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Search results for: VERTICAL GRAPHENE
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Comparison of How Graphite and Shungite Affect Thermal, Mechanical, and Dielectric Properties of Dielectric Elastomer-Based Composites
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Adsorption of cationic dyes onto Fe@graphite core–shell magnetic nanocomposite: Equilibrium, kinetics and thermodynamics
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Multi-step functionalization procedure for fabrication of vertically aligned mesoporous silica thin films with metal-containing molecules localized at the pores bottom
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Some Aspects of Measuring Nonlinear Optical Features of Advanced Vertically Aligned Mesoporous Silica Thin Films Activated by Silver and Copper Ions
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Trace analyses of gaseous products formed during heat treatment of high stage H2SO4-GICs and expanded graphite
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Removal of anionic dyes using magnetic Fe@graphite core-shell nanocomposite as an adsorbent from aqueous solutions
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Physico‐Mechanical Properties and Flammability of PUR/PIR Foams Containing Expandable Graphite Core‐Shell Composite Particles
PublicationIn this work, polyurethane/polyisocyanurate (PUR/PIR) foams were modified by two types of expandable graphite (EG) core-shell composite particles. The pulverized EG core-shell composite particles were prepared during emulsion polymerization using methyl methacrylate or glycidyl methacrylate for the synthesis of the polymeric shells (poly(methyl methacrylate) (PMMA) and poly (glycidyl methacrylate) (PGMA)), and then the obtained EG_PMMA...
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Material Design and Optimisation of Electrochemical Li-Ion Storage Properties of Ternary Silicon Oxycarbide/Graphite/Tin Nanocomposites
PublicationIn this work, we present the characterization and electrochemical performance of various ternary silicon oxycarbide/graphite/tin (SiOC/C/Sn) nanocomposites as anodes for lithium-ion batteries. In binary SiOC/Sn composites, tin nanoparticles may be produced in situ via carbothermal reduction of SnO2 to metallic Sn, which consumes free carbon from the SiOC ceramic phase, thereby limiting the carbon content in the final ceramic nanocomposite....
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Tuning the Laser-Induced Processing of 3D Porous Graphenic Nanostructures by Boron-Doped Diamond Particles for Flexible Microsupercapacitors
PublicationCarbon (sp3)-on-carbon (sp2) materials have the potential to revolutionize fields such as energy storage and microelectronics. However, the rational engineering and printing of carbon-on-carbon materials on flexible substrates remains a challenge in wearable electronics technology. This study demon-strates the scalable fabrication of flexible laser-induced graphene (LIG)-boron doped diamond nanowall (BDNW) hybrid nanostructures...
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Wpływ drążenia pionowego w silikatowych elementach murowych na nośność kotew wklejanych
PublicationThe article is showing results of measurements of the effectiveness of the assembly anchor of inmates glued in in sunk vertically lime-sandy blocks. Examinations were performed for cases of the assembly anchor in different fragments of blocks: in part fullwall, in an axis of symmetry and on the edge of the aperture vertical. An influence of the location of places of settling was examined anchor to the way of the forming of uniting...
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Searching for in vitro biomarkers of susceptibility to prostate and cervical cancers by analysis of chromosomal instability, γ-H2AX foci, polymorphisms in DNA repair genes and apoptosis
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Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors
PublicationIn this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this...
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An adaptive approach to non-destructive evaluation (NDE) of cast irons containing precipitated graphite particles with the help of magnetoacoustic emission
PublicationPhysical properties of cast irons strongly depend on both their microstructure and the presence of casting defects. The paper analyses the possibility of application of magnetoacoustic emission (MAE) for nondestructive detection of flawed cast iron components. The investigated samples containing dross, chunky graphite and lamellar graphite were compared with the reference, flawless, spheroidal cast iron sample. The optimisation...
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Measurement and Analysis of the Radio Wave Polarisation in Off-Body Communications in Indoor Environment
PublicationThe paper describes an analysis of the radio wave polarisation in off-body communications in indoor environment. The measurement stand for polarisation measurements has been shortly described. Five investigated scenarios with different body postures and different antenna placements have been characterize. The vertical and horizontal components of received radio signal have been analysed. The measure used in analysis is a ratio...
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TIME-DOMAIN NUMERICAL EVALUATION OF SHIP RESISTANCE AND MOTION IN REGULAR WAVES BY USING THE CFD URANS METHOD
PublicationTaking into account the International Maritime Organization's (IMO) strategy to radically reduce the...
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A Prospective, Randomized, Double-Blind, Parallel-Group, Placebo-Controlled Study Evaluating Meniscal Healing, Clinical Outcomes, and Safety in Patients Undergoing Meniscal Repair of Unstable, Complete Vertical Meniscal Tears (Bucket Handle) Augmented with Platelet-Rich Plasma
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Application of Box–Behnken design in the optimization of a simple graphene oxide/zinc oxide nanocomposite-based pipette tip micro-solid phase extraction for the determination of Rhodamine B and Malachite green in seawater samples by spectrophotometry
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Salt saturated single drop microextraction of gold from water samples and its determination by graphite furnace atomic absorption spectrometry
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Expression of genes encoding zona pellucida glycoproteins and cortical granule distribution in porcine oocytes isolated from small and medium follicles in relation to puberty status of donors
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Flame retardant epoxy/halloysite nanotubes nanocomposite coatings: Exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardant
PublicationEpoxy nanocomposites containing halloysite nanotubes (HNTs) were developed and their low-concentration thresholds for thermal stability and flame retardancy were compared with that of epoxy system containing expandable graphite (EG), as a reference with superior flame retardancy. The effects of HNTs and EG on the peak of Heat Release Rate (pHRR), Total Heat Release (THR), and Time-To-Ignition (TTI) of the prepared samples were...
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Wpływ zawartości grafitu na właściwości mechaniczne warstw hybrydowych Ni-P/Si3N4/grafit osadzonych na stopie AW-7075 metodą redukcji chemicznej.
PublicationPrzedstawiono wpływ obecności grafitu jako fazy dyspersyjnej na właściwości mechaniczne warstw hybrydowych Ni-P/Si3N4/grafit, które osadzono metodą redukcji chemicznej na stopie glinu AW-7075. Wykonano badania morfologii powierzchni warstw metodą mikroskopii świetlnej i skaningowej. Dalszą część pracy stanowiły badania mechaniczne, czyli pomiary mikrotwardości warstw oraz ich adhezji do aluminiowego podłoża, a także analizy wpływu...
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Tailoring Defects in B, N-Codoped Carbon Nanowalls for Direct Electrochemical Oxidation of Glyphosate and its Metabolites
PublicationTailoring the defects in graphene and its related carbon allotropes has great potential to exploit their enhanced electrochemical properties for energy applications, environmental remediation, and sensing. Vertical graphene, also known as carbon nanowalls (CNWs), exhibits a large surface area, enhanced charge transfer capability, and high defect density, making it suitable for a wide range of emerging applications. However, precise...
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Expanded graphite assistant construction of gradient-structured char layer in PBS/Mg(OH)2 composites for improving flame retardancy, thermal stability and mechanical properties
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Dimethylimidazole and dicyandiamide assisted synthesized rich-defect and highly dispersed CuCo-Nx anchored hollow graphite carbon nanocages as efficient trifunctional electrocatalyst in the same electrolyte
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Nitrogen dioxide gas-sensing detection with GO modified CuO thin films
PublicationGas sensors have been continuously developed over the last few decades for several applications including air quality monitoring, automotive industry and recently for medical use. Gas sensors are usually based on metal oxides (MOXs), such as SnO2, TiO2, ZnO, WO3, CuO. Recently, new materials such as graphene oxide and heterostructures of graphene oxide and metal oxides are utilized for gassensing applications.
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Zastosowanie nowatorskich materiałów geosyntetycznych w konstrukcjach oporowych z gruntu zbrojonego
PublicationArtykuł prezentuje metodę projektowania stromych skarp wznoszonych z gruntów słabo przepuszczalnych, zbrojonych geosiatkami drenującymi. Z analiz przeprowadzonych dla różnej wodoprzepuszczalności gruntu i różnej geometrii skarpy wynika, że pionowy rozstaw i długość zbrojenia mają istotne znaczenie dla stateczności skarpy. Dla gruntów słabo przepuszczalnych, o typowych wartościach współczynników ściśliwości objętościowej oraz konsolidacji,...
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Influence of dispersed phase content on the mechanical properties of electroless nanocomposite Ni-P/Si3N4 and hybrid Ni-P/Si3N4/graphite layers deposited on the AW-7075 alloy.
PublicationThe article presents the results of mechanical testing of Ni-P/Si3N4 nanocomposite and hybrid Ni-P/Si3N4/graphite coatings deposited on AW-7075 aluminum alloy using the chemical reduction method. In terms of mechanical testing, microhardness was measured, and surface roughness and adhesion of the coatings to the aluminum substrate were determined using the “scratch test” method. The surface morphology of the deposited layers was...
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Stable Field Electron Emission and Plasma Illumination from Boron and Nitrogen Co‐Doped Edge‐Rich Diamond‐Enhanced Carbon Nanowalls
PublicationSuperior field electron emission (FEE) characteristics are achieved in edge-rich diamond-enhanced carbon nanowalls (D-ECNWs) grown in a single-step chemical vapor deposition process co-doped with boron and nitrogen. The structure consists of sharp, highly conductive graphene edges supplied by a solid, diamond-rich bottom. The Raman and transmission electron microscopy studies reveal a hybrid nature of sp3-diamond and sp2-graphene...
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New Trends in Sample Preparation Techniques for the Analysis of the Residues of Pharmaceuticals in Environmental Samples
PublicationPharmaceutical residues in the environment is a field of special interest due to the adverse effects to either human health or aquatic and soil environment. Pharmaceuticals have been already detected in underground, surface and wastewaters, soils, manure and sediments. The growing awareness of environmental pollution arising from human activity forces the need for their comprehensive determination. Environmental samples are complex...
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Study of the NO2 sensing mechanism of PEDOT-RGO film using in situ Raman Spectroscopy
PublicationIn this work, the mechanism of the NO2 reaction with PEDOT-RGO composite film has been investigated via in situ Raman spectroscopy. Reduced graphene oxide (RGO), poly(3,4-ethylenedioxytiophene)-reduced graphene oxide (PEDOT-RGO) and poly(3,4-ethylenedioxytiophene)/ClO4− (PEDOT/ClO4−) films were fabricated using an electrodeposition method and used as resistance sensors of gaseous nitrogen dioxide. The experimental results indicate...
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On analytical solution of stationary two dimensional boundary problem of natural convection
PublicationApproximate analytical solution of two dimensional problem for sta- tionary Navier-Stokes, continuity and Fourier-Kirchho equations describ- ing free convective heat transfer from isothermal surface of half innite vertical plate is presented. The problem formulation is based on the typ- ical for natural convection assumptions: the uid noncompressibility and Boussinesq approximation. We also assume that orthogonal to the plate component...
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Extended Newmark method to assess stability of slope under bidirectional seismic loading
PublicationThe paper concerns the dynamic behavior of a simple slope model subjected to simultaneous horizontal and vertical excitations. The proposed method is based on Newmark’s sliding block concept, however, four new features are introduced. The most important assumption is that the normal component of dynamic excitations affects the resisting force both before and after the initiation of the relative slope motion, making it time-dependent....
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Box-Behnken design optimization of pipette tip solid phase extraction for methyl orange and acid red determination by spectrophotometry in seawater samples using graphite based magnetic NiFe2O4 decorated exfoliated as sorbent
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Laser-Induced Graphitization of Polydopamine on Titania Nanotubes
PublicationSince the discovery of laser-induced graphite/graphene, there has been a notable surge of scientific interest in advancing diverse methodologies for their synthesis and applications. This study focuses on the utilization of a pulsed Nd:YAG laser to achieve graphitization of polydopamine (PDA) deposited on the surface of titania nanotubes. The partial graphitization is corroborated through Raman and XPS spectroscopies and supported...
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Impact of radio wave polarisation on off-body communications in indoor environments
PublicationThis paper describes the measurements and the analysis of the impact of radio wave polarisation on off-body communications in Body Area Networks in indoor environments. Measurements on polarisation impact are briefly described. Five investigated scenarios with different body postures and different antenna placements are characterised. The difference between the vertical and horizontal components of the received radio signal are...
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Behaviour of deformed steel columns exposed to impact load during earthquakes: numerical analysis
PublicationIt has been observed during earthquakes that the so called soft-storey failure of an upper floor of a building leads to considerable vertical impact load acting on structural members of the lower storeys. The aim of this paper is to investigate numerically the behaviour of horizontally deformed columns (deformation as the result of earthquake loading) that are additionally subjected to vertical impact load. In the first stage of...
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Electron energy-loss spectroscopy of excited states of the diazine molecules: Pyridazine
PublicationExcitation of the valence electronic states of the pyridazine molecules in the gas phase have been studied using the technique of electron energy-loss spectroscopy. Varying the electron scattering conditions, the residual electron energy and scattering angle, enabled the optically-allowed and -forbidden excitations to be differentiated. The measured energy-loss spectra enabled the vertical excitation energies of the observed states...
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The study of acoustic climate of the Southern Baltic
PublicationThis paper presents the statistical characteristics of seawater properties, which are necessary for predicting the propagation of acoustic waves in selected areas of the Baltic Sea. The statistics were elaborated based on long-term measurements of vertical distributions of sound speed, temperature, and salinity, and the nonlinearity parameter B/A. Nonlinear properties of the environment are considered, in connection...
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Production of singlet oxygen atoms by photodissociation of oxywater
PublicationQuantum chemical calculations are reported for the energies of the few lowest electronic singlet states of oxywater along dissociation of the oxygen-oxygen bond into water and singlet oxygen using multistate multireference second-order Møller–Plesset perturbation theory. We compute an energy of 21 kcal/mol to remove one oxygen atom in the lowest singlet state. The two lowest excited singlet states have vertical excitation energies...
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Experimental Study of Dapped-End Beams Subjected to Inclined Load
PublicationThis paper presents the results of an experimental investigation of the reinforced concrete (RC) dapped-end beams loaded with inclined forces, compared to identical ones loaded with vertical forces only. Such a load may occur in, for example, Gerber's joints or in dapped-end beams supported on corbels, where the vertical gravitation force is additionally completed with horizontal forces caused by temperature differences, shrinking,...
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Study on deformed steel columns subjected to impact load due to soft-storey failure in buildings during earthquakes
PublicationThe so called soft-storey failure is one of the most typical types of damage induced in buildings as the result of earthquake excitation. It has been observed during ground motions that the failure of an upper soft storey of a structure results in large vertical impact load acting on the lower floors. If the resistance of the structural members of the lower storeys is not sufficient it may further lead to progressive collapse of...
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Application of polyethylene glycol-coated iron oxide nanoparticles for magnetic solid phase extraction of copper from seawater samples and its determination by graphite furnace atomic absorption spectrometry using response surface methodology for optimization of extraction
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Carbon nanoarchitectures as high-performance electrodes for the electrochemical oxidation of landfill leachate
PublicationNanomaterials and assemblies of the aforementioned into complex architectures constitute an opportunity to design efficient and selective solutions to wide spread and emerging environmental issues. The limited disposal of organic matter in modern landfills generates extremely concentrated leachates characterised by high concentrations of refractory compounds. Conventional biochemical treatment methods are unsuitable, while advanced...
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Boron-doped carbon nanowalls for fast and direct detection of cytochrome C and ricin by matrix-free laser desorption/ionization mass spectrometry
PublicationDetecting proteins via surface assisted laser desorption/ionization mass spectrometry (SALDI-MS) method is still highly challenging, and only few examples of nanomaterials have been demonstrated to perform such detection so far. In this study, carbon nanowalls (CNWs), vertically aligned graphene sheet-based materials, presenting specific morphology, dimensions, and boron doping levels have shown improved performances for both qualitative...
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Orientation effects on the fracture behaviour of additively manufactured stainless steel 316L subjected to high cyclic fatigue
PublicationIn this paper, stainless steel 316L (SS316L) bars were additively manufactured (AM) in three orientations (Z – vertical, XY – horizontal, ZX45 – midway between vertical and horizontal) by using the Laser Powder Bed Fusion Melting (LPBF-M) method. The AM specimens were subjected to load control fatigue testing under full tension and compression (R = -1) at stress amplitudes ±350, ±400 and ±450 MPa. The XY and ZX45 printing orientations...
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Novel Analytic-Numerical Model of Free Convection: with Leading Edge Considered
PublicationA novel solution of the free convection boundary problem is represented in analytical form for velocity and temperature for an isothermal vertical plate, as an example. These fields are built as a Taylor Series in the x coordinate with coefficients as functions of the vertical coordinate (y). We restrict ourselves by cubic approximation for both functions. The basic Navier-Stokes and Fourier-Kirchhoff equations and boundary conditions...
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Poly(hydroxybutyrate-co-hydroxyvalerate) as a biodegradable binder in a negative electrode material for lithium-ion batteries
PublicationIn this work, graphite-based negative electrode for lithium-ion battery consisting a novel and biodegradable binder poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) is compared with standard graphite electrode with polyvinylidene fluoride (PVDF) as a binder. The rate and cycling performance of lithium ion insertion/extraction of electrodes with PHBV in a half-cell configuration are evaluated. Moreover, on the basis of the electrochemical...
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Analiza przepływu gazu w kanałowych reduktorach ciśnienia podczas zwarć łukowych w rozdzielnicach SN
PublicationW artykule przedstawiono metodę obliczania ciśnienia i temperatury gazów podczas zwarcia łukowego wewnątrz przedziału wyłącznika rozdzielnicy średniego napięcia z wykorzystaniem modelu termodynamicznego procesów towarzyszących zwarciom łukowym wewnątrz rozdzielnic z izolacją powietrzną. Następnie, w oparciu o mechanikę płynów lepkich, przedstawiono metodę obliczania rozkładu prędkości i ciśnienia gazu w kanałowych reduktorach ciśnienia...
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New insights on lithium storage in silicon oxycarbide/carbon composites: Impact of microstructure on electrochemical properties
PublicationIn this work, we study the impact of the preceramic precursor vinyltriethoxysilane (VTES) on the electrochemical performance of silicon oxycarbide (SiOC) glass/graphite composites. We apply an innovative approach based on high-power ultrasounds in order to obtain highly homogenous composites with a uniform distribution of small graphitic flakes. This procedure enhances gelation and drying of VTES-based preceramic polymer/graphite...
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Raz jeszcze o obciążeniu hydrodynamicznym falochronu pionowościennego falą stojącą
PublicationPrzedstawienie istniejących modeli matematycznych opisujących rozkłady ciśnienia hydrodynamicznego na falochron pionowościenny w wyniku oddziaływania fali stojącej. Analiza nieciągłości ciśnienia. Jakościowe porównanie metod obliczeniowych dla wybranych warunków wodno-falowych.