydajności w produkcji jonów dodatnich oraz normalizację do całkowitych przekrojów czynnych na jonizację, obliczonych metodą BEB.
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Electron-scattering total cross sections for triatomic molecules: NO2 and H2O
PublicationZmierzono całkowite przekroje czynne na rozpraszanie elektronów na drobinach NO2 i H2O, odpowiednio w zakresie energii od 3 do 370 eV oraz 0,5 do 370 eV. Dla średniej energii zderzenia obliczono ponadto przekroje na rozproszenie sprężyste i jonizację.
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Effects of dispersion on predicting longitudinal concentration profiles in activated sludge reactors
PublicationW pracy przedstawiono wpływ dyspersji na prognozowanie stężeń azotu amonowego w komorach osadu czynnego w oczyszczalni ścieków Gdańsk-Wschód. W tym celu wykorzystano jednowymiarowe równanie adwekcji-dyspersji z członem źródłowym (szybkością nitryfikacji). Współczynnik dyspersji został wyznaczony na podstawie pomiarów znacznika fluoroscencyjnego. Model został zweryfikowany w oparciu o pomiary stężeń azotu w 6 sekcjach komory tlenowej...
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Comparison of cadmium adsorption process on barley straw in batch and flow reactors
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Cross sections for electron scattering from furan molecules; measurements and calculations
PublicationZmierzono i policzono przekroje czynne (TCS) na rozproszenie elektronów na drobinach furanu (C4H4O). Całkowite przekroje czynne zmierzono metodą transmisyjną w zakresie energii 0.6 - 400 eV. Sprężysty i jonizacyjny przekrój czyny obliczono dla energii zderzenia do 4 keV; powyżej 70 eV suma obu przekrojów pozostaje w dobrej zgodności z mierzonymi wartościami TCS.
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Dynamic Analysis of the Turnout Diverging Track for HSR with Variable Curvature Sections
PublicationThe paper presents an analytical method of identifying the curvature of the turnout diverging track consisting of sections of varying curvature. Both linear and nonlinear (polynomial) curvatures of the turnout diverging track are identified and evaluated in the paper. The presented method is a universal one, it enables to assume curvature values at the beginning and end point of the geometrical layout of the turnout. The results...
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Analysis and design improvement of high class roads’ arched sections in Poland
PublicationAlthough Polish road network standards, in particular higher classes of roads are improving dynamically the number of fatalities on the network is still higher that EU’s average. Ensuring road safety and high maintaining standards is a complex issue and one that poses a major challenge for all road authorities. Road accidents at high speed roads characterize specially serious material and social consequences, thus research into...
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Electron-scattering cross sections for selected alkyne molecules: Measurements and calculations
PublicationWe report cross-section results from experimental and theoretical studies on electron collisions with 1-butyne (HC≡C–CH2CH3) and acetylene (HC≡CH) molecules and from computations for a propyne (HC≡C–CH3) molecule. Absolute grand -total electron-scattering cross sections (TCSs) were measured at impact energies ranging from about 0.5 to 300 eV using the linear electron-transmission method. The TCS energy curve for 1-butyne has a...
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ELECTRON-IMPACT IONIZATION CROSS SECTIONS CALCULATIONS FOR PURINE AND PYRIMIDINE MOLECULES
PublicationCross sections for electron-impact ionization of purine and pyrimidine molecules have been calculated using binary-encounter-Bethe method for electron energies ranging from the ionization threshold up to 5 keV. Ionization cross section for purine molecules is 1.4 times higher than for pyrimidine molecules. Acceptable agreement between experimental and theoretical ionization data for pyrimidine molecule has been found.
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Cross sections for ionization and ionic fragmentation of pyrimidine molecules by electron collisions
PublicationThe electron impact mass spectroscopy and the total ion collection measurements were used to investigate the ionization and ionic fragmentation of the pyrimidine, C4H4N2, molecules in the gasphase. The cation mass spectra were measured in the 10−85 amu range and the observed mass peaks assigned to corresponding ionic fragments. The most abundant cation in the mass spectra is the parent cation, C4H4N+2, at 80 amu. The appearance...
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Review of methods for assessing traffic conditions on basic motorway and expressway sections
PublicationMotorways and expressways are the core of each country’s road system. Road planning, design and management requires tools to ensure that roads have the right geometry, traffic layout and equipment. These include methods for capacity estimation and assessing traffic conditions. Because the paper focusses on the basic segments of motorways and expressways (sections located between interchanges and outside of their influence), its...
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On the Use of Selected 4th Generation Nuclear Reactors in Marine Power Plants
PublicationThis article provides a review of the possibility of using different types of reactors to power ships. The analyses were carried out for three different large vessels: a container ship, a liquid gas carrier and a bulk carrier. A novelty of this work is the analysis of the proposal to adapt marine power plants to ecological requirements in shipping by replacing the conventional propulsion system based on internal combustion engines...
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Evaluation of empirical formulae for estimation of the longitudinal dispersion in activated sludge reactors
PublicationBadania traserowe są szeroko stosowane do oceny hydrauliki reaktorów. Jednak w komorach osadu czynnego interpretacja wyników jest trudna z uwagi na recyrkulacje wewnętrzne i recyrkulację osadu z osadnika. Wzory empiryczne mogą być alternatywną metodą oceny warunków hydraulicznych w komorach. Celem tych badań było sprawdzenie czterech wzorów empirycznych na obliczanie współczynnika dyspersji hydrodynamicznej w oparciu o wyniki badań...
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The effect of a polyharmonic structure of the perturbation signal on the results of harmonic analysis of the current of a first-order electrode reaction
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The fixed state in impedance measurements of a two-step electrode reaction proceeding with accompanying adsorption of an intermediate product
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Convenient Synthesis of Functionalized Unsymmetrical Vinyl Disulfides and Their Inverse Electron-Demand Hetero-Diels-Alder Reaction
PublicationThe simple, convenient, and efficient methods for the preparation of unsymmetrical vinyl disulfides with additional functional groups under mild conditions with moderate to high yields were designed. The developed methods include the reaction of S-vinyl phosphorodithioate with thiotosylates or S-vinyl thiotosylate with thiols. The designed methods allow for the synthesis of unsymmetrical vinyl disulfides with additional functionalities...
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Tailoring a low-energy ball milled MnCo2O4 spinel catalyst to boost oxygen evolution reaction performance
PublicationThe development of cost-efficient oxygen evolution reaction (OER) catalysts is one of the most important tasks facing modern techniques for hydrogen production. In this work, for the first time, a low-energy ball milling process of MnCo2O4 (MCO) spinel powders, with a mechanical modification time exceeding 1 day was used. After 6 days of ball-milling, the obtained overpotential of the electrocatalyst reached the value of 375 mV...
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Raman investigation of minor component reaction during polymer synthesisprocess. IV Workshop on Atomic and Molecular Physics.
PublicationWykonano badania ramanowskie reakcji zachodzących podczas procesu wytwarzania polimerów hybrydowych w ich części organicznej. Optyczne monitorowanie przebiegu reakcji w czasie rzeczywistym umożliwiło zbadanie ich efektywności oraz czasu trwania. Wyjaśniono też rolę katalizatorów.
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Chemical-vapor generation of transition metals through the reaction with tetrahydroborate in recent achievements in analytical atomic spectrometry
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Short-term Price Reaction to Involuntary Bankruptcies Filed in Bad Faith: Empirical Evidence from Poland
PublicationPurpose: Assessing the reaction of the prices of shares of companies listed in the Warsaw Stock Exchange to the public disclosure of information about the filing a bankruptcy petition in bad faith by creditors. Design/Methodology/Approach: Event study analysis. Findings: It can therefore be assumed that the filing of an unfounded bankruptcy petition does not, in the short term, have a statistically significant negative impact on...
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Effect of preparation conditions and promoters on the structure and activity of the ammonia decomposition reaction catalyst based on nanocrystalline cobalt
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The role of aluminium in metal–organic frameworks derived carbon doped with cobalt in electrocatalytic oxygen evolution reaction
PublicationWater electrolysis is one of the most crucial processes in the development of new energy sources, where ultra-clean fuel is produced - hydrogen. Oxygen evolution reaction (OER) is the sluggish process of overall water splitting. Therefore, this study presents the design, characterization and electrochemical study of cobalt-based electrocatalysts embedded into porous carbons derived from an Al-metal–organic...
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The effect of the iron oxidation degree on distribution of promotors in the fused catalyst precursors and their activity in the ammonia synthesis reaction
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Phosphorus modified hollow, porous Nickel-Cobalt oxides nanocubes with heterostructure for oxygen evolution reaction in alkaline
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Toward an Understanding of the Chemiluminescence Accompanying the Reaction of 9-Carboxy-10-methylacridinium Phenyl Ester with Hydrogen Peroxide
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Proton transfer reaction from some C–H acids to N-bases in polar aprotic solvents
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Real-Time Monnitoring of Vegetable Oils' Thermal Degradation Using Proton Transfer Reaction Mass Spectrometry
PublicationThe volatile aldehydes, which are generated during frying, can be harmful to human health, therefore the concentration of these compounds in frying fumes should be monitored. In addition, aldehydes are markers of oils’ quality, and so it is possible to determine shelf-life or suitability for frying of these oils. Commonly, in order to determine aldehydes concentration gas chromatography is performed, however it does not allow for...
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Impact of Tetrazolium Ionic Liquid Thermal Decomposition in Solvothermal Reaction on the Remarkable Photocatalytic Properties of TiO2 Particles
PublicationIonic liquids (ILs) could serve as a structuring agent, a solvent, or a source of dopant during solvothermal synthesis of semiconductors particles. To understand the role of IL during formation of TiO2 particles, it is necessary to study the stability of this IL in solvothermal synthesis conditions, as well as studying the surface properties of formed TiO2 particles. In view of this, the effect of the 2,3,5-triphenyltetrazolium...
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Glutathione-mediated conjugation of anticancer drugs: an overview of reaction mechanisms and biological significance for drug detoxification and bioactivation.
PublicationThe effectiveness of many anticancer drugs depends on the creation of specific metabolites that may alter their therapeutic or toxic properties. One significant route of biotransformation is a conjugation of electrophilic compounds with reduced glutathione, which can be non-enzymatic and/or catalyzed by glutathione-dependent enzymes. Glutathione usually combines with anticancer drugs and/or their metabolites to form more polar...
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Relations between magnetosonic perturbations as an indicator of a magnetosonic exciter and equilibrium parameters of a plasma
PublicationThe thermodynamic relations between perturbation of pressure and pertur- bation of mass density and between components of velocity which specify a magnetosonic wave are theoretically studied. A planar flow with the wave vec- tor forming a constant angle with the equilibrium magnetic field is investigated. The theory considers deviation from the adiabaticity of a flow due to some kind of heating–cooling function and thermal conduction...
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THE ESSENCE OF THE TRANSFORMATION OF SOCIO-ECONOMIC RELATIONS IN THE NATIONAL ECONOMY: THEORETICAL AND METHODOLOGICAL ASPECT
PublicationThe article is devoted to a thorough study of the theoretical and methodological foundations of the essence of the transformation of socio-economic relations of the national economy. Based on the study of scientific sources, a proper definition of the concept of "transformation of socio-economic relations" was formed. It is proposed to consider transformational processes from the point of view of their direct or indirect impact...
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Toxicity of sediments and its relations with the mobility of pollutants on the basis of studies of Lake Turawskie
PublicationPraca niniejsza jest raportem z badań nad toksycznością i jej powiązaniem z mobilnością zanieczyszczeń. Moblilność zanieczyszczeń uzależniona jest od pH próbki. Próbki pobierano z Jez. Turawskiego, toksyczność była mierzona przy użyciu testu Microtox (AZUR Environmental, USA).
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Public relations w Polsce - funkcje, zadania, perspektywy w zjednoczonej Europie
PublicationArtykuł pokazuje tendencje w działaniach public relations - w Polsce i Europie ostatnich 10 lat, wskazując jednocześnie kierunek zmian w tej dziedzinie w Polsce po przystąpieniu Polski do Unii Europejskiej.
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Dziennikarz jako specjalista public relations - problem tożsamości czy nadużycie etyczne?
PublicationArtykuł analizuje często występujące w Polsce zjawisko łączenia zawodu dziennikarza i specjalisty public relations. Czyni to rozpatrując problem z p punktu widzenia etyki dziennikarskiej, rzetelności pracy specjalisty public relations i opinii publicznej, jej prawa do rzetelnej informacji.
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Influence of COD-fractions on removal effectiveness and accumulation of organic matter in constructed wetlands
PublicationW pracy wykazano, że efektywność usuwania substancji organicznej doprowadzanej w ściekach bytowo-gospodarczych do złóż hydrofitowych zależy od rodzaju frakcji substancji organicznej oraz ich stężeń. Na podstawie analizy poszczególnych frakcji ChZT (rozpuszczonych związków organicznych biologicznie łatwo- i nierozkładalnych oraz zawiesin organicznych biologicznie wolno- i nierozkładalnych) wykazano, że na akumulację substancji organicznej...
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Cavity-QED tests of representations of canonical commutation relations employed in field quantization
PublicationDane eksperymentalne dotyczące oscylacji Rabiego porównano z opisem teoretycznym w ramach alternatywnych sformułowań elektrodynamiki kwantowej. Okazało się, iż eksperyment nie jest w stanie rozróżnić opisu standardowego od nowego sformułowania opartego o redukowalne reprezentacje CCR. Zaproponowano nowy eksperyment, którego wynik mógłby być rozstrzygający.
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Gel-based separation of single-walled carbon nanotubes for metallic and semiconducting fractions
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FDTD Method for Electromagnetic Simulations in Media Described by Time-Fractional Constitutive Relations
PublicationIn this paper, the finite-difference time-domain (FDTD) method is derived for electromagnetic simulations in media described by the time-fractional (TF) constitutive relations. TF Maxwell’s equations are derived based on these constitutive relations and the Grünwald–Letnikov definition of a fractional derivative. Then the FDTD algorithm, which includes memory effects and energy dissipation of the considered media, is introduced....
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Crank–Nicolson FDTD Method in Media Described by Time-Fractional Constitutive Relations
PublicationIn this contribution, we present the Crank-Nicolson finite-difference time-domain (CN-FDTD) method, implemented for simulations of wave propagation in media described by time-fractional (TF) constitutive relations. That is, the considered constitutive relations involve fractional-order (FO) derivatives based on the Grünwald-Letnikov definition, allowing for description of hereditary properties and memory effects of media and processes....
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Quantitative structure activity relationships for the electron transfer reactions ofAnabaenaPCC 7119 ferredoxin-NADP+oxidoreductase with nitrobenzene and nitrobenzimidazolone derivatives: mechanistic implications
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Application of Monoferrocenylsumanenes Derived from Sonogashira Cross-Coupling or Click Chemistry Reactions in Highly Sensitive and Selective Cesium Cation Electrochemical Sensors
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Novel insights into conjugation of antitumor-active unsymmetrical bisacridine C-2028 with glutathione: characteristics of non-enzymatic and glutathione S-transferase-mediated reactions
PublicationUnsymmetrical bisacridines (UAs) are a novel potent class of antitumor-active therapeutics. A significant route of phase II drug metabolism is conjugation with glutathione (GSH), which can be non-enzymatic and/or catalyzed by GSH-dependent enzymes. The aim of this work was to investigate the GSH-mediated metabolic pathway of a representative UA, C 2028. GSH supplemented incubations of C-2028 with rat, but not with human, liver...
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A critical review on biochar-assisted free radicals mediated redox reactions influencing transformation of potentially toxic metals: Occurrence, formation, and environmental applications
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Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behavior
PublicationThis work seeks to answer the question whether or not the presence of acid functional groups accelerate epoxyamine curing reaction. Epoxy/Fe3O4 nanocomposite was considered as a case, where discussions are based on chemistry, mechanism behind curing reactions and fracture behavior influenced by acid assistance to crosslinking. Fe3O4 magnetic nanoparticles (MNPs) with nanosilica decorative layer (B-MNP) were synthesized and subsequently...
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Modification of TiO2 nanotubes by graphene–strontium and cobalt molybdate perovskite for efficient hydrogen evolution reaction in acidic medium
PublicationHerein, we demonstrate that modification of TiO2 nanotubes with graphene–strontium and cobalt molybdate perovskite can turn them into active electrocatalysts for hydrogen evolution reaction (HER). For this purpose, a simple method of hydrothermal synthesis of perovskites was developed directly on the TiO2 nanotubes substrate. Moreover, the obtained hybrids were also decorated with graphene oxide (GO) during one-step hydrothermal...