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wszystkich: 2726
wybranych: 1919
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: OXYGEN ELECTRODE INTERLAYER, ELECTRODE-ELECTROLYTE INTERFACE, SOLID OXIDE FUEL CELLS, SPRAY PYROLYSIS, NANOCRYSTALLINE LAYER, DISTRIBUTION OF RELAXATION TIMES, ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY
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Detection of the Plant Pathogen Pseudomonas Syringae pv. Lachrymans on Antibody-Modified Gold Electrodes by Electrochemical Impedance Spectroscopy
PublikacjaThe present work describes an impedimetric immunosensor for Pseudomonas syringae pv. lachrymans (Psl) detection. This pathogen infects many crop species causing considerable yield losses, thus fast and cheap detection method is in high demand. In the assay, the gold disc electrode was modified with 4-aminothiophenol (4-ATP), glutaraldehyde (GA), and anti-Psl antibodies, and free-sites were blocked with bovine serum albumin (BSA)....
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Oxide layers fabricated by spray pyrolysis for resistance random access memory
PublikacjaW pracy zbadano przydatność pirolizy aerozolowej do wytwarzania warstw dla memrystorów.
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New Method of Non-Linear Electrochemical Impedance Spectroscopy with an Amplitude-Modulated Perturbation Signal
PublikacjaThe paper presents a new method of non-linear electrochemical impedance spectroscopy (NLEIS), which allows fast and nondestructive evaluation of the corrosion rate and determination of the Tafel coefficients values for a corrosion system under investigation. This method employs amplitude modulation of the ac perturbation signal. The study demonstrated that it was possible to obtain impedance characteristic as a function of the...
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The electrochemical determination of isatin at nanocrystalline boron-doped diamond electrodes: stress monitoring of animals
PublikacjaUltra-thin nanocrystalline boron-doped diamond electrodes (B:NCD) were used for the electrochemical determination of isatin in dog urine samples using cyclic voltammetry and square wave voltammetry in a phosphate buffer saline, pH = 7.2. No additional modification or pretreatment of the electrode surface was required in this approach, being of high importance for the facile detection procedure. The increase of the peak current...
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La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone
PublikacjaInfiltration is a method, which can be applied for the electrode preparation. In this paper oxygen electrode is prepared solely by the infiltration of La0.6Sr0.4Co0.2Fe0.8O3‐δ (LSCF) into Ce0.8Gd0.2O2-δ (CGO) backbone. The use a polymer precursor as an infiltrating medium, instead of an aqueous nitrate salts solution is presented. It is shown that the polymer forms the single-phase perovskite at 600 °C, contrary to the nitrates...
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Composite materials for Solid Oxide Fuel Cells - various ways of preparation and application
PublikacjaWykonano przeglad mozliwosci zastosowania materialow kompozytowych w wysokotemperaturowych tlenkowych ogniwach paliwowych oraz scharakeryzowano najbardziej popularne metody wytwarzania i nakladania tego typu materialow.
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Evaluation of La0.3Sr0.7Ti1−xCoxO3 as a potential cathode material for solid oxide fuel cells
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Characteristics of La 0.8 Sr 0.2 Ga 0.8 Mg 0.2 O 3-δ -supported micro-tubular solid oxide fuel cells with LaCo 0.4 Ni 0.6-x Cu x O 3-δ cathodes
PublikacjaIn this study, micro-tubular solid oxide fuel cells (T-SOFCs) with extruded La0.8Sr0.2Ga0.8Mg0.2O3-δ (LSGM) electrolyte as the mechanical support and LaCo0.4Ni0.6O3-δ (LCNO) or LaCo0.4Ni0.4Cu0.2O3-δ (LCNCO) as cathodes were prepared and characterized. Partial substitution of Cu for the Ni-ion positions in the LCNO lattices was found to significantly enhance the densification and accelerate the grain growth. The porosity-corrected...
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Electrochemical detection of bacterial endotoxin lipopolysaccharide (LPS) on gold electrode modified with DAL-PEG-DK5-PEG-OH - Antimicrobial peptide conjugate
PublikacjaThis work describes fabrication of gold electrodes modified with peptide conjugate DAL-PEG-DK5-PEG-OH that enables ultra-sensitive detection of lipopolysaccharide (LPS) isolated from the reference strain of Escherichia coli O26:B6. The initial step of the established procedure implies immobilization of the fully protected DAL-PEG-DK5-PEG-OH peptide on the surface of the gold electrode previously modified by cysteamine. Then side...
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Fundamental-harmonic impedance of first-order electrode reactions
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Determination of electrode impedance by means of exponential chirp signal
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Determination of electrode impedance by means of exponential chirp signal.
PublikacjaPrzedstawiona została nowa metoda pomiaru impedancji elektrodowej. Jako pobudzenie zastosowany został niestacjonarny sygnał napięciowy, którego częstotliwość jest ekspotencjalną funkcją czasu. Zastosowanie zmodyfikowanej któtko-czasowej transformaty Fouriera (STFT) w analizie napięciowego pobudzenia i odpowiedzi prądowej pozwala na otrzymanie widma impedancyjnego.
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VOLTAMMETRIC DETERMINATION OF DEOXYRIBONUCLEIC ACID PRESENCE ON A CARBON ELECTRODE
PublikacjaThis paper presents a voltammetry as a useful method to analyse DNA from different species. This electrochemical method is well know and used in different analyses. The influence of an area of working electrode and the capacity component, is shown at equals and the measurement. In voltammetry DNA measurement the capacity component is very important and must be taken into consideration. All mathematical analyses were verify at laboratory.
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A probe for immittance spectroscopy based on the parallel electrode technique.
PublikacjaW pracy zaprezentowano konstrukcję sondy do spektroskopowych pomiarów immitancyjnych. Obliczono jej stałą, którą to wartość zweryfikowano eksperymentalnie. Pokazano przykładowe wyniki pomiarów in vivo.
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Status report on high temperature fuel cells in Poland – Recent advances and achievements
PublikacjaThe paper presents recent advances in Poland in the field of high temperature fuel cells. The achievements in the materials development, manufacturing of advanced cells, new fabrication techniques, modified electrodes and electrolytes and applications are presented. The work of the Polish teams active in the field of solid oxide fuel cells (SOFC) and molten carbonate fuel cell (MCFC) is presented and discussed. The review is oriented...
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Performance of a single layer fuel cell based on a mixed proton-electron conducting composite
PublikacjaMany of the challenges in solid oxide fuel cell technology stem from chemical and mechanical incompatibilities between the anode, cathode and electrolyte materials. Numerous attempts have been made to identify compatible materials. Here, these challenges are circumvented by the introduction of a working single layer fuel cell, fabricated from a composite of proton conducting BaCe0.6Zr0.2Y0.2O3-δ and a mixture of semiconducting...
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Impedance spectroscopy of undoped cerium oxide.
PublikacjaW pracy przedstawiono badania impedancyjne niedomieszkowanego tlenku ceru. Wyniki wskazują na występowanie zjawiska dyfuzji,???? które nie są (.. jest.?)związane z odpowiedzią elektrodową. Rozważania teoretyczne dopuszczają obserwowanie impedancji Warburga, która reprezentuje zjawisko dyfuzji w przewodnikach mieszanych, jednakże niewiele informacji na ten temat można znaleźć w literaturze. W związku z tym szczegółowe badania zródła...
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The interference between electrode and poly(ethylene oxide) electrolytes
PublikacjaSpektroskopia impedancyjna zastosowana została do scharakteryzowania granicy faz elektroda-elektrolit poli(oksyetylenowy) zawierający sole litu. Udział rozpuszczalnika w pojemności wewnętrznej warstwy, Cs(σ), dla CH3(OCH2CH2 )nOCH3 DLA N=4,8,10 oraz dla PMEO [(CH2CH2O)mCH2O]m m=5-10 został wyznaczony z wartości pojemności warstwy sztywnej pomniejszonej o udział metalu CM. Wyznaczono wartość pojemności dipolowej Ci(dip) dla PEO...
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A new model of fuel spray shape at early stage of injection in a marine Diesel engine
PublikacjaIn the cylinders of a marine diesel engine, self-ignition occurs in very shortly time after the fuel injection into the combustion chamber. Therefore, the paper present was to develop a model of diesel fuel spray for the early stage of fuel spray for in marine diesel engine. There were taken into consideration the main aspects technical such as nozzle diameter of marine engine injector and backpressure in combustion chamber. In...
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Quantification of interlayer adhesion in protective coating systems using impedance spectroscopy
PublikacjaNowoczesne systemy powłokowe stosowane w praktyce są wielowarstwowe. Potencjalnie słabymi obszarami z punktu widzenia właściwości ochronnych są obszary międzywarstwowe. Osiągnięcie odpowiedniej przyczepności pomiędzy warstwami pozwala na polepszenie zdolności ochronnych całego zestawu. Tradycyjne metody pomiaru adhezji międzywarstwowej są destrukcyjne. Zaproponowano nową metodę oceny przyczepności międzywarstwowej przy użyciu...
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Dynamic electrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses
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Dynamic electrochemical impedance spectroscopy measurements of passive layer cracking under static tensile stresses.
PublikacjaDynamiczna Elektrochemiczna Spektroskopia Impedancyjna umożliwia badanie podatności i odporności korozyjnej różnych materiałów konstrukcyjnych, a w szczególności określenie właściwości elektrochemicznych warstw pasywnych występujących na ich powierzchni. W wielu przypadkach pęknięcie warstwy pasywnej pod wpływem działania naprężeń rozciągających prowadzi do korozji naprężeniowej. Z tego względu badania pękania warstw pasywnych...
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Heterogeneous oxidation of highly boron-doped diamond electrodes and its influence on the surface distribution of electrochemical activity
PublikacjaThe electrochemical active surface area (EASA) of polycrystalline boron-doped diamond (BDD) electrodes is heterogeneous and can be affected by numerous factors. There is a strong need for proper consideration of BDD heterogeneity in order to improve this material's range of application in electrochemistry. Localized changes in surface termination due to the influence of oxidation agent result in increased surface resistance. The...
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Enhanced capacitance of composite TiO2 nanotube / boron-doped diamond electrodes studied by impedance spectroscopy
PublikacjaWe report on the novel composite nanostructures based on boron-doped diamond thin film grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2...
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Fabrication methods of porous perovskite type ceramics for Solid Oxide Fuel Cells (SOFCs)
PublikacjaPublikacja opisuje metody wytwarzania porowatych materiałów ceramicznych o strukturze perowskitu.
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Cation-ordered perovskite-type anode and cathode materials for solid oxide fuel cells
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Thin layer of ordered boron-doped TiO2 nanotubes fabricated in a novel type of electrolyte and characterized by remarkably improved photoactivity
PublikacjaThis paper reports a novel method of boron doped titania nanotube arrays preparation by electrochemical anodization in electrolyte containing boron precursor – boron trifluoride diethyl etherate (BF3 C4H10O), simultaneously acting as an anodizing agent. A pure, ordered TiO2 nanotubes array, as a reference sample, was also prepared in solution containing a standard etching compound: ammonium fluoride. The doped and pure titania...
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Application of bismuth film electrode for determination of heavy metals by stripping voltammetry
PublikacjaWhen Wang's research group introduced a new type of a working electrode: bismuth film plated electrode (BiFE), it has started attracting increasing attention in the field of electrochemical stripping analysis. These electrodes are shown to be very attractive alternative to common mercury-based electrodes, which are predominantly used in analysis of trace heavy metals.For the determination of heavy metals (Zn, Cd, Pb, Cu) used square...
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The Influence of Thin Gold Electrodes on the High-Temperature Impedance of Oxide Glasses
PublikacjaThe influence of thin gold electrodes on the electrical measurements of glasses at high temperatures was studied using impedance spectroscopy. The impedance was measured several times over a wide frequency range from 10 mHz to 1 MHz and the temperature ranged from 213 to 673 K under air and nitrogen atmospheres. The results showed a drop in the conductivity of more than an order of magnitude at a temperature around 603 K during...
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Zirconia-based mixed potential sensor with Pt electrode prepared by spin-coating of polymeric precursor
PublikacjaMany types of yttria-stabilized zirconia (YSZ) based gas sensors have been explored extensively in recent years. Great attention have been directed to mixed-potential-type gas sensors. It is due to growing concerns with environmental issues. Not without a significance is the fact of very attractive performance of this type of sensor allowing to detect low concentration of pollutant gases. In this paper two types of YSZ based mixed-potential...
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Pumping effect measured by PIV method in multi-layer spike electrode EHD device for air cleaning
PublikacjaDust particles can be harmful for human health when inhaled. Especially dangerous are submicron dust particles, which can contain traces of toxic elements and can easily penetrate into human respiratory system. Thus, new devices for air cleaning are needed. In this work the flow velocity field patterns measured by Particle Image Velocimetry (PIV) method in an electrohydrodynamic (EHD) device for air cleaning are presented. The...
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Dynamic Electrochemical Impedance Spectroscopy (DEIS) as a Tool for Analyzing Surface Oxidation Processes on Boron-Doped Diamond Electrodes
PublikacjaSurface oxidation processes play a key role in understanding electrochemical properties of boron-doped diamond (BDD) electrodes. The type of surface termination groups, which create the potential window of electrolytic water stability or hydrophobicity, influences such properties. In this study the kinetics of oxidation process under anodic polarization were studied in situ by means of Dynamic Electrochemical Impedance Spectroscopy...
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Poly(hydroxybutyrate-co-hydroxyvalerate) as a biodegradable binder in a negative electrode material for lithium-ion batteries
PublikacjaIn this work, graphite-based negative electrode for lithium-ion battery consisting a novel and biodegradable binder poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) is compared with standard graphite electrode with polyvinylidene fluoride (PVDF) as a binder. The rate and cycling performance of lithium ion insertion/extraction of electrodes with PHBV in a half-cell configuration are evaluated. Moreover, on the basis of the electrochemical...
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Sinusoidal Alternating-Current Voltammetry and Metrological Properties of a Flat Voltammetric Electrode in the Time Domain
PublikacjaIn this paper there were analyzed metrological properties of a flat electrode used to mark ions with the method of sinusoidal alternating-current voltammetry in the situation where on its surface an electrochemical reversible reaction of oxidizing / reduction takes place. The result of the analysis conducted is that such a voltammetric electrode functions like a converter type I. Metrological properties of such an electrode in...
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The impedance of hydrogen oxidation reaction in a proton exchange membrane fuel cell in the presence of carbon monoxide in hydrogen stream
PublikacjaEvaluation of performance of a proton exchange membrane fuel cell, which is affected by carbon monoxide that pollutes the hydrogen stream, was presented. This influence was studied for carbon monoxide concentration of 125–325 ppb, which are close to values specified in ISO 14687:2019 standard. Performed studies provided crucial information for further development of fuel cell as an energy source for automotive application. Impedance...
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Influence of electrode geometric arrangement on the operation of narrow circular electrostatic precipitator
PublikacjaIn this work the influence of electrode geometric arrangement on the operation of a circular electrostatic precipitator (ESP) was investigated using Particle Image Velocimetry (PIV) method. The ESP was a glass circular cylinder (29 mm in diameter, 300 mm long) equipped with a wire discharge electrode and circular-cylinder collecting electrode. The stainless-steel discharge wire electrode (0.23 mm in diameter, 100 mm long) was mounted...
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The Use of Direct Shear Test for Optimization of Interlayer Bonding Under a Poroelastic Layer
PublikacjaPoroelastic Road Surfaces (PERS) are characterised by porous structure with air void content of 20% or higher and stiffness almost 10 times lower than that of a standard asphalt course. Such properties enable noise reduction by up to 12 dB in comparison to SMA 11 mixture. However, the disadvantage of a poroelastic pavement is its low durability, which partially results from delamination from the lower layer. The paper aims to investigate...
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3D Hierarchical Boron-Doped Diamond-Multilayered Graphene Nanowalls as an Efficient Supercapacitor Electrode
PublikacjaSynthesis of stable hybrid carbon nanostructure for high-performance supercapacitor electrode with long life-cycle for electronic and energy storage devices is a real challenge. Here, we present a one-step synthesis method to produce conductive boron-doped hybrid carbon nanowalls (HCNWs), where sp2-bonded graphene has been integrated with and over a three-dimensional curved wall-like network of sp3-bonded diamond. The spectroscopic...
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New possibilities of the passive layer cracking dynamics detection using a new Dynamic Electrochemical Impedance Spectroscopy.
PublikacjaNowa metoda Dynamicznej Elektrochemicznej Spektroskopii Impedancyjnej opracowana w Katedrze Elektrochemii, Korozji i Inżynierii Materiałowej Politechniki Gdańskiej daje możliwości określania charakterystyki impedancyjnej w dziedzinie czasu podczas procesu pękania ochronnej warstwy pasywnej. Fakt ten jest związany z procedurą analizującą wspomnianej techniki, która umożliwia selektywną analizę czasowo-częstotliwościową uzyskanych...
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Enhanced stability of electrochemical performance of few-layer black phosphorus electrodes by noncovalent adsorption of 1,4-diamine-9,10-anthraquinone
PublikacjaIn this paper, the novel noncovalent functionalisation strategy of few-layer black phosphorus by 1,4-diamine-9,10-anthraquinone electrode was proposed and studied. The degradation of few-layer black phosphorus under exposure to oxygen and water is a significant obstacle to its use as an electroanalytical electrode. The anthraquinone compound adsorbed at black phosphorus flakes results in improved prevention of the phosphorus surface...
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Low temperature processed MnCo2O4 and MnCo1.8Fe0.2O4 as effective protective coatings for solid oxide fuel cell interconnects at 750 °C
PublikacjaIn this study two materials, MnCo2O4 and MnCo1.8Fe0.2O4 are studied as potential protective coatings for Solid Oxide Fuel Cell interconnects working at 750 °C. First powder fabrication by a modified Pechini method is described followed by a description of the coating procedure. The protective action of the coating applied on Crofer 22 APU is evaluated by following the area specific resistance (ASR) of the scale/coating for 5500...
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Tin oxide nanoparticles from laser ablation encapsulated in a carbonaceous matrix – a negative electrode in lithium-ion battery applications
PublikacjaThis report concerns carbonaceous electrodes doped with tin(II) oxide nanoparticles. Tin nanoparticles are obtained by pulsed laser ablation in water. Crystalline nanoparticles have been encapsulated in a carbonaceous matrix formed after pyrolysis of a mixture consisting of tin/tin(IV) oxide nanoparticles and gelatine. The obtained material is characterized by means of X-ray diffraction, selected area diffraction, scanning electron...
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Rock salt ordered-type double perovskite anode materials for solid oxide fuel cells
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Evaluation of porous ferritic Fe22Cr stainless steel for solid oxide fuel cells at high temperature
PublikacjaW pracy przedstawiono wyniki badań korozji stali Fe22Cr w wysokich temperaturach.
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A Probe into the Corrosion Behavior of a WE43B Magnesium Alloy in a Simulated Body Fluid using Dynamic Electrochemical Impedance Spectroscopy
PublikacjaWE43B is one of the newest Mg alloys with practical application in biomedical implant technology. This work attempts to scrutinize the corrosion characteristics of WE43B alloy in a simulated body fluid (SBF) at a typical body temperature. The dynamic-electrochemical impedance spectroscopy with the capacity to track changes on surfaces in a dynamic corrosive system is used in combination with other classical techniques namely, linear...
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Application of the dynamic electrochemical impedance spectroscopy to investigation of spontaneous electrochemical oscillations
PublikacjaPrzedstawione zostały wyniki impedancyjne uzyskane podczas oscylacji prądowych miedzi w kwaśnym środowisku zawierającym jony chlorkowe. Kształt chwilowych widm impedancyjnych jest skorelowany z uzyskanym przebiegiem prądowym. Badany proces anodowego roztwarzania miedzi kontrolowany jest na przemian aktywacyjnie i dyfuzyjnie.
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Theoretical description of fundamental-harmonic impedance of a two-step electrode reaction
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Electrochemical glucose sensor based on the glucose oxidase entrapped in chitosan immobilized onto laser-processed Au-Ti electrode
PublikacjaThe study on novel electrode material composed of structured titanium foil with embedded Au nanoparticles and modified with chitosan with entrapped glucose oxidase is presented. To confirm the successful immobilization of glucose oxidase FT-IR analysis was performed. The response of electrodes were tested towards glucose in the presence of different interference compounds and biological fluids. The prepared material exhibits excellent...
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Analysis of the structure of the atomized fuel spray with marine diesel engine injector in the early stage of injection
PublikacjaThis paper presents the results of the experimental research of the atomized fuel spray with the marine diesel engine injector in the constant volume chamber. The specificity of the phenomena occurring in the marine engine cylinder was the reason to use the optical visualisation method in the studies – the Mie scattering technique. This work presents an analysis of the influence of different geometry of outlet orifice and opening...
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Low temperature deposition of dense MnCo 2 O 4 protective coatings for steel interconnects of solid oxide cells
PublikacjaIn this work manganese cobalt spinel (MnCo2O4) coatings were deposited on steel substrates by spray pyrolysis at 390 °C. This is at much lower temperatures than previously reported (typically in excess of 900 °C). It was possible to produce coatings with well controlled thickness (2-5-10 μm). The as-deposited coatings were evaluated for their microstructural changes and electrical conductivity up to 800 °C. Results confirm the...