Filters
total: 3679
-
Catalog
displaying 1000 best results Help
Search results for: BIOORTHOGONAL REACTIONS
-
Uluslararasi Iliskiler-International Relations
Journals -
Electrochemical simulation of metabolic reduction and conjugation reactions of unsymmetrical bisacridine antitumor agents, C-2028 and C-2053
PublicationElectrochemistry (EC) coupled with analysis techniques such as liquid chromatography (LC) and mass spectrometry (MS) has been developed as a powerful tool for drug metabolism simulation. The application of EC in metabolic studies is particularly favourable due to the low matrix contribution compared to in vitro or in vivo biological models. In this paper, the EC(/LC)/MS system was applied to simulate phase I metabolism of the representative...
-
Stock Markets’ Reactions to the Announcement of the Hosts. An Event Study in the Analysis of Large Sporting Events in the Years 1976–2032
PublicationThis study attempts to estimate the impact of the announcements of hosts of large sporting events on domestic stock markets. The research problem is to establish a connection between the uniqueness of a sporting event and investors’ beliefs through stock price behavior. Using appropriate estimation windows, 13 different sporting events classified as large, including mega and major events, were tested. The obtained results show...
-
Shaping of the turnout diverging track with variable curvature sections
PublicationThe paper presents an analytical method of shaping the turnout diverging railroad track with variable curvature segments on its length, which in an evident way distinguished it from a typical solution, made up of a single circular arc with no transition curves. Two separate causes including a linear and a nonlinear curvature one in the form of a polynomial have been examined. The obtained solutions of the problem have a universal...
-
A robust 18-pulse diode rectifier with coupled reactors
PublicationThe article presents the principle of operation and selected results of simulation and laboratory tests of the 18-pulse rectifier system with coupled reactors and small series active power filter. The presented system makes it possible to reduce, especially in distribution supply networks, undesired higher current harmonics. The 18-pulse nature of operation of the rectifier is reached using a set of coupled three-phase network...
-
Rational determination of dynamic characteristics of fluid-flow Reactors
PublicationPodstawowa charakterystykę reaktorów stanowi krzywa rozkładu czasu zatrzymania. Jej dokładne wyznaczenie jest trudne i kosztowne. W pracy zaproponowano wykorzystanie metody aproksymacyjnej, polegającej na zastąpieniu rzeczywistej funkcji przez jej przebieg uproszczony. Zaproponowano aproksymację rozkładem trójkątnym. Na konkretnym przykładzie pokazano, że metoda ta daje lepsze wyniki niż powszechnie stosowany model przepływu tłokowego.
-
Analysis of the radiation dose in UV-disinfection flow reactors.
PublicationTheoretical considerations devoted to the variation of UV radiation doses in flow disinfection reactors are presented. The minimal time required by the fluid to pass the reactor was determined and combined with the radiation intensity. The active zones of the reactor were determined.
-
On the generalized model of shell structures with functional cross-sections
PublicationIn the present study, a single general formulation has been presented for the analysis of various shell-shaped structures. The proposed model is comprehensive and a variety of theories can be used based on it. The cross-section of the shell structure can be arbitrarily analyzed with the presented equations. In other words, various types of shell structures, including cylindrical, conical, spherical, elliptical, hyperbolic, parabolic,...
-
Cross sections for electron collision with pyridine [C5H5N] molecule
PublicationThe absolute grand -total cross section (TCS) for electron scattering from pyridine, C5H5N, molecules has been measured at impact energies from 0.6 to 300 eV in the linear electron-transmission experiment. The obtained TCS energy dependence appears to be typical for targets of high electric-dipole moment; the cross section generally decreases with rising energy, except for the 3–20 eV range, where a broad enhancement peaked near...
-
The application of nonlinear curvature sections in the turnout diverging track
PublicationThe paper presents the analytical method of modelling the diverging track of railway turnout with nonlinear curvature sections. These sections were used for smoothing the graph of curvature in the extreme areas of turnout. The problem of the curvature distribution was identified with the use of differential equations. The resulting solutions are of universal nature for example the ability of assuming any values of curvature at...
-
On relations between gradient and classical equivariant homotopy groups of spheres
PublicationWe investigate relations between stable equivariant homotopy groups of spheres in classical and gradient categories. To this end, the auxiliary category of orthogonal equivariant maps, a natural enlargement of the category of gradient maps, is used. Our result allows for describing stable equivariant homotopy groups of spheres in the category of orthogonal maps in terms of classical stable equivariant groups of spheres with shifted...
-
Relations Among Social and Economic Order in European Union Countries
Publication -
Modele relacji między Corporate Social Responsibility a public relations
PublicationArtykuł jest próbą usystematyzowania dotychczasowych rozstrzygnięć dotyczących relacji między CSR [Corporate Social Responsibility] i public relations - występujących tak w literaturze przedmiotu jak i w praktyce organizacji. Autorka prezentuje też własną koncepcję, proponując trzy modele, które opisują i wyjaśniają nie tylko wzajemne relacje między CSR i PR, ale też i wyjaśniają funkcje, jakie nadaje się w organizacjach działaniom...
-
Etyczność działań w public relations - między amoralizmem a kazuistyką
PublicationArtykuł jest refleksją filozoficzną dotyczącą problemów moralnych public relations i dziennikarstwa. Autorka stawia w nim tezę, że dziennikarze i specjaliści public relations – wykonując profesje, których fundamentem jest informacja, komunikacja i zaufanie społeczne - współcześnie bardzo wiele swoich działań wyłączają ze sfery tych, które mogłyby być oceniane z punktu widzenia moralności. Uznają też, że ocenie etycznej można...
-
Emerging developments in ASEAN–China relations in regional production linkages
Publication -
The Poland-United States Security Relations in the light of Asymmetry Theory
Publication -
Etyka public relations - jak uczyć, dylematy nauczyciela akademickiego
PublicationArtykuł porusza niezmiernie ważny problem - jak przekazywać wiedzę o fundamentalnych zasadach etycznych w prowadzeniu wszelkiej działalności gospodarczej, jak kształcić postawy odpowiedzialnego przedsiębiorcy i pracownika. Dziedzina Public relations w ostatnich latach cieszy się bardzo złą opinią - tak w Polsce jak i na świecie - autorka artykułu porusza ten problem wskazując, że istotą public relations są działania , mające na...
-
Anticariogenic effects of extracts and fractions of Potentilla recta and their antioxidant activity
Publication -
Stress strain relations and modulus of elascity of two stage concrete.
PublicationOmówiono badania doświadczalne przeprowadzone dla betonu dwuetapowego. Beton wykonano z trzech różnych kruszyw przy zastosowaniu trzech różnych proporcji w/c i c/p. Wyznaczono związki pomiędzy naprężeniami i odkształceniami. Na drodze statystycznej opracowano wzory umożliwiające wstępne szacowanie wartości siecznego modułu Younga. Ponieważ metoda dwuetapowa pozwala na zachowanie kontaktu pomiędzy poszczególnymi elementami kamiennego...
-
Public relations jako narzędzie wspierające działalność przedsiębiorstwa budowlanego.
PublicationReferat stanowi syntetyczne przedstawienie problematyki public relations (PR). Omówiono podstawy teoretyczne obejmujące: krótki rys historyczny, podstawowe definicje, pojęcie wizerunku i tożsamości oraz model budowy wizerunku firmy jak również otoczenie przedsiębiorstwa. Następnie zaproponowano metodykę postępowania, jaką należy zastosować w przypadku wdrażania PR w przedsiębiorstwie obejmującą: działania początkowe, budowę programu...
-
Public relations uczelni, czyli szewc bez butów chodzi
PublicationRozdział w książce ''Public relations instytucji użyteczności publicznej'', poruszający problem prowadzenia działan PR na uczelniach wyższych, W rozdziale autorka analizuje specyfikę tych działań, pokazuje dziedziny i narzędzia PR, które z punktu widzenia istoty uczelni winny być realizowane i używane, analizuje też najczęściej popełniane błędy w realizacji zadań PR na uczelnich.
-
The Dynamics of Trade Relations between Ukraine and Romania: Modelling and Forecasting
PublicationThe article examines the monthly dynamics of exports, imports and balance of trade between Ukraine and Romania in the period from 2005 to 2021. Time series from 2015 to 2021 were used for modelling and forecasting (since the date the European Union–Ukraine Association Agreement took effect). Adequate models of the dynamics series of the Box-Jenkins methodology were built: additive models with seasonal component ARIMA (Autoregressive...
-
In situ insight into the low-temperature promotion of ZIF-67 in electrocatalytic oxygen evolution reaction
Publication -
Spinel of Nickel-Cobalt Oxide with Rod-Like Architecture as Electrocatalyst for Oxygen Evolution Reaction
Publication -
Electroactive heterojunctions of iron-based compounds in oxygen evolution reaction—Insight into synergy and mechanism
Publication -
Solid Phase Photocatalytic Reaction on the Soot/TiO2 Interface: The Role of Migrating OH Radicals
Publication -
Nitrogen-doped porous carbon embedded with cobalt nanoparticles for excellent oxygen reduction reaction
Publication -
Enhanced Degradation of Ethylene in ThermoPhotocatalytic Process Using TiO2/Nickel Foam: Reaction Mechanism
Publication -
A Reaction of Thioamides with Zinc Ammoniates Leading to Simple Amidines. Discovery of a New Zwitterionic Monomethylamidine
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
-
An approach to new chiral bicyclic imines and amines via Horner–Wadsworth–Emmons reaction
Publication -
Changing the Ship Propulsion System Performances Induced by Variation in Reaction Degree of Turbocharger Turbine
PublicationArtykuł przedstawia szczegółowy model matematyczny układu napędu statku obejmującego: wolnoobrotowy silnik spalinowy okrętowy, śruba okrętowa oraz regulator prędkości kątowej. Model ten, następnie jest wykorzystany do badania symulacyjnego zachowania układu zarówno w stanach ustalonych jak i nieustalonych. Model jest zweryfikowany z wynikami eksperymentalnymi. Przedstawienie oryginalnej metody oceny wrażliwości układu względem...
-
Impedance of cation-coupled electron transfer reaction: teoretical description of one pathway process
PublicationPrzyjęto możliwość występowanie dwóch wzajemnie sprzężonych reakcji. Opisana została impedancja sprzężonej reakcji przeniesienia elektronu z kationem. Wyznaczony został również model elektrycznego schematu zastępczego. Całkowita impedancja Faradayowska jest sumą impedancji przeniesienia elektronu i impedancji przeniesienia kationu. Przykłady pomiaru impedancyjnego w warunkach potencjostatycznych i potencjodynamicznych zostały omówione....
-
Impedance of cation-coupled electron transfer reaction: Theoretical description of one pathway process
PublicationIt has been assumed that cation electron coupled charge transfer can be conducted in accordance with two mutually coupled reactions. Using a differential method an expression was introduced which describes the impedance of a cation electron coupled transfer reaction. Also, an electrical equivalent circuit has been defined. The total faradaic impedance is the sum of electron transfer impedance and cation transfer impedance. Issues...
-
Toward better understanding of phosphoryl transfer reaction: the use of phosphoroorganic biocides in research studies
PublicationZamierzeniem autora było nakreślenie potencjalnych kierunków rozwoju badań z wykorzystaniem biocydów fosforoorganicznych (BFO) i związanej z nimi reakcji przeniesienia grupy fosforylowej (reakcja FT). Projektowane są nowe, wysoce selektywne inhibitory enzymów, które w pełni wyjaśniają rolę enzymów w warunkach normalnego funkcjonowania i w procesach patologicznych. Pozwoli to w konsekwencji na wyselekcjonowanie nowych terapeutyków...
-
Synthesis of sulfanylidene-diazaspirocycloalkanones in a three-component Mannich-type reaction catalyzed with lactic acid
Publication -
Soil chemical properties affect the reaction of forest soil bacteria to drought and rewetting stress
Publication -
Application of Cohen´s class time-frequency distributions in the Belousov-Zhabotinsky reaction analysis
PublicationPrzedstawiono rezultaty spektralnej analizy rejestrów Biełousowa-Żabotyńskiego za pomocą czasowo-częstotliwościowych metod analizy sygnałów należących do klasy Cohen´a. Przykładowy rejestr zmian potencjału elektrody bromo-selektywnej został poddany analizie z wykorzystaniem rozkładu Wignera-Ville´a oraz rozkładu stożkowego. Zastosowanie powyższych algorytmów pozwoliło na uzyskanie spektrogramów przedstawiających zależność pomiędzy...
-
MnxCo3-xO4 spinel oxides as efficient oxygen evolution reaction catalysts in alkaline media
PublicationThe design of efficient electrocatalysts for oxygen evolution reaction (OER) is an essential task in developing sustainable water splitting technology for the production of hydrogen. In this work, manganese cobalt spinel oxides with a general formula of MnxCo3-xO4 (x=0, 0.5, 1, 1.5, 2) were synthesised via a soft chemistry method. Non-equilibrium mixed powder compositions were produced, resulting in high electrocatalytic activity....
-
Thermal Self-Action Effects of Acoustic Beam in a Gas with Reversible or Irreversible Chemical Reaction
PublicationThermal self-action of acoustic beam in a gas where an exothermic chemical reaction takes place, is studied. This kind of thermal self-action differs from that in a newtonian fluid. In dependence on the type of a chemical reaction, reversible or not, heating or cooling of a medium occurs. A beam in the case of the irreversible reaction may be unusually self-focusing. The self-action effects relating to wave beams containing shock...
-
The Influence of External Additional Loading on the Muscle Activity and Ground Reaction Forces during Gait
PublicationAsymmetrical external loading acting on the usculoskeletal system is generally considered unhealthy. Despite this knowledge, carrying loads in an asymmetrical manner like carrying on one shoulder, with one hand, or on the strap across the torso is a common practice. This study is aimed at presenting the effects of the mentioned load carrying methods on muscle activity assessed by using thermal field and ground reaction forces....
-
Human awareness versus Autonomous Vehicles view: comparison of reaction times during emergencies
PublicationHuman safety is one of the most critical factors when a new technology is introduced to the everyday use. It was no different in the case of Autonomous Vehicles (AV), designed to replace generally available Conventional Vehicles (CV) in the future. AV rules, from the start, focus on guaranteeing safety for passengers and other road users, and these assumptions usually work during normal traffic conditions. However, there is still...
-
Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides
PublicationThe cure kinetics analysis of thermoset polymer composites gives useful information about their properties. In this work, two types of layered double hydroxide (LDH) consisting of Mg2+ and Zn2+ as divalent metal ions and CO32− as an anion intercalating agent were synthesized and functionalized with hydroxyapatite (HA) to make a potential thermal resistant nanocomposite. The curing potential of the synthesized nanoplatelets in the...
-
INTERNATIONAL JOURNAL OF TISSUE REACTIONS-EXPERIMENTAL AND CLINICAL ASPECTS
Journals -
FTIR, NMR and kinetic studies of proton transfer reactions from nitro-substituted diarylmethanes to N-bases with guanidine character
Publication -
Thermodynamics and Intermolecular Interactions of Nicotinamide in Neat and Binary Solutions: Experimental Measurements and COSMO-RS Concentration Dependent Reactions Investigations
PublicationIn this study, the temperature-dependent solubility of nicotinamide (niacin) was measured in six neat solvents and five aqueous-organic binary mixtures (methanol, 1,4-dioxane, acetonitrile, DMSO and DMF). It was discovered that the selected set of organic solvents offer all sorts of solvent effects, including co-solvent, synergistic, and anti-solvent features, enabling flexible tuning of niacin solubility. In addition, differential...
-
Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
-
Multisine impedimetric probing of biocatalytic reactions for label-free detection of DEFB1 gene: How to verify that your dog is not human?
PublicationAlbert is a dog (Canis familiaris), but he does not realize this. Albert loves human food (and beer), watching movies on the internet, sleeping in bed, and more. But he should not do all these things. To convince him that, we have desinged a test procedure. The DEFB1 gene is unique to human species. Detecting its presence from saliva and in short periods may offer an advantage in the field of forensic medicine, and influence Albert’s...
-
Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions - a serious environmental issue: A review
PublicationChemical compounds containing nitro group (nitro-products) are a one of toxic by-products, that can be formed during wastewater treatment processes. In case of presence of nitrite or nitrate ions, the formation of nitro-products during advanced oxidation processes (AOPs) is very common. It is caused by the reactive nitrogen species (RNs) such as nitrate radical (NO3•), nitrite radical (NO2•), nitrogen oxide radical (NO•) and peroxynirite...
-
Ethylene photocatalytic decomposition in high temperature reaction chamber
Open Research DataData contain data logs of measurements performed on High Temperature Chamber "The Praying Mantis" coupled with SRI 8010 gas chromatograph. Measurement was performed for TiO2 irradiated by UV and under flowing of ethylene gas diluted in air and with the use of elevated temperature.
-
Photocatalytic degradation of acetaldehyde in high temperature reaction chamber
Open Research DataThis dataset contains chromatograms recorded during the decomposition of acetaldehyde in a high-temperature reaction chamber under UV irradiation using TiO2 (titanium dioxide) as photocatalysts. It includes data on the influence of flow rate, TiO2 (titanium dioxide) filling the entire reactor, a thin layer of TiO2 (titanium dioxide) supported on KBr...