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Search results for: HALOGEN BONDS
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Jaroslaw Spychala dr
PeopleOprócz bardzo dobrego wykształcenia osoba posiada również wieloletnie doświadczenie zawodowe, które jest poświadczeniem tego, że potrafi wykorzystać swoją wiedzę teoretyczną w praktycznych działaniach. Doświadczenie zawodowe jest bardzo bogate i rozbudowane. Ze względu na nabyte całkiem nowe umiejętności zwiększa się atrakcyjność doświadczonego pracownika. Są to między innymi kreatywne myślenie, zorientowanie na cel, odporność...
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Clays as Inhibitors of Polyurethane Foams’ Flammability
PublicationPolyurethanes are a very important group of polymers with an extensive range of applications in different branches of industry. In the form of foams, they are mainly used in bedding, furniture, building, construction, and automotive sectors. Due to human safety reasons, these applications require an appropriate level of flame retardance, often required by various law regulations. Nevertheless, without the proper modifications,...
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The Optical Coherence Tomography and Raman Spectroscopy for Sensing of the Bone Demineralization Process
PublicationThe presented research was intended to seek new optical methods to investigate the demineralization process of bones. Optical examination of the bone condition could facilitate clinical trials and improve the safety of patients. The authors used a set of complementary methods: polarization-sensitive optical coherence tomography (PS-OCT) and Raman spectroscopy. Chicken bone samples were used in this research. To stimulate in laboratory...
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Star Polymers vs. Dendrimers: Studies of the Synthesis Based on Computer Simulations
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Technology of real-world analyzers (TAUR)
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A Model of Thermally Activated Molecular Transport: Implementation in a Massive FPGA Cluster
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A Wideband Corrugated Ridged Horn Antenna with Enhanced Gain and Stable Phase Center for X- and Ku-Band Applications
PublicationIn this letter, a structure and design procedure of a novel double-flared conical horn antenna with an improved gain and a stable phase center is presented. The antenna incorporates a hybrid ridged and corrugated structure. A double-ridged section is responsible for ensuring a wideband operation, whereas the corrugated section supports the hybrid mode. The antenna impedance bandwidth (VSWR < 2) is 6 GHz to 20 GHz. Excellent performance...
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Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures
PublicationDeep eutectic solvents have quickly attracted the attention of researchers because they better meet the requirements of green chemistry and thus have the potential to replace conventional hazardous organic solvents in some areas. To better understand the nature of these mixtures, as well as expand the possibilities of their use in different industries, a detailed examination of their physical properties, such as density, viscosity,...
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FTIR spectroscopic and thermogravimetric characterization of ground tyre rubber devulcanized by microwave treatment
PublicationIn this work, the phenomena involved in the microwave devulcanization of ground tyre rubber (GTR) were investigated. Three types of GTR with different content of organic compounds (elastomers, plasticizers, etc.), carbon black and ash have been studied. The chemical structure of GTR before and after a microwave devulcanization process was analyzed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA)...
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Computational algorithm for the analysis of mechatronic systems with distributed parameter elements
PublicationThe paper presents a systematic computational package for analysis of complex systems composed of multiple lumped and distributed parameter subsystems. The algorithm is based on the transfer function method (DTFM). With this algorithm, a bond graph technique for the modelling is developed to simplify computations. Analysis of different systems requires only changing the inputs data in the form of the bond graph diagram
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Cross-linking of polymer films using phenol-formaldehyde resins with different functional groups
PublicationWell-know phenol-formaldehyde resins are used in the production of press-materials, glues, protective coating, mastics. They take a special place among known oligomers because the products based on them are characterized by a low cost and a series of positive properties. Aim of the work: to show the possibility to create polymeric films based on epoxy resins and modified phenol-formaldehyde resins, which contain unsaturated double...
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Modelling of Mechatronic Systems with Distributed Parameter Components
PublicationThe paper presents an uniform, port-based approach to modelling of both lumped and distributed parameter systems. Port-based model of distributed system has been defined by application of the bond graph methodology and the distributed transfer function method (DTFM). The proposed method of modelling enables to formulate input data for computer analysis by application of the DTFM. The computational package for the analysis of complex...
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Analiza czasowej i przestrzennej zmienności opadów w zlewni potoku Strzyża w Gdańsku
PublicationCharakterystyka opadów w Gdańsku. Analiza opadów zarejestrowanych na stacjach pomiarowych na obszarze zlewni potoku Strzyża w Gdańsku. Porównanie relacji natężenie-czas trwania deszczu dla wybranych wartości prawdopodobieństwa wystąpienia opadu. Porównanie relacji natężenie – prawdopodobieństwo wystąpienia deszczu dla określonych czasów trwania opadów. Dyskusja wyników i wnioski.
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Application of the CCHE1D model to the problem of flood control in Nysa Kłodzka reservoir system in Poland
PublicationW pracy przedstawiono wyniki zastosowania modelu CCHE1D do sterowania pracą zbiorników retencyjnych na Nysie Kłodzkiej w trakcie przejścia fali wezbraniowej wywołanej opadami deszczu na zlewni. Okazało się, że zastosowane do sterowania algorytmy optymalizacyjne są efektywne tylko w przypadku stosowania uproszczonych modeli transformacji fali wezbraniowej w rzece. Modele hydrodynamiczne, jak zastosowany model CCHE1D wydłużają proces...
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Simplified Numerical Model for Transient Flow of Slurries at Low Concentration
PublicationRapid transients are particularly dangerous in industrial hydro-transport systems, where solid-liquid mixtures are transported via long pressure pipelines. A mathematical description of such flow is difficult due to the complexity of phenomena and difficulties in determining parameters. The main aim of the study was to examine the influence of the simplified mixture density and wave celerity description on satisfactory reproduction...
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Melioracje i odwodnienia C+P (dla II st. stac. IW) 22/23 - Nowy
e-Learning CoursesKurs przeznaczony jest dla Studentów II stopnia studiów stacjonarnych na WILiŚ, na specj. Infrastruktura wodna (sem.II). Kurs dedykowany jest zajęciom ćwiczeniowym i projektowym z przedmiotu Melioracje i odwodnienia. Wykłady z przedmiotu Melioracje i odwodnienia objęte są oddzielnym e-kursem. Zakres tematyczny kursu obejmuje problemy gospodarowania wodą opadową w terenach zabudowanych z uwzględnieniem idei błękitno-zielonej...
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Seminarium dyplomowe sem.7 IW (WILiŚ IŚ) 2023/24
e-Learning CoursesKurs dedykowany jest Studentom uczestniczącym w zajęciach Seminarium dyplomowego na semestrze 7. studiów inżynierskich na WILiŚ, kierunek IŚ, specj. IW. Z założenia przeznaczony jest przede wszystkim (ale nie jedynie) dla Studentów wykonujących prace dyplomowe w Katedrze Geotechniki i Inżynierii Wodnej i/lub rozważających studiowanie na studiach II st. na specjalności Infrastruktura wodna. Treści zajęć w ramach Seminarium dyplomowego...
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Hydrologia zlewni zurbanizowanej (stc. IŚ IZW) 2022/23
e-Learning CoursesKurs stanowi wsparcie dla nauczania przedmiotu "Hydrologia zlewni zurbanizowanej", realizowanego na I sem. studiów stacjonarnych II stopnia na WILiŚ, na kierunku Inżynierii Środowiska, specjalność Inżynieria zasobów wodnych.
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Hydrologia zlewni zurbanizowanej NSTC. - dla st. niestacj IS (2023/24)
e-Learning CoursesKurs stanowi wsparcie dla nauczania przedmiotu "Hydrologia zlewni zurbanizowanej" , realizowanego na III sem. studiów niestacjonarnych II stopnia na WILiŚ, na kierunku Inżynierii Środowiska, specjalność IS
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Hydrologia dla ZT (Geologia i hydrologia) 2023/24
e-Learning Courseswsparcie dla prowadzenia zajęć z części hydrologicznej przedmiotu Geologia i hydrologia dla studentów studiów stacj. stopnia I na Wydziału Chemicznym, kierunek Zielone Technologie
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Hydrologia zlewni zurbanizowanej NSTC. - dla st. niestacj IS (2022/23)
e-Learning CoursesKurs stanowi wsparcie dla nauczania przedmiotu "Hydrologia zlewni zurbanizowanej" , realizowanego na III sem. studiów niestacjonarnych II stopnia na WILiŚ, na kierunku Inżynierii Środowiska, specjalność IS
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Hydrologia zlewni zurbanizowanej NSTC. (2022/23) LATO
e-Learning CoursesKurs stanowi wsparcie dla nauczania przedmiotu "Hydrologia zlewni zurbanizowanej" , realizowanego na III sem. studiów niestacjonarnych II stopnia na WILiŚ, na kierunku Inżynierii Środowiska, specjalność IS "GRUPA POŚCIGOWA"
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Urban hydrology 2023/24 (winter)
e-Learning CoursesThe course provides support for teaching the subject of Urban hydrology during the 3rd semester of MSc Studies in Environmental Engineering (Faculty of Civil and Environmental Engineering). The course covers hydrological issues related to urban catchments. Wsparcie dla nauczania przedmiotu Urban hydrology na kierunku Environmental Engineering (WILiŚ). Przedmiot realizowany na III semestrze studiów II stopnia. Obejmuje zagadnienia...
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Urban hydrology 2022/23 (summer)
e-Learning CoursesThe course provides support for teaching the subject of Urban hydrology during the 3rd semester of MSc Studies in Environmental Engineering (Faculty of Civil and Environmental Engineering). The course covers hydrological issues related to urban catchments. Wsparcie dla nauczania przedmiotu Urban hydrology na kierunku Environmental Engineering (WILiŚ). Przedmiot realizowany na III semestrze studiów II stopnia. Obejmuje zagadnienia...
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Hydrologia zlewni zurbanizowanej (stc. IŚ IZW) 2023/24
e-Learning CoursesKurs stanowi wsparcie dla nauczania przedmiotu "Hydrologia zlewni zurbanizowanej", realizowanego na I sem. studiów stacjonarnych II stopnia na WILiŚ, na kierunku Inżynierii Środowiska, specjalność Inżynieria zasobów wodnych.
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Urban hydrology 2023/24 (summer)
e-Learning CoursesThe course provides support for teaching the subject of Urban hydrology during the 3rd semester of MSc Studies in Environmental Engineering (Faculty of Civil and Environmental Engineering). The course covers hydrological issues related to urban catchments. Wsparcie dla nauczania przedmiotu Urban hydrology na kierunku Environmental Engineering (WILiŚ). Przedmiot realizowany na III semestrze studiów II stopnia. Obejmuje zagadnienia...
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Novel Versatile Topologies and Design Optimization of Wide-Bandstop Frequency Selective Surfaces for X-Band, Ku-Band and Millimeter-Wave Applications
PublicationNovel designs of frequency selective surface (FSS) are presented for wideband applications in X, Ku and mmWave (millimeter Wave) bands. Two identical metallic layers of FSS are imprinted on both sides of the RO4003 substrate. The geometry parameters are optimized to maximize the bandstop at the specified in-band maximum transmission level of –10 dB; satisfaction of the latter condition is enforced through appropriate formulation...
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Crystal Structure of N-(2-Benzoyl-4,5-dimethoxyphenethyl)-2-phenylacetamide
PublicationThe crystal structure of N-(2-benzoyl-4,5-dimethoxyphenethyl)-2-phenylacetamide indicates that the compound crystallizes in the monoclinic C2/c space group with eight molecules in the unit cell. The heteroatoms from the amide group form a chain of intermolecular N-H ··· O hydrogen bonds propagating along the b axis. The carbonyl group from the benzoyl substituent participates in short contacts with two H-atoms from the ethyl or...
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Redox State Sensitive Spectroscopy of the Model Compound [(H-dcbpy)(2)Ru-II(NCS)(2)](2-) (dcbpy=2,2 '-Bipyridine-4,4 '-dicarboxylato)
PublicationThe charge transfer reaction mechanism in a ruthenium polypyridine model complex with isothiocyanato ligands, i.e., [(H-dcbpy)(2)Ru(NCS)(2)](2-) 2Bu(4)N(+) (Ru2H) (dcbpy = 2,2'-bipyridine-4,4'-dicarboxylato), has been investigated by combining UV-vis absorption, resonance Raman spectroscopy, and electrochemical methods. Understanding the photophysics of light-harvesting complexes of this class is an indispensable prerequisite to...
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Polaronic and Mott insulating phase of layered magnetic vanadium trihalide VCl3
PublicationTwo-dimensional (2D) van der Waals (vdW) magnetic 3d-transition metal trihalides are a new class of functional materials showing exotic physical properties useful for spintronic and memory storage applications. In this article, we report the synthesis and electromagnetic characterization of single-crystalline vanadium trichloride, VCl 3 , a novel 2D layered vdW Mott insulator, which has a rhombohedral structure (R3, No. 148) at...
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Hyaluronan-Chondroitin Sulfate Anomalous Crosslinking Due to Temperature Changes
PublicationGlycosaminoglycans are a wide class of biopolymers showing great lubricating properties due to their structure and high affinity to water. Two of them, hyaluronic acid and chondroitin sulfate, play an important role in articular cartilage lubrication. In this work, we present results of the all-atom molecular dynamics simulations of both molecules placed in water-based solution. To mimic changes of the physiological conditions,...
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Parity vertex colouring of graphs
PublicationA parity path in a vertex colouring of a graph is a path along which each colour is used an even number of times. Let Xp(G) be the least number of colours in a proper vertex colouring of G having no parity path. It is proved that for any graph G we have the following tight bounds X(G) <= Xp(G) <=|V(G)|− a(G)+1, where X(G) and a(G) are the chromatic number and the independence number of G, respectively. The bounds are improved for...
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The allergic and irritating reactions to metallic implants with trauma - orthopaedic patients
PublicationThe article presents the analysis of clinical operation complications after the treatment of long bones by mean of ostheosynthesis with the use of metal implants and endoprothesoplastic of hip joints.
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Guided wave propagation for assessment of adhesive bonding between steel and concrete
PublicationAdhesive bonding is becoming more increasingly important in joining of structural elements. In civil engineering, there is a growing interest in connection by adhesive bonding in steel-concrete flexural members. This study concerns the guided wave propagation technique applied to condition assessment of an adhesive connection between a steel member and a concrete beam. Various states of degradation were considered by producing...
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Calibration images under different lighting conditions vol. 2
Open Research DataDataset description: Calibration images under different lighting conditions vol. 1
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Calibration images under different lighting conditions - static for feature localisation
Open Research DataDataset description: Calibration images under different lighting conditions - static mode for feature detection
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Transient detection for speech coding applications
PublicationSignal quality in speech codecs may be improved by selecting transients from speech signal and encoding them using a suitable method. This paper presents an algorithm for transient detection in speech signal. This algorithm operates in several frequency bands. Transient detection functions are calculated from energy measured in short frames of the signal. The final selection of transient frames is based on results of detection...
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Raman spectroscopic investigation of blood and related materials
PublicationThis paper reports preliminary studies on use of Raman spectroscopy for investigation of blood. High quality blood spectra were recorded in-vitro with excitation wavelengths of 830 nm. Because of complex composition of the blood as well as by light attenuation and scattering in the tissues, spectra set up from wide, low-intensive Raman bands and intensive optical background. To get information about origin of bands in Raman spectra...
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The possibility of use keratin products in various branches of industry
PublicationBird's feather, the main by-product of the poultry industry, are not enough utilized and negatively influencing the environment. They contain large amount of keratin, the protein with high cystine content. The aim of our work was to obtain hydrolysates and isolates of keratin, which can be used in various areas of food, cosmetics, pharmaceutical industry and as animal feed. Keratin can be hydrolyzed and extracted from feather after...
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Why is the cubic structure preferred in newly formed ice?
PublicationMolecular dynamics was employed to explain the preference for the cubic structure in newly formed crystals of ice. The results showed that in supercooled liquid water the molecules connected by hydrogen bonds are more likely to adopt relative orientations similar to the ones characteristic for cubic ice. The observed preference for certain relative orientations of molecules in the hydrogen-bonded pairs results in the higher probability...
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Preparation of porous TiO2 films by means of pulsed laser deposition for photocatalytic applications
PublicationIn this work the preparation and structure properties of porous thin films of TiO2 were investigated. The films were produced by means of the pulsed laser deposition technique using laser pulses at 266nm (10Hz) and at fluencies of 1-3.5J/cm2. The process was performed in vacuum using O2 buffer gas and films were deposited on the SiO2 glass or Si substrate. X-ray diffraction (XRD) and Raman analysis of the structure and chemical...
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Electron Transport in Naphthalene Diimide Derivatives
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Effect of Chitosan Solution on Low-Cohesive Soil’s Shear Modulus G Determined through Resonant Column and Torsional Shearing Tests
PublicationIn this study the effect of using a biopolymer soil stabilizer on soil stiffness characteristics was investigated. Chitosan is a bio-waste material that is obtained by chemical treatment of chitin (a chemical component of fungi or crustaceans’ shells). Using chitosan solution as a soil stabilizer is based on the assumption that the biopolymer forms temporary bonds with soil particles. What is important is that these bonds are biodegradable,...
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Tailoring Diffusional Fields in Zwitterion/Dopamine Copolymer Electropolymerized at Carbon Nanowalls for Sensitive Recognition of Neurotransmitters
PublicationThe importance of neurotransmitter sensing in the diagnosis and treatment of many psychological illnesses and neurodegenerative diseases is non-negotiable. For electrochemical sensors to become widespread and accurate, a long journey must be undertaken for each device, from understanding the materials at the molecular level to real applications in biological fluids. We report a modification of diamondized boron-doped carbon nanowalls...
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Design of a continuous intra-oral distraction device for mandibular bone
PublicationIn this paper we present example of a specific device used for distraction osteogenesis. Distraction osteogenesis (also called callus distraction, collotasis or osteodistraction) is a surgical process for reconstructing bone deformities or lengthening bones.
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Ultra-Compact SIRC-Based Self-Triplexing Antenna with High Isolation
PublicationAn ultra-compact self-triplexing antenna realized on a substrate-integrated rectangular cavity (SIRC) is discussed in this study. The proposed structure employs two L-shaped slots and an in-verted U-shaped slot to radiate at three independent operating frequency bands. Three 50-ohm microstrip feed lines are used to excite the radiation in these slots. The operating frequency is individually tuned using the slot size. The slot placement...
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Imidazolium silanethiolates relevant to the active site of cysteineproteases. A cooperative effect in a chain of NH(+)...S(-) hydrogenbonds
PublicationThree imidazolium silanethiolates relevant to the active site of cysteine proteases have been synthesized and investigated by X-ray diffraction, IR spectroscopy and computational methods. As indicated by crystallographic and FT-IR data in the solid state, the transfer of proton from thiol to imidazole takes place and a thiolato-imidazolium ion pair is formed. The FT-IR spectra of crystalline imidazolium silanethiolates exhibit...
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Surface-enhanced Raman scattering of water in aqueous dispersions of silver nanoparticles
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Conjectured strong complementary-correlations tradeoff
PublicationWe conjecture uncertainty relations that restrict correlations between the results of measurements performed by two separate parties on a shared quantum state. The first uncertainty relation bounds the sum of two mutual informations when one party measures a single observable and the other party measures one of two observables. The uncertainty relation does not follow from the Maassen-Uffink uncertainty relation and is much stronger...
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An interval estimator for chlorine monitoring in drinking water distribution systems under uncertain system dynamics, inputs and chlorine concentration measurement errors
PublicationThe design of an interval observer for estimation of unmeasured state variables with application to drinking water distribution systems is described. In particular, the design process of such an observer is considered for estimation of the water quality described by the concentration of free chlorine. The interval observer is derived to produce the robust interval bounds on the estimated water quality state variables. The stability...