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Microwave-assisted synthesis of zinc derivatives of potato starch
PublikacjaZincatated potato starch was prepared in a solid-state, microwave-assisted reaction using generated in situ sodium tetrahydroxozincate [Na2Zn(OH)4]. For comparison, zincatation of starch was also carriedout on convectional heating. Depending on the irradiation conditions, the products of either mono- or crosslinking esterification were formed. Higher power applied at shorter exposition offered products ofmonoesterification, and...
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The influence of sterilization with EnbioJet Microwave Flow Pasteurizer on composition and bioactivity of aronia and blue-berried honeysuckle juices
PublikacjaIn this study, fruit juices that are rich sources of anthocyanins, obtained from aronia (Am. chokeberry, Aronia melanocarpa) and blueberry honeysuckle (Lonicera caerulea L. var. edulis) were used to examine the preservation of plant phytochemicals and bioactivity upon sterilization -either thermal, or with an EnbioJet microwave flow pasteurizer. The chemical properties verified included determinations of anthocyanins and other...
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Synthesis, thermal, structural and electrical properties of vanadium-doped lithium-manganese-borate glass and nanocomposites
PublikacjaA glassy sample with a nominal formula LiMn1−3x/2VxBO3 (where x = 0.05) was synthesised using the melt-quenching method. Material was characterised by differential thermal analysis (DTA), X-ray diffactometry (XRD) at room temperature and as a function of temperature (HT-XRD), X-ray photoelectron spectroscopy (XPS), impedance spectroscopy (IS) and scanning electron microscopy (SEM). Dependences of glass transition and crystallisation...
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EFFECT OF PRESS DRYING ON DIMENSION STABILITY AND DENSITY OF BEECH WOOD,
PublikacjaTimber is traditionally dried in kilns by processes that often take several days or weeks to complete. At present, it is possible to apply several methods of rapid drying of timber, including, for example, press drying. This research is based on the use of this process. Drying was performed using the heating plates with a temperature of 160 °C. Three pressures were compared in the research 1.0 MPa, 1.4 MPa, and 1.8 MPa. The density...
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Determination of benzo(a)pyrene content in PM10 using regression methods
PublikacjaThe paper presents an attempt of application of multidimensional linear regression to estimation of an empirical model describing the factors influencing on B(a)P content in suspended dust PM10 in Olsztyn and Elbląg city regions between 2010 and 2013. During this period annual average concentration of B(a)P in PM10 exceeded the admissible level 1.5-3 times. Conducted investigations confirm that the reasons of B(a)P concentration...
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Hysteresis curves for some periodic and aperiodic perturbations in magnetosonic flow
PublikacjaA thermodynamic relation between perturbations of pressure and mass density in the magnetohydrodynamic flow is theoretically studied. Planar magnetohydrodynamic perturbations with the wave vector, which forms a constant angle with the equilibrium magnetic field, are under study. The theory considers thermal conduction of a plasma and the deviation from adiabaticity of a flow due to some kind of heating–cooling function. It also...
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Sustainable energy consumption – Empirical evidence of a household in Poland
PublikacjaThere is an expected increase in the demand for electricity from households in European countries. The outcome of the growing proportion of renewable energy sources in the energy supply mix should result in improved customer awareness regarding their electricity usage. Additionally, they must assume a more proactive role in overseeing their electricity usage. Innovation and pollution management have become crucial catalysts for...
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One-dimensional chaos in a system with dry friction: analytical approach
PublikacjaWe introduce a new analytical method, which allows to find chaotic regimes in non-smooth dynamical systems. A simple mechanical system consisting of a mass and a dry friction element is considered. The corresponding mathematical model is being studied. We show that the considered dynamical system is a skew product over a piecewise smooth mapping of a segment (the so-called base map). For this base map we demonstrate existence of...
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NON-LOCAL VOLUMETRIC APPROACH TO ANALYSIS DEFECT'S SHAPE INFLUENCE ON SPECIMENS DURABILITY SUBJECTED TO BENDING AND TORSION
PublikacjaThe influence of defect features on fatigue behaviour is a complex trivial issue. Although the important advances over the last decades, the dialectical relationship between the defect orientation and durability is not clearly understood. The paper aims at studying the influence of the orientation of elliptical defects on the durability of samples made of C45 steel. Three types of samples with elliptical defects were subjected...
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The Issues of Reactive Power Compensation in High-voltage Transmission Lines
PublikacjaThis paper discusses the selection of compensation shunt reactors for a double-circuit 400 kV transmission line using the example of the newly built Elk Bis – Alytus transmission line. The analysis takes into account various conditions of the power system. The published results relate to voltage levels in steady states and during switching processes and short circuits.
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Dobór głównych parametrów instalacji grzewczych spalinowych siłowni okrętowych z wykorzystaniem metod i modeli probabilistycznych
PublikacjaPraca doktorska przedstawia nowatorską metodę projektowania okrętowych instalacji grzewczych. Metoda ta powstała dzięki analizie statystycznej danych zebranych z kilkunastu statków dotyczących między innymi wytwarzania pary w kotłach utylizacyjnych i zapotrzebowania na ciepło przez odbiorniki pary. Zaproponowany w pracy proces projektowy wykorzystuje równania korelacji wynikające z analizy statystycznej. Wytwarzanie ciepła oraz...
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Synthesis of Combretastatin A-4 Analogs and their Biological Activities
PublikacjaCombretastatin A-4 (CA-4) is a natural product, which consists of two phenyl rings, linked by an ethylene bridge. CA-4, inhibitor of polymerization of tubulin to microtubules, possesses a strong antitumor and anti-vascular properties both in vitro and in vivo. Previous studies showed that disodium phosphate salt of CA-4, a water-soluble prodrug is well tolerated at therapeutically useful doses. However, it should be noted that...
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Experimental investigation of Steel–Concrete–Polymer composite barrier for the ship internal tank construction
PublikacjaTransportation of dangerous cargo by ships demands ensuring an appropriate protection level in case of an accident. Two of the most dangerous accident types resulting in an oil spill are grounding and ship to ship collision. The article presents results of research on a new composite construction for a ship hull that increases structural safety during collision. The concept of semi-elastic Steel–Concrete–Polymer structure is presented....
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An inverse algorithm for contact heat conduction problems with an interfacial heat source based on a first-order thermocouple model
PublikacjaInverse problems of contact heat conduction with an interfacial heat source are common in various fields of science, engineering and technology. In this study, an algorithm for their solution is developed based on an inverse parametric optimisation method with an impulse response function describing the heat partition and contact heat transfer. A first-order thermocouple model with a time constant parameter is embedded in the impulse...
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Computational fluid dynamics simulation of heat transfer from densely packed gold nanoparticles to isotropic media
PublikacjaThis work aims to determine and compare heat generation and propagation of densely packed gold nanoparticles (Au NPs) induced by a resonant laser beam (532 nm) according to the Mie theory. The heat flux propagation is transferred into the materials, which here are: silica glass; soda-lime-silica glass; borosilicate glass; polymethyl methacrylate (PMMA); polycarbonate (PC); and polydimetylosiloxane (PDMS). This analysis aims to...
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Thermal and Chemical Expansion in Proton Ceramic Electrolytes and Compatible Electrodes
PublikacjaThis review paper focuses on the phenomenon of thermochemical expansion of two specific categories of conducting ceramics: Proton Conducting Ceramics (PCC) and Mixed Ionic-Electronic Conductors (MIEC). The theory of thermal expansion of ceramics is underlined from microscopic to macroscopic points of view while the chemical expansion is explained based on crystallography and defect chemistry. Modelling methods are used to predict...
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Elementary analysis and energetic potential of the municipal sewage sludges from the Gdańsk and Kościerzyna WWTPs
PublikacjaThis paper aims to present municipal sewage sludge (MSS) elementary analysis and energetic potential based on measurement of heat of combustion (higher heating value HHV) and calculation of calorific values (lower heating value LHV). The analysis takes into the consideration water content in sewage sludge, at different utilization stages, in wastewater treatment plants in Gdańsk Wschód and Kościerzyna – Pomeranian Voivodeship....
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Comparative analysis of earthships and conventional buildings in terms of investment and operating costs
PublikacjaThe aim of the master's thesis is to present the idea of earthships and compare them with conventional buildings in terms of investment and operating costs. Earthships are buildings erected from tires and other wastes whose characteristic feature is their self-sufficiency. The first part of the master's thesis is to discuss the basic issues related to the earthship building. The beginnings of tire homes and their development are...
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Gas selectivity enhancement by sampling-and-hold method in resistive gas sensors
PublikacjaCommercial resistive gas sensors exhibit various sensitivity to numerous gases when working at different elevated temperatures. That effect is due to a change in velocity of adsorption and desorption processes which can be modulated by temperature. Thus, to reach better selectivity of gas detection, we propose to apply a known method (called the sampling-and-hold method) of cooling down the gas sensor in the presence of the investigated...
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Effects of mechanical stress on electrical arameters and noise of supercapacitors
PublikacjaResults of noise and electrical parameters measurements of prototype electrochemical double layer capacitors (EDLC) are reported at the presence of selected mechanical stress. This issue is of great importance due to future applications in wearable technology. The measurement results are compared, and we may conclude than flicker noise is more sensitive to any stress than other considered electrical parameters.
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Thermogravimetric analysis/ pyrolysis of used tyres and waste rubber
PublikacjaThe process of pyrolysis is investigated in this paper. The pyrolysis results of two samples: waste tyres and rubber at different heating rates (10, 20, 50 K/min), were compared. In other experiments the degradation of two pyrolysis products, char and oil was examined. The kinetic study using the thermogravimetry equipment (TG) was done, which allowed determination of the kinetic mechanism of the process. The elemental analysis...
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Effects of the preheating laser treatment on microstructure and corrosion resistance of Ti6Al4V bioalloy
PublikacjaThe laser remelting of the Ti6Al4V alloy was made on specimens pre-heated at elevated temperatures. The laser treatment effected in change of microstructures of surface layers and an appearance of blisters and numerous cracks. The corrosion tests demonstrated the decrease in corrosion resistance for each preheating temperature. The observed effects were attributed to negative influence of excessive compressive stresses with no...
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Modelowanie i ograniczanie skutków ataków uzurpacji uprawnień w systemach teleinformatycznych wspierających różnicowanie poziomu QoS
PublikacjaW wieloagentowych systemach teleinformatycznych pracujących w paradygmacie Klient-Serwer i wspierających różnicowanie poziomu QoS poważnym zagrożeniem są ataki uzurpacji uprawnień metodą Fałszywego VIPa. Ich celem jest zapewnienie Klientowi nienależnie wysokiego poziomu QoS, co powoduje nadużycie zasobów Serwera i szkody dla innych Klientów. W referacie podjęto próbę sforma-lizowania modelu takich ataków oraz zaproponowa-no obustronnie...
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Gate Driver with Overcurrent Protection Circuit for GaN Transistors
PublikacjaThe improvement of the gate driver for GaN transistor is presented in this paper. The proposed topology contains the overcurrent protectionwith the two-stage turning off and independent control of turn on and off time of the GaN transistor. The operation of driver and its application in thehalf-bridge converter are described using both simulation and prototype measurements. The overcurrent protection was tested in Double Pulse...
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TSR method for burns investigation approach
PublikacjaThe article presents the possibilities of applying the TSR method for the diagnosis of burn wounds. The wound area is stimulated by cold gas and a sequence of thermograms of heating the tissue is recorded. Next, TSR algorithms are used to determine the parameters that allow the wound to be classified into one of the classes: the wound heals within three weeks, the wound will not heal in three weeks. The method was...
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Reliability assessment of an OVH HV power line truss transmission tower subjected to seismic loading
PublikacjaThe study focuses on the reliability of a transmission tower OS24 ON150 + 10, an element of an OVH HV power line, under seismic loading. In order to describe the seismic force, the real-life recording of the horizontal component of the El Centro earthquake was adopted. The amplitude and the period of this excitation are assumed random, their variation is described by Weibull distribution. The possible space state of the phenomenon...
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Self-healing mechanism of metallopolymers investigated by QM/MM simulations and Raman spectroscopy
PublikacjaThe thermally induced self-healing mechanisms in metallopolymers based on bisterpyridine complexes of iron(II) sulfate and cadmium(II) bromide, respectively, were studied by means of combined quantum mechanical/molecular mechanical (QM/MM) simulations and Raman spectroscopy. Two possible healing schemes, one based on a decomplexation of the cross-linking complexes and a second one relying on the dissociation of ionic clusters,...
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Possibility to use engine compression ignition engines in floating power plants marine
PublikacjaCompression-ignition engines used in ship technology as main propulsion engines are large units reaching even to 50-60 MW. The engines can be used in power industry for electricity generation in a simple or combined steam turbine system in combined heat and power plants. The leading engine in such an arrangement is an internal-combustion piston engine. The main propulsion engines are used in large piston internal-combustion engines...
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Assessment of the Effective Variants Leading to Higher Efficiency for the Geothermal Doublet, Using Numerical Analysis‒Case Study from Poland (Szczecin Trough)
PublikacjaNumerical models of geothermal doublet allows us to reduce the high risk associated with the selection of the most eective location of a production well. Furthermore, modeling is a suitable tool to verify possible changes in operational geothermal parameters, which guarantees liveliness of the system. An appropriate selection of software as well as the methodology used to generate numerical models significantly aects the quality...
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A new viscoelastic method of calculation of low-temperature thermal stresses in asphalt layers of pavements
PublikacjaThe paper presents a new method of calculation of thermal stresses in asphalt layers of pavements induced by cooling or heating. The method, developed by the author, is based on the analytical solution for the linear viscoelastic Burgers model extended numerically for the case of asphalt layers whose rheological parameters are strongly dependent on temperature. The coefficient of thermal expansion and Poisson’s ratio may optionally...
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Infrared techniques for natural convection investigations in channels between two vertical, parallel, isothermal and symmetrically heated plates
PublikacjaThe effect of the gap width between two symmetrically heated vertical, parallel, isothermal plates on intensity of natural convective heat transfer in a gas (Pr = 0.71) was experimentally studied using the balance and gradient methods. In the former method heat fluxes were determined based on measurements of the voltage and electric current supplying the heaters placed inside the walls. In the latter, heat fluxes were calculated...
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Cure Index demonstrates curing of epoxy composites containing silica nanoparticles of variable morphology and porosity
PublikacjaAn image was taken by Cure Index on curability of epoxy with silica nanoparticles having variable morphology and porosity. Three kinds of silica nanoparticles with non-porous curved-rod, non-porous spherical, and mesoporous spherical microstructures were synthesized and characterized by Fourier-transform infrared spectroscopy, scanning electron microscopy (SEM) and Brunauer–Emmett–Teller analyses. Epoxy nanocomposites containing...
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Application of nonmetallic frustrated cations in the activation of small molecules
PublikacjaThe concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated...
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Calculations of Short-Circuit Current Flows in Earth Wires of HV Lines
PublikacjaThis paper presents a method which enables calculating flows of short-circuit currents in earth wires of high voltage transmission lines, and its implementation in the form of a computer programme. The algorithm enables performing calculations for a double-fed line and starconnected lines (three terminal lines). The developed programme enables verifying dimensioning of earth wires in the context of their short-circuit thermal withstand...
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Acoustic field and the entropy mode induced by it in a waveguide filled with some non-equilibrium gases
PublikacjaThe non-linear propagation of an acoustic beam in a rectangular waveguide is considered. The medium of sound propagation, is a gas where thermodynamically non-equilibrium processes take place: such as exothermic chemical reactions or excitation of vibrational degrees of a molecule’s freedom. The incident and reflected compounds of the acoustic field do not interact in the leading order in the case of periodic weakly nonlinear sound...
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Efficient Method for the Synthesis of Functionalized Basic Maleimides
PublikacjaA three-step procedure involving Diels-Alder condensation of maleic anhydride with furane, formation of N-substituted imide upon reaction with appropriate diamine and a final retro Diels-Alder regeneration of the maleic carbon-carbon double bond is proposed for an unequivocal synthesis of N-substituted basic maleimides. The novel method is characterized by mild reaction conditions, easy work-up, high yields and no need for additional...
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Free convection of water-Al2O3 nanofluid from horizontal porous coated tube
PublikacjaNanofluids are expected to enhance heat transfer in many thermal systems. Present efforts are concentrated on boiling heat transfer of nanofluids, although single phase convection is of key importance in various appliances such as car radiators or heating systems. This paper presents experimental results of heat transfer during free convection of water-Al3O3 nanofluid from horizontal tube covered with metallic porous coating. Contrary...
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Unraveling the role of boron dimers in the electrical anisotropy and superconductivity in boron-doped diamond
PublikacjaWe use quantum mechanics (QM) to determine the states formed by B dopants in diamond. We find that isolated B sites prefer to form BB dimers and that the dimers pair up to form tetramers (BBCBB) that prefer to aggregate parallel to the (111) surface in the <110> direction, one double layer below the H-terminated surface double layer. These tetramers lead to metallic character (Mott metal Insulator Transition) with holes in the...
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Adhesive Monitoring with Instrumented Wedge Test
PublikacjaThe wedge test (sometimes called the Boeing wedge test) is amongst the most readily exploitable techniques for assessment of the rate-dependent fracture energy of adhesive materials when used to bond relatively rigid substrates. With its siblings: the double cantilever beam (DCB), and the tapered double cantilever beam (TDCB), a force is applied, essentially in cleavage, to provoke substrate separation perpendicularly to the bondline...
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Mechanical analysis of eccentric defected bilayer graphene sheets considering the van der Waals force
PublikacjaIn this article, we have tried to simulate nonlinear bending analysis of a double-layered graphene sheet which contains a geometrical imperfection based on an eccentric hole. The first-order shear deformation theory is considered to obtain the governing equations. Also, the nonlinear von Kármán strain field has been assumed in order to obtain large deformations. Whereas the double-layered graphene sheet has been considered, the...
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Effects of CO2 and Nd:YAG Laser Remelting of the Ti6Al4V Alloy on the Surface Quality and Residual Stresses
PublikacjaThe titanium alloys are materials susceptible to tribological wear and the laser treatment can be applied in surface treatment processes to obtain for example higher hardness level. From the other side, it is important to take into consideration, that hardness increase that can be connected with cracks . The aim of this research was to investigate the effects of different lasers and the process parameters on the form and level...
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Entrained Flow Plasma Gasification of Sewage Sludge–Proof-of-Concept and Fate of Inorganics
PublikacjaSewage sludge is a residue of wastewater processing that is biologically active and consists of water, organic matter, including dead and living pathogens, polycyclic aromatic hydrocarbons, and heavy metals, as well as organic and inorganic pollutants. Landfilling is on the decline, giving way to more environmentally friendly utilisation routes. This paper presents the results of a two-stage gasification–vitrification system, using...
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On energy, exergy, and environmental aspects of a combined gas-steam cycle for heat and power generation undergoing a process of retrofitting by steam injection
PublikacjaThe paper presents a study of retrofitting of a combined heat and power (CHP) plant aimed to increase the electric to heating power ratio. The modification would involve diverting part of the steam to the gas turbine, instead of letting it go to the steam turbine, using injection technique into a combustion chamber. Therefore, two potential retrofitting approaches are analyzed: steam injection gas turbine (STIGT) and combined steam...
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An Analysis of Elliptical-Rectangular Patch Structure on Multilayer Elliptic Cylinders
PublikacjaThe resonance frequency problem of an ellipticalrectangular patch mounted on multilayered dielectric coated elliptic conducting cylinder, is investigated in this paper. A fullwave analysis and a moment-method calculation are employed. The analysis is carried out considering the expansion of the field as a series of Mathieu functions. An additional theorem for Mathieu functions is utilized to investigate the non-confocal ellipse...
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Cross-linking of polymer films using phenol-formaldehyde resins with different functional groups
PublikacjaWell-know phenol-formaldehyde resins are used in the production of press-materials, glues, protective coating, mastics. They take a special place among known oligomers because the products based on them are characterized by a low cost and a series of positive properties. Aim of the work: to show the possibility to create polymeric films based on epoxy resins and modified phenol-formaldehyde resins, which contain unsaturated double...
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Thermal Self-Action Effects of Acoustic Beam in a Gas with Reversible or Irreversible Chemical Reaction
PublikacjaThermal self-action of acoustic beam in a gas where an exothermic chemical reaction takes place, is studied. This kind of thermal self-action differs from that in a newtonian fluid. In dependence on the type of a chemical reaction, reversible or not, heating or cooling of a medium occurs. A beam in the case of the irreversible reaction may be unusually self-focusing. The self-action effects relating to wave beams containing shock...
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Research on the phenomena of warming up and free cooling down the car engine
PublikacjaThe average cold start temperature in Europe is 9 degrees C. However, not the average is the most important for the composition of exhaust gases and associated air pollution. The most onerous for the environment are the winter starts when automotive emissions of harmful gases add up in cities with those of home heating systems. The paper presents preliminary studies of warming up and cooling down processes in various environmental conditions....
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How digital platforms support public values through government-citizen collaboration?
PublikacjaDigital platforms are becoming a popular means of multi-sided interactions between public institutions and their constituents. By enabling information sharing, consultation, and other forms of government-citizen collaboration, they facilitate co-decision-making and co-creation. Although digital platforms are not, the mechanism through which they can create public value, although important for government institutions and citizens...
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Accounting for the distributions of input quantities in the procedure for the measurement uncertainty evaluation when calibrating the goniometer
PublikacjaThe discords concerning the measurement uncertainty evaluation in the Guide to the Expressing of Uncertainty in Measurement (GUM) and its Supplement 1 are considered. To overcome these discords, the authors of the paper propose to use the kurtosis method and the law of the propagation of the expanded uncertainty. Using the example of the goniometer calibration, the features of accounting for the distribution laws of input quantities...
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Secure Quaternion Feistel Cipher for DICOM Images
PublikacjaAn improved and extended version of a quaternion-based lossless encryption technique for digital image and communication on medicine (DICOM) images is proposed. We highlight and address several security flaws present in the previous version of the algorithm originally proposed by Dzwonkowski et al. (2015). The newly proposed secure quater- nion Feistel cipher (S-QFC) algorithm...